DE69214572T2 - Verfahren zur Herstellung von Alkoholen - Google Patents

Verfahren zur Herstellung von Alkoholen

Info

Publication number
DE69214572T2
DE69214572T2 DE69214572T DE69214572T DE69214572T2 DE 69214572 T2 DE69214572 T2 DE 69214572T2 DE 69214572 T DE69214572 T DE 69214572T DE 69214572 T DE69214572 T DE 69214572T DE 69214572 T2 DE69214572 T2 DE 69214572T2
Authority
DE
Germany
Prior art keywords
process according
acid
group
aldehyde
mmol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69214572T
Other languages
German (de)
English (en)
Other versions
DE69214572D1 (de
Inventor
Eit Drent
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Application granted granted Critical
Publication of DE69214572D1 publication Critical patent/DE69214572D1/de
Publication of DE69214572T2 publication Critical patent/DE69214572T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
    • B01J31/2428—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member with more than one complexing phosphine-P atom
    • B01J31/2433—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/828—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE69214572T 1991-08-30 1992-07-08 Verfahren zur Herstellung von Alkoholen Expired - Fee Related DE69214572T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB919118603A GB9118603D0 (en) 1991-08-30 1991-08-30 Process for the preparation of alcohols

Publications (2)

Publication Number Publication Date
DE69214572D1 DE69214572D1 (de) 1996-11-21
DE69214572T2 true DE69214572T2 (de) 1997-03-20

Family

ID=10700683

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69214572T Expired - Fee Related DE69214572T2 (de) 1991-08-30 1992-07-08 Verfahren zur Herstellung von Alkoholen

Country Status (7)

Country Link
US (1) US5214220A (enExample)
EP (1) EP0529698B1 (enExample)
KR (1) KR100251076B1 (enExample)
DE (1) DE69214572T2 (enExample)
ES (1) ES2092627T3 (enExample)
GB (1) GB9118603D0 (enExample)
IN (1) IN185880B (enExample)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100338320B1 (ko) * 1993-08-19 2003-01-24 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 히드로포르밀화방법
US5488174A (en) * 1993-08-19 1996-01-30 Shell Oil Company Hydroformylation process
US5763688A (en) * 1994-12-07 1998-06-09 Research Development Corporation Of Japan Method for producing an alcohol
US6756411B2 (en) * 1995-06-29 2004-06-29 Sasol Technology (Proprietary) Limited Process for producing oxygenated products
CN1071731C (zh) * 1995-08-25 2001-09-26 纳幕尔杜邦公司 加氢甲酰化方法
US5744655A (en) * 1996-06-19 1998-04-28 The Dow Chemical Company Process to make 2,3-dihalopropanols
TW476746B (en) * 1997-07-23 2002-02-21 Shell Int Research Hydrogenolysis of glycerol
DE69802360T2 (de) * 1997-09-18 2002-10-17 Shell Internationale Research Maatschappij B.V., Den Haag/S'gravenhage Hydroformylierungsverfahren
EP1358009A2 (en) * 2001-01-31 2003-11-05 Shell Internationale Researchmaatschappij B.V. Process for the carbonylation of ethylenically unsaturated compounds, bidentate diphosphine composition used in this process and processes for preparation of this bidentate diphosphine composition
US7084089B2 (en) 2002-07-31 2006-08-01 Shell Oil Company Process for the carbonylation of ethylenically unsaturated compounds, bidentate diphosphine composition used in this process and a process for preparation of this bidentate diphosphine composition
US6806391B2 (en) 2002-07-31 2004-10-19 Shell Oil Company Process for the carbonylation of ethylenically unsaturated compounds and bidentate diphosphine composition used in this process
JP2007511599A (ja) * 2003-11-18 2007-05-10 サソール テクノロジー（プロプライエタリー）リミテッド 酸素化生成物の製造
DE102004047836A1 (de) 2004-09-29 2006-03-30 Basf Ag Verfahren zur Herstellung von optisch aktiven 2-Methylalkanolen
WO2010067442A1 (ja) * 2008-12-11 2010-06-17 高砂香料工業株式会社 アルコール化合物の製造方法
US8697881B2 (en) * 2008-12-11 2014-04-15 Takasago International Corporation Method for producing alcohol compound
CN102395427B (zh) 2009-03-17 2016-03-16 约翰森·马瑟公开有限公司 在Ru(II)催化剂存在下氢化酮类的方法
WO2020057878A1 (en) 2018-09-17 2020-03-26 Exxonmobil Chemical Patents Inc. Transfer hydroformylation for the production of oxygenates
DE102020106009A1 (de) * 2020-03-05 2021-09-09 Linde Gmbh Verfahren und anlage zur herstellung einer zielverbindung
EP4603474A1 (de) * 2024-02-14 2025-08-20 Evonik Oxeno GmbH & Co. KG Verfahren zur herstellung eines omega-hydroxycarbonsäureesters aus einem trioxanderivat

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1130743A (en) * 1965-06-11 1968-10-16 Ici Ltd Organo-iridium complexes
US3456017A (en) * 1965-10-21 1969-07-15 Shell Oil Co Glycol production
US3454644A (en) * 1966-05-09 1969-07-08 Shell Oil Co Homogeneous hydrogenation process employing a complex of ruthenium or osmium as catalyst
DE1793398A1 (de) * 1968-09-11 1972-02-03 Basf Ag Verfahren zur Herstellung von Alkoholen
US3876672A (en) 1972-02-21 1975-04-08 Du Pont Hydroformylation of olefins
FR2408388A1 (fr) * 1977-11-10 1979-06-08 Ugine Kuhlmann Complexe binucleaire du rhodium en tant que catalyseur d'hydroformylation et d'hydrogenation
US4215077A (en) * 1978-02-09 1980-07-29 Kuraray Co., Ltd. Hydroformylation of olefins
JPS55151521A (en) * 1979-05-15 1980-11-26 Toyo Soda Mfg Co Ltd Preparation of alcohol
EP0061337A1 (en) * 1981-03-25 1982-09-29 Johnson Matthey Public Limited Company Catalytic process
GB2100260B (en) * 1981-05-28 1985-09-04 Johnson Matthey Plc Catalytic hydrogenation and carbonylation of unsaturated compounds and metal/phosphine complex catalysts
DE3530839A1 (de) * 1985-08-29 1987-03-05 Ruhrchemie Ag Verfahren zur herstellung von 2-ethylhexanol
JPH06104638B2 (ja) * 1985-12-19 1994-12-21 三菱化成株式会社 アルコ−ルの製造方法
JPS62298543A (ja) * 1986-06-17 1987-12-25 Kawasaki Steel Corp エタノ−ルの製造方法
FR2623799B1 (fr) * 1987-12-01 1990-01-26 Rhone Poulenc Sante Procede de preparation d'alcools insatures
DE3915495A1 (de) * 1989-05-12 1990-11-15 Bayer Ag Kernfluorierte trifluormethylbenzaldehyde

Also Published As

Publication number Publication date
IN185880B (enExample) 2001-05-12
DE69214572D1 (de) 1996-11-21
KR100251076B1 (ko) 2000-04-15
EP0529698A3 (en) 1994-06-22
KR930004239A (ko) 1993-03-22
US5214220A (en) 1993-05-25
EP0529698A2 (en) 1993-03-03
ES2092627T3 (es) 1996-12-01
GB9118603D0 (en) 1991-10-16
EP0529698B1 (en) 1996-10-16

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Legal Events

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8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee