DE69412623T2 - Verfahren zur Herstellung von Oligomeren von alpha-Olefinen - Google Patents
Verfahren zur Herstellung von Oligomeren von alpha-OlefinenInfo
- Publication number
- DE69412623T2 DE69412623T2 DE69412623T DE69412623T DE69412623T2 DE 69412623 T2 DE69412623 T2 DE 69412623T2 DE 69412623 T DE69412623 T DE 69412623T DE 69412623 T DE69412623 T DE 69412623T DE 69412623 T2 DE69412623 T2 DE 69412623T2
- Authority
- DE
- Germany
- Prior art keywords
- oligomers
- preparation
- alpha olefins
- olefins
- alpha
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004711 α-olefin Substances 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0212—Alkoxylates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0237—Amines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/62—Chromium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2800793 | 1993-02-17 | ||
JP10308493 | 1993-04-28 | ||
JP28606893 | 1993-10-20 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69412623D1 DE69412623D1 (de) | 1998-09-24 |
DE69412623T2 true DE69412623T2 (de) | 1998-12-24 |
Family
ID=27286034
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69412623T Expired - Lifetime DE69412623T2 (de) | 1993-02-17 | 1994-02-16 | Verfahren zur Herstellung von Oligomeren von alpha-Olefinen |
DE69403972T Expired - Lifetime DE69403972T3 (de) | 1993-02-17 | 1994-02-16 | Verfahren zur Herstellung von Zusammensetzungen von Oligemeren von Alpha-Olefinen |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69403972T Expired - Lifetime DE69403972T3 (de) | 1993-02-17 | 1994-02-16 | Verfahren zur Herstellung von Zusammensetzungen von Oligemeren von Alpha-Olefinen |
Country Status (8)
Country | Link |
---|---|
US (1) | US5750817A (de) |
EP (2) | EP0706983B1 (de) |
KR (1) | KR100289103B1 (de) |
DE (2) | DE69412623T2 (de) |
MY (1) | MY115304A (de) |
SA (1) | SA94140723B1 (de) |
SG (1) | SG40042A1 (de) |
TW (1) | TW354300B (de) |
Families Citing this family (70)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5376612A (en) * | 1989-08-10 | 1994-12-27 | Phillips Petroleum Company | Chromium catalysts and process for making chromium catalysts |
TW279167B (de) * | 1993-03-12 | 1996-06-21 | Sumitomo Chemical Co | |
US5910619A (en) * | 1994-06-21 | 1999-06-08 | Mitsubishi Chemical Corporation | Process for producing α-olefin oligomers |
JP3613642B2 (ja) | 1994-09-05 | 2005-01-26 | 住友化学株式会社 | 1−ヘキセンの製造方法 |
KR100414008B1 (ko) * | 1995-03-02 | 2004-04-29 | 미쓰비시 가가꾸 가부시키가이샤 | α-올레핀올리고머의제조방법 |
EP0861854A4 (de) * | 1996-08-21 | 2000-10-18 | Japan Polyolefins Co Ltd | Verfahren zur herstellung von ethylenischem polymer |
KR19980075888A (ko) * | 1997-04-03 | 1998-11-16 | 정몽혁 | 알파올레핀 저중합체의 제조방법 |
FR2764524B1 (fr) * | 1997-06-17 | 1999-07-16 | Inst Francais Du Petrole | Composition catalytique et procede pour l'oligomerisation de l'ethylene, en particulier en butene-1 et/ou hexene-1 |
US20020182124A1 (en) | 1997-10-14 | 2002-12-05 | William M. Woodard | Olefin production process |
US20010053742A1 (en) * | 1998-12-18 | 2001-12-20 | Ronald D. Knudsen | Catalyst and processes for olefin trimerization |
US6380451B1 (en) | 1999-12-29 | 2002-04-30 | Phillips Petroleum Company | Methods for restoring the heat transfer coefficient of an oligomerization reactor |
US7396970B1 (en) * | 2000-11-03 | 2008-07-08 | Chevron Phillips Chemical Company Lp | Monitoring and control of processes for making 1-hexene |
FR2833191B1 (fr) * | 2001-12-10 | 2004-08-20 | Inst Francais Du Petrole | Composition catalytique et procede ameliores pour l'oligomerisation de l'ethylene, en particulier en hexene-1 |
JP4266827B2 (ja) | 2001-12-20 | 2009-05-20 | サソル テクノロジー (ピーティーワイ)リミテッド | クロムを主成分とした触媒を使用したオレフィン類の三量化およびオリゴマー化 |
TW200502038A (en) * | 2003-03-14 | 2005-01-16 | Chevron Phillips Chemical Co | Process to decrease or eliminate corrosion from the decomposition of halide containing olefin catalysts |
US20050187418A1 (en) * | 2004-02-19 | 2005-08-25 | Small Brooke L. | Olefin oligomerization |
US20050187098A1 (en) * | 2004-02-20 | 2005-08-25 | Knudsen Ronald D. | Methods of preparation of an olefin oligomerization catalyst |
US9550841B2 (en) | 2004-02-20 | 2017-01-24 | Chevron Phillips Chemical Company Lp | Methods of preparation of an olefin oligomerization catalyst |
US7384886B2 (en) * | 2004-02-20 | 2008-06-10 | Chevron Phillips Chemical Company Lp | Methods of preparation of an olefin oligomerization catalyst |
US20070043181A1 (en) * | 2005-08-19 | 2007-02-22 | Knudsen Ronald D | Methods of preparation of an olefin oligomerization catalyst |
US7414006B2 (en) * | 2005-03-09 | 2008-08-19 | Exxonmobil Chemical Patents Inc. | Methods for oligomerizing olefins |
JP5448142B2 (ja) * | 2005-03-09 | 2014-03-19 | エクソンモービル・ケミカル・パテンツ・インク | オレフィンのオリゴマー化 |
EP1752433B1 (de) * | 2005-08-10 | 2012-10-03 | Linde AG | Verbessertes Trocknungsverfahren linearer Alpha-Olefine |
EP1754694A1 (de) * | 2005-08-10 | 2007-02-21 | Linde AG | Verfahren zur Desaktivierung und Entfernung von Katalysatorbestandteilen aus der Ethylenoligomerisierung |
US8003839B2 (en) * | 2006-02-03 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Process for generating linear apha olefin comonomers |
US7982085B2 (en) * | 2006-02-03 | 2011-07-19 | Exxonmobil Chemical Patents Inc. | In-line process for generating comonomer |
WO2007092136A2 (en) * | 2006-02-03 | 2007-08-16 | Exxonmobil Chemical Patents, Inc. | Process for generating alpha olefin comonomers |
US8404915B2 (en) * | 2006-08-30 | 2013-03-26 | Exxonmobil Chemical Patents Inc. | Phosphine ligand-metal compositions, complexes, and catalysts for ethylene trimerizations |
EP2114974A1 (de) * | 2007-01-08 | 2009-11-11 | ExxonMobil Chemical Patents Inc. | Verfahren zur oligomerisierung von olefinen mit chrom-pyridinether-katalysatoren |
US20080182951A1 (en) * | 2007-01-08 | 2008-07-31 | Ackerman Lily J | Chromium Pyridine Bis(Oxazoline) And Related Catalysts For Ethylene Dimerization |
WO2008085655A1 (en) * | 2007-01-08 | 2008-07-17 | Exxonmobil Chemical Patents Inc. | Methods for oligomerizing olefins with chromium pyridine mono-oxazoline catalysts |
EP2114973A1 (de) * | 2007-01-08 | 2009-11-11 | ExxonMobil Chemical Patents Inc. | Verfahren zur oligomerisierung von olefinen mit chrom-pyridinthioether-katalysatoren |
MY150515A (en) * | 2007-11-28 | 2014-01-30 | Linde Ag | Catalyst composition and process for oligomerization of ethylene |
US7902415B2 (en) * | 2007-12-21 | 2011-03-08 | Chevron Phillips Chemical Company Lp | Processes for dimerizing or isomerizing olefins |
CA2639870A1 (en) * | 2008-09-29 | 2010-03-29 | Nova Chemicals Corporation | Trimerization |
CA2639882C (en) * | 2008-09-29 | 2016-07-12 | Nova Chemicals Corporation | Tetramerization |
WO2010092554A1 (en) * | 2009-02-16 | 2010-08-19 | Sasol Technology (Pty) Limited | Oligomerisation of olefinic compounds in the presence of an activated oligomerisation catalyst |
WO2010110801A1 (en) * | 2009-03-27 | 2010-09-30 | Exxonmobil Chemical Patents Inc. | Olefin oligomerization reaction processes exhibiting reduced fouling |
EP2488473B1 (de) | 2009-10-16 | 2013-12-25 | Sasol Technology (Proprietary) Limited | Abscheidung von komponenten aus einem ethylen enthaltenden mehrkomponentigen kohlenwasserstoffstrom |
WO2012062469A1 (en) | 2010-11-10 | 2012-05-18 | Stichting Dutch Polymer Institute | Ethylene oligomerization catalyst |
US9586872B2 (en) | 2011-12-30 | 2017-03-07 | Chevron Phillips Chemical Company Lp | Olefin oligomerization methods |
CA2765429C (en) | 2012-01-25 | 2019-12-31 | Nova Chemicals Corporation | P-n-p ligand |
CN104284714B (zh) | 2012-05-09 | 2016-06-29 | 沙索技术有限公司 | 用于使烃低聚以形成至少一种共聚单体产物的方法 |
EP2847149B1 (de) | 2012-05-09 | 2022-01-12 | Sasol Technology (Proprietary) Limited | Oligomerisierung von olefinischen verbindungen mit verminderter polymerbildung |
CA2866773A1 (en) | 2012-05-09 | 2013-11-14 | Sasol Technology (Proprietary) Limited | Tetramerisation of ethylene |
BR112014027792B1 (pt) | 2012-05-09 | 2020-03-24 | Sasol Technology (Pty) Ltd | Tetramerização de etileno |
WO2013168098A1 (en) | 2012-05-09 | 2013-11-14 | Sasol Technology (Proprietary) Limited | Separation of components from a multi-component hydrocarbon stream |
NL1039868C2 (en) | 2012-11-01 | 2014-05-06 | Stichting Dutch Polymer Inst | Process for producing an oligo(alpha-olefin) and the use of a particular form of methylaluminoxane in such process. |
CA2908608C (en) | 2013-05-09 | 2021-03-09 | Sasol Technology (Proprietary) Limited | Tetramerisation of ethylene |
BR112015027058B1 (pt) | 2013-05-09 | 2021-09-14 | Sasol Technology (Proprietary) Limited | Processo de oligomerização de etileno em misturas de 1-hexeno e 1-octeno |
CA2908588C (en) | 2013-05-09 | 2021-08-17 | Sasol Technology (Proprietary) Limited | Oligomerisation of ethylene to mixtures of 1-hexene and 1-octene |
US9175109B1 (en) | 2014-05-20 | 2015-11-03 | Chevron Phillips Chemical Company Lp | Oligomerization processes and polymer compositions produced therefrom |
US9505675B2 (en) | 2015-02-09 | 2016-11-29 | Chevron Phillips Chemical Company Lp | Deactivation of a process by-product |
BR112017019416B1 (pt) | 2015-03-13 | 2023-05-02 | Dow Global Technologies Llc | Composição e processo para preparar uma composição |
RU2682668C1 (ru) * | 2015-03-27 | 2019-03-20 | Мицубиси Кемикал Корпорейшн | СПОСОБ ДЛЯ ПРОИЗВОДСТВА НИЗКОМОЛЕКУЛЯРНОГО ПОЛИМЕРА α-ОЛЕФИНА |
WO2017010998A1 (en) | 2015-07-14 | 2017-01-19 | Chevron Phillips Chemical Company Lp | Olefin compositions |
KR102058142B1 (ko) * | 2015-09-02 | 2019-12-20 | 주식회사 엘지화학 | 리간드 화합물, 올레핀 올리고머화용 촉매계, 및 이를 이용한 올레핀 올리고머화 방법 |
US10519077B2 (en) | 2015-09-18 | 2019-12-31 | Chevron Phillips Chemical Company Lp | Ethylene oligomerization/trimerization/tetramerization reactor |
US10513473B2 (en) | 2015-09-18 | 2019-12-24 | Chevron Phillips Chemical Company Lp | Ethylene oligomerization/trimerization/tetramerization reactor |
JP6871358B2 (ja) * | 2016-07-15 | 2021-05-12 | パブリック・ジョイント・ストック・カンパニー・“シブール・ホールディング” | オレフィンのオリゴマー化法 |
WO2018056643A1 (ko) * | 2016-09-21 | 2018-03-29 | 롯데케미칼 주식회사 | 올레핀 올리고머화용 촉매계 및 이를 이용한 올레핀 올리고머 제조방법 |
KR101880809B1 (ko) * | 2016-09-21 | 2018-08-20 | 롯데케미칼 주식회사 | 올레핀 올리고머 제조방법 |
JP6804644B2 (ja) * | 2016-11-14 | 2020-12-23 | パブリック・ジョイント・ストック・カンパニー・“シブール・ホールディング” | オレフィンオリゴマー化に使用される触媒系及びオレフィンオリゴマー化方法 |
CN111225893B (zh) * | 2017-10-11 | 2023-04-21 | 乐天化学株式会社 | 用于烯烃低聚的催化剂体系及利用其的烯烃低聚物制备方法 |
US11117846B2 (en) | 2017-10-11 | 2021-09-14 | Lotte Chemical Corporation | Catalyst system for olefin oligomerization and method for preparing olefin oligomer by using same |
WO2019113752A1 (zh) | 2017-12-11 | 2019-06-20 | 天津科技大学 | 用于乙烯选择性齐聚的催化剂体系及乙烯齐聚反应方法 |
WO2019191098A1 (en) * | 2018-03-30 | 2019-10-03 | Dow Global Technologies Llc | Olefin polymerization activators |
CN108939947B (zh) | 2018-08-06 | 2020-12-04 | 天津工业大学 | 聚偏氟乙烯和超高分子量聚乙烯共混微孔膜及其制备方法 |
FR3113054B1 (fr) | 2020-07-30 | 2022-11-04 | Ifp Energies Now | Procede d’oligomerisation d’ethylene comprenant la preparation in situ de la composition catalytique |
FR3112969B1 (fr) | 2020-07-30 | 2022-08-05 | Ifp Energies Now | Nouvelle composition catalytique a base de chrome et procede associe pour la trimerisation de l’ethylene en hexene-1 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3347840A (en) * | 1964-06-16 | 1967-10-17 | Union Carbide Corp | Polymerization process |
US4182810A (en) | 1978-04-21 | 1980-01-08 | Phillips Petroleum Company | Prevention of fouling in polymerization reactors |
JPS5964604A (ja) | 1982-10-06 | 1984-04-12 | Sumitomo Chem Co Ltd | ポリオレフインの製造方法 |
US4688838A (en) * | 1986-03-03 | 1987-08-25 | Burlington Industries, Inc. | Twister bobbin lifter and carrier |
US4668838A (en) * | 1986-03-14 | 1987-05-26 | Union Carbide Corporation | Process for trimerization |
US4853356A (en) * | 1986-03-14 | 1989-08-01 | Union Carbide Corporation | Process for trimerization |
CA2021410C (en) † | 1989-08-10 | 1998-06-02 | William Kevin Reagen | Process for olefin polymerization |
CA2020509C (en) * | 1989-08-10 | 1998-04-28 | William K. Reagen | Chromium compounds and uses thereof |
US5198563A (en) * | 1989-08-10 | 1993-03-30 | Phillips Petroleum Company | Chromium compounds and uses thereof |
US5376612A (en) * | 1989-08-10 | 1994-12-27 | Phillips Petroleum Company | Chromium catalysts and process for making chromium catalysts |
US5744677A (en) * | 1991-10-16 | 1998-04-28 | Amoco Corporation | Ethylene oligomerization |
SG112881A1 (en) * | 1992-09-17 | 2005-07-28 | Mitsubishi Chem Corp | Method for oligomerizing an alpha-olefin |
CA2087578C (en) * | 1993-01-19 | 1998-10-27 | William Kevin Reagen | Preparing catalyst for olefin polymerization |
ZA93350B (en) * | 1993-01-19 | 1993-08-25 | Phillips Petroleum Co | Preparing catalyst for olefin polymerization. |
US5859303A (en) * | 1995-12-18 | 1999-01-12 | Phillips Petroleum Company | Olefin production |
-
1994
- 1994-02-15 TW TW083101157A patent/TW354300B/zh not_active IP Right Cessation
- 1994-02-16 EP EP95116782A patent/EP0706983B1/de not_active Expired - Lifetime
- 1994-02-16 EP EP94301097A patent/EP0611743B2/de not_active Expired - Lifetime
- 1994-02-16 DE DE69412623T patent/DE69412623T2/de not_active Expired - Lifetime
- 1994-02-16 DE DE69403972T patent/DE69403972T3/de not_active Expired - Lifetime
- 1994-02-16 MY MYPI94000345A patent/MY115304A/en unknown
- 1994-02-16 SG SG1995001642A patent/SG40042A1/en unknown
- 1994-02-17 KR KR1019940003005A patent/KR100289103B1/ko not_active IP Right Cessation
- 1994-05-11 SA SA94140723A patent/SA94140723B1/ar unknown
-
1996
- 1996-03-13 US US08/614,905 patent/US5750817A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0706983A1 (de) | 1996-04-17 |
DE69412623D1 (de) | 1998-09-24 |
EP0706983B1 (de) | 1998-08-19 |
KR940019666A (ko) | 1994-09-14 |
DE69403972D1 (de) | 1997-08-07 |
DE69403972T2 (de) | 1997-10-16 |
EP0611743A2 (de) | 1994-08-24 |
MY115304A (en) | 2003-05-31 |
KR100289103B1 (ko) | 2001-05-02 |
EP0611743A3 (de) | 1994-10-19 |
TW354300B (en) | 1999-03-11 |
SA94140723B1 (ar) | 2005-06-07 |
DE69403972T3 (de) | 2000-11-02 |
EP0611743B2 (de) | 2000-08-09 |
EP0611743B1 (de) | 1997-07-02 |
US5750817A (en) | 1998-05-12 |
SG40042A1 (en) | 1997-06-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE69412623D1 (de) | Verfahren zur Herstellung von Oligomeren von alpha-Olefinen | |
DE69119011T2 (de) | Verfahren zur Herstellung von Olefinoligomeren | |
DE59302486D1 (de) | Verfahren zur Herstellung von Propenoligomeren | |
DE69511520D1 (de) | Verfahren zur Herstellung von linearen alpha-Olefinen | |
DE69432091T2 (de) | Verfahren zur Herstellung von Polycarbonatoligomeren | |
DE69403042D1 (de) | Verfahren zur Herstellung von Alkylcyclopentadienen | |
DE59403144D1 (de) | Verfahren zur Herstellung von aromatischen Olefinen | |
DE59407416D1 (de) | Verfahren zur Herstellung von N-Alkenylpyrrolidonen | |
DE69210933T2 (de) | Verfahren zur Herstellung von Alpha, Omega-Dihydroxyperfluoroalkylethylmethylpolysiloxanen | |
DE69306099D1 (de) | Verfahren zur Herstellung von Monoalkenylbenzolen | |
DE59401893D1 (de) | Verfahren zur Herstellung von Trifluormethylanilinen | |
DE59401525D1 (de) | Verfahren zur Herstellung von Acetoacetarylamiden | |
DE59402596D1 (de) | Verfahren zur Herstellung von 5-Acetoacetylaminobenzimidazolon-2 | |
DE69223818D1 (de) | Verfahren zur Herstellung von Olefinoligomer | |
DE59403834D1 (de) | Verfahren zur Herstellung von m-Chloraromaten | |
DE69404103T2 (de) | Verfahren zur Herstellung von Dibenzylaminen | |
DE59405751D1 (de) | Verfahren zur Herstellung von Aminopropionitrilen | |
DE69406222T2 (de) | Verfahren zur Herstellung von Alpha-Olefinen | |
DE69400951D1 (de) | Verfahren zur Herstellung von Dicyclopentyldichlorosilan | |
DE59400502D1 (de) | Verfahren zur Herstellung von Acylcyclopropanen | |
DE59407426D1 (de) | Verfahren zur Herstellung von Fluorbenzonitrilen | |
DE59407425D1 (de) | Verfahren zur Herstellung von Fluornitrobenzolen | |
DE69304508T2 (de) | Verfahren zur Herstellung von Monoalkenylbenzolen | |
DE69405290T2 (de) | Verfahren zur Herstellung von Diacetoxybuten | |
DE59400401D1 (de) | Verfahren zur Herstellung von 2-Amino-5-aminomethyl-pyridin |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition |