DE69208095D1 - Katalysator und Verfahren zur Oligomerisierung von Olefinen - Google Patents

Katalysator und Verfahren zur Oligomerisierung von Olefinen

Info

Publication number
DE69208095D1
DE69208095D1 DE69208095T DE69208095T DE69208095D1 DE 69208095 D1 DE69208095 D1 DE 69208095D1 DE 69208095 T DE69208095 T DE 69208095T DE 69208095 T DE69208095 T DE 69208095T DE 69208095 D1 DE69208095 D1 DE 69208095D1
Authority
DE
Germany
Prior art keywords
pct
catalyst
isobutene
angstrom
alumina
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69208095T
Other languages
English (en)
Other versions
DE69208095T2 (de
Inventor
Maurizio Brunelli
Walter Castelvetro
Giuseppe Bellussi
Stefano Peratello
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eni Tecnologie SpA
Original Assignee
Eniricerche SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eniricerche SpA filed Critical Eniricerche SpA
Publication of DE69208095D1 publication Critical patent/DE69208095D1/de
Application granted granted Critical
Publication of DE69208095T2 publication Critical patent/DE69208095T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/10—Catalytic processes with metal oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/033—Using Hydrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00026—Controlling or regulating the heat exchange system
    • B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2208/00044—Temperature measurement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00433—Controlling the temperature using electromagnetic heating
    • B01J2208/0046—Infrared radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00477—Controlling the temperature by thermal insulation means
    • B01J2208/00495—Controlling the temperature by thermal insulation means using insulating materials or refractories
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
DE69208095T 1991-10-04 1992-10-02 Katalysator und Verfahren zur Oligomerisierung von Olefinen Expired - Fee Related DE69208095T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI912651A IT1251614B (it) 1991-10-04 1991-10-04 Catalizzatore e procedimento per la oligomerizzazione di olefine
PCT/EP1992/002286 WO1993006926A1 (en) 1991-10-04 1992-10-02 Catalyst and process for oligomerizing olefins

Publications (2)

Publication Number Publication Date
DE69208095D1 true DE69208095D1 (de) 1996-03-14
DE69208095T2 DE69208095T2 (de) 1996-08-22

Family

ID=11360821

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69208095T Expired - Fee Related DE69208095T2 (de) 1991-10-04 1992-10-02 Katalysator und Verfahren zur Oligomerisierung von Olefinen

Country Status (10)

Country Link
US (1) US5510555A (de)
EP (1) EP0606314B1 (de)
AT (1) ATE133583T1 (de)
DE (1) DE69208095T2 (de)
DK (1) DK0606314T3 (de)
ES (1) ES2083193T3 (de)
GR (1) GR3019107T3 (de)
IT (1) IT1251614B (de)
RU (1) RU2094119C1 (de)
WO (1) WO1993006926A1 (de)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4319909C2 (de) * 1993-06-16 1996-11-07 Solvay Deutschland Palladium, Platin, Nickel, Kobalt und/oder Kupfer umfassender Aerogel-Trägerkatalysator, Verfahren zu seiner Herstellung und Verwendung eines Palladium-Aerogel-Trägerkatalysators
US5439624A (en) * 1994-02-14 1995-08-08 Wisconsin Alumni Research Foundation Method for forming porous ceramic materials
IT1270069B (it) * 1994-07-06 1997-04-28 Eniricerche Spa Gel micro-mesoporoso e procedimento per la sua preparazione
BE1009400A3 (fr) * 1995-05-24 1997-03-04 Solvay Procede de preparation d'un catalyseur et son utilisation pour la conversion d'alcanes chlores en alcenes moins chlores.
CN1150956A (zh) * 1995-11-23 1997-06-04 杨亚力 处理塑料废弃物的催化剂
IT1311999B1 (it) * 1999-03-31 2002-03-22 Snam Progetti Miscela liquida adatta come benzina.
US7273957B2 (en) * 1999-05-04 2007-09-25 Catalytic Distillation Technologies Process for the production of gasoline stocks
US6274783B1 (en) 2000-03-20 2001-08-14 Catalytic Distillation Technologies Catalytic distillation process for the production of C8 alkanes
ES2193801B1 (es) * 2000-05-29 2005-03-01 Universidad De Zaragoza Reactor para la obtencion de compuestos para gasolina de alto indice de octano a partir de olefinas ligeras.
EP1388528B1 (de) 2002-08-06 2015-04-08 Evonik Degussa GmbH Verfahren zur Oligomerisierung von Isobuten in n-Buten-haltigen Kohlenwasserstoffströmen
EP1410844A1 (de) * 2002-10-15 2004-04-21 Centre National De La Recherche Scientifique (Cnrs) Siliziumbasiertes poröses Katalysatorsystem zur Oligomerisierung von leichten Olefinen
US7145049B2 (en) * 2003-07-25 2006-12-05 Catalytic Distillation Technologies Oligomerization process
WO2005056503A1 (en) * 2003-12-12 2005-06-23 University Of Waterloo Composite catalyst for the selective oligomerization of lower alkenes and the production of high octane products
US7649123B2 (en) * 2008-01-15 2010-01-19 Catalytic Distillation Technologies Propylene oligomerization process
US8153854B2 (en) * 2008-06-06 2012-04-10 Catalytic Distillation Technologies Gasoline alkylate RVP control
CN102099113A (zh) * 2008-07-23 2011-06-15 三井化学株式会社 乙烯低聚催化剂及其用途
US8853483B2 (en) * 2008-12-02 2014-10-07 Catalytic Distillation Technologies Oligomerization process
US8124819B2 (en) * 2009-01-08 2012-02-28 Catalytic Distillation Technologies Oligomerization process
US8492603B2 (en) * 2009-01-12 2013-07-23 Catalytic Distillation Technologies Selectivated isoolefin dimerization using metalized resins
DE102009027408A1 (de) 2009-07-01 2011-01-05 Evonik Oxeno Gmbh Regenerierung von Oligomerisierungskatalysatoren
US8124821B2 (en) 2009-08-10 2012-02-28 Chevron U.S.A. Inc. Oligomerization of propylene to produce base oil products using ionic liquids-based catalysis
US8101809B2 (en) * 2009-08-10 2012-01-24 Chevron U.S.A. Inc. Base oil composition comprising oligomerized olefins
US9272965B2 (en) * 2009-12-22 2016-03-01 Catalytic Distillation Technologies Process for the conversion of alcohols to olefins
CN107824189A (zh) * 2017-11-15 2018-03-23 西南化工研究设计院有限公司 一种新型镍基丙烯齐聚催化剂的制备方法
US10882028B2 (en) 2018-03-14 2021-01-05 Evonik Operations Gmbh Ni-containing catalyst for the oligomerization of olefins
US10850261B2 (en) * 2018-03-14 2020-12-01 Evonik Operations Gmbh Oligomerization catalyst and process for the production thereof

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB619231A (en) * 1945-06-15 1949-03-07 Phillips Petroleum Co Improvements in or relating to catalytic polymerization of olefins
US2921971A (en) * 1956-03-14 1960-01-19 Phillips Petroleum Co Process and catalyst for the poly-merization of olefins
US3322686A (en) * 1963-02-05 1967-05-30 Herbert C Brown Hydrogenation of chemical compounds and catalysts therefor
GB1215943A (en) * 1967-11-07 1970-12-16 British Petroleum Co Polymerisation process
GB1197878A (en) * 1968-03-04 1970-07-08 Ici Ltd Dimerisation of Olefines
US4272409A (en) * 1977-08-31 1981-06-09 E. I. Du Pont De Nemours And Company Aluminosilicate sols and powders
US4472531A (en) * 1980-01-14 1984-09-18 National Petro Chemicals Corporation Polymerization catalyst and method of preparing the same
DD152331A1 (de) * 1980-08-04 1981-11-25 Erich Fritsch Verfahren zur dimerisierung von propen
US4414137A (en) * 1982-03-09 1983-11-08 Union Oil Company Of California Catalytically active amorphous silica
US4717708A (en) * 1983-12-27 1988-01-05 Stauffer Chemical Company Inorganic oxide aerogels and their preparation
IT1219692B (it) * 1988-05-06 1990-05-24 Eniricerche Spa Gel di silice e allumina cataliticamente attivo e procedimento per la sua preparazione
US5169824A (en) * 1991-01-22 1992-12-08 Exxon Chemical Patents Inc. Catalyst comprising amorphous NiO on silica/alumina support
IT1251613B (it) * 1991-10-04 1995-05-17 Eniricerche Spa Procedimento di dimerizzazione catalitica di isobutene

Also Published As

Publication number Publication date
GR3019107T3 (en) 1996-05-31
EP0606314A1 (de) 1994-07-20
DK0606314T3 (da) 1996-04-09
US5510555A (en) 1996-04-23
WO1993006926A1 (en) 1993-04-15
ATE133583T1 (de) 1996-02-15
ITMI912651A0 (it) 1991-10-04
DE69208095T2 (de) 1996-08-22
ITMI912651A1 (it) 1993-04-04
RU2094119C1 (ru) 1997-10-27
ES2083193T3 (es) 1996-04-01
EP0606314B1 (de) 1996-01-31
IT1251614B (it) 1995-05-17

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