KR100251076B1 - 카르보닐 화합물의 수소화에 의한 알코올 제조 방법 - Google Patents

카르보닐 화합물의 수소화에 의한 알코올 제조 방법 Download PDF

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Publication number
KR100251076B1
KR100251076B1 KR1019920015419A KR920015419A KR100251076B1 KR 100251076 B1 KR100251076 B1 KR 100251076B1 KR 1019920015419 A KR1019920015419 A KR 1019920015419A KR 920015419 A KR920015419 A KR 920015419A KR 100251076 B1 KR100251076 B1 KR 100251076B1
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South Korea
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alcohol
hydrogenation
mmol
acid
bis
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KR1019920015419A
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Korean (ko)
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KR930004239A (ko
Inventor
아이트드렌트
Original Assignee
오노 알버어스
셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
    • B01J31/2428—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member with more than one complexing phosphine-P atom
    • B01J31/2433—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/828—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1019920015419A 1991-08-30 1992-08-26 카르보닐 화합물의 수소화에 의한 알코올 제조 방법 Expired - Fee Related KR100251076B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB919118603A GB9118603D0 (en) 1991-08-30 1991-08-30 Process for the preparation of alcohols
GB9118603.1 1991-08-30
EP92202087A EP0529698B1 (en) 1991-08-30 1992-07-08 Process for the preparation of alcohols
EP92202087.0 1992-07-08

Publications (2)

Publication Number Publication Date
KR930004239A KR930004239A (ko) 1993-03-22
KR100251076B1 true KR100251076B1 (ko) 2000-04-15

Family

ID=10700683

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920015419A Expired - Fee Related KR100251076B1 (ko) 1991-08-30 1992-08-26 카르보닐 화합물의 수소화에 의한 알코올 제조 방법

Country Status (7)

Country Link
US (1) US5214220A (enExample)
EP (1) EP0529698B1 (enExample)
KR (1) KR100251076B1 (enExample)
DE (1) DE69214572T2 (enExample)
ES (1) ES2092627T3 (enExample)
GB (1) GB9118603D0 (enExample)
IN (1) IN185880B (enExample)

Families Citing this family (19)

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CN1072633C (zh) * 1993-08-19 2001-10-10 国际壳牌研究有限公司 加氢甲酰化方法
US5488174A (en) * 1993-08-19 1996-01-30 Shell Oil Company Hydroformylation process
US5763688A (en) * 1994-12-07 1998-06-09 Research Development Corporation Of Japan Method for producing an alcohol
US6756411B2 (en) * 1995-06-29 2004-06-29 Sasol Technology (Proprietary) Limited Process for producing oxygenated products
WO1997008124A1 (en) * 1995-08-25 1997-03-06 E.I. Du Pont De Nemours And Company Hydroformylation process
US5744655A (en) * 1996-06-19 1998-04-28 The Dow Chemical Company Process to make 2,3-dihalopropanols
TW476746B (en) * 1997-07-23 2002-02-21 Shell Int Research Hydrogenolysis of glycerol
EP0903333B1 (en) * 1997-09-18 2001-11-07 Shell Internationale Researchmaatschappij B.V. Hydroformylation process
CN1535180A (zh) * 2001-01-31 2004-10-06 国际壳牌研究有限公司 烯属不饱和化合物的羰基化方法,用于此方法的双齿二膦组合物和此双齿二膦组合物的制备方法
US7084089B2 (en) 2002-07-31 2006-08-01 Shell Oil Company Process for the carbonylation of ethylenically unsaturated compounds, bidentate diphosphine composition used in this process and a process for preparation of this bidentate diphosphine composition
US6806391B2 (en) 2002-07-31 2004-10-19 Shell Oil Company Process for the carbonylation of ethylenically unsaturated compounds and bidentate diphosphine composition used in this process
JP2007511599A (ja) * 2003-11-18 2007-05-10 サソール テクノロジー（プロプライエタリー）リミテッド 酸素化生成物の製造
DE102004047836A1 (de) * 2004-09-29 2006-03-30 Basf Ag Verfahren zur Herstellung von optisch aktiven 2-Methylalkanolen
WO2010067441A1 (ja) * 2008-12-11 2010-06-17 高砂香料工業株式会社 アルコール化合物の製造方法
EP2377841A4 (en) * 2008-12-11 2012-08-01 Takasago Perfumery Co Ltd METHOD FOR PRODUCING AN ALCOHOL COMPOUND
SI2408557T1 (sl) 2009-03-17 2017-05-31 Johnson Matthey Public Limited Company 5th Floor Postopek za pripravo katalizatorjev Ru (II)
EP3853198A1 (en) 2018-09-17 2021-07-28 ExxonMobil Chemical Patents Inc. Transfer hydroformylation for the production of oxygenates
DE102020106009A1 (de) * 2020-03-05 2021-09-09 Linde Gmbh Verfahren und anlage zur herstellung einer zielverbindung
EP4603474A1 (de) * 2024-02-14 2025-08-20 Evonik Oxeno GmbH & Co. KG Verfahren zur herstellung eines omega-hydroxycarbonsäureesters aus einem trioxanderivat

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GB1135979A (en) * 1965-06-11 1968-12-11 Ici Ltd Hydrogenation process
US3456017A (en) * 1965-10-21 1969-07-15 Shell Oil Co Glycol production
US3454644A (en) * 1966-05-09 1969-07-08 Shell Oil Co Homogeneous hydrogenation process employing a complex of ruthenium or osmium as catalyst
DE1793398A1 (de) * 1968-09-11 1972-02-03 Basf Ag Verfahren zur Herstellung von Alkoholen
US3876672A (en) 1972-02-21 1975-04-08 Du Pont Hydroformylation of olefins
FR2408388A1 (fr) * 1977-11-10 1979-06-08 Ugine Kuhlmann Complexe binucleaire du rhodium en tant que catalyseur d'hydroformylation et d'hydrogenation
US4215077A (en) * 1978-02-09 1980-07-29 Kuraray Co., Ltd. Hydroformylation of olefins
JPS55151521A (en) * 1979-05-15 1980-11-26 Toyo Soda Mfg Co Ltd Preparation of alcohol
EP0061337A1 (en) * 1981-03-25 1982-09-29 Johnson Matthey Public Limited Company Catalytic process
GB2100260B (en) * 1981-05-28 1985-09-04 Johnson Matthey Plc Catalytic hydrogenation and carbonylation of unsaturated compounds and metal/phosphine complex catalysts
DE3530839A1 (de) * 1985-08-29 1987-03-05 Ruhrchemie Ag Verfahren zur herstellung von 2-ethylhexanol
JPH06104638B2 (ja) * 1985-12-19 1994-12-21 三菱化成株式会社 アルコ−ルの製造方法
JPS62298543A (ja) * 1986-06-17 1987-12-25 Kawasaki Steel Corp エタノ−ルの製造方法
FR2623799B1 (fr) * 1987-12-01 1990-01-26 Rhone Poulenc Sante Procede de preparation d'alcools insatures
DE3915495A1 (de) * 1989-05-12 1990-11-15 Bayer Ag Kernfluorierte trifluormethylbenzaldehyde

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Also Published As

Publication number Publication date
EP0529698A3 (en) 1994-06-22
ES2092627T3 (es) 1996-12-01
EP0529698B1 (en) 1996-10-16
DE69214572D1 (de) 1996-11-21
KR930004239A (ko) 1993-03-22
DE69214572T2 (de) 1997-03-20
GB9118603D0 (en) 1991-10-16
US5214220A (en) 1993-05-25
IN185880B (enExample) 2001-05-12
EP0529698A2 (en) 1993-03-03

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