IT1251614B - Catalizzatore e procedimento per la oligomerizzazione di olefine - Google Patents

Catalizzatore e procedimento per la oligomerizzazione di olefine

Info

Publication number
IT1251614B
IT1251614B ITMI912651A ITMI912651A IT1251614B IT 1251614 B IT1251614 B IT 1251614B IT MI912651 A ITMI912651 A IT MI912651A IT MI912651 A ITMI912651 A IT MI912651A IT 1251614 B IT1251614 B IT 1251614B
Authority
IT
Italy
Prior art keywords
catalyst
oligomerization
sio2
alumina
molar ratio
Prior art date
Application number
ITMI912651A
Other languages
English (en)
Inventor
Maurizio Brunelli
Walter Castelvetro
Giuseppe Bellussi
Stefano Peratello
Original Assignee
Eniricerche Spa
Euron Spa
Snam Progetti
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eniricerche Spa, Euron Spa, Snam Progetti filed Critical Eniricerche Spa
Publication of ITMI912651A0 publication Critical patent/ITMI912651A0/it
Priority to ITMI912651A priority Critical patent/IT1251614B/it
Priority to ES92920491T priority patent/ES2083193T3/es
Priority to PCT/EP1992/002286 priority patent/WO1993006926A1/en
Priority to EP92920491A priority patent/EP0606314B1/en
Priority to DE69208095T priority patent/DE69208095T2/de
Priority to RU94017657/04A priority patent/RU2094119C1/ru
Priority to US08/193,168 priority patent/US5510555A/en
Priority to DK92920491.5T priority patent/DK0606314T3/da
Priority to AT92920491T priority patent/ATE133583T1/de
Publication of ITMI912651A1 publication Critical patent/ITMI912651A1/it
Application granted granted Critical
Publication of IT1251614B publication Critical patent/IT1251614B/it
Priority to GR960400529T priority patent/GR3019107T3/el

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/10—Catalytic processes with metal oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/033—Using Hydrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00026—Controlling or regulating the heat exchange system
    • B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2208/00044—Temperature measurement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00433—Controlling the temperature using electromagnetic heating
    • B01J2208/0046—Infrared radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00477—Controlling the temperature by thermal insulation means
    • B01J2208/00495—Controlling the temperature by thermal insulation means using insulating materials or refractories
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Un catalizzatore attivo nella oligomerizzazione delle olefine è un gel di silice, allumina ed ossido di nichel, amorfo all'analisi ai raggi X, con un rapporto molare SiO2/A12O3 da 30/1 a 500/1, con un rapporto molare NiO2/SiO2 da 0,001/1 a 0,01/1, con area superficiale da 500 a 1.000 m2/g, con porosità da 0,3 a 0,6 m1/g, con diametro medio dei pori di circa 10 A (Angstrom) e privo di pori con diametro superiore a 30 A.Il catalizzatore dimerizza selettivamente l'isobutene in ? e ?-diisobutene ed oligomerizza il propilene nei relativi dimeri. e trimeri.Viene descritto un procedimento per la preparazione del gel di silice, allumina ed ossido di nichel.
ITMI912651A 1991-01-04 1991-10-04 Catalizzatore e procedimento per la oligomerizzazione di olefine IT1251614B (it)

Priority Applications (10)

Application Number Priority Date Filing Date Title
ITMI912651A IT1251614B (it) 1991-10-04 1991-10-04 Catalizzatore e procedimento per la oligomerizzazione di olefine
DE69208095T DE69208095T2 (de) 1991-10-04 1992-10-02 Katalysator und Verfahren zur Oligomerisierung von Olefinen
PCT/EP1992/002286 WO1993006926A1 (en) 1991-10-04 1992-10-02 Catalyst and process for oligomerizing olefins
EP92920491A EP0606314B1 (en) 1991-10-04 1992-10-02 Catalyst and process for oligomerizing olefins
ES92920491T ES2083193T3 (es) 1991-10-04 1992-10-02 Catalizador y procedimiento de oligomerizacion de olefinas.
RU94017657/04A RU2094119C1 (ru) 1991-10-04 1992-10-02 Аморфный к рентгеновскому излучению каталитически активный кремний-алюминий-никелевый окисный гель, способ его получения, способ димеризации изобутилена и способ получения димеров и тримеров пропилена
US08/193,168 US5510555A (en) 1991-01-04 1992-10-02 Catalyst and process for oligomerizing olefins
DK92920491.5T DK0606314T3 (da) 1991-10-04 1992-10-02 Katalysator og fremgangsmåde til oligomerisation af olefiner
AT92920491T ATE133583T1 (de) 1991-10-04 1992-10-02 Katalysator und verfahren zur oligomerisierung von olefinen
GR960400529T GR3019107T3 (en) 1991-10-04 1996-02-23 Catalyst and process for oligomerizing olefins.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI912651A IT1251614B (it) 1991-10-04 1991-10-04 Catalizzatore e procedimento per la oligomerizzazione di olefine

Publications (3)

Publication Number Publication Date
ITMI912651A0 ITMI912651A0 (it) 1991-10-04
ITMI912651A1 ITMI912651A1 (it) 1993-04-04
IT1251614B true IT1251614B (it) 1995-05-17

Family

ID=11360821

Family Applications (1)

Application Number Title Priority Date Filing Date
ITMI912651A IT1251614B (it) 1991-01-04 1991-10-04 Catalizzatore e procedimento per la oligomerizzazione di olefine

Country Status (10)

Country Link
US (1) US5510555A (it)
EP (1) EP0606314B1 (it)
AT (1) ATE133583T1 (it)
DE (1) DE69208095T2 (it)
DK (1) DK0606314T3 (it)
ES (1) ES2083193T3 (it)
GR (1) GR3019107T3 (it)
IT (1) IT1251614B (it)
RU (1) RU2094119C1 (it)
WO (1) WO1993006926A1 (it)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4319909C2 (de) * 1993-06-16 1996-11-07 Solvay Deutschland Palladium, Platin, Nickel, Kobalt und/oder Kupfer umfassender Aerogel-Trägerkatalysator, Verfahren zu seiner Herstellung und Verwendung eines Palladium-Aerogel-Trägerkatalysators
US5439624A (en) * 1994-02-14 1995-08-08 Wisconsin Alumni Research Foundation Method for forming porous ceramic materials
IT1270069B (it) * 1994-07-06 1997-04-28 Eniricerche Spa Gel micro-mesoporoso e procedimento per la sua preparazione
BE1009400A3 (fr) * 1995-05-24 1997-03-04 Solvay Procede de preparation d'un catalyseur et son utilisation pour la conversion d'alcanes chlores en alcenes moins chlores.
CN1150956A (zh) * 1995-11-23 1997-06-04 杨亚力 处理塑料废弃物的催化剂
IT1311999B1 (it) * 1999-03-31 2002-03-22 Snam Progetti Miscela liquida adatta come benzina.
US7273957B2 (en) * 1999-05-04 2007-09-25 Catalytic Distillation Technologies Process for the production of gasoline stocks
US6274783B1 (en) 2000-03-20 2001-08-14 Catalytic Distillation Technologies Catalytic distillation process for the production of C8 alkanes
ES2193801B1 (es) * 2000-05-29 2005-03-01 Universidad De Zaragoza Reactor para la obtencion de compuestos para gasolina de alto indice de octano a partir de olefinas ligeras.
EP1388528B1 (de) 2002-08-06 2015-04-08 Evonik Degussa GmbH Verfahren zur Oligomerisierung von Isobuten in n-Buten-haltigen Kohlenwasserstoffströmen
EP1410844A1 (en) * 2002-10-15 2004-04-21 Centre National De La Recherche Scientifique (Cnrs) Silicon-based porous catalytic system for oligomerising light olefins
US7145049B2 (en) * 2003-07-25 2006-12-05 Catalytic Distillation Technologies Oligomerization process
ZA200605251B (en) * 2003-12-12 2007-11-28 Univ Waterloo Composite catalyst for the selective oligomerization of lower alkenes and the production of high octane products
US7649123B2 (en) * 2008-01-15 2010-01-19 Catalytic Distillation Technologies Propylene oligomerization process
US8153854B2 (en) * 2008-06-06 2012-04-10 Catalytic Distillation Technologies Gasoline alkylate RVP control
KR101250627B1 (ko) * 2008-07-23 2013-04-03 미쓰이 가가쿠 가부시키가이샤 에틸렌의 올리고머화 촉매 및 그 용도
US8853483B2 (en) * 2008-12-02 2014-10-07 Catalytic Distillation Technologies Oligomerization process
US8124819B2 (en) * 2009-01-08 2012-02-28 Catalytic Distillation Technologies Oligomerization process
US8492603B2 (en) * 2009-01-12 2013-07-23 Catalytic Distillation Technologies Selectivated isoolefin dimerization using metalized resins
DE102009027408A1 (de) 2009-07-01 2011-01-05 Evonik Oxeno Gmbh Regenerierung von Oligomerisierungskatalysatoren
US8124821B2 (en) 2009-08-10 2012-02-28 Chevron U.S.A. Inc. Oligomerization of propylene to produce base oil products using ionic liquids-based catalysis
US8101809B2 (en) * 2009-08-10 2012-01-24 Chevron U.S.A. Inc. Base oil composition comprising oligomerized olefins
US9272965B2 (en) * 2009-12-22 2016-03-01 Catalytic Distillation Technologies Process for the conversion of alcohols to olefins
CN107824189A (zh) * 2017-11-15 2018-03-23 西南化工研究设计院有限公司 一种新型镍基丙烯齐聚催化剂的制备方法
US10882028B2 (en) 2018-03-14 2021-01-05 Evonik Operations Gmbh Ni-containing catalyst for the oligomerization of olefins
US10850261B2 (en) * 2018-03-14 2020-12-01 Evonik Operations Gmbh Oligomerization catalyst and process for the production thereof

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB619231A (en) * 1945-06-15 1949-03-07 Phillips Petroleum Co Improvements in or relating to catalytic polymerization of olefins
US2921971A (en) * 1956-03-14 1960-01-19 Phillips Petroleum Co Process and catalyst for the poly-merization of olefins
US3322686A (en) * 1963-02-05 1967-05-30 Herbert C Brown Hydrogenation of chemical compounds and catalysts therefor
GB1215943A (en) * 1967-11-07 1970-12-16 British Petroleum Co Polymerisation process
GB1197878A (en) * 1968-03-04 1970-07-08 Ici Ltd Dimerisation of Olefines
US4257874A (en) * 1977-08-31 1981-03-24 E. I. Du Pont De Nemours And Company Petroleum refinery processes using catalyst of aluminosilicate sols and powders
US4472531A (en) * 1980-01-14 1984-09-18 National Petro Chemicals Corporation Polymerization catalyst and method of preparing the same
DD152331A1 (de) * 1980-08-04 1981-11-25 Erich Fritsch Verfahren zur dimerisierung von propen
US4414137A (en) * 1982-03-09 1983-11-08 Union Oil Company Of California Catalytically active amorphous silica
US4717708A (en) * 1983-12-27 1988-01-05 Stauffer Chemical Company Inorganic oxide aerogels and their preparation
IT1219692B (it) * 1988-05-06 1990-05-24 Eniricerche Spa Gel di silice e allumina cataliticamente attivo e procedimento per la sua preparazione
US5169824A (en) * 1991-01-22 1992-12-08 Exxon Chemical Patents Inc. Catalyst comprising amorphous NiO on silica/alumina support
IT1251613B (it) * 1991-10-04 1995-05-17 Eniricerche Spa Procedimento di dimerizzazione catalitica di isobutene

Also Published As

Publication number Publication date
RU2094119C1 (ru) 1997-10-27
DK0606314T3 (da) 1996-04-09
ATE133583T1 (de) 1996-02-15
ITMI912651A0 (it) 1991-10-04
ES2083193T3 (es) 1996-04-01
GR3019107T3 (en) 1996-05-31
DE69208095T2 (de) 1996-08-22
EP0606314A1 (en) 1994-07-20
ITMI912651A1 (it) 1993-04-04
DE69208095D1 (de) 1996-03-14
US5510555A (en) 1996-04-23
EP0606314B1 (en) 1996-01-31
WO1993006926A1 (en) 1993-04-15

Similar Documents

Publication Publication Date Title
IT1251614B (it) Catalizzatore e procedimento per la oligomerizzazione di olefine
BR8902503A (pt) Processo de preparacao de gel de silica e alumina cataliticamente ativo e de sua utilizacao na dimerizacao de olefinas lineares
RU94017657A (ru) Каталитически активный кремний-алюминий-никелиевый гель, способ его получения и процесс олигомеризации олефинов
IT1272923B (it) Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
ES8603765A1 (es) Un procedimiento para la preparacion de un catalizador de craqueo de zeolita-arcilla-gel de silice-alumina
IT8920329A0 (it) Componenti e catalizzatori per la polimerizzazione di olefine.
ITMI941516A0 (it) Catalizzatori per la polimerizzazione delle olefine
ITMI940645A0 (it) Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
IT8348976A0 (it) Catalizzatore di polimerizzazione e interpolimerizzazione di olefine, e procedimento di preparazione ed uso
IT1221654B (it) Catalizzatori per la polimerizzazione delle olefine
IT8922826A0 (it) Componenti e catalizzatori per la polimerizzazione di olefine
IT1248985B (it) Procedimento per oligomerizzare olefine leggere
IT1251613B (it) Procedimento di dimerizzazione catalitica di isobutene
ITMI912682A0 (it) Catalizzatori per la polimerizzazione delle olefine
IT1252647B (it) Catalizzatore estruso a base di gel di silice ed allumina e procedimento per la sua preparazione
ITMI920486A1 (it) Catalizzatore eterogeneo per la preparazione di copolimeri alternati olefine/ossido di carbonio
ITMI920414A0 (it) Catalizzatore per la polimerizzazione di olefine
IT8723149A0 (it) Catalizzatore di deidrogenazione, procedimento per la sua preparazione e suo uso nella produzione di olefine lineari da paraffine lineari.
ITMI922179A0 (it) Catalizzatori per la polimerizzazione di olefine
ITMI921498A0 (it) Catalizzatore per la polimerizzazione di olefine
IT8522981A0 (it) Catalizzatore per la polimerizzazione e copolimerizzazione di olefine.

Legal Events

Date Code Title Description
0001 Granted
TA Fee payment date (situation as of event date), data collected since 19931001

Effective date: 19971014