DE69524532T2 - Zirconium und Cyclo-Alkadienylgruppen enthaltene fester Katalysatorbestandteil, Verfahren zu seiner Herstellung und Olefinpolymerisationsverfahren unter Anwendung desselben - Google Patents

Zirconium und Cyclo-Alkadienylgruppen enthaltene fester Katalysatorbestandteil, Verfahren zu seiner Herstellung und Olefinpolymerisationsverfahren unter Anwendung desselben

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Publication number
DE69524532T2
DE69524532T2 DE69524532T DE69524532T DE69524532T2 DE 69524532 T2 DE69524532 T2 DE 69524532T2 DE 69524532 T DE69524532 T DE 69524532T DE 69524532 T DE69524532 T DE 69524532T DE 69524532 T2 DE69524532 T2 DE 69524532T2
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DE
Germany
Prior art keywords
cyclo
preparation
solid catalyst
same
catalyst component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69524532T
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English (en)
Other versions
DE69524532D1 (de
Inventor
Roger Spitz
Veronique Pasquet
Jerome Dupuy
Jean Malinge
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Arkema France SA
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Atofina SA
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Application filed by Atofina SA filed Critical Atofina SA
Application granted granted Critical
Publication of DE69524532D1 publication Critical patent/DE69524532D1/de
Publication of DE69524532T2 publication Critical patent/DE69524532T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69524532T 1994-10-21 1995-09-15 Zirconium und Cyclo-Alkadienylgruppen enthaltene fester Katalysatorbestandteil, Verfahren zu seiner Herstellung und Olefinpolymerisationsverfahren unter Anwendung desselben Expired - Lifetime DE69524532T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9412604A FR2725993B1 (fr) 1994-10-21 1994-10-21 Composante catalytique solide contenant du zirconium et des groupements cycloalcadienyles, son procede d'obtention et procede de polymerisation des olefines en sa presence

Publications (2)

Publication Number Publication Date
DE69524532D1 DE69524532D1 (de) 2002-01-24
DE69524532T2 true DE69524532T2 (de) 2002-07-04

Family

ID=9468083

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69524532T Expired - Lifetime DE69524532T2 (de) 1994-10-21 1995-09-15 Zirconium und Cyclo-Alkadienylgruppen enthaltene fester Katalysatorbestandteil, Verfahren zu seiner Herstellung und Olefinpolymerisationsverfahren unter Anwendung desselben

Country Status (12)

Country Link
US (1) US5739226A (de)
EP (1) EP0708116B1 (de)
JP (1) JP3819957B2 (de)
KR (1) KR100397862B1 (de)
CN (2) CN1069907C (de)
AT (1) ATE210686T1 (de)
CA (1) CA2161061C (de)
DE (1) DE69524532T2 (de)
ES (1) ES2168105T3 (de)
FI (1) FI955017A (de)
FR (1) FR2725993B1 (de)
NO (1) NO315052B1 (de)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE59601827D1 (de) * 1995-02-24 1999-06-10 Basf Ag Verfahren zur herstellung von polymerisaten von vinylaromatischen verbindungen unter verwendung von polymere enthaltenden katalysatorsystemen
HUP9600824A3 (en) * 1995-03-29 1997-11-28 Union Carbide Chem Plastic Ethylene polymer and film
US5965477A (en) * 1997-02-21 1999-10-12 Council Of Scientific & Industrial Research Process for the preparation of supported metallocene catalyst
EP0878483B1 (de) * 1997-03-27 2008-03-12 Council of Scientific and Industrial Research Verfahren zur Polymerisation und Copolymerisation von Olefinen
DE69735755T2 (de) * 1997-05-14 2007-04-12 Council Of Scientific And Industrial Research Verfahren zur Polymerisation von Olefinen
FR2765225B1 (fr) * 1997-06-30 2000-01-14 Atochem Elf Sa Composante catalytique solide pour la polymerisation des olefines
CN1261460C (zh) * 2001-09-11 2006-06-28 埃克森美孚化学专利公司 制备聚烯烃的方法
EP1293589A3 (de) * 2001-09-17 2004-10-13 Nissan Motor Company, Limited Anlage zur Vorbehandlung vor dem Lackieren
US8080699B2 (en) * 2009-08-28 2011-12-20 Chemtura Corporation Two-stage process and system for forming high viscosity polyalphaolefins
JP5480147B2 (ja) 2007-10-16 2014-04-23 中国石化揚子石油化工有限公司 担持非メタロセン触媒およびその製造方法
EP2202246B1 (de) 2007-10-16 2016-06-15 Sinopec Yangzi Petrochemical Company Ltd. Durch eine magnesiumverbindung gestützter nicht-metallocen-katalysator und verfahren zu seiner herstellung
EP2251362A1 (de) * 2009-05-07 2010-11-17 Total Petrochemicals Research Feluy Aktivierung von Trägern mit kontrollierter Verteilung von OH-Gruppen
EP2500365B1 (de) 2009-11-13 2020-05-06 China Petroleum & Chemical Corporation Geträgerter nicht-metallocen-katalysator sowie verfahren zu seiner herstellung und verwendung
JP5670465B2 (ja) 2009-11-13 2015-02-18 中國石油化工股▲分▼有限公司 担持型非メタロセン触媒、その製造方法およびその使用
WO2014078919A1 (pt) 2012-11-26 2014-05-30 Braskem S.A. Catalisador metaloceno suportado em suporte híbrido, processo de obtenção do mesmo, processo de polimerização para obtenção de um homopolímero ou copolímero de etileno com distribuição de massa molar ampla ou bimodal, uso do catalisador de metaloceno suportado e polímero de etileno com distribuição de massa molar ampla ou bimodal
EP2816064B1 (de) * 2013-04-19 2018-12-26 LG Chem, Ltd. Polyethylen mit gesteuertem wachsgehalt, chloriertes polyethylen daraus und daraus hergestelltes formprodukt
KR101597421B1 (ko) 2013-04-19 2016-02-24 주식회사 엘지화학 왁스 함량이 조절된 폴리에틸렌, 이의 염소화 폴리에틸렌 및 이로부터 제조된 성형품

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3166542A (en) * 1960-01-18 1965-01-19 Cabot Corp Surface treated inorganic solid polymerization catalyst and method of polymerization therewith
US3243421A (en) * 1963-07-31 1966-03-29 Cabot Corp Catalysts for polymerization
GB1400453A (en) * 1971-07-21 1975-07-16 Ici Ltd Copolymerisation of olefins
IT951956B (it) * 1971-12-27 1973-07-10 Sir Soc Italiana Resine Spa Procedimento per la polimerizzazio ne di olefine
US4043941A (en) * 1975-11-26 1977-08-23 Emery Industries, Inc. Supported transition metal catalysts and process for their preparation
SU589209A1 (ru) * 1976-04-05 1978-01-25 Институт Физической Химии Им. Л.В.Писаржевского Ан Украинской Сср Способ получени высокодисперсных окислов металлов
JPS5846838A (ja) * 1981-09-14 1983-03-18 株式会社東芝 直流高電圧発生装置
US4459372A (en) * 1982-08-25 1984-07-10 Uop Inc. Surface-metallated refractory inorganic oxides, method of their preparation and catalyst supported on the oxides
JPS59174557A (ja) * 1983-03-18 1984-10-03 三井造船株式会社 多孔質セラミツクスの製造方法
US5202398A (en) * 1987-06-05 1993-04-13 Hoechst Aktiengesellschaft Process for the preparation of a 1-olefin polymer
DE3718888A1 (de) * 1987-06-05 1988-12-22 Hoechst Ag Verfahren zur herstellung eines 1-olefinpolymers
EP0426643B1 (de) * 1989-10-30 1995-12-27 Fina Research S.A. Verfahren zur Herstellung von Metallocenen
US5117020A (en) * 1989-10-30 1992-05-26 Fina Research, S.A. Process for the preparation of metallocenes
US5075394A (en) * 1990-06-07 1991-12-24 Phillips Petroleum Company Olefin polymerization using supported pentadienyl derivative-transition metal complexes
JP2957242B2 (ja) * 1990-07-26 1999-10-04 三菱化学株式会社 オレフィン重合用触媒およびその製造法ならびにオレフィン重合体の製造法
US5466766A (en) * 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
EP0585512B1 (de) * 1992-08-31 1999-01-13 Fina Research S.A. Katalysatorkomponente für Olefinpolymerisation
EP0587440A3 (de) * 1992-09-10 1995-03-08 Nippon Oil Co Ltd Katalysatorbestandteil für Olefinpolymerisation und Olefinpolymerisationsverfahren unter Anwendung derselben.
US5332706A (en) * 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
FI96611C (fi) * 1993-09-10 1996-07-25 Neste Oy Heterogeeninen polymerointikatalyytti ja menetelmä sen valmistamiseksi

Also Published As

Publication number Publication date
FI955017A (fi) 1996-04-22
KR960014170A (ko) 1996-05-22
EP0708116B1 (de) 2001-12-12
ATE210686T1 (de) 2001-12-15
JP3819957B2 (ja) 2006-09-13
NO315052B1 (no) 2003-06-30
FR2725993B1 (fr) 1996-11-29
JPH08301918A (ja) 1996-11-19
FI955017A0 (fi) 1995-10-20
CN1131676A (zh) 1996-09-25
CA2161061A1 (fr) 1996-04-22
EP0708116A1 (de) 1996-04-24
FR2725993A1 (fr) 1996-04-26
CN1148387C (zh) 2004-05-05
NO954148D0 (no) 1995-10-18
DE69524532D1 (de) 2002-01-24
KR100397862B1 (ko) 2003-12-11
ES2168105T3 (es) 2002-06-01
CA2161061C (fr) 2007-01-09
CN1309139A (zh) 2001-08-22
CN1069907C (zh) 2001-08-22
US5739226A (en) 1998-04-14
NO954148L (no) 1996-04-22

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Representative=s name: PATENTANWAELTE GESTHUYSEN, VON ROHR & EGGERT, 45128