DE69424918T2 - Rauhlederartiges Kunstleder - Google Patents

Rauhlederartiges Kunstleder

Info

Publication number
DE69424918T2
DE69424918T2 DE69424918T DE69424918T DE69424918T2 DE 69424918 T2 DE69424918 T2 DE 69424918T2 DE 69424918 T DE69424918 T DE 69424918T DE 69424918 T DE69424918 T DE 69424918T DE 69424918 T2 DE69424918 T2 DE 69424918T2
Authority
DE
Germany
Prior art keywords
suede
artificial leather
leather
artificial
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69424918T
Other languages
English (en)
Other versions
DE69424918D1 (de
Inventor
Tetsuya Ashida
Hisao Yoneda
Tuyosi Yamasaki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kuraray Co Ltd
Original Assignee
Kuraray Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kuraray Co Ltd filed Critical Kuraray Co Ltd
Application granted granted Critical
Publication of DE69424918D1 publication Critical patent/DE69424918D1/de
Publication of DE69424918T2 publication Critical patent/DE69424918T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/12Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H11/00Non-woven pile fabrics
    • D04H11/08Non-woven pile fabrics formed by creation of a pile on at least one surface of a non-woven fabric without addition of pile-forming material, e.g. by needling, by differential shrinking
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0004Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using ultra-fine two-component fibres, e.g. island/sea, or ultra-fine one component fibres (< 1 denier)
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0065Organic pigments, e.g. dyes, brighteners
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/903Microfiber, less than 100 micron diameter
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/904Artificial leather
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/23907Pile or nap type surface or component
    • Y10T428/23986With coating, impregnation, or bond
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24438Artificial wood or leather grain surface
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • Y10T428/24595Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness and varying density
    • Y10T428/24603Fiber containing component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • Y10T428/24612Composite web or sheet

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
DE69424918T 1993-10-29 1994-10-28 Rauhlederartiges Kunstleder Expired - Fee Related DE69424918T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP27178993 1993-10-29

Publications (2)

Publication Number Publication Date
DE69424918D1 DE69424918D1 (de) 2000-07-20
DE69424918T2 true DE69424918T2 (de) 2000-10-12

Family

ID=17504878

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69424918T Expired - Fee Related DE69424918T2 (de) 1993-10-29 1994-10-28 Rauhlederartiges Kunstleder

Country Status (6)

Country Link
US (1) US5503899A (de)
EP (1) EP0651090B1 (de)
KR (1) KR0180949B1 (de)
CN (1) CN1067451C (de)
DE (1) DE69424918T2 (de)
TW (1) TW257814B (de)

Families Citing this family (64)

* Cited by examiner, † Cited by third party
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US6322851B1 (en) * 1998-06-30 2001-11-27 Kuraray Co., Ltd. Manufacturing process for leather-like sheet
JP4128312B2 (ja) 1999-02-24 2008-07-30 株式会社クラレ 表面立毛を有する皮革様シート
TWI223019B (en) 1999-03-16 2004-11-01 Kuraray Co Artificial leather sheet substrate and production process thereof
US6479153B1 (en) * 1999-03-30 2002-11-12 Kuraray Co., Ltd. Process for producing a leather-like sheet
JP4204707B2 (ja) * 1999-07-05 2009-01-07 株式会社クラレ 人工皮革用繊維質基体およびこれを用いた人工皮革
TW476834B (en) 1999-08-23 2002-02-21 Kuraray Co Oil tone artificial leather sheet
TW491757B (en) * 2000-06-19 2002-06-21 Kuraray Co Abrasive sheet for texturing and method of producing same
US20030124935A1 (en) * 2000-07-06 2003-07-03 Nicole Smith Scrub pad with printed rigid plates and associated methods
US6962739B1 (en) * 2000-07-06 2005-11-08 Higher Dimension Medical, Inc. Supple penetration resistant fabric and method of making
US6743273B2 (en) 2000-09-05 2004-06-01 Donaldson Company, Inc. Polymer, polymer microfiber, polymer nanofiber and applications including filter structures
CN101469462A (zh) * 2000-09-05 2009-07-01 唐纳森公司 聚合物,聚合物微米/纳米纤维和包括过滤器结构的用途
US6815378B1 (en) * 2000-09-08 2004-11-09 Polymer Group, Inc. Abrasion resistant and drapeable nonwoven fabric
JP2002294571A (ja) * 2001-03-30 2002-10-09 Kuraray Co Ltd 難燃性皮革様シート基体およびその製造方法
JP4212787B2 (ja) * 2001-07-02 2009-01-21 株式会社クラレ 皮革様シート
DE10132255A1 (de) * 2001-07-04 2003-01-23 Achter Viktor Gmbh & Co Kg Kunstwildleder und ein Herstellungsverfahren hierfür
DE60238998D1 (de) * 2001-07-31 2011-03-03 Kuraray Co Lederartiges flächengebilde und verfahren zu dessen herstellung
TWI230216B (en) * 2002-03-11 2005-04-01 San Fang Chemical Industry Co Manufacture method for artificial leather composite reinforced with ultra-fine fiber non-woven fabric
WO2003097924A1 (fr) * 2002-05-20 2003-11-27 Kuraray Co.,Ltd. Article sous forme de nappe et procede de preparation de cet article
EP1371774B1 (de) * 2002-06-12 2005-12-28 Kuraray Co., Ltd. Flammfestes, lederartiges bahnenförmiges Substrat und Verfahren zu seiner Herstellung
CN100402714C (zh) * 2002-06-18 2008-07-16 三芳化学工业股份有限公司 微多孔超细纤维基布及其制法
DE10231453A1 (de) 2002-07-11 2004-02-12 Viktor Achter Gmbh & Co Kg Lederimitat mit Polyurethan-Beschichtung
KR100607899B1 (ko) * 2002-08-05 2006-08-03 가부시키가이샤 구라레 피혁 유사 시트 및 그 제조방법
KR101027365B1 (ko) * 2002-08-22 2011-04-11 데이진 고도레 가부시키가이샤 피혁형 시트상물 및 그 제조 방법
TWI247834B (en) * 2003-01-13 2006-01-21 San Fang Chemical Industry Co Method for artificial leather
CN1325722C (zh) * 2003-02-07 2007-07-11 可乐丽股份有限公司 仿麂皮风格的类似皮革的片材及其制造方法
US20040191412A1 (en) * 2003-03-11 2004-09-30 San Fang Chemical Industry Co., Ltd. Process for making ultra micro fiber artificial leather
KR100601767B1 (ko) * 2003-08-28 2006-07-19 가부시키가이샤 구라레 인공 피혁 및 그 제조 방법
TWI285697B (en) * 2003-12-29 2007-08-21 San Fang Chemical Industry Co Flameproof environmentally friendly artificial leather and process for making the same
TW200521167A (en) * 2003-12-31 2005-07-01 San Fang Chemical Industry Co Polymer sheet material and method for making the same
TWI245704B (en) * 2003-12-31 2005-12-21 San Fang Chemical Industry Co Sheet made of high molecular material and method for making same
US20060249244A1 (en) * 2004-01-09 2006-11-09 San Fang Chemical Industry Co. Ltd. Method for producing environmental friendly artificial leather product
US20070207687A1 (en) * 2004-05-03 2007-09-06 San Fang Chemical Industry Co., Ltd. Method for producing artificial leather
US20050244654A1 (en) * 2004-05-03 2005-11-03 San Fang Chemical Industry Co. Ltd. Artificial leather
TWI285590B (en) * 2005-01-19 2007-08-21 San Fang Chemical Industry Co Moisture-absorbing, quick drying, thermally insulating, elastic composite and method for making
US20060272770A1 (en) * 2004-08-24 2006-12-07 San Fang Chemical Industry Co., Ltd. Method for making artificial leather with superficial texture
TWI293094B (en) * 2004-08-24 2008-02-01 San Fang Chemical Industry Co Artificial leather with real feeling and method thereof
TWI275679B (en) * 2004-09-16 2007-03-11 San Fang Chemical Industry Co Artificial leather materials having elongational elasticity
US20080149264A1 (en) * 2004-11-09 2008-06-26 Chung-Chih Feng Method for Making Flameproof Environmentally Friendly Artificial Leather
US20080095945A1 (en) * 2004-12-30 2008-04-24 Ching-Tang Wang Method for Making Macromolecular Laminate
TWI301166B (en) * 2005-03-30 2008-09-21 San Fang Chemical Industry Co Manufacturing method for environment friendly artificial leather made from ultramicro fiber without solvent treatment
TWI297049B (en) * 2005-05-17 2008-05-21 San Fang Chemical Industry Co Artificial leather having ultramicro fiber in conjugate fiber of substrate
TW200641193A (en) * 2005-05-27 2006-12-01 San Fang Chemical Industry Co A polishing panel of micro fibers and its manufacturing method
WO2006134966A1 (ja) * 2005-06-17 2006-12-21 Kuraray Co., Ltd. 人工皮革用基材およびその製造方法
US20080187715A1 (en) * 2005-08-08 2008-08-07 Ko-Feng Wang Elastic Laminate and Method for Making The Same
EP1930495B1 (de) * 2005-09-30 2011-05-04 Kuraray Co., Ltd. Lederartiges bahnenmaterial und herstellungsverfahren dafür
WO2007069628A1 (ja) 2005-12-14 2007-06-21 Kuraray Co., Ltd. 人工皮革用基材およびその基材を用いた人工皮革
US20070155268A1 (en) * 2005-12-30 2007-07-05 San Fang Chemical Industry Co., Ltd. Polishing pad and method for manufacturing the polishing pad
US20080220701A1 (en) * 2005-12-30 2008-09-11 Chung-Ching Feng Polishing Pad and Method for Making the Same
TWI286583B (en) * 2006-03-15 2007-09-11 San Fang Chemical Industry Co Artificial leather with even pressing grain and the manufacturing method thereof
US8349232B2 (en) 2006-03-28 2013-01-08 North Carolina State University Micro and nanofiber nonwoven spunbonded fabric
TWI302575B (en) * 2006-12-07 2008-11-01 San Fang Chemical Industry Co Manufacturing method for ultrafine carbon fiber by using core and sheath conjugate melt spinning
TW200825244A (en) 2006-12-13 2008-06-16 San Fang Chemical Industry Co Flexible artificial leather and its manufacturing method
KR101161490B1 (ko) 2007-06-06 2012-07-12 하이어 디멘션 머티리얼즈, 인크. 절단, 마멸 및/또는 관통 내성을 가진 니트 장갑
CN101886315B (zh) * 2009-05-11 2012-01-11 浙江梅盛实业股份有限公司 高仿真麂皮面料的制造工艺
EP2439331B1 (de) * 2009-06-04 2014-04-16 Kolon Industries, Inc Kunstleder und herstellungsverfahren dafür
US9394630B2 (en) * 2009-09-03 2016-07-19 Toray Industries, Inc. Pilling-resistant artificial leather
CA2801077C (en) * 2010-06-08 2018-01-09 Dow Global Technologies Llc Partially impregnated, fiber reinforced thermoplastic strength member
CN103154358B (zh) * 2010-09-29 2014-12-31 可隆工业株式会社 人造革及其制造方法
US20160215444A1 (en) * 2013-09-30 2016-07-28 Kuraray Co., Ltd. Napped artificial leather and production method thereof
CN103628267B (zh) * 2013-12-04 2015-09-30 北京富泰革基布股份有限公司 聚酰胺纤维和聚酯纤维复合合成革及加工工艺
TWI666359B (zh) 2014-03-31 2019-07-21 日商東麗股份有限公司 染色人工皮革及其製造方法
KR102255796B1 (ko) * 2014-03-31 2021-05-25 도레이 카부시키가이샤 인공 피혁과 그의 제조 방법
CN108976408A (zh) * 2018-07-27 2018-12-11 辽宁银珠化纺集团有限公司 一种阳离子易染尼龙66树脂及其制备方法
JP7249352B2 (ja) * 2018-08-27 2023-03-30 株式会社クラレ 人工皮革基材、その製造方法及び立毛人工皮革

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JP2905538B2 (ja) * 1990-03-08 1999-06-14 株式会社クラレ 繊維質シート
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TWI427374B (zh) * 2006-12-27 2014-02-21 Fujifilm Corp 遲延度補償元件、垂直配向向列型液晶顯示裝置、及液晶投影機

Also Published As

Publication number Publication date
KR0180949B1 (ko) 1999-04-01
EP0651090B1 (de) 2000-06-14
EP0651090A1 (de) 1995-05-03
TW257814B (de) 1995-09-21
US5503899A (en) 1996-04-02
CN1116669A (zh) 1996-02-14
KR950011757A (ko) 1995-05-16
CN1067451C (zh) 2001-06-20
DE69424918D1 (de) 2000-07-20

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