KR940019666A - α-올레핀 올리고머 및 α-올레핀 올리고머 조성물의 제조방법 - Google Patents

α-올레핀 올리고머 및 α-올레핀 올리고머 조성물의 제조방법 Download PDF

Info

Publication number
KR940019666A
KR940019666A KR1019940003005A KR19940003005A KR940019666A KR 940019666 A KR940019666 A KR 940019666A KR 1019940003005 A KR1019940003005 A KR 1019940003005A KR 19940003005 A KR19940003005 A KR 19940003005A KR 940019666 A KR940019666 A KR 940019666A
Authority
KR
South Korea
Prior art keywords
compound
olefin
amine
reaction
metal amide
Prior art date
Application number
KR1019940003005A
Other languages
English (en)
Other versions
KR100289103B1 (ko
Inventor
에이지 다나카
히사오 우라타
도시유키 오시키
다카유키 아오시마
리이치로우 가와시마
신지 이와데
히로후미 나카무라
슌지 가츠키
다케시 오카노
Original Assignee
미야베 요시카즈
미쓰비시 가세이 가부시끼가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27286034&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=KR940019666(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by 미야베 요시카즈, 미쓰비시 가세이 가부시끼가이샤 filed Critical 미야베 요시카즈
Publication of KR940019666A publication Critical patent/KR940019666A/ko
Application granted granted Critical
Publication of KR100289103B1 publication Critical patent/KR100289103B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

적어도 크롬 화합물, 아민 또는 금속 아미드 및 알킬알루미늄 화합물과 조합물을 포함하는 크롬 기제 촉매계중에서 α-올레핀을 크롬 화합물 및 알킬알루미늄 화합물이 미리 서로 접촉되지 않는 접촉방식으로 반응시킴으로써 용매중에서 α-올레핀으 올리고머화를 실시하는 것을 포함하는 α-올레핀 올리고머의 제조 방법이 기재되어 있다.

Description

α-올레핀 올리고머 및 α-올레핀 올리고머 조성물의 제조방법.
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. 적어도 크롬 화합물, 아민 또는 금속 아미드 및 알킬알루미늄 화합물과 조합물을 포함하는 크롬 기제 촉매계중에서 α-올레핀을 크롬 화합물 및 알킬알루미늄 화합물이 미리 서로 접촉되지 않는 접촉방식으로 반응시킴으로써 용매중에서 α-올레핀으 올리고머화를 실행하는 것을 포함하는 α-올레핀 올리고머의 제조 방법.
  2. 제1항에 있어서, 아민 또는 금속 아미드 및 알킬알루미늄 화합물을 함유하는 용액에 α-올레핀 및 크롬 화합물을 도입하는 방법.
  3. 제1항에 있어서, 크롬 화합물 및 아민 또는 금속 아미드를 함유하는 용액에 α-올레핀 및 알킬알루미늄 화합물을 도입하는 방법.
  4. 제1항에 있어서, 크롬 화합물을 함유하는 용액에 α-올레핀, 아민 또는 금속 아미드 및 알킬알루미늄 화합물을 도입하는 방법.
  5. 제1항에 있어서, 알킬알루미늄 화합물을 함유하는 용액에 α-올레핀, 크롬 화합물 및 아민 또는 금속 아미드를 도입하는 방법.
  6. 제1항에 있어서, 크롬 화합물, 아민 또는 금속 아미드, 알킬알루미늄 화합물 및 α-올레핀을 반응기에 동시에 및 별도로 도입하는 방법.
  7. 제1항에 있어서, (a) 크롬 화합물, (b) 아민 또는 금속아미드, 및 (c) 알킬알루미늄 화합물의 몰비가 (a):(b):(c)=1:2 내지 4:4 내지 8이고 또 반응이 0 내지 70℃의 온도에서 실시되는 방법.
  8. 제1항에 있어서, 반응이 비-배위 루이스 산 함유 화합물 존재하에 실시되는 방법.
  9. 제1항에 있어서, 반응이 비-콘쥬게이트형 디엔 화합물 존재하에 실시되는 방법.
  10. 제1항에 있어서, 반응이 방향족 탄화수소 화합물 존재하에 실시되는 방법.
  11. 적어도 크롬 화합물, 아민 또는 금속 아미드 및 알킬알루미늄 화합물및 하기 일반식(6) 또는 (7)로 표시되는 비-배위 루이스산 함유 화합물의 조합물을 포함하는 크롬 기제 촉매계중에서 α-올레핀을 반응시킴으로써 용매중에서 α-올레핀의 올리고머화를 실시하는 것을 포함하는 α-올레핀 올리고머의 제조 방법.
    상기식에서, M1및 M2는 각각 주기율표의 IIIB, IVB, VB 및 VIB족 원소로 구성된 군으로부터 선정된 원소이고; R1내지 R7은 각각 유기 기 무기 기 또는 음이온 원자이며; 또 [L]+는 주기율표의 IA, VIIA, VIII, IB 및 IIIB-VIB족 원소로 구성된 군으로 부터 선정된 원소를 포함한 양이온을 의미함.
  12. 제1항 또는 제11항에 있어서, 아민 또는 금속 아미드, 알킬알루미늄 화합물 및 비-배위 루이스산 함유 화합물을 함유하는 용액에 α-올레핀, 크롬 화합물 및 아민 또는 금속 아미드를 도입하는 방법.
  13. 제1항 또는 제11항에 있어서, 알킬알루미늄 화합물 및 비-배위 루이스산 함유 화합물을 함유하는 용액에 α-올레핀, 크롬 화합물 및 아민 또는 금속 아미드를 도입하는 방법.
  14. 제1항 또는 제11항에 있어서, 크롬 화합물, 아민 또는 금속 아미드 및 비-배위 루이스산 함유 화합물을 함유하는 용액에 α-올레핀 및 알킬알루미늄 화합물을 도입하는 방법.
  15. 제1항 또는 제11항에 있어서, 7개 이하의 탄소원자를 갖는 포화 탄화수소 용매 중, 0 내지 70℃의 온도에서 α-올레핀의 올리고머화 반응을 실시한 다음 반응 혼합물 중에 생긴 부생 중합체를 분리제거하여 생성물 중합체를 용융시키지 않고 α-올레핀 올리고머를 회수하는 방법.
  16. 제1항 또는 제11항에 있어서, 촉매 성분을 함유하는 반응 혼합물을 산성 또는 알칼리성 수용액과 접촉시켜 촉매 성분을 제거하는 방법.
  17. 제1항 또는 제11항에 있어서, 1-헥센의 비점보다 높은 비점을 갖는 반응 용매 중, 10㎏/㎠(G)이상의 압력하에 에틸렌을 올리고머화시켜 1-헥센을 함유하는 α-올레핀 올리고머 조성물을 수득한 다음 배기시키는 것에 의해 반응계의 압력을 3㎏/㎠(G) 이하로 감소시키며 또 그로부터 부생성물을 분리하는 것을 포함하는 1-헥센의 제조방법.
  18. 제1항 또는 제11항에 있어서, 에틸렌의 올리고머화 반응을 실시하여 1-헥센의 함량이 50중량% 이상인 α-올레핀 올리고머 조성물을 수득한 다음 상기 반응 용매 및 α-올레핀 올리고머 조성물을 함유하는 반응 혼합물로부터 1-헥센 및 반응 용매를 중류제거하고 회수된 반응 용매를 반응계로 되돌려보내는 것을 포함하는 1-헥센의 제조방법.
  19. α-올레핀의 올리고머화 반응으로부터 수득되고, 또 85중량% 이상의 1-헥센 및 10개 이상의 탄소원자를 갖는 15중량% 이하의 올리고머 및/또는 중합체를 포함하는 α-올레핀 올리고머 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940003005A 1993-02-17 1994-02-17 α-올레핀 올리고머 및 α-올레핀 올리고머 조성물의 제조방법 KR100289103B1 (ko)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
JP2800793 1993-02-17
JP93/28007 1993-02-17
FR93/28007 1993-02-17
FR93/103084 1993-04-28
JP10308493 1993-04-28
JP93/103084 1993-04-28
FR93/286068 1993-10-20
JP93/286068 1993-10-20
JP28606893 1993-10-20

Publications (2)

Publication Number Publication Date
KR940019666A true KR940019666A (ko) 1994-09-14
KR100289103B1 KR100289103B1 (ko) 2001-05-02

Family

ID=27286034

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019940003005A KR100289103B1 (ko) 1993-02-17 1994-02-17 α-올레핀 올리고머 및 α-올레핀 올리고머 조성물의 제조방법

Country Status (8)

Country Link
US (1) US5750817A (ko)
EP (2) EP0706983B1 (ko)
KR (1) KR100289103B1 (ko)
DE (2) DE69403972T3 (ko)
MY (1) MY115304A (ko)
SA (1) SA94140723B1 (ko)
SG (1) SG40042A1 (ko)
TW (1) TW354300B (ko)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR19980075888A (ko) * 1997-04-03 1998-11-16 정몽혁 알파올레핀 저중합체의 제조방법
WO2017039353A1 (ko) * 2015-09-02 2017-03-09 주식회사 엘지화학 리간드 화합물, 올레핀 올리고머화용 촉매계, 및 이를 이용한 올레핀 올리고머화 방법

Families Citing this family (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5376612A (en) * 1989-08-10 1994-12-27 Phillips Petroleum Company Chromium catalysts and process for making chromium catalysts
TW279167B (ko) * 1993-03-12 1996-06-21 Sumitomo Chemical Co
US5910619A (en) * 1994-06-21 1999-06-08 Mitsubishi Chemical Corporation Process for producing α-olefin oligomers
JP3613642B2 (ja) 1994-09-05 2005-01-26 住友化学株式会社 １−ヘキセンの製造方法
KR100414008B1 (ko) * 1995-03-02 2004-04-29 미쓰비시 가가꾸 가부시키가이샤 α-올레핀올리고머의제조방법
EP0861854A4 (en) * 1996-08-21 2000-10-18 Japan Polyolefins Co Ltd PROCESS FOR THE PREPARATION OF ETHYLENIC POLYMER
FR2764524B1 (fr) * 1997-06-17 1999-07-16 Inst Francais Du Petrole Composition catalytique et procede pour l'oligomerisation de l'ethylene, en particulier en butene-1 et/ou hexene-1
US20020182124A1 (en) 1997-10-14 2002-12-05 William M. Woodard Olefin production process
US20010053742A1 (en) * 1998-12-18 2001-12-20 Ronald D. Knudsen Catalyst and processes for olefin trimerization
US6380451B1 (en) 1999-12-29 2002-04-30 Phillips Petroleum Company Methods for restoring the heat transfer coefficient of an oligomerization reactor
US7396970B1 (en) * 2000-11-03 2008-07-08 Chevron Phillips Chemical Company Lp Monitoring and control of processes for making 1-hexene
FR2833191B1 (fr) * 2001-12-10 2004-08-20 Inst Francais Du Petrole Composition catalytique et procede ameliores pour l'oligomerisation de l'ethylene, en particulier en hexene-1
CN1606539A (zh) 2001-12-20 2005-04-13 Sasol技术股份有限公司 使用铬基催化剂的烯烃寡聚和三聚
TW200502038A (en) * 2003-03-14 2005-01-16 Chevron Phillips Chemical Co Process to decrease or eliminate corrosion from the decomposition of halide containing olefin catalysts
US20050187418A1 (en) * 2004-02-19 2005-08-25 Small Brooke L. Olefin oligomerization
US20050187098A1 (en) * 2004-02-20 2005-08-25 Knudsen Ronald D. Methods of preparation of an olefin oligomerization catalyst
US9550841B2 (en) 2004-02-20 2017-01-24 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US20070043181A1 (en) * 2005-08-19 2007-02-22 Knudsen Ronald D Methods of preparation of an olefin oligomerization catalyst
US7384886B2 (en) * 2004-02-20 2008-06-10 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US7425661B2 (en) * 2005-03-09 2008-09-16 Exxonmobil Chemicals Patents Inc. Methods for oligomerizing olefins
US7414006B2 (en) * 2005-03-09 2008-08-19 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins
EP1752433B1 (en) * 2005-08-10 2012-10-03 Linde AG Improved drying process for linear alpha-olefins
EP1754694A1 (en) * 2005-08-10 2007-02-21 Linde AG Method for deactivation and removal of catalytic components in the oligomerisation of ethylene
US7982085B2 (en) * 2006-02-03 2011-07-19 Exxonmobil Chemical Patents Inc. In-line process for generating comonomer
US8003839B2 (en) * 2006-02-03 2011-08-23 Exxonmobil Chemical Patents Inc. Process for generating linear apha olefin comonomers
EP1987047B1 (en) * 2006-02-03 2015-07-01 ExxonMobil Chemical Patents Inc. Process for generating alpha olefin comonomers
US8404915B2 (en) * 2006-08-30 2013-03-26 Exxonmobil Chemical Patents Inc. Phosphine ligand-metal compositions, complexes, and catalysts for ethylene trimerizations
WO2008085657A1 (en) * 2007-01-08 2008-07-17 Exxonmobil Chemical Patents Inc. Chromium complexes of pyridine bis (oxazoline)- ligands for ethylene dimeri zation
WO2008085658A1 (en) * 2007-01-08 2008-07-17 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins with chromium pyridine thioether catalysts
WO2008085659A1 (en) * 2007-01-08 2008-07-17 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins with chromium pyridine ether catalysts
WO2008085655A1 (en) * 2007-01-08 2008-07-17 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins with chromium pyridine mono-oxazoline catalysts
CA2703021C (en) * 2007-11-28 2015-01-20 Vugar Aliyev Catalyst composition and process for oligomerization of ethylene
US7902415B2 (en) * 2007-12-21 2011-03-08 Chevron Phillips Chemical Company Lp Processes for dimerizing or isomerizing olefins
CA2639870A1 (en) * 2008-09-29 2010-03-29 Nova Chemicals Corporation Trimerization
CA2639882C (en) * 2008-09-29 2016-07-12 Nova Chemicals Corporation Tetramerization
WO2010092554A1 (en) * 2009-02-16 2010-08-19 Sasol Technology (Pty) Limited Oligomerisation of olefinic compounds in the presence of an activated oligomerisation catalyst
US8227653B2 (en) * 2009-03-27 2012-07-24 Exxonmobil Chemical Patents Inc. Olefin oligomerization reaction processes exhibiting reduced fouling
ES2447293T3 (es) 2009-10-16 2014-03-11 Sasol Technology (Proprietary) Limited Separación de los componentes de una corriente hidrocarbonada de componentes múltiples que incluye etileno
WO2012062469A1 (en) 2010-11-10 2012-05-18 Stichting Dutch Polymer Institute Ethylene oligomerization catalyst
US9586872B2 (en) 2011-12-30 2017-03-07 Chevron Phillips Chemical Company Lp Olefin oligomerization methods
CA2765429C (en) 2012-01-25 2019-12-31 Nova Chemicals Corporation P-n-p ligand
CA2869701C (en) 2012-05-09 2020-01-07 Sasol Technology (Proprietary) Limited A process for oligomerising a hydrocarbon to form at least one co-monomer product
BR112014027665B1 (pt) 2012-05-09 2021-04-13 Sasol Technology (Proprietary) Limited Processo para separar um fluxo de hidrocarbonetos multicomponente e processo de oligomerização de etileno
KR102102347B1 (ko) 2012-05-09 2020-04-21 사솔 테크날러지 (프로프라이어터리) 리미티드 에틸렌의 사량체화
CA2866773A1 (en) 2012-05-09 2013-11-14 Sasol Technology (Proprietary) Limited Tetramerisation of ethylene
MX352923B (es) 2012-05-09 2017-12-14 Sasol Tech Pty Ltd Oligomerizacion de compuestos olefinicos con menor formacion de polimeros.
NL1039868C2 (en) 2012-11-01 2014-05-06 Stichting Dutch Polymer Inst Process for producing an oligo(alpha-olefin) and the use of a particular form of methylaluminoxane in such process.
CN105228973B (zh) 2013-05-09 2017-08-29 沙索技术有限公司 乙烯低聚成1‑己烯和1‑辛烯的混合物的低聚方法
BR112015027067B1 (pt) 2013-05-09 2020-10-06 Sasol Technology (Pty) Ltd. Processo para a tetramerização de etileno
CA2908588C (en) 2013-05-09 2021-08-17 Sasol Technology (Proprietary) Limited Oligomerisation of ethylene to mixtures of 1-hexene and 1-octene
US9175109B1 (en) 2014-05-20 2015-11-03 Chevron Phillips Chemical Company Lp Oligomerization processes and polymer compositions produced therefrom
US9505675B2 (en) 2015-02-09 2016-11-29 Chevron Phillips Chemical Company Lp Deactivation of a process by-product
WO2016149025A2 (en) 2015-03-13 2016-09-22 Dow Global Technologies Llc Phosphacycle compounds and process for preparation thereof
KR102525260B1 (ko) * 2015-03-27 2023-04-24 미쯔비시 케미컬 주식회사 α-올레핀 저중합체의 제조 방법
WO2017010998A1 (en) 2015-07-14 2017-01-19 Chevron Phillips Chemical Company Lp Olefin compositions
US10519077B2 (en) 2015-09-18 2019-12-31 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
US10513473B2 (en) 2015-09-18 2019-12-24 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
SG11201900267YA (en) * 2016-07-15 2019-02-27 Sibur Holding Public Joint Stock Co Method of oligomerization of olefins
KR101880809B1 (ko) * 2016-09-21 2018-08-20 롯데케미칼 주식회사 올레핀 올리고머 제조방법
CN109715587A (zh) * 2016-09-21 2019-05-03 乐天化学株式会社 烯烃低聚的催化剂体系和使用其制备烯烃低聚物的方法
BR112019005775B1 (pt) * 2016-11-14 2022-09-20 Public Joint Stock Company "Sibur Holding" Sistema catalisador utilizado na oligomerização de olefinas e método para a oligomerização de olefinas
US11117846B2 (en) 2017-10-11 2021-09-14 Lotte Chemical Corporation Catalyst system for olefin oligomerization and method for preparing olefin oligomer by using same
CN111225893B (zh) 2017-10-11 2023-04-21 乐天化学株式会社 用于烯烃低聚的催化剂体系及利用其的烯烃低聚物制备方法
WO2019113752A1 (zh) * 2017-12-11 2019-06-20 天津科技大学 用于乙烯选择性齐聚的催化剂体系及乙烯齐聚反应方法
JP2021519362A (ja) * 2018-03-30 2021-08-10 ダウ グローバル テクノロジーズ エルエルシー オレフィン重合活性化剤
CN108939947B (zh) 2018-08-06 2020-12-04 天津工业大学 聚偏氟乙烯和超高分子量聚乙烯共混微孔膜及其制备方法
FR3113054B1 (fr) 2020-07-30 2022-11-04 Ifp Energies Now Procede d’oligomerisation d’ethylene comprenant la preparation in situ de la composition catalytique
FR3112969B1 (fr) 2020-07-30 2022-08-05 Ifp Energies Now Nouvelle composition catalytique a base de chrome et procede associe pour la trimerisation de l’ethylene en hexene-1

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3347840A (en) * 1964-06-16 1967-10-17 Union Carbide Corp Polymerization process
US4182810A (en) 1978-04-21 1980-01-08 Phillips Petroleum Company Prevention of fouling in polymerization reactors
JPS5964604A (ja) 1982-10-06 1984-04-12 Sumitomo Chem Co Ltd ポリオレフインの製造方法
US4688838A (en) * 1986-03-03 1987-08-25 Burlington Industries, Inc. Twister bobbin lifter and carrier
US4853356A (en) * 1986-03-14 1989-08-01 Union Carbide Corporation Process for trimerization
US4668838A (en) * 1986-03-14 1987-05-26 Union Carbide Corporation Process for trimerization
CA2020509C (en) * 1989-08-10 1998-04-28 William K. Reagen Chromium compounds and uses thereof
CA2021410C (en) † 1989-08-10 1998-06-02 William Kevin Reagen Process for olefin polymerization
US5376612A (en) * 1989-08-10 1994-12-27 Phillips Petroleum Company Chromium catalysts and process for making chromium catalysts
US5198563A (en) * 1989-08-10 1993-03-30 Phillips Petroleum Company Chromium compounds and uses thereof
US5744677A (en) * 1991-10-16 1998-04-28 Amoco Corporation Ethylene oligomerization
GB2271116B (en) * 1992-09-17 1997-04-09 Mitsubishi Chem Ind Method for oligomerizing and an a-olefin
CA2087578C (en) * 1993-01-19 1998-10-27 William Kevin Reagen Preparing catalyst for olefin polymerization
ZA93350B (en) * 1993-01-19 1993-08-25 Phillips Petroleum Co Preparing catalyst for olefin polymerization.
US5859303A (en) * 1995-12-18 1999-01-12 Phillips Petroleum Company Olefin production

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR19980075888A (ko) * 1997-04-03 1998-11-16 정몽혁 알파올레핀 저중합체의 제조방법
WO2017039353A1 (ko) * 2015-09-02 2017-03-09 주식회사 엘지화학 리간드 화합물, 올레핀 올리고머화용 촉매계, 및 이를 이용한 올레핀 올리고머화 방법

Also Published As

Publication number Publication date
SA94140723B1 (ar) 2005-06-07
US5750817A (en) 1998-05-12
DE69412623T2 (de) 1998-12-24
DE69403972T3 (de) 2000-11-02
EP0611743B1 (en) 1997-07-02
EP0611743A2 (en) 1994-08-24
KR100289103B1 (ko) 2001-05-02
EP0611743B2 (en) 2000-08-09
DE69403972D1 (de) 1997-08-07
DE69412623D1 (de) 1998-09-24
TW354300B (en) 1999-03-11
EP0706983A1 (en) 1996-04-17
DE69403972T2 (de) 1997-10-16
MY115304A (en) 2003-05-31
SG40042A1 (en) 1997-06-14
EP0611743A3 (en) 1994-10-19
EP0706983B1 (en) 1998-08-19

Similar Documents

Publication Publication Date Title
KR940019666A (ko) α-올레핀 올리고머 및 α-올레핀 올리고머 조성물의 제조방법
KR950025014A (ko) 올레핀 생성에 사용되는 삼합체화 촉매 시스템의 활성을 억제하는 방법
KR900016072A (ko) 올레핀 제조 방법
AU765402B2 (en) Process for separating olefins from saturated hydrocarbons
MY129122A (en) Method for producing essentially unbranched octenes and dodecenes by oligomerising of unbranched butenes
KR20010032041A (ko) 이소부틸렌의 소중합체 제조방법
KR900006370A (ko) 유기 염화 알루미늄 촉매작용된 개선된 폴리-n-부텐의 제조방법
KR960034235A (ko) α-올레핀 올리고머의 제조방법
KR840007862A (ko) 알카디엔으로부터 알켄을 분리하는 방법
EP1247790A1 (en) Process for producing low polymer of ethylene
US4915794A (en) Process for converting internal olefins to alpha olefins
US5929297A (en) Olefin oligomerization process
EP0051328A1 (en) Process for the preparation of alcohols
US3459826A (en) Olefin oligomerization
JPS6320278B2 (ko)
KR930000444A (ko) 알킬벤젠 제조법
US4319064A (en) Olefin dimerization
KR900007893A (ko) 탄화수소-방향족 하이드 록실-함유 수지의 제조방법
RU2002110125A (ru) Олигомеризация олефинов
US4463212A (en) Selective oligomerization of olefins
AU751343B2 (en) Improved process for the production of linear alpha-olefins
KR910007846A (ko) 1,1-디클로로테트라플루오로에탄의 제조 방법
CA2001537C (en) Process for producing alpha olefins
US4511753A (en) Selective removal of vinylidene olefin from olefin mixtures
US4764297A (en) Protic solvent in a dehydrohalogenation process, the product obtained therefrom and lubricant compositions containing same

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20130118

Year of fee payment: 13

FPAY Annual fee payment

Payment date: 20140117

Year of fee payment: 14

EXPY Expiration of term