DE69231033T2 - 5-sulfonyl-substituierte benzotriazole, uv-absorber und stabilisierte mischungen - Google Patents
5-sulfonyl-substituierte benzotriazole, uv-absorber und stabilisierte mischungenInfo
- Publication number
- DE69231033T2 DE69231033T2 DE69231033T DE69231033T DE69231033T2 DE 69231033 T2 DE69231033 T2 DE 69231033T2 DE 69231033 T DE69231033 T DE 69231033T DE 69231033 T DE69231033 T DE 69231033T DE 69231033 T2 DE69231033 T2 DE 69231033T2
- Authority
- DE
- Germany
- Prior art keywords
- sulfonyl
- absorber
- substituted benzotriazole
- stabilized mixtures
- stabilized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- -1 5-SULFONYL-SUBSTITUTED BENZOTRIAZOLE Chemical class 0.000 title 1
- 239000006096 absorbing agent Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having three nitrogen atoms as the only ring hetero atoms
- C07F9/6518—Five-membered rings
- C07F9/65188—Five-membered rings condensed with carbocyclic rings or carbocyclic ring systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/16—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms condensed with carbocyclic rings or ring systems
- C07D249/18—Benzotriazoles
- C07D249/20—Benzotriazoles with aryl radicals directly attached in position 2
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1896—Compounds having one or more Si-O-acyl linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/38—Esters containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/38—Esters containing sulfur
- C08F220/387—Esters containing sulfur and containing nitrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/48—Stabilisers against degradation by oxygen, light or heat
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Biochemistry (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US65415591A | 1991-02-12 | 1991-02-12 | |
US07/828,291 US5280124A (en) | 1991-02-12 | 1992-02-05 | 5-sulfonyl-substituted benzotriazole UV-absorbers |
PCT/US1992/001081 WO1992014717A1 (en) | 1991-02-12 | 1992-02-11 | 5-sulfonyl-substituted benzotriazole uv-absorbers and stabilized compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69231033D1 DE69231033D1 (de) | 2000-06-15 |
DE69231033T2 true DE69231033T2 (de) | 2000-09-14 |
Family
ID=27096671
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69231033T Expired - Fee Related DE69231033T2 (de) | 1991-02-12 | 1992-02-11 | 5-sulfonyl-substituierte benzotriazole, uv-absorber und stabilisierte mischungen |
Country Status (10)
Country | Link |
---|---|
US (2) | US5280124A (de) |
EP (1) | EP0572554B1 (de) |
JP (1) | JP3180137B2 (de) |
KR (1) | KR0178553B1 (de) |
CA (1) | CA2098999C (de) |
DE (1) | DE69231033T2 (de) |
ES (1) | ES2146211T3 (de) |
MX (1) | MX9200602A (de) |
RU (1) | RU2127264C1 (de) |
WO (1) | WO1992014717A1 (de) |
Families Citing this family (73)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5278314A (en) * | 1991-02-12 | 1994-01-11 | Ciba-Geigy Corporation | 5-thio-substituted benzotriazole UV-absorbers |
US5280124A (en) * | 1991-02-12 | 1994-01-18 | Ciba-Geigy Corporation | 5-sulfonyl-substituted benzotriazole UV-absorbers |
CA2102477A1 (en) * | 1992-11-24 | 1994-05-25 | Paul J. Deslauriers | Compositions comprising sulfur-containing derivatives of hydroxyphenylbenzotriazole and process therefor |
US6153309A (en) * | 1994-07-01 | 2000-11-28 | Razavi; Homaune A. | UV-protected vinyl laminates |
EP0698637A3 (de) | 1994-08-22 | 1996-07-10 | Ciba Geigy Ag | Mit ausgewählten 5-substituierten Benzotriazol-UV-Absorbern stabilisierte Polyurethane |
US6015575A (en) * | 1995-03-17 | 2000-01-18 | Ciba Specialty Chemicals Corporation | Liposomogenic UV absorbers |
EP1266889A3 (de) * | 1996-07-18 | 2003-12-03 | Ciba SC Holding AG | Polyoxyalkylen substituierte und verbrückte Triazin- und Benzotriazol-derivate |
US5977219A (en) * | 1997-10-30 | 1999-11-02 | Ciba Specialty Chemicals Corporation | Benzotriazole UV absorbers having enhanced durability |
FR2755444B1 (fr) * | 1996-11-07 | 2004-10-08 | Ciba Sc Holding Ag | Composition de revetement comprenant un compose stabilisant ledit compose et son utilisation |
US6166218A (en) | 1996-11-07 | 2000-12-26 | Ciba Specialty Chemicals Corporation | Benzotriazole UV absorbers having enhanced durability |
US6059991A (en) * | 1997-12-12 | 2000-05-09 | Troy Technology Corporation, Inc. | Stabilized composition containing halopropynyl compounds |
US6235819B1 (en) * | 1997-12-31 | 2001-05-22 | Bridgestone Corporation | Process to scavenge amines in polymeric compounds by treatment with triazine derivatives and compositions therefrom |
US5938825A (en) * | 1998-05-21 | 1999-08-17 | Troy Technology Corporation Inc. | Stabilized antimicrobial compositions containing halopropynyl compounds |
US6040455A (en) * | 1999-01-21 | 2000-03-21 | Ciba Specialty Chemicals Corporation | One-pot process for the preparation of 5-sulfonyl-substituted benzotriazoles UV absorbers |
US6187845B1 (en) | 1999-05-03 | 2001-02-13 | Ciba Specialty Chemicals Corporation | Stabilized adhesive compositions containing highly soluble, red-shifted, photostable benzotriazole UV absorbers and laminated articles derived therefrom |
US6245915B1 (en) | 1999-05-03 | 2001-06-12 | Ciba Specialty Chemicals Corporation | Asymmetrical bisbenzotriazoles substituted by a perfluoroalkyl moiety |
US6268415B1 (en) | 1999-05-03 | 2001-07-31 | Ciba Specialty Chemicals Corporation | Stabilized adhesive compositions containing highly soluble, photostable benzotriazole UV absorbers and laminated articles derived therefrom |
US20040009353A1 (en) * | 1999-06-14 | 2004-01-15 | Knowles Timothy R. | PCM/aligned fiber composite thermal interface |
AU779934B2 (en) | 1999-11-16 | 2005-02-17 | Ciba Specialty Chemicals Holding Inc. | Use of benzotriazole UV absorbers |
WO2001057124A2 (en) * | 2000-02-01 | 2001-08-09 | Ciba Specialty Chemicals Holding Inc. | Method of content protection with durable uv absorbers |
US6380285B1 (en) | 2000-02-01 | 2002-04-30 | Ciba Specialty Chemicals Corporation | Bloom-resistant benzotriazole UV absorbers and compositions stabilized therewith |
US6472424B1 (en) | 2000-06-07 | 2002-10-29 | Troy Technology Corporation, Inc. | Stabilized antimicrobial compositions containing halopropynyl compounds and benzylidene camphors |
US6649770B1 (en) | 2000-11-27 | 2003-11-18 | Ciba Specialty Chemicals Corporation | Substituted 5-aryl-2-(2-hydroxyphenyl)-2H-benzotriazole UV absorbers, compositions stabilized therewith and process for preparation thereof |
US6387992B1 (en) | 2000-11-27 | 2002-05-14 | Ciba Specialty Chemicals Corporation | Substituted 5-heteroaryl-2-(2-hydroxyphenyl)-2h-benzotriazole UV absorbers, a process for preparation thereof and compositions stabilized therewith |
US6846929B2 (en) * | 2001-04-02 | 2005-01-25 | Ciba Specialty Chemicals Corporation | Benzotriazole/hals molecular combinations and compositions stabilized therewith |
EP1383832A1 (de) * | 2001-04-02 | 2004-01-28 | Ciba SC Holding AG | Stabilisierter kerzenwachs |
WO2003070819A1 (en) * | 2002-02-19 | 2003-08-28 | Ciba Specialty Chemicals Holding Inc. | Containers or films comprising hydroxyphenlbenzotriazole uv absorbers for protecting contents against the effects of uv radiation |
EP1520450B1 (de) | 2002-06-06 | 2017-08-02 | UDC Ireland Limited | Elektrolumineszierende vorrichtung |
WO2004076419A1 (en) | 2003-02-26 | 2004-09-10 | Ciba Specialty Chemicals Holding Inc. | Water compatible sterically hindered alkoxyamines and hydroxy substituted alkoxyamines |
US7153588B2 (en) * | 2003-05-30 | 2006-12-26 | 3M Innovative Properties Company | UV resistant naphthalate polyester articles |
US6974850B2 (en) * | 2003-05-30 | 2005-12-13 | 3M Innovative Properties Company | Outdoor weatherable photopolymerizable coatings |
JP4163561B2 (ja) * | 2003-06-17 | 2008-10-08 | 富士フイルム株式会社 | 色素化合物 |
US7595011B2 (en) | 2004-07-12 | 2009-09-29 | Ciba Specialty Chemicals Corporation | Stabilized electrochromic media |
US20060122293A1 (en) * | 2004-12-03 | 2006-06-08 | Rick Wilk | Ultraviolet light absorber stabilizer combination |
DE102005012056A1 (de) * | 2005-03-16 | 2006-09-28 | Basf Coatings Ag | Mehrschichtlackierungen, Verfahren zu ihrer Herstellung und deren Verwendung im Automobilbau |
US7468412B2 (en) * | 2005-10-05 | 2008-12-23 | Geo Specialty Chemicals, Inc. | Method and composition for the suppression of bloom in peroxide crosslinked polymeric articles |
WO2008000646A1 (en) * | 2006-06-27 | 2008-01-03 | Ciba Holding Inc. | Long wavelength shifted benzotriazole uv-absorbers and their use |
US8092909B2 (en) * | 2006-09-07 | 2012-01-10 | Columbia Insurance Company | Color foundation coat and color top coat paint system |
WO2009003930A1 (en) | 2007-06-29 | 2009-01-08 | Basell Poliolefine Italia S.R.L. | An irradiated polyolefin composition comprising a non - phenolic stabilizer |
BRPI0923420A2 (pt) | 2008-12-22 | 2018-10-16 | Basf Se | uso, ou método de uso, ou processo de uso de um agente de redução de fricção em combinação com um polímero enxertado , em adição a uma amida de acido graxo. |
CN102471090B (zh) | 2009-07-07 | 2015-11-25 | 巴斯夫欧洲公司 | 钾铯钨青铜颗粒 |
JP6246223B2 (ja) | 2012-10-23 | 2017-12-13 | ビーエーエスエフ エスイー | ポリマー安定剤基を含有するエチレン性不飽和オリゴマー |
US8669281B1 (en) | 2013-03-14 | 2014-03-11 | Alkermes Pharma Ireland Limited | Prodrugs of fumarates and their use in treating various diseases |
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US10294423B2 (en) | 2013-11-22 | 2019-05-21 | Polnox Corporation | Macromolecular antioxidants based on dual type moiety per molecule: structures, methods of making and using the same |
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EP3110793B1 (de) | 2014-02-24 | 2019-08-21 | Alkermes Pharma Ireland Limited | Sulfonamid und sulfinamid-prodrugs von fumaraten und deren verwendung zur behandlung verschiedener erkrankungen |
TWI483987B (zh) * | 2014-03-10 | 2015-05-11 | Sino Japan Chemical Co Ltd | 液態反應型紫外線吸收劑及其製造方法與應用 |
EP3178898B1 (de) | 2014-08-05 | 2023-10-04 | Miyoshi Oil & Fat Co., Ltd. | Additive zur verleihung von uv-absorptionsvermögen und/oder eines hohen brechungsindex für eine matrix und harzelement mit verwendung davon |
EP3201292B1 (de) * | 2014-09-30 | 2018-08-01 | Transitions Optical, Inc. | Uv-lichtabsorber |
US11401400B2 (en) | 2015-04-30 | 2022-08-02 | Tokai Optical Co., Ltd. | Plastic lens |
EP3564299B1 (de) | 2015-07-20 | 2023-09-06 | Basf Se | Flammhemmende polyolefinartikel |
EP3630693A1 (de) | 2017-06-02 | 2020-04-08 | DSM IP Assets B.V. | Wärmebeständige strahlungshärtbare beschichtungen für optische fasern |
CN111263755A (zh) * | 2017-10-31 | 2020-06-09 | 三吉油脂株式会社 | 苯并三唑化合物 |
CN111315701B (zh) | 2017-11-03 | 2022-10-14 | 科思创(荷兰)有限公司 | 包含用液体可辐射固化超吸收性聚合物组合物涂布的纤维的阻水体系 |
EP3802453A1 (de) | 2018-06-01 | 2021-04-14 | DSM IP Assets B.V. | Strahlungshärtbare zusammensetzungen zur beschichtung von optischen fasern und daraus hergestellte beschichtungen |
CN110563661B (zh) * | 2018-06-05 | 2021-08-27 | 台湾永光化学工业股份有限公司 | 具红移效应的苯并三唑紫外线吸收剂及其用途 |
CN112771108B (zh) | 2018-08-22 | 2023-05-05 | 巴斯夫欧洲公司 | 稳定的滚塑聚烯烃 |
US11964906B2 (en) | 2018-08-30 | 2024-04-23 | Covestro (Netherlands) B.V. | Radiation curable compositions for coating optical fiber |
CN113165971A (zh) | 2018-12-03 | 2021-07-23 | Ms控股有限公司 | 用于涂布光纤的填充式可辐射固化组合物以及由其产生的涂层 |
EP3941970A1 (de) | 2019-03-18 | 2022-01-26 | Basf Se | Uv-härtbare zusammensetzungen für schmutzaufnahmebeständigkeit |
JP2022533453A (ja) | 2019-05-24 | 2022-07-22 | コベストロ (ネザーランズ) ビー.ヴィー. | 強化された高速加工性を備えた光ファイバーをコーティングするための放射線硬化性組成物 |
WO2020239563A1 (en) | 2019-05-24 | 2020-12-03 | Dsm Ip Assets B.V. | Radiation curable compositions for coating optical fiber with enhanced high-speed processability |
WO2020243748A1 (en) | 2019-05-31 | 2020-12-03 | The Procter & Gamble Company | Methods of making a deflection member |
US20220282064A1 (en) | 2019-07-30 | 2022-09-08 | Basf Se | Stabilizer composition |
JP2022543200A (ja) | 2019-07-31 | 2022-10-11 | コベストロ (ネザーランズ) ビー.ブイ. | 光ファイバーを被覆するための多官能性長アームオリゴマーを含む放射線硬化性組成物 |
TWI723738B (zh) * | 2020-01-13 | 2021-04-01 | 臺灣永光化學工業股份有限公司 | 新型反應型苯并三唑紫外線吸收劑及其用途 |
WO2021202638A1 (en) | 2020-04-03 | 2021-10-07 | Dsm Ip Assets B.V. | Multi-layered optical devices |
EP4127794A1 (de) | 2020-04-03 | 2023-02-08 | Covestro (Netherlands) B.V. | Selbstheilende optische fasern und zusammensetzungen zu ihrer herstellung |
WO2023205223A1 (en) | 2022-04-21 | 2023-10-26 | Covestro (Netherlands) B.V. | Radiation curable compositions for coating optical fibers |
WO2023209004A1 (en) | 2022-04-29 | 2023-11-02 | Ineos Styrolution Group Gmbh | Acrylonitrile styrene acrylate copolymer composition with improved uv resistance |
WO2023209007A1 (en) | 2022-04-29 | 2023-11-02 | Ineos Styrolution Group Gmbh | Acrylonitrile styrene acrylate (asa) copolymer composition having good uv resistance with reduced uv absorber content |
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BE563210A (de) * | 1956-12-14 | 1958-06-13 | ||
US3072585A (en) * | 1960-01-13 | 1963-01-08 | American Cyanamid Co | Vinylbenzyloxy phenylbenzotriazoles |
NL262038A (de) * | 1960-03-08 | |||
NL279774A (de) * | 1961-06-16 | |||
NL124488C (de) * | 1961-06-16 | |||
NL126744C (de) * | 1961-06-16 | 1969-01-15 | ||
CH494060A (de) * | 1961-06-16 | 1970-07-31 | Geigy Ag J R | Verwendung von 2-(2'-Hydrophenyl)-benztriazolverbindungen als Lichtschutzmittel |
US3341535A (en) * | 1965-04-07 | 1967-09-12 | Taisho Pharmaceutical Co Ltd | Benzimidazole derivatives |
US3438992A (en) * | 1966-11-09 | 1969-04-15 | Merck & Co Inc | Certain lower-alkyl sulfinylmethyl pyridines |
US3480643A (en) * | 1967-05-09 | 1969-11-25 | American Cyanamid Co | Alkylsulfonylbenzimidazoles |
DE1965042A1 (de) * | 1969-12-27 | 1971-07-15 | Konishiroku Photo Ind | Lichtempfindliches,farbfotographisches Aufzeichnungsmaterial |
DE3264154D1 (en) * | 1981-01-23 | 1985-07-25 | Ciba Geigy Ag | 2-(2-hydroxyphenyl)-benzotriazoles, their use as ultraviolet stabilizers and their preparation |
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US5278314A (en) * | 1991-02-12 | 1994-01-11 | Ciba-Geigy Corporation | 5-thio-substituted benzotriazole UV-absorbers |
US5280124A (en) * | 1991-02-12 | 1994-01-18 | Ciba-Geigy Corporation | 5-sulfonyl-substituted benzotriazole UV-absorbers |
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-
1992
- 1992-02-05 US US07/828,291 patent/US5280124A/en not_active Expired - Lifetime
- 1992-02-11 DE DE69231033T patent/DE69231033T2/de not_active Expired - Fee Related
- 1992-02-11 KR KR1019930702365A patent/KR0178553B1/ko not_active IP Right Cessation
- 1992-02-11 ES ES92907725T patent/ES2146211T3/es not_active Expired - Lifetime
- 1992-02-11 EP EP92907725A patent/EP0572554B1/de not_active Expired - Lifetime
- 1992-02-11 RU RU93050567A patent/RU2127264C1/ru active
- 1992-02-11 CA CA002098999A patent/CA2098999C/en not_active Expired - Fee Related
- 1992-02-11 JP JP50728092A patent/JP3180137B2/ja not_active Expired - Fee Related
- 1992-02-11 WO PCT/US1992/001081 patent/WO1992014717A1/en active IP Right Grant
- 1992-02-12 MX MX9200602A patent/MX9200602A/es not_active IP Right Cessation
-
1993
- 1993-11-01 US US08/146,338 patent/US5436349A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
ES2146211T3 (es) | 2000-08-01 |
US5280124A (en) | 1994-01-18 |
CA2098999A1 (en) | 1992-08-13 |
JPH06505743A (ja) | 1994-06-30 |
RU2127264C1 (ru) | 1999-03-10 |
KR0178553B1 (ko) | 1999-03-20 |
US5436349A (en) | 1995-07-25 |
JP3180137B2 (ja) | 2001-06-25 |
KR930703273A (ko) | 1993-11-29 |
CA2098999C (en) | 2002-11-19 |
MX9200602A (es) | 1992-08-01 |
DE69231033D1 (de) | 2000-06-15 |
WO1992014717A1 (en) | 1992-09-03 |
EP0572554B1 (de) | 2000-05-10 |
EP0572554A1 (de) | 1993-12-08 |
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