DE60114896T8 - Überbrückte Bisindenylmetallocenverbindungen - Google Patents

Überbrückte Bisindenylmetallocenverbindungen Download PDF

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Publication number
DE60114896T8
DE60114896T8 DE60114896T DE60114896T DE60114896T8 DE 60114896 T8 DE60114896 T8 DE 60114896T8 DE 60114896 T DE60114896 T DE 60114896T DE 60114896 T DE60114896 T DE 60114896T DE 60114896 T8 DE60114896 T8 DE 60114896T8
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DE
Germany
Prior art keywords
alkenyl
aryl
alkyl
metallocene compound
arylalkenyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
DE60114896T
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German (de)
English (en)
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DE60114896D1 (de
DE60114896T2 (de
Inventor
Matthew C. Kuchta
Udo M. Stehling
Robert T. Li
William T. Haygood
Terry J. Burkhardt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Priority claimed from US09/620,359 external-priority patent/US6376413B1/en
Priority claimed from US09/620,613 external-priority patent/US6380331B1/en
Priority claimed from US09/620,302 external-priority patent/US6376411B1/en
Priority claimed from US09/620,341 external-priority patent/US6380123B1/en
Priority claimed from US09/619,749 external-priority patent/US6376407B1/en
Priority claimed from US09/620,303 external-priority patent/US6414095B1/en
Priority claimed from US09/620,046 external-priority patent/US6380122B1/en
Priority claimed from US09/620,198 external-priority patent/US6380330B1/en
Priority claimed from US09/619,750 external-priority patent/US6380120B1/en
Priority claimed from US09/619,764 external-priority patent/US6376409B1/en
Priority claimed from US09/619,751 external-priority patent/US6380121B1/en
Priority claimed from US09/619,757 external-priority patent/US6380334B1/en
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of DE60114896D1 publication Critical patent/DE60114896D1/de
Application granted granted Critical
Publication of DE60114896T2 publication Critical patent/DE60114896T2/de
Publication of DE60114896T8 publication Critical patent/DE60114896T8/de
Active legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Indole Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
DE60114896T 2000-06-30 2001-05-21 Überbrückte Bisindenylmetallocenverbindungen Active DE60114896T8 (de)

Applications Claiming Priority (28)

Application Number Priority Date Filing Date Title
US21545900P 2000-06-30 2000-06-30
US21559700P 2000-06-30 2000-06-30
US215459P 2000-06-30
US215597P 2000-06-30
US09/620,303 US6414095B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,046 US6380122B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US620341 2000-07-19
US09/620,198 US6380330B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,764 US6376409B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US620302 2000-07-19
US09/619,751 US6380121B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US620613 2000-07-19
US619757 2000-07-19
US620198 2000-07-19
US09/620,613 US6380331B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US620303 2000-07-19
US09/619,757 US6380334B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US619764 2000-07-19
US09/620,359 US6376413B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,750 US6380120B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US619749 2000-07-19
US620359 2000-07-19
US619750 2000-07-19
US619751 2000-07-19
US09/619,749 US6376407B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US620046 2000-07-19
US09/620,341 US6380123B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,302 US6376411B1 (en) 2000-06-30 2000-07-19 Metallocene compositions

Publications (3)

Publication Number Publication Date
DE60114896D1 DE60114896D1 (de) 2005-12-15
DE60114896T2 DE60114896T2 (de) 2006-07-27
DE60114896T8 true DE60114896T8 (de) 2007-04-26

Family

ID=27585093

Family Applications (2)

Application Number Title Priority Date Filing Date
DE60102156T Active DE60102156T8 (de) 2000-06-30 2001-05-21 Verbrückte Bisindenyl Substituierte Metallocen-Verbindungen
DE60114896T Active DE60114896T8 (de) 2000-06-30 2001-05-21 Überbrückte Bisindenylmetallocenverbindungen

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE60102156T Active DE60102156T8 (de) 2000-06-30 2001-05-21 Verbrückte Bisindenyl Substituierte Metallocen-Verbindungen

Country Status (6)

Country Link
EP (2) EP1411058B1 (OSRAM)
JP (1) JP2004502698A (OSRAM)
AT (2) ATE260289T1 (OSRAM)
DE (2) DE60102156T8 (OSRAM)
ES (2) ES2247473T3 (OSRAM)
WO (1) WO2002002575A1 (OSRAM)

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CN105377904B (zh) 2013-07-17 2018-07-10 埃克森美孚化学专利公司 金属茂和由其衍生的催化剂组合物
JP2016531978A (ja) 2013-07-17 2016-10-13 エクソンモービル ケミカル パテンツ インコーポレイテッド 置換メタロセン触媒
EP3022233B1 (en) 2013-07-17 2019-05-01 ExxonMobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
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JP6201853B2 (ja) * 2014-03-25 2017-09-27 日本ポリプロ株式会社 メタロセン錯体及びオレフィン重合体の製造方法
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TW294669B (OSRAM) * 1992-06-27 1997-01-01 Hoechst Ag

Also Published As

Publication number Publication date
JP2004502698A (ja) 2004-01-29
ES2211808T3 (es) 2004-07-16
ATE309259T1 (de) 2005-11-15
WO2002002575A1 (en) 2002-01-10
DE60102156T2 (de) 2004-12-09
DE60114896D1 (de) 2005-12-15
ATE260289T1 (de) 2004-03-15
EP1294733A1 (en) 2003-03-26
DE60114896T2 (de) 2006-07-27
EP1411058A1 (en) 2004-04-21
EP1294733B1 (en) 2004-02-25
DE60102156D1 (de) 2004-04-01
EP1411058B1 (en) 2005-11-09
DE60102156T8 (de) 2005-06-23
ES2247473T3 (es) 2006-03-01

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