ES2168105T3 - Componente catalitico solido, que contiene circonio y agrupamientos ciclo-alcadienilo, su procedimiento de obtencion y procedimiento para la polimerizacion de olefinas en su presencia. - Google Patents
Componente catalitico solido, que contiene circonio y agrupamientos ciclo-alcadienilo, su procedimiento de obtencion y procedimiento para la polimerizacion de olefinas en su presencia.Info
- Publication number
- ES2168105T3 ES2168105T3 ES95402085T ES95402085T ES2168105T3 ES 2168105 T3 ES2168105 T3 ES 2168105T3 ES 95402085 T ES95402085 T ES 95402085T ES 95402085 T ES95402085 T ES 95402085T ES 2168105 T3 ES2168105 T3 ES 2168105T3
- Authority
- ES
- Spain
- Prior art keywords
- procedure
- olefins
- polymerization
- catalytic component
- circony
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
LA COMPONENTE CATALITICA SEGUN LA INVENCION SE OBTIENE POR A) TRATAMIENTO DE UN SOPORTE DE COMPONENTE CATALITICA POR ZRCL4 O HFCL4 EN FASE GASEOSA, SEGUIDO POR B) TRATAMIENTO POR UNA SOLUCION O SUSPENSION DE UN COMPUESTO CAPAZ DE INJERTAR UN GRUPO AL ESQUELETO CICLOALCADIENILO AL ZR O HF CONTENIDO EN EL SOPORTE. LA POLIMERIZACION DE LAS OLEFINAS EN PRESENCIA DE TAL COMPONENTE CATALITICA LLEVA POLIMEROS EN BAJAS POLIMOLECULARIDADES CON PRODUCTIVIDADES ELEVADAS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9412604A FR2725993B1 (fr) | 1994-10-21 | 1994-10-21 | Composante catalytique solide contenant du zirconium et des groupements cycloalcadienyles, son procede d'obtention et procede de polymerisation des olefines en sa presence |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2168105T3 true ES2168105T3 (es) | 2002-06-01 |
Family
ID=9468083
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES95402085T Expired - Lifetime ES2168105T3 (es) | 1994-10-21 | 1995-09-15 | Componente catalitico solido, que contiene circonio y agrupamientos ciclo-alcadienilo, su procedimiento de obtencion y procedimiento para la polimerizacion de olefinas en su presencia. |
Country Status (12)
Country | Link |
---|---|
US (1) | US5739226A (es) |
EP (1) | EP0708116B1 (es) |
JP (1) | JP3819957B2 (es) |
KR (1) | KR100397862B1 (es) |
CN (2) | CN1069907C (es) |
AT (1) | ATE210686T1 (es) |
CA (1) | CA2161061C (es) |
DE (1) | DE69524532T2 (es) |
ES (1) | ES2168105T3 (es) |
FI (1) | FI955017A (es) |
FR (1) | FR2725993B1 (es) |
NO (1) | NO315052B1 (es) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE59601827D1 (de) * | 1995-02-24 | 1999-06-10 | Basf Ag | Verfahren zur herstellung von polymerisaten von vinylaromatischen verbindungen unter verwendung von polymere enthaltenden katalysatorsystemen |
DE69624398T2 (de) * | 1995-03-29 | 2003-06-12 | Univation Tech Llc | Ethylenpolymere mit enger Polydispersität und Verfahren zu ihrer Herstellung |
US5965477A (en) * | 1997-02-21 | 1999-10-12 | Council Of Scientific & Industrial Research | Process for the preparation of supported metallocene catalyst |
US5955554A (en) * | 1997-03-27 | 1999-09-21 | Council Of Scientific Industrial Research | Process for polymerization and copolymerization of olefins |
EP0878485B1 (en) * | 1997-05-14 | 2006-04-26 | Council of Scientific and Industrial Research | A process for polymerization of olefins |
FR2765225B1 (fr) * | 1997-06-30 | 2000-01-14 | Atochem Elf Sa | Composante catalytique solide pour la polymerisation des olefines |
WO2003022890A1 (en) * | 2001-09-11 | 2003-03-20 | Exxonmobil Chemical Patents Inc. | Method for preparing polyolefins |
EP1293589A3 (en) * | 2001-09-17 | 2004-10-13 | Nissan Motor Company, Limited | Apparatus for pretreatment prior to painting |
US8080699B2 (en) * | 2009-08-28 | 2011-12-20 | Chemtura Corporation | Two-stage process and system for forming high viscosity polyalphaolefins |
EP2202247B1 (en) | 2007-10-16 | 2012-12-12 | Sinopec Yangzi Petrochemical Company Ltd. | Supported non-metallocene catalyst and its preparation method |
JP5480148B2 (ja) | 2007-10-16 | 2014-04-23 | 中国石化揚子石油化工有限公司 | マグネシウム化合物担持非メタロセン触媒およびその製造 |
EP2251362A1 (en) * | 2009-05-07 | 2010-11-17 | Total Petrochemicals Research Feluy | Activating supports with controlled distribution of OH groups |
US8957169B2 (en) | 2009-11-13 | 2015-02-17 | China Petroleum & Chemical Corp. | Supported nonmetallocene catalyst, preparation and use thereof |
WO2011057469A1 (zh) | 2009-11-13 | 2011-05-19 | 中国石油化工股份有限公司 | 负载型非茂金属催化剂、其制备方法及其应用 |
BR112015011215B1 (pt) | 2012-11-26 | 2018-11-21 | Braskem S.A. | Catalisador metaloceno suportado em suporte híbrido, processo de obtenção do mesmo, processo de polimerização para obtenção de um homopolímero ou copolímero de etileno com distribuição de massa molar ampla ou bimodal, uso do catalisador de metalocenosuportado e polímero de etileno com distribuição de massa molar ampla ou bimodal |
WO2014171775A1 (ko) * | 2013-04-19 | 2014-10-23 | (주) 엘지화학 | 왁스 함량이 조절된 폴리에틸렌, 이의 염소화 폴리에틸렌 및 이로부터 제조된 성형품 |
KR101597421B1 (ko) | 2013-04-19 | 2016-02-24 | 주식회사 엘지화학 | 왁스 함량이 조절된 폴리에틸렌, 이의 염소화 폴리에틸렌 및 이로부터 제조된 성형품 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3166542A (en) * | 1960-01-18 | 1965-01-19 | Cabot Corp | Surface treated inorganic solid polymerization catalyst and method of polymerization therewith |
US3243421A (en) * | 1963-07-31 | 1966-03-29 | Cabot Corp | Catalysts for polymerization |
GB1400453A (en) * | 1971-07-21 | 1975-07-16 | Ici Ltd | Copolymerisation of olefins |
IT951956B (it) * | 1971-12-27 | 1973-07-10 | Sir Soc Italiana Resine Spa | Procedimento per la polimerizzazio ne di olefine |
US4043941A (en) * | 1975-11-26 | 1977-08-23 | Emery Industries, Inc. | Supported transition metal catalysts and process for their preparation |
SU589209A1 (ru) * | 1976-04-05 | 1978-01-25 | Институт Физической Химии Им. Л.В.Писаржевского Ан Украинской Сср | Способ получени высокодисперсных окислов металлов |
JPS5846838A (ja) * | 1981-09-14 | 1983-03-18 | 株式会社東芝 | 直流高電圧発生装置 |
US4459372A (en) * | 1982-08-25 | 1984-07-10 | Uop Inc. | Surface-metallated refractory inorganic oxides, method of their preparation and catalyst supported on the oxides |
JPS59174557A (ja) * | 1983-03-18 | 1984-10-03 | 三井造船株式会社 | 多孔質セラミツクスの製造方法 |
US5202398A (en) * | 1987-06-05 | 1993-04-13 | Hoechst Aktiengesellschaft | Process for the preparation of a 1-olefin polymer |
DE3718888A1 (de) * | 1987-06-05 | 1988-12-22 | Hoechst Ag | Verfahren zur herstellung eines 1-olefinpolymers |
EP0426643B1 (en) * | 1989-10-30 | 1995-12-27 | Fina Research S.A. | Process for the preparation of metallocenes |
US5117020A (en) * | 1989-10-30 | 1992-05-26 | Fina Research, S.A. | Process for the preparation of metallocenes |
US5075394A (en) * | 1990-06-07 | 1991-12-24 | Phillips Petroleum Company | Olefin polymerization using supported pentadienyl derivative-transition metal complexes |
JP2957242B2 (ja) * | 1990-07-26 | 1999-10-04 | 三菱化学株式会社 | オレフィン重合用触媒およびその製造法ならびにオレフィン重合体の製造法 |
US5466766A (en) * | 1991-05-09 | 1995-11-14 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
EP0585512B1 (en) * | 1992-08-31 | 1999-01-13 | Fina Research S.A. | Process for the preparation of an olefin polymerization catalyst component |
EP0587440A3 (en) * | 1992-09-10 | 1995-03-08 | Nippon Oil Co Ltd | Catalyst component for olefin polymerization and olefin polymerization processes using the same. |
US5332706A (en) * | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
FI96611C (fi) * | 1993-09-10 | 1996-07-25 | Neste Oy | Heterogeeninen polymerointikatalyytti ja menetelmä sen valmistamiseksi |
-
1994
- 1994-10-21 FR FR9412604A patent/FR2725993B1/fr not_active Expired - Fee Related
-
1995
- 1995-09-15 DE DE69524532T patent/DE69524532T2/de not_active Expired - Lifetime
- 1995-09-15 ES ES95402085T patent/ES2168105T3/es not_active Expired - Lifetime
- 1995-09-15 AT AT95402085T patent/ATE210686T1/de not_active IP Right Cessation
- 1995-09-15 EP EP95402085A patent/EP0708116B1/fr not_active Expired - Lifetime
- 1995-10-14 KR KR1019950035494A patent/KR100397862B1/ko not_active IP Right Cessation
- 1995-10-18 US US08/544,699 patent/US5739226A/en not_active Expired - Lifetime
- 1995-10-18 NO NO19954148A patent/NO315052B1/no unknown
- 1995-10-19 CN CN95118720A patent/CN1069907C/zh not_active Expired - Fee Related
- 1995-10-20 JP JP27308095A patent/JP3819957B2/ja not_active Expired - Fee Related
- 1995-10-20 FI FI955017A patent/FI955017A/fi not_active Application Discontinuation
- 1995-10-20 CA CA002161061A patent/CA2161061C/fr not_active Expired - Fee Related
-
2000
- 2000-12-18 CN CNB00135552XA patent/CN1148387C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JPH08301918A (ja) | 1996-11-19 |
KR100397862B1 (ko) | 2003-12-11 |
FI955017A0 (fi) | 1995-10-20 |
CA2161061A1 (fr) | 1996-04-22 |
FI955017A (fi) | 1996-04-22 |
NO954148L (no) | 1996-04-22 |
FR2725993B1 (fr) | 1996-11-29 |
NO954148D0 (no) | 1995-10-18 |
JP3819957B2 (ja) | 2006-09-13 |
EP0708116B1 (fr) | 2001-12-12 |
NO315052B1 (no) | 2003-06-30 |
DE69524532T2 (de) | 2002-07-04 |
CN1309139A (zh) | 2001-08-22 |
CN1148387C (zh) | 2004-05-05 |
FR2725993A1 (fr) | 1996-04-26 |
EP0708116A1 (fr) | 1996-04-24 |
KR960014170A (ko) | 1996-05-22 |
DE69524532D1 (de) | 2002-01-24 |
ATE210686T1 (de) | 2001-12-15 |
CN1131676A (zh) | 1996-09-25 |
CN1069907C (zh) | 2001-08-22 |
CA2161061C (fr) | 2007-01-09 |
US5739226A (en) | 1998-04-14 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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