DE69917900T2 - Emulgierbare polyolefinwachse - Google Patents
Emulgierbare polyolefinwachse Download PDFInfo
- Publication number
- DE69917900T2 DE69917900T2 DE69917900T DE69917900T DE69917900T2 DE 69917900 T2 DE69917900 T2 DE 69917900T2 DE 69917900 T DE69917900 T DE 69917900T DE 69917900 T DE69917900 T DE 69917900T DE 69917900 T2 DE69917900 T2 DE 69917900T2
- Authority
- DE
- Germany
- Prior art keywords
- polyolefin wax
- emulsifiable
- wax
- emulsion
- starting material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000098 polyolefin Polymers 0.000 title claims description 81
- 239000000839 emulsion Substances 0.000 claims description 57
- 239000007858 starting material Substances 0.000 claims description 42
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 34
- 238000006243 chemical reaction Methods 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 17
- -1 polypropylene Polymers 0.000 claims description 17
- 239000000126 substance Substances 0.000 claims description 16
- 239000004743 Polypropylene Substances 0.000 claims description 14
- 229920001155 polypropylene Polymers 0.000 claims description 13
- 238000007127 saponification reaction Methods 0.000 claims description 11
- 239000000155 melt Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 230000001804 emulsifying effect Effects 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 7
- 239000003999 initiator Substances 0.000 claims description 6
- 239000012736 aqueous medium Substances 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000002834 transmittance Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 2
- 230000005540 biological transmission Effects 0.000 claims 3
- 230000003287 optical effect Effects 0.000 claims 3
- 238000010923 batch production Methods 0.000 claims 1
- 150000001451 organic peroxides Chemical group 0.000 claims 1
- 239000001993 wax Substances 0.000 description 101
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 30
- 238000007306 functionalization reaction Methods 0.000 description 11
- 239000000047 product Substances 0.000 description 8
- 238000002844 melting Methods 0.000 description 7
- 230000008018 melting Effects 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000007844 bleaching agent Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- XSZYESUNPWGWFQ-UHFFFAOYSA-N 1-(2-hydroperoxypropan-2-yl)-4-methylcyclohexane Chemical compound CC1CCC(C(C)(C)OO)CC1 XSZYESUNPWGWFQ-UHFFFAOYSA-N 0.000 description 1
- PAOHAQSLJSMLAT-UHFFFAOYSA-N 1-butylperoxybutane Chemical class CCCCOOCCCC PAOHAQSLJSMLAT-UHFFFAOYSA-N 0.000 description 1
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000012969 di-tertiary-butyl peroxide Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229930004008 p-menthane Natural products 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- FBWNMEQMRUMQSO-UHFFFAOYSA-N tergitol NP-9 Chemical compound CCCCCCCCCC1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 FBWNMEQMRUMQSO-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- CFJYNSNXFXLKNS-UHFFFAOYSA-N trans-p-menthane Natural products CC(C)C1CCC(C)CC1 CFJYNSNXFXLKNS-UHFFFAOYSA-N 0.000 description 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
- C08F255/023—On to modified polymers, e.g. chlorinated polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/46—Reaction with unsaturated dicarboxylic acids or anhydrides thereof, e.g. maleinisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
- C08J3/05—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media from solid polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Graft Or Block Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Colloid Chemistry (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/067,355 US6362280B1 (en) | 1998-04-27 | 1998-04-27 | Emulsible polyolefin wax |
| US67355 | 1998-04-27 | ||
| PCT/US1999/008531 WO1999055744A1 (en) | 1998-04-27 | 1999-04-16 | Emulsible polyolefin wax |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69917900D1 DE69917900D1 (de) | 2004-07-15 |
| DE69917900T2 true DE69917900T2 (de) | 2005-06-09 |
Family
ID=22075460
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69917900T Expired - Lifetime DE69917900T2 (de) | 1998-04-27 | 1999-04-16 | Emulgierbare polyolefinwachse |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US6362280B1 (enExample) |
| EP (1) | EP1080119B1 (enExample) |
| JP (1) | JP4371581B2 (enExample) |
| KR (1) | KR100552572B1 (enExample) |
| AU (1) | AU3751099A (enExample) |
| CA (1) | CA2330306A1 (enExample) |
| DE (1) | DE69917900T2 (enExample) |
| MY (1) | MY133168A (enExample) |
| TW (1) | TW445268B (enExample) |
| WO (1) | WO1999055744A1 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6362280B1 (en) * | 1998-04-27 | 2002-03-26 | Honeywell International Inc. | Emulsible polyolefin wax |
| DE60019172T3 (de) † | 2000-08-29 | 2008-05-21 | E.I. Dupont De Nemours And Co., Wilmington | Propylenpropfpolymer mit hohem propfungsgrad und mit hohem schmelzfluss |
| US7256236B1 (en) * | 2001-05-06 | 2007-08-14 | Honeywell International Inc. | Maleated polypropylenes and processes for the preparation thereof |
| US20060223945A1 (en) * | 2003-01-21 | 2006-10-05 | Hollingshurst Claire L | Low color polyisobutylene succinic anhydride-derived emulsifiers |
| CN1813008B (zh) * | 2003-06-30 | 2010-12-01 | 日本瑞翁株式会社 | 酸改性石油树脂以及热熔融型路面标记线标示用材料 |
| US6774181B1 (en) * | 2003-07-01 | 2004-08-10 | Crompton Corporation | Process for the preparation of a self-emulsifiable polyolefin emulsion and hybrid polyolefin-polyurethane dispersion derived therefrom |
| US20060069209A1 (en) * | 2004-09-29 | 2006-03-30 | Klosiewicz Daniel W | Heat stable functionalized polyolefin emulsions |
| JP5011668B2 (ja) * | 2005-07-22 | 2012-08-29 | 東洋紡績株式会社 | 水性樹脂組成物およびその製造方法 |
| US7750078B2 (en) * | 2005-12-07 | 2010-07-06 | Exxonmobil Chemical Patents Inc. | Systems and methods used for functionalization of polymeric material and polymeric materials prepared therefrom |
| ES2803224T3 (es) | 2006-06-15 | 2021-01-25 | Dow Global Technologies Llc | Interpolímeros de olefina funcionalizados, composiciones y artículos preparados a partir de ellos, y procedimientos para obtener los mismos |
| EP2061573A2 (en) * | 2006-10-10 | 2009-05-27 | Dow Corning Corporation | Silicone foam control agent |
| US7622031B2 (en) * | 2007-01-15 | 2009-11-24 | Honeywell International Inc | Method for preparing oxidized polyolefin waxes |
| DE102007056440A1 (de) * | 2007-11-23 | 2009-05-28 | Clariant International Limited | Ionomere aus Poly-1-Olefinwachsen |
| US8853284B2 (en) | 2008-06-02 | 2014-10-07 | Honeywell International Inc. | Wax dispersion formulations, method of producing same, and uses |
| KR101664816B1 (ko) | 2009-03-10 | 2016-10-11 | 다우 코닝 도레이 캄파니 리미티드 | 수중유 실리콘 에멀젼 조성물 |
| GB0905502D0 (en) * | 2009-03-31 | 2009-05-13 | Dow Corning | Organopolysiloxane emulsions and their production |
| GB0905507D0 (en) | 2009-03-31 | 2009-05-13 | Dow Corning | Organopol Ysiloxane Compositions Containing An Active Material |
| EP2589627B1 (en) | 2010-07-02 | 2016-10-12 | Dow Corning Toray Co., Ltd. | Oil-in-water silicone emulsion composition |
| WO2018176298A1 (en) * | 2017-03-30 | 2018-10-04 | Rohm And Haas Company | Formaldehyde-free curable composition |
| JP7758594B2 (ja) * | 2022-02-16 | 2025-10-22 | 三井化学株式会社 | 水分散体、表面処理剤、処理繊維および処理フィラー |
Family Cites Families (51)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT574913A (enExample) | 1957-01-09 | 1900-01-01 | ||
| US2973344A (en) | 1957-12-11 | 1961-02-28 | Exxon Research Engineering Co | Modified polymers |
| US3284380A (en) | 1961-07-14 | 1966-11-08 | Hercules Inc | Polar polymer modified-ethylene-propylene copolymer latices |
| US3414551A (en) | 1965-06-24 | 1968-12-03 | Hercules Inc | Modification of crystalline propylene polymers |
| US3481910A (en) | 1965-10-04 | 1969-12-02 | Eastman Kodak Co | Reaction products of unsaturated dicarboxylic acids,anhydrides,esters with degraded poly - alpha - olefin polymers |
| US3484403A (en) | 1966-03-14 | 1969-12-16 | Eastman Kodak Co | Preparation of polyamide-carboxylated polyolefin melt blends |
| US3642722A (en) | 1967-11-29 | 1972-02-15 | Eastman Kodak Co | Process for preparing modified polyolefins |
| US3658948A (en) | 1970-11-23 | 1972-04-25 | Eastman Kodak Co | Hot melt composition comprising maleated polyethylene and polyolefin |
| US3862265A (en) | 1971-04-09 | 1975-01-21 | Exxon Research Engineering Co | Polymers with improved properties and process therefor |
| US3856889A (en) | 1972-09-11 | 1974-12-24 | Eastman Kodak Co | Blends containing polyethylene and an unsaturated polycarboxylic acid modified polyolefin |
| JPS5239636B2 (enExample) | 1973-05-01 | 1977-10-06 | ||
| US4028436A (en) | 1975-04-01 | 1977-06-07 | Eastman Kodak Company | Melt phase process for the preparation of emulsifiable polyethylene waxes |
| JPS6016442B2 (ja) | 1976-03-08 | 1985-04-25 | 日石三菱株式会社 | 変性ポリオレフインワツクスの製造法 |
| US4147740A (en) | 1976-09-15 | 1979-04-03 | General Electric Company | Graft modified polyethylene process and product |
| US4613679A (en) * | 1977-08-01 | 1986-09-23 | Eastman Kodak Company | Emulsifiable modified polymers |
| US4177336A (en) | 1977-12-12 | 1979-12-04 | Allied Chemical Corporation | Preparation of polyolefin containing multiple olefinic unsaturation and carboxylic acid groups and polyolefin so prepared |
| JPS5626915A (en) | 1979-08-10 | 1981-03-16 | Mitsui Petrochem Ind Ltd | Highly maleinized wax and preparation of the same |
| US4382128A (en) | 1980-07-28 | 1983-05-03 | Standard Oil Company | Polyolefin grafted with polycarboxylic acid, ester or anhydride and modified with polyhydroxy compound |
| US4358564A (en) | 1981-05-29 | 1982-11-09 | Eastman Kodak Company | Process for controlling the viscosity during the preparation of grafted polyethylene and ethylene/alpha olefin waxes |
| US4376855A (en) | 1981-06-22 | 1983-03-15 | Eastman Kodak Company | Emulsifiable ethylene containing polyolefin waxes having improved emulsifiability and process for their preparation |
| US4639495A (en) | 1981-12-21 | 1987-01-27 | E. I. Du Pont De Nemours And Company | Extruding process for preparing functionalized polyolefin polymers |
| US4506056A (en) | 1982-06-07 | 1985-03-19 | Gaylord Research Institute Inc. | Maleic anhydride-modified polymers and process for preparation thereof |
| US4927888A (en) | 1986-09-05 | 1990-05-22 | The Dow Chemical Company | Maleic anhydride graft copolymers having low yellowness index and films containing the same |
| US4762890A (en) | 1986-09-05 | 1988-08-09 | The Dow Chemical Company | Method of grafting maleic anhydride to polymers |
| DE3585777D1 (de) | 1984-11-30 | 1992-05-07 | Mitsui Petrochemical Ind | Waermefixierbarer elektrophotographischer toner. |
| US4670349A (en) | 1984-12-20 | 1987-06-02 | Mitsui Petrochemical Industries, Ltd. | Adhesive resin composition |
| US4880470A (en) | 1985-02-15 | 1989-11-14 | Eastman Kodak Company | Aqueous additive systems, methods and polymeric particles |
| US5190579A (en) | 1985-02-15 | 1993-03-02 | Eastman Kodak Company | Aqueous additive systems, methods and polymeric particles |
| JPS61266411A (ja) | 1985-05-20 | 1986-11-26 | Mitsubishi Petrochem Co Ltd | 無水マレイン酸変性ポリオレフインの精製方法 |
| JPH0621132B2 (ja) | 1985-07-08 | 1994-03-23 | 三菱化成株式会社 | 変性ポリオレフイン樹脂およびその組成物 |
| US5096493A (en) | 1986-02-07 | 1992-03-17 | Eastman Kodak Company | Aqueous additive systems, methods and polymeric particles |
| JPS63117008A (ja) | 1986-11-05 | 1988-05-21 | Idemitsu Petrochem Co Ltd | 変性ポリエチレンの製造方法 |
| US4767806A (en) | 1987-01-05 | 1988-08-30 | Uniroyal Chemical Company, Inc. | Carboxyl modified olefinic copolymer composition |
| JPS63291905A (ja) | 1987-05-25 | 1988-11-29 | Kao Corp | オレフィン−無水マレイン酸共重合体粒子の製造方法 |
| US4849489A (en) | 1987-08-11 | 1989-07-18 | S. C. Johnson & Son, Inc. | Continuous process and system for producing polymers comprising maleic anhydride and certain alpha-olefins |
| US4859752A (en) | 1987-09-11 | 1989-08-22 | S. C. Johnson & Son, Inc. | Alkene/excess maleic anhydride polymer manufacture |
| US5059658A (en) | 1989-04-07 | 1991-10-22 | Tonen Sekiyagaku Kabushiki Kaisha | Method of producing modified polypropylene |
| FR2646164B1 (fr) | 1989-04-19 | 1992-12-11 | Saint Gobain Vetrotex | Emulsion aqueuse a base de polyolefines greffees procede d'obtention et emploi, notamment dans les compositions d'appret |
| US5001197A (en) | 1989-05-10 | 1991-03-19 | Exxon Chemical Patents Inc. | Polypropylene composition and method for functionalization of polypropylene |
| EP0408470A1 (en) | 1989-07-06 | 1991-01-16 | Eastman Kodak Company | Maleated polypropylene blends for melt-bonding applications |
| US5153029A (en) | 1989-08-11 | 1992-10-06 | Eastman Kodak Company | Solid-form additive systems dispersible in aqueous media, methods for the preparation and application thereof to polymeric particles |
| US5204022A (en) | 1989-08-11 | 1993-04-20 | Eastman Kodak Company | Solid-form additive systems dispersible in aqueous media |
| DE4030564A1 (de) | 1990-09-27 | 1992-04-02 | Hoechst Ag | Pfropfpolymer auf basis von ultrahochmolekularem polyethylen |
| US5310806A (en) | 1991-05-22 | 1994-05-10 | Quantum Chemical Corporation | Process for preparing an ethylene-unsaturated polycarboxylic compound graft copolymer |
| US5367022A (en) | 1991-11-27 | 1994-11-22 | Quantum Chemical Corporation | Grafted polymeric products, and adhesive blends |
| US5290954A (en) | 1992-08-13 | 1994-03-01 | Eastman Kodak Company | High clarity emulsions containing high melt viscosity maleated polypropylene wax |
| DE4308591A1 (de) | 1993-03-18 | 1994-09-22 | Basf Ag | Gepfropfte Propylencopolymerisate |
| US5420303A (en) | 1993-12-16 | 1995-05-30 | Eastman Chemical Company | Process for the maleation of polyethylene waxes |
| US5492976A (en) | 1994-01-03 | 1996-02-20 | The Sherwin-Williams Company | Anhydride-functional polymers comprising ene reaction products of unsaturated anhydrides and polyolefins |
| KR970705587A (ko) | 1994-08-25 | 1997-10-09 | 그윈넬 해리 제이 | 고산가 고분자량 저색도 말레화 폴리프로필렌(maleated high acid number high molecular weight polypropylene of low color) |
| US6362280B1 (en) * | 1998-04-27 | 2002-03-26 | Honeywell International Inc. | Emulsible polyolefin wax |
-
1998
- 1998-04-27 US US09/067,355 patent/US6362280B1/en not_active Expired - Lifetime
-
1999
- 1999-04-16 CA CA002330306A patent/CA2330306A1/en not_active Abandoned
- 1999-04-16 JP JP2000545902A patent/JP4371581B2/ja not_active Expired - Lifetime
- 1999-04-16 AU AU37510/99A patent/AU3751099A/en not_active Abandoned
- 1999-04-16 WO PCT/US1999/008531 patent/WO1999055744A1/en not_active Ceased
- 1999-04-16 DE DE69917900T patent/DE69917900T2/de not_active Expired - Lifetime
- 1999-04-16 KR KR1020007011889A patent/KR100552572B1/ko not_active Expired - Lifetime
- 1999-04-16 EP EP99919892A patent/EP1080119B1/en not_active Expired - Lifetime
- 1999-04-21 MY MYPI99001560A patent/MY133168A/en unknown
- 1999-06-15 TW TW088106743A patent/TW445268B/zh not_active IP Right Cessation
-
2002
- 2002-02-05 US US10/067,513 patent/US6784251B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US20030069361A1 (en) | 2003-04-10 |
| AU3751099A (en) | 1999-11-16 |
| JP4371581B2 (ja) | 2009-11-25 |
| KR100552572B1 (ko) | 2006-02-20 |
| US6784251B2 (en) | 2004-08-31 |
| JP2002513050A (ja) | 2002-05-08 |
| DE69917900D1 (de) | 2004-07-15 |
| EP1080119B1 (en) | 2004-06-09 |
| EP1080119A1 (en) | 2001-03-07 |
| CA2330306A1 (en) | 1999-11-04 |
| WO1999055744A1 (en) | 1999-11-04 |
| MY133168A (en) | 2007-10-31 |
| KR20010043028A (ko) | 2001-05-25 |
| TW445268B (en) | 2001-07-11 |
| US6362280B1 (en) | 2002-03-26 |
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