DE69806260T2 - Verfahren zur optimierung der kohlenwasserstoffsynthese - Google Patents
Verfahren zur optimierung der kohlenwasserstoffsyntheseInfo
- Publication number
- DE69806260T2 DE69806260T2 DE69806260T DE69806260T DE69806260T2 DE 69806260 T2 DE69806260 T2 DE 69806260T2 DE 69806260 T DE69806260 T DE 69806260T DE 69806260 T DE69806260 T DE 69806260T DE 69806260 T2 DE69806260 T2 DE 69806260T2
- Authority
- DE
- Germany
- Prior art keywords
- gas
- catalyst
- carbon monoxide
- liquid medium
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 69
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 67
- 238000000034 method Methods 0.000 title claims abstract description 65
- 238000003786 synthesis reaction Methods 0.000 title claims description 48
- 230000015572 biosynthetic process Effects 0.000 title claims description 46
- 239000004215 Carbon black (E152) Substances 0.000 title description 11
- 239000007789 gas Substances 0.000 claims abstract description 175
- 238000006243 chemical reaction Methods 0.000 claims abstract description 134
- 239000007788 liquid Substances 0.000 claims abstract description 128
- 239000003054 catalyst Substances 0.000 claims abstract description 90
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 58
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 47
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 47
- 230000008569 process Effects 0.000 claims abstract description 46
- 239000001257 hydrogen Substances 0.000 claims abstract description 39
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 39
- 239000002245 particle Substances 0.000 claims abstract description 22
- 239000011949 solid catalyst Substances 0.000 claims abstract description 21
- 230000033001 locomotion Effects 0.000 claims abstract description 13
- 239000007787 solid Substances 0.000 claims abstract description 8
- 230000003068 static effect Effects 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 25
- 238000009835 boiling Methods 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 239000002826 coolant Substances 0.000 claims description 6
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 4
- 239000012188 paraffin wax Substances 0.000 claims description 4
- 239000004305 biphenyl Substances 0.000 claims description 2
- 235000010290 biphenyl Nutrition 0.000 claims description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 2
- 150000002334 glycols Chemical class 0.000 claims description 2
- 239000000047 product Substances 0.000 description 38
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 28
- 239000000376 reactant Substances 0.000 description 27
- 238000000926 separation method Methods 0.000 description 26
- 239000012530 fluid Substances 0.000 description 23
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
- 238000009826 distribution Methods 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000000446 fuel Substances 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 239000001569 carbon dioxide Substances 0.000 description 5
- 229910017052 cobalt Inorganic materials 0.000 description 5
- 239000010941 cobalt Substances 0.000 description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 5
- 230000001276 controlling effect Effects 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- MHCVCKDNQYMGEX-UHFFFAOYSA-N 1,1'-biphenyl;phenoxybenzene Chemical compound C1=CC=CC=C1C1=CC=CC=C1.C=1C=CC=CC=1OC1=CC=CC=C1 MHCVCKDNQYMGEX-UHFFFAOYSA-N 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 238000013467 fragmentation Methods 0.000 description 3
- 238000006062 fragmentation reaction Methods 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 230000000153 supplemental effect Effects 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 150000001728 carbonyl compounds Chemical class 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000005465 channeling Effects 0.000 description 2
- VLWBWEUXNYUQKJ-UHFFFAOYSA-N cobalt ruthenium Chemical compound [Co].[Ru] VLWBWEUXNYUQKJ-UHFFFAOYSA-N 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 239000012808 vapor phase Substances 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- -1 hydrocarbons Hydrocarbons Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- C10G2/342—Apparatus, reactors with moving solid catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1836—Heating and cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
- B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/06—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
- B01J2208/00132—Tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
- B01J2208/00274—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant vapours
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US5991397P | 1997-09-24 | 1997-09-24 | |
| PCT/US1998/020024 WO1999015484A1 (en) | 1997-09-24 | 1998-09-23 | A process for optimizing hydrocarbon synthesis |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69806260D1 DE69806260D1 (de) | 2002-08-01 |
| DE69806260T2 true DE69806260T2 (de) | 2002-11-07 |
Family
ID=22026092
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69806260T Expired - Lifetime DE69806260T2 (de) | 1997-09-24 | 1998-09-23 | Verfahren zur optimierung der kohlenwasserstoffsynthese |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6160026A (enExample) |
| EP (1) | EP1017655B1 (enExample) |
| JP (1) | JP4346236B2 (enExample) |
| CN (1) | CN1145598C (enExample) |
| AT (1) | ATE219761T1 (enExample) |
| AU (1) | AU734124B2 (enExample) |
| CA (1) | CA2303890A1 (enExample) |
| DE (1) | DE69806260T2 (enExample) |
| DK (1) | DK1017655T3 (enExample) |
| ES (1) | ES2179536T3 (enExample) |
| WO (1) | WO1999015484A1 (enExample) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6451864B1 (en) * | 1999-08-17 | 2002-09-17 | Battelle Memorial Institute | Catalyst structure and method of Fischer-Tropsch synthesis |
| TW511405B (en) * | 2000-12-27 | 2002-11-21 | Matsushita Electric Industrial Co Ltd | Device built-in module and manufacturing method thereof |
| WO2002096837A2 (en) * | 2001-05-25 | 2002-12-05 | Bp Exploration Operating Company Limited | Fischer-tropsch process |
| DE60213752T2 (de) * | 2001-12-25 | 2006-12-07 | Mitsubishi Gas Chemical Co., Inc. | Reaktor zur Herstellung von Nitrilverbindungen und Verfahren dazu |
| US20040235968A1 (en) * | 2003-03-28 | 2004-11-25 | Conocophillips Company | Process and apparatus for controlling flow in a multiphase reactor |
| RU2342355C2 (ru) * | 2003-05-16 | 2008-12-27 | Сэсол Текнолоджи (Проприетери) Лимитед | Способ получения жидких и газообразных продуктов из газообразных реагентов |
| US6822006B1 (en) * | 2003-07-02 | 2004-11-23 | Chevron U.S.A. Inc. | Methods of controlling the temperature of an exothermic reaction |
| US6838487B1 (en) * | 2003-12-04 | 2005-01-04 | Rentech, Inc. | Method and apparatus for regenerating an iron-based Fischer-Tropsch catalyst |
| GB2409825B (en) * | 2004-01-08 | 2007-06-13 | Statoil Asa | Heat exchange system for a slurry bubble column reactor |
| US7230034B2 (en) * | 2004-03-19 | 2007-06-12 | Conocophillips Company | Prevention of and recovering from a catalyst bed slumping in a gas-agitated multiphase reactor |
| JP2007277465A (ja) * | 2006-04-10 | 2007-10-25 | Nippon Oil Corp | 一酸化炭素の還元による炭化水素の製造方法 |
| US20070259973A1 (en) * | 2006-05-03 | 2007-11-08 | Syntroleum Corporation | Optimized hydrocarbon synthesis process |
| GB2444055B (en) * | 2006-11-23 | 2011-11-23 | Gtl F1 Ag | Gas to liquids plant with consecutive Fischer-Tropsch reactors and hydrogen make-up |
| JP5277364B2 (ja) * | 2007-03-30 | 2013-08-28 | 公益財団法人北九州産業学術推進機構 | 一酸化炭素の還元による炭化水素の製造方法 |
| JP5401318B2 (ja) * | 2007-09-27 | 2014-01-29 | 新日鉄住金エンジニアリング株式会社 | 気泡塔型炭化水素反応器、及びスラリー液面検知方法 |
| MY152110A (en) * | 2007-09-27 | 2014-08-15 | Nippon Steel Eng Co Ltd | Bubble column type hydrocarbon synthesis reator, and hydrocarbon synthesis reaction system having the same |
| US8765622B2 (en) * | 2007-12-20 | 2014-07-01 | Chevron U.S.A. Inc. | Recovery of slurry unsupported catalyst |
| JP5364714B2 (ja) * | 2008-09-30 | 2013-12-11 | 独立行政法人石油天然ガス・金属鉱物資源機構 | 液体燃料合成方法及び液体燃料合成装置 |
| WO2010038391A1 (ja) * | 2008-09-30 | 2010-04-08 | 独立行政法人石油天然ガス・金属鉱物資源機構 | 炭化水素合成反応装置及び炭化水素合成反応システム、並びに炭化水素合成方法 |
| GB2465554B (en) | 2008-11-18 | 2013-03-13 | Gtl F1 Ag | Slurry bubble column reactor |
| GB2466315B (en) | 2008-12-22 | 2013-01-09 | Gtl F1 Ag | Apparatus and method for conducting a Fischer-Tropsch synthesis reaction |
| GB2471338B (en) | 2009-06-26 | 2014-12-24 | Gtl F1 Ag | Apparatus and process for three-phase reacton |
| JP5950500B2 (ja) * | 2011-03-17 | 2016-07-13 | 独立行政法人石油天然ガス・金属鉱物資源機構 | 炭化水素の製造装置及び炭化水素の製造方法 |
| US8936927B2 (en) * | 2011-09-23 | 2015-01-20 | Coskata, Inc. | Processes for starting up deep tank anaerobic fermentation reactors for making oxygenated organic compound from carbon monoxide and hydrogen |
| CN108786669B (zh) * | 2017-04-27 | 2021-01-12 | 中国科学院大连化学物理研究所 | 流化床气体分布器、应用其的反应器及生产对二甲苯联产低碳烯烃的方法 |
| US11377598B2 (en) | 2018-05-11 | 2022-07-05 | Sabic Global Technologies B.V. | Method related to heat transfer for exothermic reactions |
| CN110465246A (zh) * | 2019-09-11 | 2019-11-19 | 上海电气电站环保工程有限公司 | 一种三相分离器 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB773274A (en) * | 1954-09-22 | 1957-04-24 | Kaiser Aluminium Chem Corp | Improvements in or relating to shipping containers |
| FR2460990A1 (fr) * | 1979-07-09 | 1981-01-30 | Inst Francais Du Petrole | Procede et appareil de conversion catalytique d'hydrocarbures |
| US4585798A (en) * | 1981-10-13 | 1986-04-29 | Gulf Research & Development Company | Synthesis gas conversion using ruthenium-promoted cobalt catalyst |
| US4521295A (en) * | 1982-12-27 | 1985-06-04 | Hri, Inc. | Sustained high hydroconversion of petroleum residua feedstocks |
| US4548702A (en) * | 1984-02-24 | 1985-10-22 | Standard Oil Company | Shale oil stabilization with a hydroprocessor |
| US4880763A (en) * | 1987-10-23 | 1989-11-14 | Den Norske Stats Olijeselskap A.S. | Catalyst for production of hydrocarbons |
| US4857559A (en) * | 1987-10-23 | 1989-08-15 | Gas-To-Oil, Inc. | Process for production of hydrocarbons |
| US4874583A (en) * | 1987-11-27 | 1989-10-17 | Texaco Inc. | Bubble cap assembly in an ebullated bed reactor |
| US5218003A (en) * | 1988-01-14 | 1993-06-08 | Air Products And Chemicals, Inc. | Liquid phase process for dimethyl ether synthesis |
| US4946477A (en) * | 1988-04-07 | 1990-08-07 | Air Products And Chemicals, Inc. | IGCC process with combined methanol synthesis/water gas shift for methanol and electrical power production |
| US4980145A (en) * | 1988-07-19 | 1990-12-25 | Air Products And Chemicals, Inc. | Liquid phase carbon monoxide shift process |
| US5108580A (en) * | 1989-03-08 | 1992-04-28 | Texaco Inc. | Two catalyst stage hydrocarbon cracking process |
| FR2694013B1 (fr) * | 1992-07-27 | 1994-09-30 | Inst Francais Du Petrole | Catalyseur à base de cobalt et procédé de conversion du gaz de synthèse en hydrocarbures. |
| US5252613A (en) * | 1992-12-18 | 1993-10-12 | Exxon Research & Engineering Company | Enhanced catalyst mixing in slurry bubble columns (OP-3723) |
| FR2741064B1 (fr) * | 1995-11-10 | 1997-12-12 | Inst Francais Du Petrole | Procede de conversion de gaz de synthese en hydrocarbures |
| MY116410A (en) * | 1996-08-08 | 2004-01-31 | Shell Int Research | Process and reactor for carrying out an exothermic reaction |
-
1998
- 1998-09-22 US US09/158,161 patent/US6160026A/en not_active Expired - Lifetime
- 1998-09-23 JP JP2000512796A patent/JP4346236B2/ja not_active Expired - Fee Related
- 1998-09-23 EP EP98948520A patent/EP1017655B1/en not_active Expired - Lifetime
- 1998-09-23 CN CNB988101904A patent/CN1145598C/zh not_active Expired - Fee Related
- 1998-09-23 AU AU95074/98A patent/AU734124B2/en not_active Ceased
- 1998-09-23 CA CA002303890A patent/CA2303890A1/en not_active Abandoned
- 1998-09-23 AT AT98948520T patent/ATE219761T1/de not_active IP Right Cessation
- 1998-09-23 WO PCT/US1998/020024 patent/WO1999015484A1/en not_active Ceased
- 1998-09-23 DK DK98948520T patent/DK1017655T3/da active
- 1998-09-23 ES ES98948520T patent/ES2179536T3/es not_active Expired - Lifetime
- 1998-09-23 DE DE69806260T patent/DE69806260T2/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CA2303890A1 (en) | 1999-04-01 |
| EP1017655B1 (en) | 2002-06-26 |
| WO1999015484A1 (en) | 1999-04-01 |
| ES2179536T3 (es) | 2003-01-16 |
| ATE219761T1 (de) | 2002-07-15 |
| AU734124B2 (en) | 2001-06-07 |
| DK1017655T3 (da) | 2002-10-21 |
| JP4346236B2 (ja) | 2009-10-21 |
| CN1275968A (zh) | 2000-12-06 |
| AU9507498A (en) | 1999-04-12 |
| DE69806260D1 (de) | 2002-08-01 |
| JP2001517645A (ja) | 2001-10-09 |
| US6160026A (en) | 2000-12-12 |
| CN1145598C (zh) | 2004-04-14 |
| EP1017655A1 (en) | 2000-07-12 |
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