ES2179536T3 - Procedimiento para la optimizacion de la sintesis de hidrocarburos. - Google Patents
Procedimiento para la optimizacion de la sintesis de hidrocarburos.Info
- Publication number
- ES2179536T3 ES2179536T3 ES98948520T ES98948520T ES2179536T3 ES 2179536 T3 ES2179536 T3 ES 2179536T3 ES 98948520 T ES98948520 T ES 98948520T ES 98948520 T ES98948520 T ES 98948520T ES 2179536 T3 ES2179536 T3 ES 2179536T3
- Authority
- ES
- Spain
- Prior art keywords
- gas
- bed
- carbon monoxide
- liquid medium
- substantially inert
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- C10G2/342—Apparatus, reactors with moving solid catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1836—Heating and cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
- B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/06—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
- B01J2208/00132—Tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
- B01J2208/00274—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant vapours
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Catalysts (AREA)
Abstract
Un procedimiento para producir hidrocarburos a partir de hidrógeno y monóxido de carbono mediante la reacción de hidrógeno y monóxido de carbono en una zona de reacción que comprende catalizador sólido en partículas y medio líquido sustancialmente inerte, que comprende: llevar a cabo la reacción en una sola zona de reacción turbulenta dentro una cubeta de reactor de lecho de ebullición adaptada para la reacción de gases en presencia de un medio líquido sustancialmente inerte y catalizador sólido en partículas, en el que el gas que comprende uno o más de entre gas hidrógeno y gas monóxido de carbono se introducen en una pluralidad de localizaciones dentro de la zona de reacción de modo tal que las burbujas de los gases fluyan hacia arriba a través de la zona de reacción que comprende partículas de catalizador sólido y medio líquido sustancialmente inerte a velocidad suficiente para expandir el lecho a un volumen mayor que su volumen estático; y en el queel medio líquido sustancialmente inerte tanto se añade como se retira de la zona de reacción, creando con ello un flujo que facilita la expansión del lecho hasta el punto en el que al menos parte del catalizador sólido está en un estado de movimiento aleatorio; y además en el que el gas hidrógeno, gas monóxido de carbono, o una mezcla de los mismos se introduce a una pluralidad de distancias predeterminadas desde la base de la cubeta.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US5991397P | 1997-09-24 | 1997-09-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2179536T3 true ES2179536T3 (es) | 2003-01-16 |
Family
ID=22026092
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES98948520T Expired - Lifetime ES2179536T3 (es) | 1997-09-24 | 1998-09-23 | Procedimiento para la optimizacion de la sintesis de hidrocarburos. |
Country Status (11)
Country | Link |
---|---|
US (1) | US6160026A (es) |
EP (1) | EP1017655B1 (es) |
JP (1) | JP4346236B2 (es) |
CN (1) | CN1145598C (es) |
AT (1) | ATE219761T1 (es) |
AU (1) | AU734124B2 (es) |
CA (1) | CA2303890A1 (es) |
DE (1) | DE69806260T2 (es) |
DK (1) | DK1017655T3 (es) |
ES (1) | ES2179536T3 (es) |
WO (1) | WO1999015484A1 (es) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6451864B1 (en) * | 1999-08-17 | 2002-09-17 | Battelle Memorial Institute | Catalyst structure and method of Fischer-Tropsch synthesis |
TW511405B (en) * | 2000-12-27 | 2002-11-21 | Matsushita Electric Ind Co Ltd | Device built-in module and manufacturing method thereof |
EA006222B1 (ru) * | 2001-05-25 | 2005-10-27 | Бп Эксплорейшн Оперейтинг Компани Лимитед | Способ проведения реакции синтеза фишера-тропша |
US20040005254A1 (en) * | 2001-12-25 | 2004-01-08 | Shuichi Ueno | Reactor for producing a nitrile compound and method for operating the reactor |
US20040235968A1 (en) * | 2003-03-28 | 2004-11-25 | Conocophillips Company | Process and apparatus for controlling flow in a multiphase reactor |
BRPI0410365B1 (pt) * | 2003-05-16 | 2014-09-09 | Sasol Tech Pty Ltd | Processo para produzir produtos liquidos e, opcionalmente, produtos gasosos a partir de reagentes gasosos |
US6822006B1 (en) * | 2003-07-02 | 2004-11-23 | Chevron U.S.A. Inc. | Methods of controlling the temperature of an exothermic reaction |
US6838487B1 (en) * | 2003-12-04 | 2005-01-04 | Rentech, Inc. | Method and apparatus for regenerating an iron-based Fischer-Tropsch catalyst |
GB2409825B (en) * | 2004-01-08 | 2007-06-13 | Statoil Asa | Heat exchange system for a slurry bubble column reactor |
US7230034B2 (en) | 2004-03-19 | 2007-06-12 | Conocophillips Company | Prevention of and recovering from a catalyst bed slumping in a gas-agitated multiphase reactor |
JP2007277465A (ja) * | 2006-04-10 | 2007-10-25 | Nippon Oil Corp | 一酸化炭素の還元による炭化水素の製造方法 |
US20070259973A1 (en) * | 2006-05-03 | 2007-11-08 | Syntroleum Corporation | Optimized hydrocarbon synthesis process |
GB2444055B (en) * | 2006-11-23 | 2011-11-23 | Gtl F1 Ag | Gas to liquids plant with consecutive Fischer-Tropsch reactors and hydrogen make-up |
JP5277364B2 (ja) * | 2007-03-30 | 2013-08-28 | 公益財団法人北九州産業学術推進機構 | 一酸化炭素の還元による炭化水素の製造方法 |
AU2008304801B2 (en) * | 2007-09-27 | 2011-03-24 | Cosmo Oil Co., Ltd. | Bubbling tower hydrocarbon reactor and method of detecting slurry surface level |
US20100247392A1 (en) * | 2007-09-27 | 2010-09-30 | Yasuhiro Onishi | Bubble column type hydrocarbon synthesis reacator, and hydrocarbon synthesis reaction system having the same |
US8765622B2 (en) * | 2007-12-20 | 2014-07-01 | Chevron U.S.A. Inc. | Recovery of slurry unsupported catalyst |
CA2738058C (en) * | 2008-09-30 | 2015-04-28 | Cosmo Oil Co., Ltd. | Liquid-fuel synthesizing method and liquid-fuel synthesizing apparatus |
US8586640B2 (en) | 2008-09-30 | 2013-11-19 | Japan Oil, Gas And Metals National Corporation | Hydrocarbon synthesis reaction apparatus, hydrocarbon synthesis reaction system, and hydrocarbon synthesizing method |
GB2465554B (en) | 2008-11-18 | 2013-03-13 | Gtl F1 Ag | Slurry bubble column reactor |
GB2466315B (en) | 2008-12-22 | 2013-01-09 | Gtl F1 Ag | Apparatus and method for conducting a Fischer-Tropsch synthesis reaction |
GB2471338B (en) | 2009-06-26 | 2014-12-24 | Gtl F1 Ag | Apparatus and process for three-phase reacton |
JP5950500B2 (ja) | 2011-03-17 | 2016-07-13 | 独立行政法人石油天然ガス・金属鉱物資源機構 | 炭化水素の製造装置及び炭化水素の製造方法 |
US8936927B2 (en) * | 2011-09-23 | 2015-01-20 | Coskata, Inc. | Processes for starting up deep tank anaerobic fermentation reactors for making oxygenated organic compound from carbon monoxide and hydrogen |
CN108786669B (zh) * | 2017-04-27 | 2021-01-12 | 中国科学院大连化学物理研究所 | 流化床气体分布器、应用其的反应器及生产对二甲苯联产低碳烯烃的方法 |
WO2019215534A1 (en) * | 2018-05-11 | 2019-11-14 | Sabic Global Technologies B.V. | Method related to heat transfer for exothermic reactions |
CN110465246A (zh) * | 2019-09-11 | 2019-11-19 | 上海电气电站环保工程有限公司 | 一种三相分离器 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB773274A (en) * | 1954-09-22 | 1957-04-24 | Kaiser Aluminium Chem Corp | Improvements in or relating to shipping containers |
FR2460990A1 (fr) * | 1979-07-09 | 1981-01-30 | Inst Francais Du Petrole | Procede et appareil de conversion catalytique d'hydrocarbures |
US4585798A (en) * | 1981-10-13 | 1986-04-29 | Gulf Research & Development Company | Synthesis gas conversion using ruthenium-promoted cobalt catalyst |
US4521295A (en) * | 1982-12-27 | 1985-06-04 | Hri, Inc. | Sustained high hydroconversion of petroleum residua feedstocks |
US4548702A (en) * | 1984-02-24 | 1985-10-22 | Standard Oil Company | Shale oil stabilization with a hydroprocessor |
US4880763A (en) * | 1987-10-23 | 1989-11-14 | Den Norske Stats Olijeselskap A.S. | Catalyst for production of hydrocarbons |
US4857559A (en) * | 1987-10-23 | 1989-08-15 | Gas-To-Oil, Inc. | Process for production of hydrocarbons |
US4874583A (en) * | 1987-11-27 | 1989-10-17 | Texaco Inc. | Bubble cap assembly in an ebullated bed reactor |
US5218003A (en) * | 1988-01-14 | 1993-06-08 | Air Products And Chemicals, Inc. | Liquid phase process for dimethyl ether synthesis |
US4946477A (en) * | 1988-04-07 | 1990-08-07 | Air Products And Chemicals, Inc. | IGCC process with combined methanol synthesis/water gas shift for methanol and electrical power production |
US4980145A (en) * | 1988-07-19 | 1990-12-25 | Air Products And Chemicals, Inc. | Liquid phase carbon monoxide shift process |
US5108580A (en) * | 1989-03-08 | 1992-04-28 | Texaco Inc. | Two catalyst stage hydrocarbon cracking process |
FR2694013B1 (fr) * | 1992-07-27 | 1994-09-30 | Inst Francais Du Petrole | Catalyseur à base de cobalt et procédé de conversion du gaz de synthèse en hydrocarbures. |
US5252613A (en) * | 1992-12-18 | 1993-10-12 | Exxon Research & Engineering Company | Enhanced catalyst mixing in slurry bubble columns (OP-3723) |
FR2741064B1 (fr) * | 1995-11-10 | 1997-12-12 | Inst Francais Du Petrole | Procede de conversion de gaz de synthese en hydrocarbures |
MY116410A (en) * | 1996-08-08 | 2004-01-31 | Shell Int Research | Process and reactor for carrying out an exothermic reaction |
-
1998
- 1998-09-22 US US09/158,161 patent/US6160026A/en not_active Expired - Lifetime
- 1998-09-23 DE DE69806260T patent/DE69806260T2/de not_active Expired - Lifetime
- 1998-09-23 DK DK98948520T patent/DK1017655T3/da active
- 1998-09-23 WO PCT/US1998/020024 patent/WO1999015484A1/en active IP Right Grant
- 1998-09-23 ES ES98948520T patent/ES2179536T3/es not_active Expired - Lifetime
- 1998-09-23 AT AT98948520T patent/ATE219761T1/de not_active IP Right Cessation
- 1998-09-23 CN CNB988101904A patent/CN1145598C/zh not_active Expired - Fee Related
- 1998-09-23 EP EP98948520A patent/EP1017655B1/en not_active Expired - Lifetime
- 1998-09-23 AU AU95074/98A patent/AU734124B2/en not_active Ceased
- 1998-09-23 CA CA002303890A patent/CA2303890A1/en not_active Abandoned
- 1998-09-23 JP JP2000512796A patent/JP4346236B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP1017655B1 (en) | 2002-06-26 |
AU9507498A (en) | 1999-04-12 |
CN1275968A (zh) | 2000-12-06 |
DE69806260T2 (de) | 2002-11-07 |
ATE219761T1 (de) | 2002-07-15 |
CA2303890A1 (en) | 1999-04-01 |
JP4346236B2 (ja) | 2009-10-21 |
CN1145598C (zh) | 2004-04-14 |
DE69806260D1 (de) | 2002-08-01 |
JP2001517645A (ja) | 2001-10-09 |
EP1017655A1 (en) | 2000-07-12 |
WO1999015484A1 (en) | 1999-04-01 |
US6160026A (en) | 2000-12-12 |
AU734124B2 (en) | 2001-06-07 |
DK1017655T3 (da) | 2002-10-21 |
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