DE69510061D1 - Fotochrome verbindungen mit einer spiro(indolin-(2,3')-benzoxazin) struktur, die in position 6' eine cyano- oder benzylsulfonylgruppe und in 7',8' des benzoxazins einen kondenzierten benzolring enthält, und ihre verwendung in der ophthalmischen optik - Google Patents
Fotochrome verbindungen mit einer spiro(indolin-(2,3')-benzoxazin) struktur, die in position 6' eine cyano- oder benzylsulfonylgruppe und in 7',8' des benzoxazins einen kondenzierten benzolring enthält, und ihre verwendung in der ophthalmischen optikInfo
- Publication number
- DE69510061D1 DE69510061D1 DE69510061T DE69510061T DE69510061D1 DE 69510061 D1 DE69510061 D1 DE 69510061D1 DE 69510061 T DE69510061 T DE 69510061T DE 69510061 T DE69510061 T DE 69510061T DE 69510061 D1 DE69510061 D1 DE 69510061D1
- Authority
- DE
- Germany
- Prior art keywords
- benzoxazine
- spiro
- cyano
- indolin
- condensed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 150000001875 compounds Chemical class 0.000 title abstract 3
- CMLFRMDBDNHMRA-UHFFFAOYSA-N 2h-1,2-benzoxazine Chemical compound C1=CC=C2C=CNOC2=C1 CMLFRMDBDNHMRA-UHFFFAOYSA-N 0.000 title 1
- -1 BENZYL SULFONYL GROUP Chemical group 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical group C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical class N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 title 1
- LPAGFVYQRIESJQ-UHFFFAOYSA-N indoline Chemical compound C1=CC=C2NCCC2=C1 LPAGFVYQRIESJQ-UHFFFAOYSA-N 0.000 title 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 125000003170 phenylsulfonyl group Chemical group C1(=CC=CC=C1)S(=O)(=O)* 0.000 abstract 1
- 125000003003 spiro group Chemical group 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 125000004434 sulfur atom Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D498/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D498/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
- C07D498/10—Spiro-condensed systems
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/685—Compositions containing spiro-condensed pyran compounds or derivatives thereof, as photosensitive substances
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Eyeglasses (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9409449A FR2723218A1 (fr) | 1994-07-29 | 1994-07-29 | Composes photochromiques de structure spiro (indoline-(2,3')-benzoxazine) a groupement cyano en 6', et leur utilisation dans le domaine de l'optique ophtalmique |
PCT/FR1995/001031 WO1996004590A1 (fr) | 1994-07-29 | 1995-07-31 | Composes photochromiques de structure spiro[indoline-[2,3']-benzoxazine] a groupement cyano ou phenylsulfonyl en 6' et comportant un cycle benzenique condense en 7', 8' du noyau benzoxazine, et leur utilisation dans le domaine de l'optique ophtalmique |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69510061D1 true DE69510061D1 (de) | 1999-07-08 |
DE69510061T2 DE69510061T2 (de) | 1999-12-09 |
Family
ID=9465904
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69510061T Expired - Fee Related DE69510061T2 (de) | 1994-07-29 | 1995-07-31 | Fotochrome verbindungen mit einer spiro(indolin-(2,3')-benzoxazin) struktur, die in position 6' eine cyano- oder benzylsulfonylgruppe und in 7',8' des benzoxazins einen kondenzierten benzolring enthält, und ihre verwendung in der ophthalmischen optik |
Country Status (9)
Country | Link |
---|---|
US (1) | US5936016A (de) |
EP (1) | EP0772798B1 (de) |
JP (1) | JPH10503764A (de) |
AT (1) | ATE180899T1 (de) |
AU (1) | AU3117795A (de) |
DE (1) | DE69510061T2 (de) |
ES (1) | ES2135077T3 (de) |
FR (1) | FR2723218A1 (de) |
WO (1) | WO1996004590A1 (de) |
Families Citing this family (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2751971B1 (fr) * | 1996-07-31 | 1998-11-20 | Essilor Int | Nouvelles spirooxazines homoazaadamantane et leur utilisation dans le domaine de l'optique ophtalmique |
FR2763070B1 (fr) * | 1997-05-06 | 1999-07-02 | Essilor Int | Nouveaux composes photochromiques spirooxazines, leur utilisation dans le domaine de l'optique ophtalmique |
US6478989B1 (en) | 1997-09-19 | 2002-11-12 | Transitions Optical, Inc. | Aromatic substituted naphthopyrans |
GB9722127D0 (en) * | 1997-10-20 | 1997-12-17 | James Robinson Ltd | Photochromic compounds |
AU6485799A (en) * | 1998-11-02 | 2000-05-22 | Skyrad Ltd. | Photochromic articles |
EP1044978A3 (de) * | 1999-03-24 | 2001-05-09 | Corning S.A. | 1-N-Alkyl-5'-[(N'-(un)substitutierte)amido]spiroindolinonaphthoxazine, deren Herstellung, Zubereitungen und diese enthaltenden (Co)polymer-Matrizen |
EP1044979A3 (de) * | 1999-03-24 | 2001-05-09 | Corning S.A. | 1-[(N-(Un)substitutierte)amidoalkyl]spiroindolinonaphthoxazine, deren Herstellung, Zubereitungen und diese enthaltende (Co)polymer-Matrizen |
FR2792010B1 (fr) | 1999-04-08 | 2001-07-27 | Essilor Int | Procede de coloration d'un article transparent en polycarbonate et article obtenu |
US6224945B1 (en) | 1999-08-02 | 2001-05-01 | Essilor International Compagnie Generale D'optique | Process for the manufacture of a crosslinked, transparent, hydrophilic and photochromic polymeric material, and optical and ophthalmic articles obtained |
FR2797266B1 (fr) * | 1999-08-02 | 2004-06-18 | Essilor Int | Procede de fabrication d'un materiau polymere reticule, transparent, hydrophile et photochromique, et article d'optique et ophtalmique obtenu |
AU770553B2 (en) * | 1999-08-02 | 2004-02-26 | Essilor International Compagnie Generale D'optique | Process for the manufacture of a crosslinked, transparent, hydrophilic and photochromic polymeric material, and optical and ophthalmic article obtained |
US6348604B1 (en) | 1999-09-17 | 2002-02-19 | Ppg Industries Ohio, Inc. | Photochromic naphthopyrans |
US6296785B1 (en) | 1999-09-17 | 2001-10-02 | Ppg Industries Ohio, Inc. | Indeno-fused photochromic naphthopyrans |
EP1287044A4 (de) * | 1999-10-22 | 2004-12-15 | Novartis Ag | Sterile, photochrome, hydrophile kontaktlinsen |
US6340766B1 (en) | 2000-01-12 | 2002-01-22 | Transition Optical, Inc. | Substituted napthopyrans |
JP2003530400A (ja) | 2000-04-06 | 2003-10-14 | イエダ・リサーチ・アンド・デベロツプメント・カンパニー・リミテツド | 光互変性スピロ(インドリン)ナフトキサジン類 |
US6572794B1 (en) | 2000-07-24 | 2003-06-03 | Essilor International Compagnie Generale D'optique | Method of manufacturing a photochromic molded article |
FR2816950B1 (fr) | 2000-11-17 | 2003-02-14 | Essilor Int | Procede d'obtention d'un latex photochromique |
JP2002153414A (ja) * | 2000-11-17 | 2002-05-28 | Asahi Optical Co Ltd | 電子内視鏡及び電子内視鏡システム |
FR2819258B1 (fr) | 2001-01-11 | 2003-04-11 | Essilor Int | Procede d'obtention d'un latex photochromique stabilise, latex obtenu et application a l'optique ophtalmique |
US6734440B2 (en) | 2001-02-27 | 2004-05-11 | Questel Adhesives | Sunlight dosage indicator |
FR2850658B1 (fr) | 2003-02-03 | 2005-04-22 | Essilor Int | Procede de preparation d'articles moules par photopolymerisation sous un rayonnement visible ou dans le proche uv |
US7262295B2 (en) * | 2003-03-20 | 2007-08-28 | Transitions Optical, Inc. | Indeno-fused photochromic naphthopyrans, naphthols and photochromic articles |
US7641337B2 (en) * | 2006-12-22 | 2010-01-05 | Bausch & Lomb Incorporated | Ophthalmic lens including photochromic material |
JP5645045B2 (ja) * | 2008-09-02 | 2014-12-24 | 株式会社リコー | フォトクロミック組成物、画像表示媒体および画像形成装置 |
JP5459528B2 (ja) * | 2008-09-02 | 2014-04-02 | 株式会社リコー | フォトクロミック組成物、画像表示媒体及び画像形成装置 |
US8697770B2 (en) | 2010-04-13 | 2014-04-15 | Johnson & Johnson Vision Care, Inc. | Pupil-only photochromic contact lenses displaying desirable optics and comfort |
US8877103B2 (en) | 2010-04-13 | 2014-11-04 | Johnson & Johnson Vision Care, Inc. | Process for manufacture of a thermochromic contact lens material |
US9690115B2 (en) | 2010-04-13 | 2017-06-27 | Johnson & Johnson Vision Care, Inc. | Contact lenses displaying reduced indoor glare |
ES2612697T3 (es) | 2013-09-20 | 2017-05-18 | Essilor International (Compagnie Générale d'Optique) | Artículo óptico con fotocromatismo con gradiente |
US11293876B2 (en) * | 2017-06-29 | 2022-04-05 | Tokai University Education System | Fluid measurement method, fluid measurement device, and measurement system |
US11724471B2 (en) | 2019-03-28 | 2023-08-15 | Johnson & Johnson Vision Care, Inc. | Methods for the manufacture of photoabsorbing contact lenses and photoabsorbing contact lenses produced thereby |
US20220244428A1 (en) * | 2019-06-27 | 2022-08-04 | Menicon Co., Ltd. | Ophthalmic medical instrument including photochromic polymer and production method for ophthalmic medical instrument |
WO2023208941A1 (en) | 2022-04-26 | 2023-11-02 | Essilor International | Photochromic optical article having a mirror coating |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1186987A (en) * | 1967-08-30 | 1970-04-08 | Fuji Photo Film Co Ltd | Photochromic Compounds |
US4342668A (en) * | 1978-09-08 | 1982-08-03 | American Optical Corporation | Photochromic compounds |
US4286957A (en) * | 1979-01-10 | 1981-09-01 | Essilor International "Cie Generale D'optique" | Process of integrating a photochromic substance into an ophthalmic lens and a photochromic lens of organic material |
US4880667A (en) * | 1985-09-24 | 1989-11-14 | Ppg Industries, Inc. | Photochromic plastic article and method for preparing same |
GB8610709D0 (en) * | 1986-05-01 | 1986-06-04 | Plinkington Bros Plc | Photochromic lenses |
JPS63175094A (ja) * | 1987-01-16 | 1988-07-19 | Toray Ind Inc | ホトクロミック性を有する組成物 |
JPS63250381A (ja) * | 1987-04-06 | 1988-10-18 | Seiko Epson Corp | フオトクロミツク化合物 |
JPS63275587A (ja) * | 1987-05-01 | 1988-11-14 | Toray Ind Inc | スピロナフトオキサジン化合物 |
IT1223067B (it) * | 1987-11-05 | 1990-09-12 | Enichem Sintesi | Composto fotocromatico ed articoli fotocromatici che lo contengono |
US4931220A (en) * | 1987-11-24 | 1990-06-05 | Ppg Industries, Inc. | Organic photochromic pigment particulates |
JPH01170904A (ja) * | 1987-12-25 | 1989-07-06 | Toray Ind Inc | フォトクロミック性を有する偏光シート |
US5000878A (en) * | 1989-02-24 | 1991-03-19 | American Optical Corporation | Photochromic articles with thermally stable photocolorability |
JPH02243694A (ja) * | 1989-03-15 | 1990-09-27 | Mitsubishi Kasei Corp | スピロオキサジン系化合物及び該化合物を使用した感光材料 |
FR2647789B1 (fr) * | 1989-06-05 | 1994-07-22 | Essilor Int | Composes photochromiques de type indolino-spiro-oxazine, leur procede de preparation, compositions et articles photochromiques contenant de tels composes |
FR2647790A1 (fr) * | 1989-06-05 | 1990-12-07 | Essilor Int | Composes photochromiques de type indolino-spiro-oxazine, leur procede de preparation, compositions et articles photochromiques contenant de tels composes |
JPH0366692A (ja) * | 1989-08-07 | 1991-03-22 | Mitsubishi Kasei Corp | スピロオキサジン系化合物及び該化合物を使用した感光材料 |
JPH0381278A (ja) * | 1989-08-22 | 1991-04-05 | Citizen Watch Co Ltd | フォトクロミック化合物 |
JP2856818B2 (ja) * | 1990-02-26 | 1999-02-10 | 株式会社トクヤマ | スピロオキサジン化合物及びその製造方法 |
GB9225347D0 (en) * | 1992-12-03 | 1993-01-27 | Pilkington Plc | Photo reactive material |
-
1994
- 1994-07-29 FR FR9409449A patent/FR2723218A1/fr active Pending
-
1995
- 1995-07-31 DE DE69510061T patent/DE69510061T2/de not_active Expired - Fee Related
- 1995-07-31 WO PCT/FR1995/001031 patent/WO1996004590A1/fr not_active Application Discontinuation
- 1995-07-31 US US08/776,025 patent/US5936016A/en not_active Expired - Fee Related
- 1995-07-31 AU AU31177/95A patent/AU3117795A/en not_active Abandoned
- 1995-07-31 JP JP8506258A patent/JPH10503764A/ja active Pending
- 1995-07-31 EP EP95927001A patent/EP0772798B1/de not_active Revoked
- 1995-07-31 ES ES95927001T patent/ES2135077T3/es not_active Expired - Lifetime
- 1995-07-31 AT AT95927001T patent/ATE180899T1/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
ATE180899T1 (de) | 1999-06-15 |
EP0772798B1 (de) | 1999-06-02 |
US5936016A (en) | 1999-08-10 |
EP0772798A1 (de) | 1997-05-14 |
ES2135077T3 (es) | 1999-10-16 |
AU3117795A (en) | 1996-03-04 |
JPH10503764A (ja) | 1998-04-07 |
WO1996004590A1 (fr) | 1996-02-15 |
DE69510061T2 (de) | 1999-12-09 |
FR2723218A1 (fr) | 1996-02-02 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8363 | Opposition against the patent | ||
8339 | Ceased/non-payment of the annual fee |