DE69506203T2 - Selektive Hydrierung von einfach und mehrfach ungesättigten Kohlenwasserstoffen enthaltende Fraktionen - Google Patents
Selektive Hydrierung von einfach und mehrfach ungesättigten Kohlenwasserstoffen enthaltende FraktionenInfo
- Publication number
- DE69506203T2 DE69506203T2 DE69506203T DE69506203T DE69506203T2 DE 69506203 T2 DE69506203 T2 DE 69506203T2 DE 69506203 T DE69506203 T DE 69506203T DE 69506203 T DE69506203 T DE 69506203T DE 69506203 T2 DE69506203 T2 DE 69506203T2
- Authority
- DE
- Germany
- Prior art keywords
- reactor
- catalyst
- static mixer
- fluids
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims description 33
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 33
- 238000005984 hydrogenation reaction Methods 0.000 title claims description 26
- 239000003054 catalyst Substances 0.000 claims description 50
- 230000003068 static effect Effects 0.000 claims description 43
- 239000012530 fluid Substances 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 27
- 230000008569 process Effects 0.000 claims description 25
- 239000004215 Carbon black (E152) Substances 0.000 claims description 22
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 19
- 239000001257 hydrogen Substances 0.000 claims description 19
- 229910052739 hydrogen Inorganic materials 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 16
- 238000011144 upstream manufacturing Methods 0.000 claims description 10
- 239000007791 liquid phase Substances 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 32
- 238000006243 chemical reaction Methods 0.000 description 16
- 239000007788 liquid Substances 0.000 description 14
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 10
- 238000004458 analytical method Methods 0.000 description 7
- 239000007792 gaseous phase Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 230000006866 deterioration Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 230000009466 transformation Effects 0.000 description 4
- 238000009826 distribution Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- UEXCJVNBTNXOEH-UHFFFAOYSA-N Ethynylbenzene Chemical group C#CC1=CC=CC=C1 UEXCJVNBTNXOEH-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 238000004523 catalytic cracking Methods 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000003889 chemical engineering Methods 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000012552 review Methods 0.000 description 2
- 238000004230 steam cracking Methods 0.000 description 2
- KLYCPFXDDDMZNQ-UHFFFAOYSA-N Benzyne Chemical compound C1=CC#CC=C1 KLYCPFXDDDMZNQ-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- IYABWNGZIDDRAK-UHFFFAOYSA-N allene Chemical compound C=C=C IYABWNGZIDDRAK-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- MWWATHDPGQKSAR-UHFFFAOYSA-N propyne Chemical group CC#C MWWATHDPGQKSAR-UHFFFAOYSA-N 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
- C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
- C07C7/163—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation
- C07C7/167—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation for removal of compounds containing a triple carbon-to-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G70/00—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
- C10G70/02—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by hydrogenation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9410943A FR2724390B1 (fr) | 1994-09-08 | 1994-09-08 | Hydrogenation selective de coupes hydrocarbonees renfermant des hydrocarbures monoinsatures et polyinsatures |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69506203D1 DE69506203D1 (de) | 1999-01-07 |
| DE69506203T2 true DE69506203T2 (de) | 1999-09-02 |
Family
ID=9466917
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69506203T Expired - Lifetime DE69506203T2 (de) | 1994-09-08 | 1995-08-21 | Selektive Hydrierung von einfach und mehrfach ungesättigten Kohlenwasserstoffen enthaltende Fraktionen |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5817901A (OSRAM) |
| EP (1) | EP0700984B1 (OSRAM) |
| JP (1) | JP3658656B2 (OSRAM) |
| KR (1) | KR100336724B1 (OSRAM) |
| DE (1) | DE69506203T2 (OSRAM) |
| ES (1) | ES2127488T3 (OSRAM) |
| FR (1) | FR2724390B1 (OSRAM) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19719833A1 (de) * | 1997-05-12 | 1998-11-19 | Basf Ag | Verfahren zur katalytischen Gasphasenhydrierung von Olefinen |
| FR2810991B1 (fr) * | 2000-06-28 | 2004-07-09 | Inst Francais Du Petrole | Procede pour l'hydrogenation de coupes contenant des hydrocarbures et notamment des molecules insaturees contenant au moins deux doubles liaisons ou au moins une triple liaison |
| US6632414B2 (en) * | 2001-03-30 | 2003-10-14 | Corning Incorporated | Mini-structured catalyst beds for three-phase chemical processing |
| US7109378B2 (en) * | 2001-08-30 | 2006-09-19 | Air Products And Chemicals, Inc. | Monolith catalytic reactor coupled to static mixer |
| DE50201084D1 (de) * | 2001-12-11 | 2004-10-28 | Crompton Gmbh | Verfahren zur Hydrierung von ungesättigten Übergangsmetallverbindungen |
| US7244868B2 (en) | 2002-06-25 | 2007-07-17 | Shell Oil Company | Process for the dehydrogenation of an unsaturated hydrocarbon |
| US7153807B2 (en) * | 2003-03-04 | 2006-12-26 | Exxon Mobil Chemical Patents Inc. | Catalysts for selective hydrogenation of alkynes and alkadienes |
| US7038097B2 (en) * | 2003-03-04 | 2006-05-02 | Exxonmobil Chemical Patents Inc. | Dual bed process using two different catalysts for selective hydrogenation of acetylene and dienes |
| DE102004021128A1 (de) * | 2004-04-29 | 2005-11-24 | Oxeno Olefinchemie Gmbh | Vorrichtung und Verfahren für die kontinuierliche Umsetzung einer Flüssigkeit mit einem Gas an einem festen Katalysator |
| US20060009666A1 (en) * | 2004-07-08 | 2006-01-12 | Abb Lummus Global, Inc. | Hydrogenation of aromatics and olefins using a mesoporous catalyst |
| MY147674A (en) * | 2007-06-21 | 2012-12-31 | Basf Se | Reactor for performing a three-phase reaction of a fluid and a gaseous phase on a packed bed catalyst |
| EP2147931A1 (en) * | 2008-07-24 | 2010-01-27 | LANXESS Inc. | Process for the continuous hydrogenation of carbon-carbon double bonds in an unsaturated polymer |
| CN102241558B (zh) * | 2011-05-13 | 2014-02-19 | 中国化学赛鼎宁波工程有限公司 | 一种苯选择性加氢制备环己烯反应装置及工艺 |
| US9162938B2 (en) | 2012-12-11 | 2015-10-20 | Chevron Lummus Global, Llc | Conversion of triacylglycerides-containing oils to hydrocarbons |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB866395A (en) * | 1959-01-09 | 1961-04-26 | Bayer Ag | A process for the selective hydrogenation of unsaturated compounds present in c -fractions |
| US3492220A (en) * | 1962-06-27 | 1970-01-27 | Pullman Inc | Hydrotreating pyrolysis gasoline |
| US3493492A (en) * | 1964-06-19 | 1970-02-03 | Lummus Co | Hydrotreating of pyrolysis gasoline (dripolene) |
| US4713424A (en) * | 1984-11-05 | 1987-12-15 | Phillips Petroleum Company | Polymerization of olefinic hydrocarbons and complex-initiator therefor |
| US4570025A (en) * | 1985-06-14 | 1986-02-11 | Phillips Petroleum Company | Preparation of alkenes and cycloalkenes |
| CH664552A5 (de) * | 1985-07-18 | 1988-03-15 | Sulzer Ag | Keramischer koerper sowie verfahren und form zur herstellung desselben. |
| US4883846A (en) * | 1987-04-20 | 1989-11-28 | The Dow Chemical Company | Anionic polymerization of purified monovinylidene aromatic monomer feed stock |
| WO1990002603A1 (de) * | 1988-09-02 | 1990-03-22 | Gebrüder Sulzer Aktiengesellschaft | Vorrichtung zur durchführung katalysierter reaktionen |
| JPH03181338A (ja) * | 1989-12-11 | 1991-08-07 | Gebr Sulzer Ag | 触媒エレメントおよび触媒反応用反応器 |
| US5156816A (en) * | 1990-10-04 | 1992-10-20 | Fina Technology, Inc. | System for purifying styrene monomer feedstock using ethylbenzene dehydrogenation waste gas |
| FR2686617B1 (fr) * | 1992-01-28 | 1994-03-18 | Institut Francais Petrole | Procede d'hydrogenation selective de charge hydrocarbonee avec des lets catalytiques mis en óoeuvre successivement. |
| US5488024A (en) * | 1994-07-01 | 1996-01-30 | Phillips Petroleum Company | Selective acetylene hydrogenation |
-
1994
- 1994-09-08 FR FR9410943A patent/FR2724390B1/fr not_active Expired - Fee Related
-
1995
- 1995-08-21 DE DE69506203T patent/DE69506203T2/de not_active Expired - Lifetime
- 1995-08-21 EP EP95401920A patent/EP0700984B1/fr not_active Expired - Lifetime
- 1995-08-21 ES ES95401920T patent/ES2127488T3/es not_active Expired - Lifetime
- 1995-09-07 US US08/524,573 patent/US5817901A/en not_active Expired - Lifetime
- 1995-09-07 KR KR1019950029276A patent/KR100336724B1/ko not_active Expired - Fee Related
- 1995-09-08 JP JP23157895A patent/JP3658656B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| FR2724390B1 (fr) | 1996-12-13 |
| EP0700984B1 (fr) | 1998-11-25 |
| KR100336724B1 (ko) | 2002-11-02 |
| FR2724390A1 (fr) | 1996-03-15 |
| JPH0892572A (ja) | 1996-04-09 |
| DE69506203D1 (de) | 1999-01-07 |
| EP0700984A3 (OSRAM) | 1996-04-10 |
| US5817901A (en) | 1998-10-06 |
| EP0700984A2 (fr) | 1996-03-13 |
| JP3658656B2 (ja) | 2005-06-08 |
| ES2127488T3 (es) | 1999-04-16 |
| KR960010832A (ko) | 1996-04-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8363 | Opposition against the patent | ||
| 8365 | Fully valid after opposition proceedings | ||
| 8328 | Change in the person/name/address of the agent |
Representative=s name: VONNEMANN, KLOIBER & KOLLEGEN, 80796 MUENCHEN |
|
| 8327 | Change in the person/name/address of the patent owner |
Owner name: IFP ENERGIES NOUVELLES, RUEIL-MALMAISON, FR |
|
| 8328 | Change in the person/name/address of the agent |
Representative=s name: VONNEMANN, KLOIBER & KOLLEGEN, 81667 MUENCHEN |