ATE390205T1 - Verfahren zur katalytischen dehydrierung und katalysator dafür - Google Patents

Verfahren zur katalytischen dehydrierung und katalysator dafür

Info

Publication number
ATE390205T1
ATE390205T1 AT03026419T AT03026419T ATE390205T1 AT E390205 T1 ATE390205 T1 AT E390205T1 AT 03026419 T AT03026419 T AT 03026419T AT 03026419 T AT03026419 T AT 03026419T AT E390205 T1 ATE390205 T1 AT E390205T1
Authority
AT
Austria
Prior art keywords
catalyst
catalytic dehydration
zeotype
dehydrogenatable hydrocarbon
process stream
Prior art date
Application number
AT03026419T
Other languages
English (en)
Inventor
Iver Schmidt
Anne Krogh
Claus Christensen
Original Assignee
Haldor Topsoe As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Haldor Topsoe As filed Critical Haldor Topsoe As
Application granted granted Critical
Publication of ATE390205T1 publication Critical patent/ATE390205T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/44—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
AT03026419T 2002-12-10 2003-11-19 Verfahren zur katalytischen dehydrierung und katalysator dafür ATE390205T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DKPA200201891 2002-12-10

Publications (1)

Publication Number Publication Date
ATE390205T1 true ATE390205T1 (de) 2008-04-15

Family

ID=32337950

Family Applications (1)

Application Number Title Priority Date Filing Date
AT03026419T ATE390205T1 (de) 2002-12-10 2003-11-19 Verfahren zur katalytischen dehydrierung und katalysator dafür

Country Status (6)

Country Link
US (1) US7045671B2 (de)
EP (1) EP1430949B1 (de)
JP (1) JP2004189743A (de)
AT (1) ATE390205T1 (de)
DE (1) DE60319940T2 (de)
ZA (1) ZA200309469B (de)

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CN100434407C (zh) * 2006-01-19 2008-11-19 中国石油化工股份有限公司 一种丙烷脱氢制丙烯的方法
US8383079B2 (en) 2006-04-17 2013-02-26 Exxonmobil Chemical Patents Inc. Molecular sieves having micro and mesoporosity, their synthesis and their use in the organic conversion reactions
BRPI0602678B1 (pt) * 2006-07-14 2015-09-01 Petroleo Brasileiro Sa Aditivo para maximização de glp e propeno adequado a operação da unidade de craqueamento catalítico fluido em baixa severidade e processo de preparo do mesmo
JP4810680B2 (ja) * 2006-12-27 2011-11-09 コニカミノルタビジネステクノロジーズ株式会社 静電荷像現像用現像剤
CN101284232B (zh) * 2007-04-13 2013-01-16 微宏动力系统（湖州）有限公司 甲烷溴氧化制溴甲烷及其转化制碳氢化合物的催化剂
JP2009167171A (ja) * 2008-01-11 2009-07-30 Rohm & Haas Co プロパンをプロペンに転化するための担持触媒およびその転化のためのプロセスにおけるその使用
KR20130081294A (ko) 2008-08-29 2013-07-16 엑손모빌 케미칼 패턴츠 인코포레이티드 페놀 제조 방법
JP5462074B2 (ja) * 2009-05-27 2014-04-02 昭和電工株式会社 アルケン製造用触媒、その製造方法及びアルケンの製造方法
WO2011096993A2 (en) * 2010-02-05 2011-08-11 Exxonmobil Chemical Patents Inc. Dehydrogenation process
CN106824186A (zh) 2010-02-05 2017-06-13 埃克森美孚化学专利公司 环己酮脱氢催化剂和方法
WO2011096990A2 (en) 2010-02-05 2011-08-11 Exxonmobil Chemical Patents Inc. Dehydrogenation catalyst and process
CN102958886B (zh) 2010-06-25 2015-07-22 埃克森美孚化学专利公司 脱氢方法
CN103121920A (zh) * 2011-11-18 2013-05-29 中国石油化工股份有限公司 二氧化碳气氛下乙苯脱氢方法
CN103121916A (zh) * 2011-11-18 2013-05-29 中国石油化工股份有限公司 Co2气氛下乙苯脱氢制备苯乙烯的方法
CN103127935B (zh) * 2011-11-21 2015-07-01 中国石油化工股份有限公司 一种介孔碳负载型铜基催化剂、其制备方法及其应用
JP2013163647A (ja) * 2012-02-09 2013-08-22 Mitsui Chemicals Inc 不飽和炭化水素の製造方法および当該方法に使用される脱水素用触媒
WO2013159884A2 (en) 2012-04-23 2013-10-31 Saudi Basic Industries Corporation Solar energy based countinuous process and reactor system for the production of an alkene by dehydrogenation of the corresponding alkane
KR101581613B1 (ko) * 2015-01-14 2015-12-31 성균관대학교산학협력단 원자층 증착법으로 제조된 저온 일산화탄소 산화용 니켈계 촉매 및 이의 활용
CN104759290B (zh) * 2015-04-29 2017-03-01 太原理工大学 Zn改性的多级孔HZSM‑5催化剂及其在液化气芳构化中的应用
CN106423240B (zh) * 2015-08-12 2019-01-01 中国石油化工股份有限公司 苯乙烯催化剂和其制备方法
CN105195210B (zh) * 2015-09-18 2018-02-13 宁波海越新材料有限公司 一种仲丁醇脱氢制甲乙酮催化剂及其制备方法
CN106362791B (zh) * 2016-08-05 2018-10-26 西南化工研究设计院有限公司 一种用于丙烷脱氢转化制丙烯介孔-微孔复合孔道分子筛催化剂及其制备方法
CN108816275B (zh) * 2018-04-19 2021-02-05 南京红太阳生物化学有限责任公司 一种用于合成气制吡啶碱的催化剂及制备方法和应用
CN108654596B (zh) * 2018-04-28 2020-05-05 洛阳市科创石化科技开发有限公司 一种丙烷脱氢催化剂及其制备方法
CN110614107A (zh) * 2018-06-20 2019-12-27 中国石油化工股份有限公司 载体为空心球状介孔分子筛硅胶复合材料的异丁烷脱氢催化剂及其制备方法和应用
WO2020018449A1 (en) * 2018-07-16 2020-01-23 Battelle Energy Alliance, Llc Composite media for non-oxidative ethane dehydrogenation, and related ethane activation systems and method of processing an ethane-containing stream
CN111408370B (zh) * 2019-01-08 2022-03-22 天津大学 一种负载型PtZn金属间合金催化剂及其制备方法和应用
CN109675548A (zh) * 2019-01-21 2019-04-26 福州大学 一种用于丙烷脱氢制丙烯的分子筛催化剂及其制备方法
CN110801861B (zh) * 2019-11-21 2020-11-24 西南化工研究设计院有限公司 一种环境友好型丙烷直接脱氢制丙烯催化剂及其制备方法
US11673845B2 (en) 2020-09-03 2023-06-13 Saudi Arabian Oil Company Aromatization of light hydrocarbons using metal-modified zeolite catalysts
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Also Published As

Publication number Publication date
ZA200309469B (en) 2004-07-28
DE60319940T2 (de) 2008-06-26
EP1430949A1 (de) 2004-06-23
US7045671B2 (en) 2006-05-16
US20040110630A1 (en) 2004-06-10
DE60319940D1 (de) 2008-05-08
EP1430949B1 (de) 2008-03-26
JP2004189743A (ja) 2004-07-08

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