DE69123164D1 - Katalysator und Prepolymere für die Polymerisation von Olefin und daraus erhältliches Ethylen(co)polymer - Google Patents

Katalysator und Prepolymere für die Polymerisation von Olefin und daraus erhältliches Ethylen(co)polymer

Info

Publication number
DE69123164D1
DE69123164D1 DE69123164T DE69123164T DE69123164D1 DE 69123164 D1 DE69123164 D1 DE 69123164D1 DE 69123164 T DE69123164 T DE 69123164T DE 69123164 T DE69123164 T DE 69123164T DE 69123164 D1 DE69123164 D1 DE 69123164D1
Authority
DE
Germany
Prior art keywords
catalyst
ethylene
solid catalyst
spheroidal particles
prepolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69123164T
Other languages
English (en)
Other versions
DE69123164T2 (de
Inventor
Jean-Claude Andre Bailly
Christine Jacqueline Chabrand
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Application granted granted Critical
Publication of DE69123164D1 publication Critical patent/DE69123164D1/de
Publication of DE69123164T2 publication Critical patent/DE69123164T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/10—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of alkaline earth metals, zinc, cadmium, mercury, copper or silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE69123164T 1990-03-12 1991-02-28 Katalysator und Prepolymere für die Polymerisation von Olefin und daraus erhältliches Ethylen(co)polymer Expired - Fee Related DE69123164T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9003367A FR2659336B1 (fr) 1990-03-12 1990-03-12 Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.

Publications (2)

Publication Number Publication Date
DE69123164D1 true DE69123164D1 (de) 1997-01-02
DE69123164T2 DE69123164T2 (de) 1997-03-13

Family

ID=9394798

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69123164T Expired - Fee Related DE69123164T2 (de) 1990-03-12 1991-02-28 Katalysator und Prepolymere für die Polymerisation von Olefin und daraus erhältliches Ethylen(co)polymer

Country Status (18)

Country Link
EP (1) EP0447071B1 (de)
JP (1) JPH04220405A (de)
KR (1) KR910016776A (de)
CN (1) CN1054775A (de)
AT (1) ATE145410T1 (de)
AU (1) AU645540B2 (de)
CA (1) CA2036766A1 (de)
CS (1) CS63191A2 (de)
DE (1) DE69123164T2 (de)
ES (1) ES2093677T3 (de)
FI (1) FI911214A (de)
FR (1) FR2659336B1 (de)
HU (1) HUT60297A (de)
NO (1) NO177719C (de)
PL (1) PL289377A1 (de)
PT (1) PT97006B (de)
SG (1) SG44343A1 (de)
ZA (1) ZA911289B (de)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2659337B1 (fr) * 1990-03-12 1992-06-05 Bp Chemicals Snc Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
AU652363B2 (en) * 1991-05-21 1994-08-25 Mobil Oil Corporation Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution
US5331071A (en) * 1991-11-12 1994-07-19 Nippon Oil Co., Ltd. Catalyst components for polymerization of olefins
EP0578838A1 (de) * 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Katalysator für die Olefinpolymerisation, Verfahren zu seiner Herstellung und seine Verwendung
WO1994025495A1 (en) * 1993-05-20 1994-11-10 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US6391817B1 (en) 1993-12-28 2002-05-21 Exxonmobil Chemical Patents Inc. Method for producing a prepolymerized catalyst
FR2717816B1 (fr) * 1994-03-23 1996-04-26 Atochem Elf Sa Composante catalytique pour la polymérisation des oléfines obtenue par impregnation d'un prépolymère par une solution d'une composante catalytique. Prépolymère et polymère obtenus à partir de ladite composante catalytique.
IT1269837B (it) * 1994-05-26 1997-04-15 Spherilene Srl Componenti e catalizzatori per la polimerizzazione delle olefine
IT1270070B (it) 1994-07-08 1997-04-28 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
US5529965A (en) * 1994-10-28 1996-06-25 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US6399533B2 (en) * 1995-05-25 2002-06-04 Basell Technology Company Bv Compounds and catalysts for the polymerization of olefins
EP0816394B1 (de) * 1996-06-26 2002-01-30 BP Chemicals S.N.C. Verfahren zur Ethylenpolymerisation in der Gasphase
ES2171640T3 (es) 1996-06-26 2002-09-16 Bp Chem Int Ltd Procedimiento para la polimerizacion de etileno en fase gaseosa.
FR2782280B1 (fr) * 1998-08-12 2000-09-22 Inst Francais Du Petrole Catalyseurs supportes utilisables dans des reactions de transformation de composes organiques
CN1096474C (zh) 1998-12-30 2002-12-18 化学工业部北京化工研究院 用于合成宽分布乙烯聚合物的复合催化剂及其制法和应用
US6265037B1 (en) 1999-04-16 2001-07-24 Andersen Corporation Polyolefin wood fiber composite
JP6108894B2 (ja) * 2013-03-19 2017-04-05 三井化学株式会社 オレフィン重合用触媒、それを用いたオレフィン系重合体の製造方法
JP7136896B2 (ja) * 2017-11-30 2022-09-13 ディーディーピー スペシャルティ エレクトロニック マテリアルズ ユーエス エイト，エルエルシー 樹脂ビーズ及び無機粒子

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1268754A (en) * 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Supported polymerization catalyst
US4659685A (en) * 1986-03-17 1987-04-21 The Dow Chemical Company Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
IT1221654B (it) * 1987-11-27 1990-07-12 Ausimont Spa Catalizzatori per la polimerizzazione delle olefine
FR2656315B1 (fr) * 1989-12-22 1992-04-17 Bp Chemicals Snc Procede de preparation d'un catalyseur a base de zirconium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
FR2656314B1 (fr) * 1989-12-22 1992-04-17 Bp Chemicals Snc Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
FR2659337B1 (fr) * 1990-03-12 1992-06-05 Bp Chemicals Snc Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.

Also Published As

Publication number Publication date
ES2093677T3 (es) 1997-01-01
FI911214A (fi) 1991-09-13
ATE145410T1 (de) 1996-12-15
ZA911289B (en) 1992-10-28
CS63191A2 (en) 1991-10-15
DE69123164T2 (de) 1997-03-13
JPH04220405A (ja) 1992-08-11
AU7134491A (en) 1991-09-12
NO910953D0 (no) 1991-03-11
HU910793D0 (en) 1991-09-30
NO177719C (no) 1995-11-08
NO910953L (no) 1991-09-13
CA2036766A1 (en) 1991-09-13
PL289377A1 (en) 1992-03-09
HUT60297A (en) 1992-08-28
PT97006A (pt) 1991-10-31
EP0447071A1 (de) 1991-09-18
SG44343A1 (en) 1997-12-19
PT97006B (pt) 1998-07-31
CN1054775A (zh) 1991-09-25
FR2659336B1 (fr) 1993-05-07
AU645540B2 (en) 1994-01-20
NO177719B (no) 1995-07-31
FI911214A0 (fi) 1991-03-12
FR2659336A1 (fr) 1991-09-13
EP0447071B1 (de) 1996-11-20
KR910016776A (ko) 1991-11-05

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ATE142651T1 (de) Katalysator und prepolymer für herstellung von polyolefinen
DE69123164T2 (de) Katalysator und Prepolymere für die Polymerisation von Olefin und daraus erhältliches Ethylen(co)polymer
US4931517A (en) Polymerization of ethylene
FR2656315B1 (fr) Procede de preparation d'un catalyseur a base de zirconium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
ATE121758T1 (de) Katalysator und prepolymere für die polymerisation von olefinen und daraus erhältliches ethylen(co)polymer.
ES2116188B1 (es) Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales.

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee