DE68928822T2 - Verfahren zur Herstellung von gebleichten chemithermomechanischen Zellstoffen - Google Patents
Verfahren zur Herstellung von gebleichten chemithermomechanischen ZellstoffenInfo
- Publication number
- DE68928822T2 DE68928822T2 DE68928822T DE68928822T DE68928822T2 DE 68928822 T2 DE68928822 T2 DE 68928822T2 DE 68928822 T DE68928822 T DE 68928822T DE 68928822 T DE68928822 T DE 68928822T DE 68928822 T2 DE68928822 T2 DE 68928822T2
- Authority
- DE
- Germany
- Prior art keywords
- pulp
- weight
- process according
- treatment
- bleaching
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 47
- 238000004519 manufacturing process Methods 0.000 title abstract description 14
- 238000011282 treatment Methods 0.000 claims abstract description 31
- 238000004061 bleaching Methods 0.000 claims abstract description 30
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 28
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims abstract description 12
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims abstract description 5
- 239000007787 solid Substances 0.000 claims abstract description 5
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 239000002023 wood Substances 0.000 claims description 14
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 9
- 229920001131 Pulp (paper) Polymers 0.000 claims description 7
- 229920002678 cellulose Polymers 0.000 claims description 7
- 239000001913 cellulose Substances 0.000 claims description 7
- 235000010265 sodium sulphite Nutrition 0.000 claims description 6
- 239000012279 sodium borohydride Substances 0.000 claims description 5
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 5
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 4
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 235000010269 sulphur dioxide Nutrition 0.000 claims description 4
- RYYXDZDBXNUPOG-UHFFFAOYSA-N 4,5,6,7-tetrahydro-1,3-benzothiazole-2,6-diamine;dihydrochloride Chemical compound Cl.Cl.C1C(N)CCC2=C1SC(N)=N2 RYYXDZDBXNUPOG-UHFFFAOYSA-N 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 3
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 claims description 3
- 239000004291 sulphur dioxide Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 102100031260 Acyl-coenzyme A thioesterase THEM4 Human genes 0.000 abstract description 23
- 101000638510 Homo sapiens Acyl-coenzyme A thioesterase THEM4 Proteins 0.000 abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000003153 chemical reaction reagent Substances 0.000 description 12
- 238000005406 washing Methods 0.000 description 10
- 229960003330 pentetic acid Drugs 0.000 description 8
- 238000010790 dilution Methods 0.000 description 7
- 239000012895 dilution Substances 0.000 description 7
- 238000007670 refining Methods 0.000 description 7
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000007858 starting material Substances 0.000 description 5
- 239000003638 chemical reducing agent Substances 0.000 description 4
- 238000004537 pulping Methods 0.000 description 4
- 239000010865 sewage Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- XQIMLPCOVYNASM-UHFFFAOYSA-N borole Chemical compound B1C=CC=C1 XQIMLPCOVYNASM-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000004513 sizing Methods 0.000 description 3
- 239000011122 softwood Substances 0.000 description 3
- -1 sulphite ions Chemical class 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 239000010842 industrial wastewater Substances 0.000 description 2
- 239000011344 liquid material Substances 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- NYYSPVRERVXMLJ-UHFFFAOYSA-N 4,4-difluorocyclohexan-1-one Chemical compound FC1(F)CCC(=O)CC1 NYYSPVRERVXMLJ-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 108091081062 Repeated sequence (DNA) Proteins 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 238000009897 hydrogen peroxide bleaching Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/04—Pulping cellulose-containing materials with acids, acid salts or acid anhydrides
- D21C3/06—Pulping cellulose-containing materials with acids, acid salts or acid anhydrides sulfur dioxide; sulfurous acid; bisulfites sulfites
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/16—Bleaching ; Apparatus therefor with per compounds
- D21C9/163—Bleaching ; Apparatus therefor with per compounds with peroxides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Seasonings (AREA)
- Thermotherapy And Cooling Therapy Devices (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Glass Compositions (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8809703A FR2634233B1 (fr) | 1988-07-12 | 1988-07-12 | Procede de fabrication de pates chimicothermomecaniques blanchies |
Publications (2)
Publication Number | Publication Date |
---|---|
DE68928822D1 DE68928822D1 (de) | 1998-11-05 |
DE68928822T2 true DE68928822T2 (de) | 1999-05-27 |
Family
ID=9368520
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE68928822T Expired - Fee Related DE68928822T2 (de) | 1988-07-12 | 1989-07-06 | Verfahren zur Herstellung von gebleichten chemithermomechanischen Zellstoffen |
DE198989420245T Pending DE351330T1 (de) | 1988-07-12 | 1989-07-06 | Verfahren zur herstellung von gebleichten chemithermomechanischen zellstoffen. |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE198989420245T Pending DE351330T1 (de) | 1988-07-12 | 1989-07-06 | Verfahren zur herstellung von gebleichten chemithermomechanischen zellstoffen. |
Country Status (12)
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2615874B1 (fr) * | 1987-05-25 | 1992-02-21 | Atochem | Procede de preparation de pates chimicothermomecaniques |
FR2675518B1 (fr) * | 1991-04-17 | 1996-10-18 | Atochem | Procede de preparation de pate a papier a haut rendement et blanchie, a partir de copeaux de bois. |
US20030062138A1 (en) * | 2001-05-09 | 2003-04-03 | Hache Maurice Joseph Albert | Method for brightening mechanical pulps |
JP4501329B2 (ja) * | 2002-03-29 | 2010-07-14 | 日本製紙株式会社 | グラビア印刷用塗工紙 |
ES2447870T3 (es) * | 2007-04-24 | 2014-03-13 | Basf Se | Procedimiento para la fabricación de partículas de madera blanqueadas y materias derivadas de la madera de claras a blancas |
US9932709B2 (en) | 2013-03-15 | 2018-04-03 | Ecolab Usa Inc. | Processes and compositions for brightness improvement in paper production |
US20100224333A1 (en) * | 2009-03-09 | 2010-09-09 | Prasad Duggirala | Method and chemical composition to improve efficiency of mechanical pulp |
EP2924166A1 (de) * | 2014-03-25 | 2015-09-30 | Basf Se | Verfahren zur Herstellung von gebleichtem Holzfaserstoff |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE834808C (de) * | 1950-08-31 | 1952-03-24 | Degussa | Verfahren zum Bleichen von mechanisch erzeugten, schwer bleichbaren Faserstoffen, insbesondere Holzschliff |
US3284283A (en) * | 1964-02-17 | 1966-11-08 | Fmc Corp | Production of wood pulps including treatment of cellulosic fibers with bisulfite ion followed by alkali metal borohydride |
SE416481B (sv) * | 1977-05-02 | 1981-01-05 | Mo Och Domsjoe Ab | Fofarande och anordning for behandling av vedflis for avlegsnande av tungmetaller och harts |
CA1212505A (en) * | 1984-07-17 | 1986-10-14 | Rudy Vit | Method, process and apparatus for converting wood, wood residue and or biomass into pulp |
US4718980A (en) * | 1985-12-30 | 1988-01-12 | Weyerhaeuser Company | Interstage treatment of mechanical pulp |
FR2615874B1 (fr) * | 1987-05-25 | 1992-02-21 | Atochem | Procede de preparation de pates chimicothermomecaniques |
SE460124B (sv) * | 1988-09-14 | 1989-09-11 | Sunds Defibrator | Saett foer framstaellning av kemimekanisk massa av loevved |
-
1988
- 1988-07-12 FR FR8809703A patent/FR2634233B1/fr not_active Expired - Fee Related
-
1989
- 1989-07-06 EP EP89420245A patent/EP0351330B1/fr not_active Expired - Lifetime
- 1989-07-06 NO NO892805A patent/NO176726C/no unknown
- 1989-07-06 DE DE68928822T patent/DE68928822T2/de not_active Expired - Fee Related
- 1989-07-06 AT AT89420245T patent/ATE171741T1/de not_active IP Right Cessation
- 1989-07-06 DE DE198989420245T patent/DE351330T1/de active Pending
- 1989-07-06 ES ES89420245T patent/ES2012324T3/es not_active Expired - Lifetime
- 1989-07-11 AU AU37999/89A patent/AU616541B2/en not_active Ceased
- 1989-07-11 FI FI893372A patent/FI96522C/fi not_active IP Right Cessation
- 1989-07-11 PT PT91128A patent/PT91128B/pt not_active IP Right Cessation
- 1989-07-11 NZ NZ229902A patent/NZ229902A/xx unknown
- 1989-07-11 CA CA000605392A patent/CA1335406C/fr not_active Expired - Fee Related
- 1989-07-12 JP JP1180113A patent/JPH0268377A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
AU3799989A (en) | 1990-01-18 |
CA1335406C (fr) | 1995-05-02 |
EP0351330A1 (fr) | 1990-01-17 |
DE351330T1 (de) | 1990-06-13 |
PT91128B (pt) | 1994-12-30 |
FI96522B (fi) | 1996-03-29 |
FI893372L (fi) | 1990-01-13 |
NO892805D0 (no) | 1989-07-06 |
DE68928822D1 (de) | 1998-11-05 |
PT91128A (pt) | 1990-02-08 |
NO176726C (no) | 1995-05-16 |
AU616541B2 (en) | 1991-10-31 |
NZ229902A (en) | 1991-09-25 |
NO892805L (no) | 1990-01-15 |
FR2634233A1 (fr) | 1990-01-19 |
ATE171741T1 (de) | 1998-10-15 |
ES2012324A4 (es) | 1990-03-16 |
FI96522C (fi) | 1996-07-10 |
FI893372A0 (fi) | 1989-07-11 |
JPH0268377A (ja) | 1990-03-07 |
EP0351330B1 (fr) | 1998-09-30 |
NO176726B (no) | 1995-02-06 |
FR2634233B1 (fr) | 1995-04-14 |
ES2012324T3 (es) | 1998-11-16 |
JPH0250236B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1990-11-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8328 | Change in the person/name/address of the agent |
Representative=s name: PATENTANWAELTE GESTHUYSEN, VON ROHR & EGGERT, 45128 |
|
8339 | Ceased/non-payment of the annual fee |