CA2330306A1 - Emulsible polyolefin wax - Google Patents
Emulsible polyolefin wax Download PDFInfo
- Publication number
- CA2330306A1 CA2330306A1 CA002330306A CA2330306A CA2330306A1 CA 2330306 A1 CA2330306 A1 CA 2330306A1 CA 002330306 A CA002330306 A CA 002330306A CA 2330306 A CA2330306 A CA 2330306A CA 2330306 A1 CA2330306 A1 CA 2330306A1
- Authority
- CA
- Canada
- Prior art keywords
- wax
- polyolefin wax
- emulsible
- polyolefin
- emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 77
- 239000000839 emulsion Substances 0.000 claims abstract description 54
- 238000002834 transmittance Methods 0.000 claims abstract description 12
- 239000012736 aqueous medium Substances 0.000 claims abstract description 9
- 239000000155 melt Substances 0.000 claims abstract description 7
- 150000001875 compounds Chemical class 0.000 claims description 38
- 239000007858 starting material Substances 0.000 claims description 36
- 239000000203 mixture Substances 0.000 claims description 26
- 238000006243 chemical reaction Methods 0.000 claims description 25
- -1 polypropylene Polymers 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 21
- 239000004743 Polypropylene Substances 0.000 claims description 15
- 239000000126 substance Substances 0.000 claims description 15
- 229920001155 polypropylene Polymers 0.000 claims description 14
- 150000003254 radicals Chemical class 0.000 claims description 12
- 238000007127 saponification reaction Methods 0.000 claims description 8
- 239000003999 initiator Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 4
- 150000001451 organic peroxides Chemical group 0.000 claims 2
- 238000010923 batch production Methods 0.000 claims 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims 1
- 239000001993 wax Substances 0.000 description 94
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 33
- 150000008064 anhydrides Chemical class 0.000 description 9
- 239000002245 particle Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 238000007306 functionalization reaction Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 5
- 150000002978 peroxides Chemical class 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 239000007844 bleaching agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000004945 emulsification Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 238000013459 approach Methods 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 230000001419 dependent effect Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- DFVOXRAAHOJJBN-UHFFFAOYSA-N 6-methylhept-1-ene Chemical compound CC(C)CCCC=C DFVOXRAAHOJJBN-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- XSZYESUNPWGWFQ-UHFFFAOYSA-N 1-(2-hydroperoxypropan-2-yl)-4-methylcyclohexane Chemical compound CC1CCC(C(C)(C)OO)CC1 XSZYESUNPWGWFQ-UHFFFAOYSA-N 0.000 description 1
- GVJRTUUUJYMTNQ-UHFFFAOYSA-N 2-(2,5-dioxofuran-3-yl)acetic acid Chemical compound OC(=O)CC1=CC(=O)OC1=O GVJRTUUUJYMTNQ-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
- AYKYXWQEBUNJCN-UHFFFAOYSA-N 3-methylfuran-2,5-dione Chemical compound CC1=CC(=O)OC1=O AYKYXWQEBUNJCN-UHFFFAOYSA-N 0.000 description 1
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 1
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
- KLCNJIQZXOQYTE-UHFFFAOYSA-N 4,4-dimethylpent-1-ene Chemical compound CC(C)(C)CC=C KLCNJIQZXOQYTE-UHFFFAOYSA-N 0.000 description 1
- SUWJESCICIOQHO-UHFFFAOYSA-N 4-methylhex-1-ene Chemical compound CCC(C)CC=C SUWJESCICIOQHO-UHFFFAOYSA-N 0.000 description 1
- JDOZUYVDIAKODH-PLNGDYQASA-N 4-o-ethyl 1-o-methyl (z)-but-2-enedioate Chemical compound CCOC(=O)\C=C/C(=O)OC JDOZUYVDIAKODH-PLNGDYQASA-N 0.000 description 1
- WNEYWVBECXCQRT-UHFFFAOYSA-N 5-methylhept-1-ene Chemical compound CCC(C)CCC=C WNEYWVBECXCQRT-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000012969 di-tertiary-butyl peroxide Substances 0.000 description 1
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- LDCRTTXIJACKKU-ONEGZZNKSA-N dimethyl fumarate Chemical compound COC(=O)\C=C\C(=O)OC LDCRTTXIJACKKU-ONEGZZNKSA-N 0.000 description 1
- 229960004419 dimethyl fumarate Drugs 0.000 description 1
- LDCRTTXIJACKKU-ARJAWSKDSA-N dimethyl maleate Chemical compound COC(=O)\C=C/C(=O)OC LDCRTTXIJACKKU-ARJAWSKDSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 229930004008 p-menthane Natural products 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- CFJYNSNXFXLKNS-UHFFFAOYSA-N trans-p-menthane Natural products CC(C)C1CCC(C)CC1 CFJYNSNXFXLKNS-UHFFFAOYSA-N 0.000 description 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
- C08F255/023—On to modified polymers, e.g. chlorinated polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/46—Reaction with unsaturated dicarboxylic acids or anhydrides thereof, e.g. maleinisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
- C08J3/05—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media from solid polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Graft Or Block Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Colloid Chemistry (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/067,355 US6362280B1 (en) | 1998-04-27 | 1998-04-27 | Emulsible polyolefin wax |
| US09/067,355 | 1998-04-27 | ||
| PCT/US1999/008531 WO1999055744A1 (en) | 1998-04-27 | 1999-04-16 | Emulsible polyolefin wax |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2330306A1 true CA2330306A1 (en) | 1999-11-04 |
Family
ID=22075460
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002330306A Abandoned CA2330306A1 (en) | 1998-04-27 | 1999-04-16 | Emulsible polyolefin wax |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US6362280B1 (enExample) |
| EP (1) | EP1080119B1 (enExample) |
| JP (1) | JP4371581B2 (enExample) |
| KR (1) | KR100552572B1 (enExample) |
| AU (1) | AU3751099A (enExample) |
| CA (1) | CA2330306A1 (enExample) |
| DE (1) | DE69917900T2 (enExample) |
| MY (1) | MY133168A (enExample) |
| TW (1) | TW445268B (enExample) |
| WO (1) | WO1999055744A1 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6362280B1 (en) * | 1998-04-27 | 2002-03-26 | Honeywell International Inc. | Emulsible polyolefin wax |
| DE60019172T3 (de) † | 2000-08-29 | 2008-05-21 | E.I. Dupont De Nemours And Co., Wilmington | Propylenpropfpolymer mit hohem propfungsgrad und mit hohem schmelzfluss |
| US7256236B1 (en) * | 2001-05-06 | 2007-08-14 | Honeywell International Inc. | Maleated polypropylenes and processes for the preparation thereof |
| US20060223945A1 (en) * | 2003-01-21 | 2006-10-05 | Hollingshurst Claire L | Low color polyisobutylene succinic anhydride-derived emulsifiers |
| CN1813008B (zh) * | 2003-06-30 | 2010-12-01 | 日本瑞翁株式会社 | 酸改性石油树脂以及热熔融型路面标记线标示用材料 |
| US6774181B1 (en) * | 2003-07-01 | 2004-08-10 | Crompton Corporation | Process for the preparation of a self-emulsifiable polyolefin emulsion and hybrid polyolefin-polyurethane dispersion derived therefrom |
| US20060069209A1 (en) * | 2004-09-29 | 2006-03-30 | Klosiewicz Daniel W | Heat stable functionalized polyolefin emulsions |
| JP5011668B2 (ja) * | 2005-07-22 | 2012-08-29 | 東洋紡績株式会社 | 水性樹脂組成物およびその製造方法 |
| US7750078B2 (en) * | 2005-12-07 | 2010-07-06 | Exxonmobil Chemical Patents Inc. | Systems and methods used for functionalization of polymeric material and polymeric materials prepared therefrom |
| ES2803224T3 (es) | 2006-06-15 | 2021-01-25 | Dow Global Technologies Llc | Interpolímeros de olefina funcionalizados, composiciones y artículos preparados a partir de ellos, y procedimientos para obtener los mismos |
| EP2061573A2 (en) * | 2006-10-10 | 2009-05-27 | Dow Corning Corporation | Silicone foam control agent |
| US7622031B2 (en) * | 2007-01-15 | 2009-11-24 | Honeywell International Inc | Method for preparing oxidized polyolefin waxes |
| DE102007056440A1 (de) * | 2007-11-23 | 2009-05-28 | Clariant International Limited | Ionomere aus Poly-1-Olefinwachsen |
| US8853284B2 (en) | 2008-06-02 | 2014-10-07 | Honeywell International Inc. | Wax dispersion formulations, method of producing same, and uses |
| KR101664816B1 (ko) | 2009-03-10 | 2016-10-11 | 다우 코닝 도레이 캄파니 리미티드 | 수중유 실리콘 에멀젼 조성물 |
| GB0905502D0 (en) * | 2009-03-31 | 2009-05-13 | Dow Corning | Organopolysiloxane emulsions and their production |
| GB0905507D0 (en) | 2009-03-31 | 2009-05-13 | Dow Corning | Organopol Ysiloxane Compositions Containing An Active Material |
| EP2589627B1 (en) | 2010-07-02 | 2016-10-12 | Dow Corning Toray Co., Ltd. | Oil-in-water silicone emulsion composition |
| WO2018176298A1 (en) * | 2017-03-30 | 2018-10-04 | Rohm And Haas Company | Formaldehyde-free curable composition |
| JP7758594B2 (ja) * | 2022-02-16 | 2025-10-22 | 三井化学株式会社 | 水分散体、表面処理剤、処理繊維および処理フィラー |
Family Cites Families (51)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT574913A (enExample) | 1957-01-09 | 1900-01-01 | ||
| US2973344A (en) | 1957-12-11 | 1961-02-28 | Exxon Research Engineering Co | Modified polymers |
| US3284380A (en) | 1961-07-14 | 1966-11-08 | Hercules Inc | Polar polymer modified-ethylene-propylene copolymer latices |
| US3414551A (en) | 1965-06-24 | 1968-12-03 | Hercules Inc | Modification of crystalline propylene polymers |
| US3481910A (en) | 1965-10-04 | 1969-12-02 | Eastman Kodak Co | Reaction products of unsaturated dicarboxylic acids,anhydrides,esters with degraded poly - alpha - olefin polymers |
| US3484403A (en) | 1966-03-14 | 1969-12-16 | Eastman Kodak Co | Preparation of polyamide-carboxylated polyolefin melt blends |
| US3642722A (en) | 1967-11-29 | 1972-02-15 | Eastman Kodak Co | Process for preparing modified polyolefins |
| US3658948A (en) | 1970-11-23 | 1972-04-25 | Eastman Kodak Co | Hot melt composition comprising maleated polyethylene and polyolefin |
| US3862265A (en) | 1971-04-09 | 1975-01-21 | Exxon Research Engineering Co | Polymers with improved properties and process therefor |
| US3856889A (en) | 1972-09-11 | 1974-12-24 | Eastman Kodak Co | Blends containing polyethylene and an unsaturated polycarboxylic acid modified polyolefin |
| JPS5239636B2 (enExample) | 1973-05-01 | 1977-10-06 | ||
| US4028436A (en) | 1975-04-01 | 1977-06-07 | Eastman Kodak Company | Melt phase process for the preparation of emulsifiable polyethylene waxes |
| JPS6016442B2 (ja) | 1976-03-08 | 1985-04-25 | 日石三菱株式会社 | 変性ポリオレフインワツクスの製造法 |
| US4147740A (en) | 1976-09-15 | 1979-04-03 | General Electric Company | Graft modified polyethylene process and product |
| US4613679A (en) * | 1977-08-01 | 1986-09-23 | Eastman Kodak Company | Emulsifiable modified polymers |
| US4177336A (en) | 1977-12-12 | 1979-12-04 | Allied Chemical Corporation | Preparation of polyolefin containing multiple olefinic unsaturation and carboxylic acid groups and polyolefin so prepared |
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| US6362280B1 (en) * | 1998-04-27 | 2002-03-26 | Honeywell International Inc. | Emulsible polyolefin wax |
-
1998
- 1998-04-27 US US09/067,355 patent/US6362280B1/en not_active Expired - Lifetime
-
1999
- 1999-04-16 CA CA002330306A patent/CA2330306A1/en not_active Abandoned
- 1999-04-16 JP JP2000545902A patent/JP4371581B2/ja not_active Expired - Lifetime
- 1999-04-16 AU AU37510/99A patent/AU3751099A/en not_active Abandoned
- 1999-04-16 WO PCT/US1999/008531 patent/WO1999055744A1/en not_active Ceased
- 1999-04-16 DE DE69917900T patent/DE69917900T2/de not_active Expired - Lifetime
- 1999-04-16 KR KR1020007011889A patent/KR100552572B1/ko not_active Expired - Lifetime
- 1999-04-16 EP EP99919892A patent/EP1080119B1/en not_active Expired - Lifetime
- 1999-04-21 MY MYPI99001560A patent/MY133168A/en unknown
- 1999-06-15 TW TW088106743A patent/TW445268B/zh not_active IP Right Cessation
-
2002
- 2002-02-05 US US10/067,513 patent/US6784251B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US20030069361A1 (en) | 2003-04-10 |
| AU3751099A (en) | 1999-11-16 |
| JP4371581B2 (ja) | 2009-11-25 |
| KR100552572B1 (ko) | 2006-02-20 |
| US6784251B2 (en) | 2004-08-31 |
| JP2002513050A (ja) | 2002-05-08 |
| DE69917900T2 (de) | 2005-06-09 |
| DE69917900D1 (de) | 2004-07-15 |
| EP1080119B1 (en) | 2004-06-09 |
| EP1080119A1 (en) | 2001-03-07 |
| WO1999055744A1 (en) | 1999-11-04 |
| MY133168A (en) | 2007-10-31 |
| KR20010043028A (ko) | 2001-05-25 |
| TW445268B (en) | 2001-07-11 |
| US6362280B1 (en) | 2002-03-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |