DE69301566T2 - Öliges veredlungsmittel mit hohem schmiermittelanteil - Google Patents
Öliges veredlungsmittel mit hohem schmiermittelanteilInfo
- Publication number
- DE69301566T2 DE69301566T2 DE69301566T DE69301566T DE69301566T2 DE 69301566 T2 DE69301566 T2 DE 69301566T2 DE 69301566 T DE69301566 T DE 69301566T DE 69301566 T DE69301566 T DE 69301566T DE 69301566 T2 DE69301566 T2 DE 69301566T2
- Authority
- DE
- Germany
- Prior art keywords
- filament
- finish
- composition
- weight
- branched
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000314 lubricant Substances 0.000 title claims description 26
- 239000003795 chemical substances by application Substances 0.000 title claims description 4
- 238000007670 refining Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 claims description 47
- -1 alkali metal salt Chemical class 0.000 claims description 23
- 239000002736 nonionic surfactant Substances 0.000 claims description 21
- 239000002421 finishing Substances 0.000 claims description 20
- 239000003921 oil Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 239000003381 stabilizer Substances 0.000 claims description 10
- 229910052783 alkali metal Inorganic materials 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 8
- 229920000728 polyester Polymers 0.000 claims description 7
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 6
- 239000004952 Polyamide Substances 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 229920001519 homopolymer Polymers 0.000 claims description 6
- 239000011630 iodine Substances 0.000 claims description 6
- 229910052740 iodine Inorganic materials 0.000 claims description 6
- 229920002647 polyamide Polymers 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 239000000344 soap Substances 0.000 description 23
- 235000019198 oils Nutrition 0.000 description 15
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 10
- 238000004513 sizing Methods 0.000 description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 7
- 238000011065 in-situ storage Methods 0.000 description 7
- 150000002763 monocarboxylic acids Chemical class 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 238000005303 weighing Methods 0.000 description 6
- IBKKMFMBXQARGV-UHFFFAOYSA-N [3-nonanoyloxy-2,2-bis(nonanoyloxymethyl)propyl] nonanoate Chemical compound CCCCCCCCC(=O)OCC(COC(=O)CCCCCCCC)(COC(=O)CCCCCCCC)COC(=O)CCCCCCCC IBKKMFMBXQARGV-UHFFFAOYSA-N 0.000 description 5
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 229920002125 Sokalan® Polymers 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- 238000010525 oxidative degradation reaction Methods 0.000 description 3
- 239000004584 polyacrylic acid Substances 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 159000000001 potassium salts Chemical class 0.000 description 2
- NGNZTXNWCGRXKL-UHFFFAOYSA-M potassium;16-methylheptadecanoate Chemical compound [K+].CC(C)CCCCCCCCCCCCCCC([O-])=O NGNZTXNWCGRXKL-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- GWFGDXZQZYMSMJ-UHFFFAOYSA-N Octadecansaeure-heptadecylester Natural products CCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC GWFGDXZQZYMSMJ-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- AWNFRSYMBMFGLK-UHFFFAOYSA-N [2,2-dimethyl-3-(16-methylheptadecanoyloxy)propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(C)(C)COC(=O)CCCCCCCCCCCCCCC(C)C AWNFRSYMBMFGLK-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- 229940100540 neopentyl glycol diisostearate Drugs 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- FRHNXUKHAUWMOQ-UHFFFAOYSA-M sodium;16-methylheptadecanoate Chemical compound [Na+].CC(C)CCCCCCCCCCCCCCC([O-])=O FRHNXUKHAUWMOQ-UHFFFAOYSA-M 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Lubricants (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US83774392A | 1992-02-19 | 1992-02-19 | |
| PCT/US1993/001276 WO1993017170A1 (en) | 1992-02-19 | 1993-02-12 | Oil finish with high lubricant content |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69301566D1 DE69301566D1 (de) | 1996-03-28 |
| DE69301566T2 true DE69301566T2 (de) | 1996-08-22 |
Family
ID=25275293
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69301566T Expired - Fee Related DE69301566T2 (de) | 1992-02-19 | 1993-02-12 | Öliges veredlungsmittel mit hohem schmiermittelanteil |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5370804A (en:Method) |
| EP (1) | EP0627026B1 (en:Method) |
| JP (1) | JP3253081B2 (en:Method) |
| KR (1) | KR100229828B1 (en:Method) |
| CN (2) | CN1079266A (en:Method) |
| AU (1) | AU3618493A (en:Method) |
| CA (1) | CA2130463A1 (en:Method) |
| DE (1) | DE69301566T2 (en:Method) |
| ES (1) | ES2083849T3 (en:Method) |
| MX (1) | MX9300872A (en:Method) |
| RU (1) | RU94044675A (en:Method) |
| TR (1) | TR28934A (en:Method) |
| TW (1) | TW218399B (en:Method) |
| WO (1) | WO1993017170A1 (en:Method) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6068805A (en) * | 1999-01-11 | 2000-05-30 | 3M Innovative Properties Company | Method for making a fiber containing a fluorochemical polymer melt additive and having a low melting, high solids spin finish |
| US6077468A (en) * | 1999-01-11 | 2000-06-20 | 3M Innovative Properties Company | Process of drawing fibers |
| US6117353A (en) * | 1999-01-11 | 2000-09-12 | 3M Innovative Properties Company | High solids spin finish composition comprising a hydrocarbon surfactant and a fluorochemical emulsion |
| US6537662B1 (en) | 1999-01-11 | 2003-03-25 | 3M Innovative Properties Company | Soil-resistant spin finish compositions |
| US6120695A (en) * | 1999-01-11 | 2000-09-19 | 3M Innovative Properties Company | High solids, shelf-stable spin finish composition |
| US6207088B1 (en) | 1999-01-11 | 2001-03-27 | 3M Innovative Properties Company | Process of drawing fibers through the use of a spin finish composition having a hydrocarbon sufactant, a repellent fluorochemical, and a fluorochemical compatibilizer |
| US7476352B2 (en) * | 2004-05-21 | 2009-01-13 | 3M Innovative Properties Company | Lubricated flow fiber extrusion |
| CN102876438B (zh) * | 2011-08-29 | 2014-01-22 | 孝感市江雁化工有限公司 | 一种光整液及其制备方法 |
| WO2016164777A1 (en) | 2015-04-08 | 2016-10-13 | Shaw Industries Group, Inc. | Yarn texturizing apparatus and method |
| CN108624995A (zh) * | 2018-04-25 | 2018-10-09 | 科凯精细化工（上海）有限公司 | 一种锦纶纺丝油剂的制备方法 |
| CN115552068B (zh) * | 2020-08-07 | 2024-05-10 | 电化株式会社 | 人工毛发用纤维 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1789331A (en) * | 1926-09-20 | 1931-01-20 | Standard Oil Dev Co | Method of lubricating textile machinery |
| GB325938A (en) * | 1929-01-05 | 1930-03-06 | Houghton & Co E F | Process for lubricating, conditioning and laying the fly of raw cotton |
| US2078886A (en) * | 1934-07-26 | 1937-04-27 | Celanese Corp | Mixed textile material and method of making same |
| US2298432A (en) * | 1940-12-16 | 1942-10-13 | Eastman Kodak Co | Lubrication and fugitive tinting of synthetic yarns |
| US3039895A (en) * | 1960-03-29 | 1962-06-19 | Du Pont | Textile |
| US3223623A (en) * | 1962-05-18 | 1965-12-14 | Tenneco Chem | Textile lubricants |
| US3311691A (en) * | 1963-09-26 | 1967-03-28 | Du Pont | Process for drawing a polyamide yarn |
| US3248258A (en) * | 1965-02-10 | 1966-04-26 | Du Pont | Nylon yarn treated with a finishing composition |
| NL298620A (en:Method) * | 1965-05-07 | |||
| US3503880A (en) * | 1966-10-14 | 1970-03-31 | Du Pont | Yarn |
| US3563892A (en) * | 1967-06-12 | 1971-02-16 | Du Pont | Textile-treating composition and process |
| US3575856A (en) * | 1967-07-06 | 1971-04-20 | Du Pont | Fiber lubricating composition and method |
| US3704160A (en) * | 1970-12-30 | 1972-11-28 | Fiber Industries Inc | Finish for nylon or polyester rope |
| CA1136117A (en) * | 1978-10-20 | 1982-11-23 | John D. Shepley | Process for the manufacture of tufted textile articles; lubricating oil compositions and primary backing fabrics |
| US4442249A (en) * | 1982-10-07 | 1984-04-10 | Fiber Industries, Inc. | Partially oriented polyester yarn finish |
| US4900496A (en) * | 1986-09-26 | 1990-02-13 | E. I. Du Pont De Nemours And Company | Process for making a tire cord using yarns containing a dip penetration regulator |
| US4946375A (en) * | 1987-07-15 | 1990-08-07 | E. I. Du Pont De Nemours And Company | Low temperature finish |
| US4920000A (en) * | 1989-04-28 | 1990-04-24 | E. I. Du Pont De Nemours And Company | Blend of cotton, nylon and heat-resistant fibers |
-
1993
- 1993-02-09 TW TW082100890A patent/TW218399B/zh active
- 1993-02-12 AU AU36184/93A patent/AU3618493A/en not_active Abandoned
- 1993-02-12 JP JP51490093A patent/JP3253081B2/ja not_active Expired - Fee Related
- 1993-02-12 KR KR1019940702842A patent/KR100229828B1/ko not_active Expired - Fee Related
- 1993-02-12 DE DE69301566T patent/DE69301566T2/de not_active Expired - Fee Related
- 1993-02-12 ES ES93905041T patent/ES2083849T3/es not_active Expired - Lifetime
- 1993-02-12 EP EP93905041A patent/EP0627026B1/en not_active Expired - Lifetime
- 1993-02-12 RU RU94044675/04A patent/RU94044675A/ru unknown
- 1993-02-12 CA CA002130463A patent/CA2130463A1/en not_active Abandoned
- 1993-02-12 WO PCT/US1993/001276 patent/WO1993017170A1/en active IP Right Grant
- 1993-02-18 MX MX9300872A patent/MX9300872A/es not_active IP Right Cessation
- 1993-02-18 TR TR00144/93A patent/TR28934A/xx unknown
- 1993-02-19 CN CN93103441A patent/CN1079266A/zh active Pending
- 1993-02-19 CN CNB031070396A patent/CN1307338C/zh not_active Expired - Fee Related
- 1993-09-27 US US08/126,662 patent/US5370804A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| KR950700452A (ko) | 1995-01-16 |
| CN1307338C (zh) | 2007-03-28 |
| DE69301566D1 (de) | 1996-03-28 |
| EP0627026A1 (en) | 1994-12-07 |
| EP0627026B1 (en) | 1996-02-14 |
| CN1079266A (zh) | 1993-12-08 |
| RU94044675A (ru) | 1997-05-27 |
| MX9300872A (es) | 1994-07-29 |
| JPH07504001A (ja) | 1995-04-27 |
| WO1993017170A1 (en) | 1993-09-02 |
| TR28934A (tr) | 1997-07-21 |
| AU3618493A (en) | 1993-09-13 |
| CA2130463A1 (en) | 1993-09-02 |
| TW218399B (en:Method) | 1994-01-01 |
| ES2083849T3 (es) | 1996-04-16 |
| US5370804A (en) | 1994-12-06 |
| KR100229828B1 (ko) | 1999-11-15 |
| CN1524999A (zh) | 2004-09-01 |
| JP3253081B2 (ja) | 2002-02-04 |
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