JP2001517645A5 - - Google Patents
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- Publication number
- JP2001517645A5 JP2001517645A5 JP2000512796A JP2000512796A JP2001517645A5 JP 2001517645 A5 JP2001517645 A5 JP 2001517645A5 JP 2000512796 A JP2000512796 A JP 2000512796A JP 2000512796 A JP2000512796 A JP 2000512796A JP 2001517645 A5 JP2001517645 A5 JP 2001517645A5
- Authority
- JP
- Japan
- Prior art keywords
- gas
- reactor
- liquid
- catalyst
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007789 gas Substances 0.000 description 123
- 238000006243 chemical reaction Methods 0.000 description 96
- 239000007788 liquid Substances 0.000 description 94
- 238000000034 method Methods 0.000 description 57
- 239000003054 catalyst Substances 0.000 description 54
- 230000008569 process Effects 0.000 description 53
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 42
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 32
- 229910002091 carbon monoxide Inorganic materials 0.000 description 32
- 239000001257 hydrogen Substances 0.000 description 28
- 229910052739 hydrogen Inorganic materials 0.000 description 28
- 229930195733 hydrocarbon Natural products 0.000 description 25
- 150000002430 hydrocarbons Chemical class 0.000 description 25
- 230000015572 biosynthetic process Effects 0.000 description 24
- 238000003786 synthesis reaction Methods 0.000 description 24
- 238000000926 separation method Methods 0.000 description 22
- 238000009835 boiling Methods 0.000 description 14
- 239000012530 fluid Substances 0.000 description 14
- 239000002245 particle Substances 0.000 description 14
- 239000011949 solid catalyst Substances 0.000 description 13
- 238000009826 distribution Methods 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 230000033001 locomotion Effects 0.000 description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- 239000000376 reactant Substances 0.000 description 8
- 239000002826 coolant Substances 0.000 description 7
- 239000012495 reaction gas Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000004215 Carbon black (E152) Substances 0.000 description 6
- 239000000446 fuel Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 230000001276 controlling effect Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 230000003068 static effect Effects 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000007812 deficiency Effects 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 230000004907 flux Effects 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910002090 carbon oxide Inorganic materials 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 230000003134 recirculating effect Effects 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- MHCVCKDNQYMGEX-UHFFFAOYSA-N 1,1'-biphenyl;phenoxybenzene Chemical compound C1=CC=CC=C1C1=CC=CC=C1.C=1C=CC=CC=1OC1=CC=CC=C1 MHCVCKDNQYMGEX-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- WDNQRCVBPNOTNV-UHFFFAOYSA-N dinonylnaphthylsulfonic acid Chemical compound C1=CC=C2C(S(O)(=O)=O)=C(CCCCCCCCC)C(CCCCCCCCC)=CC2=C1 WDNQRCVBPNOTNV-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US5991397P | 1997-09-24 | 1997-09-24 | |
| US60/059,913 | 1997-09-24 | ||
| PCT/US1998/020024 WO1999015484A1 (en) | 1997-09-24 | 1998-09-23 | A process for optimizing hydrocarbon synthesis |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2001517645A JP2001517645A (ja) | 2001-10-09 |
| JP2001517645A5 true JP2001517645A5 (enExample) | 2009-07-16 |
| JP4346236B2 JP4346236B2 (ja) | 2009-10-21 |
Family
ID=22026092
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000512796A Expired - Fee Related JP4346236B2 (ja) | 1997-09-24 | 1998-09-23 | 炭化水素合成の最適化プロセス |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6160026A (enExample) |
| EP (1) | EP1017655B1 (enExample) |
| JP (1) | JP4346236B2 (enExample) |
| CN (1) | CN1145598C (enExample) |
| AT (1) | ATE219761T1 (enExample) |
| AU (1) | AU734124B2 (enExample) |
| CA (1) | CA2303890A1 (enExample) |
| DE (1) | DE69806260T2 (enExample) |
| DK (1) | DK1017655T3 (enExample) |
| ES (1) | ES2179536T3 (enExample) |
| WO (1) | WO1999015484A1 (enExample) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6451864B1 (en) * | 1999-08-17 | 2002-09-17 | Battelle Memorial Institute | Catalyst structure and method of Fischer-Tropsch synthesis |
| TW511405B (en) * | 2000-12-27 | 2002-11-21 | Matsushita Electric Industrial Co Ltd | Device built-in module and manufacturing method thereof |
| DE60202604T2 (de) * | 2001-05-25 | 2005-06-16 | Bp Exploration Operating Co. Ltd. | Fischer-tropschverfahren |
| US20040005254A1 (en) * | 2001-12-25 | 2004-01-08 | Shuichi Ueno | Reactor for producing a nitrile compound and method for operating the reactor |
| WO2004088227A2 (en) * | 2003-03-28 | 2004-10-14 | Conocophillips Company | Process and apparatus for controlling flow in a multiphase reactor |
| DE602004015984D1 (de) * | 2003-05-16 | 2008-10-02 | Sasol Tech Pty Ltd | Verfahren zur herstellung von flüssigen und gegebenenfalls gasförmigen produkten aus gasförmigen reaktanten |
| US6822006B1 (en) * | 2003-07-02 | 2004-11-23 | Chevron U.S.A. Inc. | Methods of controlling the temperature of an exothermic reaction |
| US6838487B1 (en) * | 2003-12-04 | 2005-01-04 | Rentech, Inc. | Method and apparatus for regenerating an iron-based Fischer-Tropsch catalyst |
| GB2409825B (en) * | 2004-01-08 | 2007-06-13 | Statoil Asa | Heat exchange system for a slurry bubble column reactor |
| US7230034B2 (en) * | 2004-03-19 | 2007-06-12 | Conocophillips Company | Prevention of and recovering from a catalyst bed slumping in a gas-agitated multiphase reactor |
| JP2007277465A (ja) * | 2006-04-10 | 2007-10-25 | Nippon Oil Corp | 一酸化炭素の還元による炭化水素の製造方法 |
| US20070259973A1 (en) * | 2006-05-03 | 2007-11-08 | Syntroleum Corporation | Optimized hydrocarbon synthesis process |
| GB2444055B (en) * | 2006-11-23 | 2011-11-23 | Gtl F1 Ag | Gas to liquids plant with consecutive Fischer-Tropsch reactors and hydrogen make-up |
| JP5277364B2 (ja) * | 2007-03-30 | 2013-08-28 | 公益財団法人北九州産業学術推進機構 | 一酸化炭素の還元による炭化水素の製造方法 |
| JP5220755B2 (ja) * | 2007-09-27 | 2013-06-26 | 新日鉄住金エンジニアリング株式会社 | 気泡塔型炭化水素合成反応器及びこれを備える炭化水素合成反応システム |
| EA019139B1 (ru) * | 2007-09-27 | 2014-01-30 | Ниппон Стил Инджиниринг Ко., Лтд. | Реактор синтеза углеводородов типа барботажной колонны и способ определения уровня суспензии |
| US8765622B2 (en) * | 2007-12-20 | 2014-07-01 | Chevron U.S.A. Inc. | Recovery of slurry unsupported catalyst |
| BRPI0920735A2 (pt) * | 2008-09-30 | 2015-12-29 | Cosmo Oil Co Ltd | método de sintetização de combustível líquido e aparelho de sintetização de combustível líquido |
| WO2010038391A1 (ja) * | 2008-09-30 | 2010-04-08 | 独立行政法人石油天然ガス・金属鉱物資源機構 | 炭化水素合成反応装置及び炭化水素合成反応システム、並びに炭化水素合成方法 |
| GB2465554B (en) | 2008-11-18 | 2013-03-13 | Gtl F1 Ag | Slurry bubble column reactor |
| GB2466315B (en) | 2008-12-22 | 2013-01-09 | Gtl F1 Ag | Apparatus and method for conducting a Fischer-Tropsch synthesis reaction |
| GB2471338B (en) | 2009-06-26 | 2014-12-24 | Gtl F1 Ag | Apparatus and process for three-phase reacton |
| JP5950500B2 (ja) | 2011-03-17 | 2016-07-13 | 独立行政法人石油天然ガス・金属鉱物資源機構 | 炭化水素の製造装置及び炭化水素の製造方法 |
| US8936927B2 (en) * | 2011-09-23 | 2015-01-20 | Coskata, Inc. | Processes for starting up deep tank anaerobic fermentation reactors for making oxygenated organic compound from carbon monoxide and hydrogen |
| CN108786669B (zh) * | 2017-04-27 | 2021-01-12 | 中国科学院大连化学物理研究所 | 流化床气体分布器、应用其的反应器及生产对二甲苯联产低碳烯烃的方法 |
| WO2019215534A1 (en) * | 2018-05-11 | 2019-11-14 | Sabic Global Technologies B.V. | Method related to heat transfer for exothermic reactions |
| CN110465246A (zh) * | 2019-09-11 | 2019-11-19 | 上海电气电站环保工程有限公司 | 一种三相分离器 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB773274A (en) * | 1954-09-22 | 1957-04-24 | Kaiser Aluminium Chem Corp | Improvements in or relating to shipping containers |
| FR2460990A1 (fr) * | 1979-07-09 | 1981-01-30 | Inst Francais Du Petrole | Procede et appareil de conversion catalytique d'hydrocarbures |
| US4585798A (en) * | 1981-10-13 | 1986-04-29 | Gulf Research & Development Company | Synthesis gas conversion using ruthenium-promoted cobalt catalyst |
| US4521295A (en) * | 1982-12-27 | 1985-06-04 | Hri, Inc. | Sustained high hydroconversion of petroleum residua feedstocks |
| US4548702A (en) * | 1984-02-24 | 1985-10-22 | Standard Oil Company | Shale oil stabilization with a hydroprocessor |
| US4857559A (en) * | 1987-10-23 | 1989-08-15 | Gas-To-Oil, Inc. | Process for production of hydrocarbons |
| US4880763A (en) * | 1987-10-23 | 1989-11-14 | Den Norske Stats Olijeselskap A.S. | Catalyst for production of hydrocarbons |
| US4874583A (en) * | 1987-11-27 | 1989-10-17 | Texaco Inc. | Bubble cap assembly in an ebullated bed reactor |
| US5218003A (en) * | 1988-01-14 | 1993-06-08 | Air Products And Chemicals, Inc. | Liquid phase process for dimethyl ether synthesis |
| US4946477A (en) * | 1988-04-07 | 1990-08-07 | Air Products And Chemicals, Inc. | IGCC process with combined methanol synthesis/water gas shift for methanol and electrical power production |
| US4980145A (en) * | 1988-07-19 | 1990-12-25 | Air Products And Chemicals, Inc. | Liquid phase carbon monoxide shift process |
| US5108580A (en) * | 1989-03-08 | 1992-04-28 | Texaco Inc. | Two catalyst stage hydrocarbon cracking process |
| FR2694013B1 (fr) * | 1992-07-27 | 1994-09-30 | Inst Francais Du Petrole | Catalyseur à base de cobalt et procédé de conversion du gaz de synthèse en hydrocarbures. |
| US5252613A (en) * | 1992-12-18 | 1993-10-12 | Exxon Research & Engineering Company | Enhanced catalyst mixing in slurry bubble columns (OP-3723) |
| FR2741064B1 (fr) * | 1995-11-10 | 1997-12-12 | Inst Francais Du Petrole | Procede de conversion de gaz de synthese en hydrocarbures |
| MY116410A (en) * | 1996-08-08 | 2004-01-31 | Shell Int Research | Process and reactor for carrying out an exothermic reaction |
-
1998
- 1998-09-22 US US09/158,161 patent/US6160026A/en not_active Expired - Lifetime
- 1998-09-23 DK DK98948520T patent/DK1017655T3/da active
- 1998-09-23 AT AT98948520T patent/ATE219761T1/de not_active IP Right Cessation
- 1998-09-23 WO PCT/US1998/020024 patent/WO1999015484A1/en not_active Ceased
- 1998-09-23 DE DE69806260T patent/DE69806260T2/de not_active Expired - Lifetime
- 1998-09-23 ES ES98948520T patent/ES2179536T3/es not_active Expired - Lifetime
- 1998-09-23 AU AU95074/98A patent/AU734124B2/en not_active Ceased
- 1998-09-23 CA CA002303890A patent/CA2303890A1/en not_active Abandoned
- 1998-09-23 EP EP98948520A patent/EP1017655B1/en not_active Expired - Lifetime
- 1998-09-23 JP JP2000512796A patent/JP4346236B2/ja not_active Expired - Fee Related
- 1998-09-23 CN CNB988101904A patent/CN1145598C/zh not_active Expired - Fee Related
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