DE69912411D1 - Olefinpolymerisation - Google Patents

Olefinpolymerisation

Info

Publication number
DE69912411D1
DE69912411D1 DE69912411T DE69912411T DE69912411D1 DE 69912411 D1 DE69912411 D1 DE 69912411D1 DE 69912411 T DE69912411 T DE 69912411T DE 69912411 T DE69912411 T DE 69912411T DE 69912411 D1 DE69912411 D1 DE 69912411D1
Authority
DE
Germany
Prior art keywords
olefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69912411T
Other languages
English (en)
Other versions
DE69912411T2 (de
DE69912411T3 (de
Inventor
Margaret Bennett
Bryan Coughlin
David Citron
Lin Wang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26762969&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE69912411(D1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of DE69912411D1 publication Critical patent/DE69912411D1/de
Publication of DE69912411T2 publication Critical patent/DE69912411T2/de
Application granted granted Critical
Publication of DE69912411T3 publication Critical patent/DE69912411T3/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/7039—Tridentate ligand
    • C08F4/704—Neutral ligand
    • C08F4/7042—NNN
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/04—Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69912411T 1998-03-30 1999-03-29 Olefinpolymerisation Expired - Lifetime DE69912411T3 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US8001898P 1998-03-30 1998-03-30
US80018P 1998-03-30
US11747199P 1999-01-27 1999-01-27
US117471P 1999-01-27
PCT/US1999/006769 WO1999050318A1 (en) 1998-03-30 1999-03-29 Polymerization of olefins

Publications (3)

Publication Number Publication Date
DE69912411D1 true DE69912411D1 (de) 2003-12-04
DE69912411T2 DE69912411T2 (de) 2004-08-05
DE69912411T3 DE69912411T3 (de) 2007-10-31

Family

ID=26762969

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69912411T Expired - Lifetime DE69912411T3 (de) 1998-03-30 1999-03-29 Olefinpolymerisation

Country Status (13)

Country Link
EP (1) EP1068245B2 (de)
JP (2) JP2002509954A (de)
KR (1) KR100541311B1 (de)
CN (1) CN1198855C (de)
AR (1) AR018173A1 (de)
AT (1) ATE253087T1 (de)
AU (1) AU752734B2 (de)
BR (1) BR9908406B1 (de)
CA (1) CA2324310A1 (de)
DE (1) DE69912411T3 (de)
EA (1) EA200001002A1 (de)
IL (1) IL138017A0 (de)
WO (1) WO1999050318A1 (de)

Families Citing this family (44)

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AU752734B2 (en) † 1998-03-30 2002-09-26 E.I. Du Pont De Nemours And Company Polymerization of olefins
US6255414B1 (en) 1998-09-01 2001-07-03 E. I. Du Pont De Nemours And Company Polymerization of olefins
US6620896B1 (en) * 1999-02-23 2003-09-16 Eastman Chemical Company Mixed olefin polymerization catalysts, processes employing such catalysts, and polymers obtained therefrom
GB9906296D0 (en) * 1999-03-18 1999-05-12 Bp Chem Int Ltd Polymerisation catalysts
US6620895B1 (en) 1999-03-22 2003-09-16 E. I. Du Pont De Nemours And Company Processing polyethylenes
US6458979B1 (en) * 1999-04-29 2002-10-01 E. I. Du Pont De Nemours And Company Polymerization of ethylene
GB9918189D0 (en) * 1999-08-02 1999-10-06 Bp Chem Int Ltd Polymerisation process
KR100675240B1 (ko) * 1999-09-29 2007-01-30 이 아이 듀폰 디 네모아 앤드 캄파니 개선된 가공 폴리에틸렌
CA2379607A1 (en) 1999-09-29 2001-04-05 E.I. Du Pont De Nemours And Company Manufacture of polyethylenes
US6407188B1 (en) 1999-09-29 2002-06-18 E. I. Du Pont De Nemours And Company Polymerization of olefins
EP1237949B1 (de) * 1999-09-29 2004-07-14 E.I. Du Pont De Nemours And Company Olefinpolymerisation mit verwendung von bimetallischen katalysatorsystemen
BR0014636A (pt) † 1999-09-29 2002-06-11 Du Pont Processo de preparação de uma poliolefina, sistema de catalisador de polimerização e poliolefina
DE19960123A1 (de) * 1999-12-13 2001-06-21 Basf Ag Verfahren zur homogenkatalytischen Herstellung von hochverzweigten amorphen Polyolefinen
US6586541B2 (en) * 2000-02-02 2003-07-01 E. I. Du Pont De Nemours And Company Process for production of polyolefins
US6828398B2 (en) 2000-02-10 2004-12-07 Bp Chemicals Limited Polymerization catalyst
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US6534691B2 (en) * 2000-07-18 2003-03-18 E. I. Du Pont De Nemours And Company Manufacturing process for α-olefins
BE1014196A3 (fr) 2001-05-23 2003-06-03 Solvay Complexes catalytiques et leur utilisation pour la polymerisation des alpha-olefines.
WO2003059511A1 (en) * 2002-01-09 2003-07-24 E.I. Du Pont De Nemours And Company Catalyst for olefin polymerization
EP1532181B1 (de) * 2002-08-29 2016-03-16 LG Chem, Ltd. Fulven und dessen herstellung
EP1403288A1 (de) * 2002-09-27 2004-03-31 ATOFINA Research Hafnocenverbindungen enthaltendes Dual-site Katalysatorsystem zur Herstellung von bimodalen Polyolefinen
DE102004020524A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
EP1650231A1 (de) * 2004-10-21 2006-04-26 Total Petrochemicals Research Feluy Polyolefine hergestellt mit Metallocen- und neuen Single-Site-Katalysatorkomponenten in einem Reaktor
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US7268096B2 (en) 2005-07-21 2007-09-11 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
US7271121B2 (en) 2005-07-21 2007-09-18 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
US7727926B2 (en) 2005-07-21 2010-06-01 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization
DE102007017903A1 (de) * 2007-04-13 2008-10-16 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung
WO2009080359A1 (en) * 2007-12-24 2009-07-02 Basell Polyolefine Gmbh Multistage process for the polymerization of olefins
WO2010034520A1 (en) * 2008-09-25 2010-04-01 Basell Polyolefine Gmbh Impact resistant lldpe composition and films made thereof
JP2012503686A (ja) * 2008-09-25 2012-02-09 バーゼル・ポリオレフィン・ゲーエムベーハー 耐衝撃性ｌｌｄｐｅ組成物及びそれから製造されるフィルム
DE102009028353A1 (de) 2009-08-07 2011-04-14 Wacker Chemie Ag Bindemittel auf der Basis von silangruppenhaltigen hochverzweigten Polyolefinen
JP5749718B2 (ja) * 2009-08-17 2015-07-15 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ オレフィン重合法の改善
US8916664B2 (en) 2010-03-29 2014-12-23 E I Du Pont De Nemours And Company Olefin polymerization process
JP2012224842A (ja) * 2011-03-30 2012-11-15 Sumitomo Chemical Co Ltd エチレン系重合体製造用触媒およびエチレン系重合体の製造方法
JP6123165B2 (ja) * 2011-03-30 2017-05-10 住友化学株式会社 エチレン系重合体製造用触媒の製造方法、エチレン系重合体製造用触媒及びエチレン系重合体の製造方法
US9586872B2 (en) 2011-12-30 2017-03-07 Chevron Phillips Chemical Company Lp Olefin oligomerization methods
JP6848195B2 (ja) * 2016-03-29 2021-03-24 日本ポリエチレン株式会社 特定の触媒と特定の工程によるエチレン共重合体の製造方法
US9944661B2 (en) 2016-08-09 2018-04-17 Chevron Phillips Chemical Company Lp Olefin hydroboration
CN109790246A (zh) * 2016-09-29 2019-05-21 陶氏环球技术有限责任公司 聚合烯烃的方法
EP3519452B1 (de) 2016-09-29 2024-05-29 Dow Global Technologies LLC Modifizierter ziegler-natta (pro)katalysator und system
JP6850192B2 (ja) * 2017-05-10 2021-03-31 Ｅｎｅｏｓ株式会社 オリゴマーの製造方法
CN115246896B (zh) * 2021-04-28 2023-08-15 中国石油化工股份有限公司 一种双/多金属催化剂及其制备方法与应用
WO2024128572A1 (ko) * 2022-12-15 2024-06-20 주식회사 엘지화학 혼성 메탈로센 촉매 및 이를 이용한 폴리에틸렌의 제조방법

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GB9906296D0 (en) † 1999-03-18 1999-05-12 Bp Chem Int Ltd Polymerisation catalysts

Also Published As

Publication number Publication date
CN1296499A (zh) 2001-05-23
ATE253087T1 (de) 2003-11-15
EP1068245B2 (de) 2007-05-23
CN1198855C (zh) 2005-04-27
BR9908406A (pt) 2000-10-17
AR018173A1 (es) 2001-10-31
JP2002509954A (ja) 2002-04-02
DE69912411T2 (de) 2004-08-05
AU3454599A (en) 1999-10-18
CA2324310A1 (en) 1999-10-07
JP2011032482A (ja) 2011-02-17
DE69912411T3 (de) 2007-10-31
AU752734B2 (en) 2002-09-26
WO1999050318A1 (en) 1999-10-07
EA200001002A1 (ru) 2001-02-26
KR20010042304A (ko) 2001-05-25
IL138017A0 (en) 2001-10-31
BR9908406B1 (pt) 2009-01-13
KR100541311B1 (ko) 2006-01-10
EP1068245B1 (de) 2003-10-29
EP1068245A1 (de) 2001-01-17

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Legal Events

Date Code Title Description
8363 Opposition against the patent
8366 Restricted maintained after opposition proceedings