DE60024605T2 - Katalytische prozesse für die kontrollierte polymerisation von freiradikalischen, copolymerisierbaren monomeren und funktionellpolymersysteme hergestellt davon - Google Patents

Katalytische prozesse für die kontrollierte polymerisation von freiradikalischen, copolymerisierbaren monomeren und funktionellpolymersysteme hergestellt davon Download PDF

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Publication number
DE60024605T2
DE60024605T2 DE60024605T DE60024605T DE60024605T2 DE 60024605 T2 DE60024605 T2 DE 60024605T2 DE 60024605 T DE60024605 T DE 60024605T DE 60024605 T DE60024605 T DE 60024605T DE 60024605 T2 DE60024605 T2 DE 60024605T2
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Prior art keywords
polymerization
polymer
transition metal
atrp
initiator
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Expired - Lifetime
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DE60024605T
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German (de)
English (en)
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DE60024605D1 (de
Inventor
Krzysztof Matyjaszewski
G. Scott GAYNOR
Hyun-Jong Paik
Tomislav Pintauer
Jeff Pyun
Jian Qiu
Mircea Teodorescu
Jianhui Xia
Xuan Zhang
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Carnegie Mellon University
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Carnegie Mellon University
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/30—Electrodes characterised by their material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13—Energy storage using capacitors
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Power Engineering (AREA)
  • Materials Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
DE60024605T 1999-03-23 2000-03-23 Katalytische prozesse für die kontrollierte polymerisation von freiradikalischen, copolymerisierbaren monomeren und funktionellpolymersysteme hergestellt davon Expired - Lifetime DE60024605T2 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US12580999P 1999-03-23 1999-03-23
US125809P 1999-03-23
US14298099P 1999-07-12 1999-07-12
US142980P 1999-07-12
PCT/US2000/007905 WO2000056795A1 (en) 1999-03-23 2000-03-23 Catalytic processes for the controlled polymerization of free radically (co)polymerizable monomers and functional polymeric systems prepared thereby

Publications (2)

Publication Number Publication Date
DE60024605D1 DE60024605D1 (de) 2006-01-12
DE60024605T2 true DE60024605T2 (de) 2006-08-24

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Application Number Title Priority Date Filing Date
DE60024605T Expired - Lifetime DE60024605T2 (de) 1999-03-23 2000-03-23 Katalytische prozesse für die kontrollierte polymerisation von freiradikalischen, copolymerisierbaren monomeren und funktionellpolymersysteme hergestellt davon

Country Status (7)

Country Link
US (2) US7825199B1 (enExample)
EP (1) EP1171496B1 (enExample)
JP (2) JP5264030B2 (enExample)
AU (1) AU3919500A (enExample)
DE (1) DE60024605T2 (enExample)
TW (1) TWI291472B (enExample)
WO (1) WO2000056795A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007051694A1 (de) 2007-10-26 2009-04-30 Justus-Liebig-Universität Giessen Kupfer-Sauerstoff-Adduktkomplexe
DE102008002016A1 (de) * 2008-05-28 2009-12-03 Evonik Röhm Gmbh Verfahren zur Herstellung von silyl-funktionalisierten ABA-Triblockcopolymeren auf (Meth)acrylatbasis

Families Citing this family (132)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5807937A (en) 1995-11-15 1998-09-15 Carnegie Mellon University Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties
US7125938B2 (en) 1997-03-11 2006-10-24 Carnegie Mellon University Atom or group transfer radical polymerization
JP5264030B2 (ja) 1999-03-23 2013-08-14 カーネギー−メロン ユニバーシティ フリーラジカル的に（共）重合可能なモノマーの制御された重合のための触媒法、およびそれによって製造される官能性高分子系
US7049373B2 (en) 1999-08-06 2006-05-23 Carnegie Mellon University Process for preparation of graft polymers
US7141646B2 (en) 2000-05-12 2006-11-28 Kaneka Corporation Method of purifying vinyl polymer
AU2001296670A1 (en) 2000-10-06 2002-04-15 Carnegie-Mellon University A catalyst system for controlled polymerization
US7332550B2 (en) 2000-10-06 2008-02-19 Carnegie Mellon University Stabilization of transition metal complexes for catalysis in diverse environments
WO2002068485A1 (en) * 2000-12-22 2002-09-06 Carnegie Mellon University Process for preparation of graft polymers
AU2002307151A1 (en) 2001-04-06 2002-10-21 Carnegie Mellon University A process for the preparation of nanostructured materials
US6716949B2 (en) * 2001-09-20 2004-04-06 Hewlett-Packard Development Company, L.P. Amphipathic polymer particles and methods of manufacturing the same
US6723299B1 (en) 2001-05-17 2004-04-20 Zyvex Corporation System and method for manipulating nanotubes
EP1440988A4 (en) * 2001-08-31 2005-08-31 Kaneka Corp POLYOLEFINPROPOPOPOLYMER MADE IN THE PRESENCE OF A COORDINATION POLYMERIZATION CATALYST BASED ON A COMPLEX OF A LATE TRANSITION METAL AND METHOD FOR THE PRODUCTION THEREOF
WO2003031481A2 (en) 2001-10-12 2003-04-17 Carnegie Mellon University Simultaneous reverse and normal initiation of atrp
US7064166B2 (en) 2001-10-12 2006-06-20 Carnegie Mellon University Process for monomer sequence control in polymerizations
US7276574B2 (en) 2001-10-17 2007-10-02 Kaneka Corporation Process for producing vinyl polymer
WO2003038837A1 (en) 2001-10-29 2003-05-08 Hyperion Catalysis International, Inc. Polymer containing functionalized carbon nanotubes
US20040034177A1 (en) 2002-05-02 2004-02-19 Jian Chen Polymer and method for using the polymer for solubilizing nanotubes
US6905667B1 (en) 2002-05-02 2005-06-14 Zyvex Corporation Polymer and method for using the polymer for noncovalently functionalizing nanotubes
US6942120B2 (en) 2002-06-07 2005-09-13 S.C. Johnson & Son, Inc. Disposable bakeware with improved drip resistance at elevated temperatures
US20060052545A1 (en) * 2002-07-26 2006-03-09 Olvier Guerret Adhesive composition for a humid medium, based on block compolymers comprising at least one hydrophilic block
EP1534764B1 (en) 2002-08-09 2014-07-16 Carnegie Mellon University Polymers, supersoft elastomers and methods for preparing the same
US6992156B2 (en) * 2002-12-31 2006-01-31 The Goodyear Tire & Rubber Company Controlled polymerization
JP2004240114A (ja) * 2003-02-05 2004-08-26 Fuji Photo Film Co Ltd 表面機能性部材
DE10312278A1 (de) 2003-03-19 2004-09-30 Röhm GmbH & Co. KG Verfahren zur Abrennung von Übergangsmetallen aus Polymeren
WO2004106420A2 (en) 2003-05-22 2004-12-09 Zyvex Corporation Nanocomposites and method for production
GB0314472D0 (en) * 2003-06-20 2003-07-23 Warwick Effect Polymers Ltd Polymer
US7226957B1 (en) * 2003-11-03 2007-06-05 University Of Iowa Research Foundation Method for producing polymers with controlled molecular weight and end group functionality using photopolymerization in microemulsions
US7795355B2 (en) 2004-03-05 2010-09-14 Carnegie Mellon University Preparation of functional polymers
US7893174B2 (en) 2004-03-05 2011-02-22 Carnegie Mellon University Atom transfer radical polymerization process
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
FR2870245B1 (fr) * 2004-05-14 2008-08-22 Rhodia Chimie Sa Synthese de copolymeres en forme d'etoile mikto par polymerisation radicalaire controlee
US20080044733A1 (en) * 2004-05-14 2008-02-21 Tsumoru Ohata Lithium Ion Secondary Battery and Method for Producing the Same
US7296576B2 (en) 2004-08-18 2007-11-20 Zyvex Performance Materials, Llc Polymers for enhanced solubility of nanomaterials, compositions and methods therefor
US7420019B2 (en) * 2004-08-20 2008-09-02 Chevron Oronite Company Llc Method for preparation of polyolefins containing exo-olefin chain ends
US7705090B2 (en) * 2004-08-20 2010-04-27 Chevron Oronite Company Llc Method for preparing polyolefins containing a high percentage of exo-olefin chain ends
EP1786843A4 (en) * 2004-08-20 2011-08-31 Chevron Oronite Co PROCESS FOR PREPARING POLYOLEFINES WITH EXO-OLEFIN CHAIN ENDS
JP4645103B2 (ja) * 2004-08-30 2011-03-09 チッソ株式会社 ケイ素化合物
US8986780B2 (en) * 2004-11-19 2015-03-24 Massachusetts Institute Of Technology Method and apparatus for depositing LED organic film
EP1833894A1 (en) * 2004-12-16 2007-09-19 Pirelli & C. S.p.A. Process for manufacturing a thermoplastic elastomeric material
US7960305B2 (en) 2005-02-25 2011-06-14 Mitsui Chemicals, Inc. Polymerization catalyst composition and process for production of polymer
JP4543151B2 (ja) * 2005-03-17 2010-09-15 株式会社産学連携機構九州 重合体およびブロック共重合体の製造方法
US8153435B1 (en) 2005-03-30 2012-04-10 Tracer Detection Technology Corp. Methods and articles for identifying objects using encapsulated perfluorocarbon tracers
US20060264590A1 (en) * 2005-05-20 2006-11-23 Bridgestone Corporation Anionic polymerization initiators and polymers therefrom
US20060260677A1 (en) * 2005-05-23 2006-11-23 Cornell Research Foundation, Inc. Polypropylene silicate nanocomposites
EP1928919B1 (en) 2005-08-23 2010-02-17 Carnegie-Mellon University Atom transfer radical polymerization in microemulsion and true emulsion polymerization
CN101379091B (zh) 2005-08-26 2012-05-30 卡内基梅隆大学 在催化剂再生下的聚合方法
US20100311920A1 (en) * 2005-08-26 2010-12-09 Cid Centro De Investigacion Y Desarrollo Tecnologico Sa De Cv Using Reactive Block Copolymers as Chain Extenders and Surface Modifiers
EP1919972A1 (en) * 2005-08-30 2008-05-14 Pirelli & C. S.p.A. Process for manufacturing a thermoplastic elastomeric material
KR101046892B1 (ko) 2005-09-07 2011-07-06 닛뽕소다 가부시키가이샤 스타 폴리머 및 그 제조 방법
EP1944325B1 (en) * 2005-09-14 2014-06-04 Kyushu University, National University Corporation Process for production of polymer using iron complex as catalyst
DE602006010296D1 (de) * 2005-09-26 2009-12-24 Nippon Catalytic Chem Ind POLYMER UND VERFAHREN ZU SEINER HERSTELLUNG und ZEMENTMischung mit Polymer
US7723422B2 (en) 2005-12-23 2010-05-25 Boston Scientific Scimed, Inc. Functionalized block copolymers
US7470466B2 (en) 2005-12-23 2008-12-30 Boston Scientific Scimed, Inc. Nanoparticle structures and composite materials comprising a silicon-containing compound having a chemical linker that forms a non-covalent bond with a polymer
US8455088B2 (en) 2005-12-23 2013-06-04 Boston Scientific Scimed, Inc. Spun nanofiber, medical devices, and methods
KR20090005089A (ko) 2006-03-29 2009-01-12 미쓰이 가가쿠 가부시키가이샤 올레핀계 블록 폴리머를 포함하여 이루어지는 수지 조성물 및 그의 용도
EP2043776A4 (en) * 2006-05-29 2009-12-30 Ge Healthcare Bio Sciences Ab PREPARATION OF MONOLITHIC ARTICLES
CN101906195B (zh) 2006-07-11 2014-01-08 日本曹达株式会社 星形聚合物及其制造方法
US8349410B2 (en) 2006-08-17 2013-01-08 University of Pittsburgh—of the Commonwealth System of Higher Education Modification of surfaces with polymers
US20100311849A1 (en) * 2006-08-23 2010-12-09 Cid Centro De Investigacion Y Desarrollo Tecnologico Sa De Cv Using Reactive Block Copolymers as Chain Extenders and Surface Modifiers
WO2008057163A2 (en) 2006-10-09 2008-05-15 Carnegie Mellon University Preparation of functional gel particles with a dual crosslink network
CA2668925A1 (en) * 2006-11-10 2008-05-22 The Regents Of The University Of California Atmospheric pressure plasma-induced graft polymerization
AU2007341256B2 (en) * 2006-12-28 2012-09-20 Allnex Netherlands B.V. Waterborne polymeric dispersions
JP4344779B2 (ja) * 2007-03-20 2009-10-14 国立大学法人九州大学 鉄錯体及び該鉄錯体を触媒とする重合体の製造方法
US8865797B2 (en) 2007-05-23 2014-10-21 Carnegie Mellon University Hybrid particle composite structures with reduced scattering
GB2463199B (en) 2007-05-23 2012-09-26 Univ Carnegie Mellon Atom transfer dispersion polymerization
KR20100041850A (ko) * 2007-07-25 2010-04-22 리달 솔루테크 비.브이. 친수성 막
AU2008297315A1 (en) * 2007-09-12 2009-03-19 Construction Research & Technology Gmbh Method for producing silane-modified copolymers
EP2055720A1 (en) * 2007-11-05 2009-05-06 Total Petrochemicals Research Feluy Predictive model for density and melt index of polymer leaving loop reactor
JP2009215373A (ja) * 2008-03-07 2009-09-24 Sumitomo Chemical Co Ltd ブロック共重合体、およびその製造方法
US20090311540A1 (en) * 2008-06-11 2009-12-17 Yoram Cohen Highly Sensitive and Selective Nano-Structured Grafted Polymer Layers
US20090312586A1 (en) * 2008-06-13 2009-12-17 Marathon Gtf Technology, Ltd. Hydrogenation of multi-brominated alkanes
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
DE102008043658A1 (de) * 2008-11-12 2010-05-20 Evonik Röhm Gmbh Verfahren zur Herstellung von AB-Diblockcopolymeren mit einem breit verteilten A-Block
DE102008043669A1 (de) * 2008-11-12 2010-05-20 Evonik Röhm Gmbh Verfahren zur Herstellung von ABA-Triblockcopolymeren mit einem breit verteilten B-Block
DE102008043668A1 (de) * 2008-11-12 2010-05-20 Evonik Röhm Gmbh Verfahren zur Herstellung von ABA-Triblockcopolymeren mit einem bimodalen B-Block
JP5495736B2 (ja) * 2008-12-11 2014-05-21 三菱レイヨン株式会社 改良された重合方法
JP5638003B2 (ja) 2009-01-12 2014-12-10 ユニバーシティ オブ マサチューセッツ ローウェル ポリイソブチレン系ポリウレタン
WO2010111708A1 (en) 2009-03-27 2010-09-30 Carnegie Mellon University Preparation of functional star macromolecules
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8816001B2 (en) 2010-09-10 2014-08-26 Franklin And Marshall College Genetically encoded initiator for polymer growth from proteins
US9644042B2 (en) 2010-12-17 2017-05-09 Carnegie Mellon University Electrochemically mediated atom transfer radical polymerization
JP5890324B2 (ja) * 2011-01-27 2016-03-22 東亞合成株式会社 カルボキシル基含有重合体の製造方法
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
CN102286112B (zh) * 2011-05-12 2012-10-17 北京化工大学 一种水溶性单体可控/活性自由基聚合的方法
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US20140275420A1 (en) 2011-08-22 2014-09-18 Carnegie Mellon University Atom transfer radical polymerization under biologically compatible conditions
SG2014014492A (en) 2011-08-30 2014-05-29 Basf Se Production of polymers by means of controlled radical polymerisation
US9790305B2 (en) 2011-09-09 2017-10-17 Franklin And Marshall College Site specifically incorporated initiator for growth of polymers from proteins
JP6055833B2 (ja) * 2011-09-19 2016-12-27 ヘンケル アイピー アンド ホールディング ゲゼルシャフト ミット ベシュレンクテル ハフツング 高官能化樹脂ブレンド
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
WO2013158183A2 (en) 2012-01-27 2013-10-24 Carnegie Mellon University Processable self-organizing nanoparticles
WO2013126745A2 (en) * 2012-02-23 2013-08-29 Carnegie Mellon University Ligands designed to provide highly active catalyst complexes
CN104870485A (zh) 2012-12-18 2015-08-26 汉高知识产权控股有限责任公司 支化聚丙烯酸酯的受控自由基聚合的方法
WO2014116672A1 (en) 2013-01-22 2014-07-31 Carnegie Mellon University Lignin-containing polymers and compositions including lignin-containing polymers
US8883941B2 (en) * 2013-03-18 2014-11-11 Henkel Corporation Methods and apparatus for controlled single electron transfer living radical polymerization
KR101466479B1 (ko) * 2013-04-12 2014-12-02 영남대학교 산학협력단 원자이동라디칼중합(atrp)을 이용한 폴리비닐아세테이트 합성방법 및 상기 합성방법에 따라 얻어진 폴리비닐아세테이트
US9765169B2 (en) 2013-04-18 2017-09-19 Carnegie Mellon University Functionalized polymer hybrids
US9782727B2 (en) 2014-07-14 2017-10-10 International Business Machines Corporation Filtration membranes with functionalized star polymers
KR101652176B1 (ko) * 2014-10-22 2016-08-30 영남대학교 산학협력단 초임계이산화탄소 내에서 전자이동활성제 재생 원자이동라디칼중합을 이용한 폴리비닐아세테이트 합성방법
US9982070B2 (en) 2015-01-12 2018-05-29 Carnegie Mellon University Aqueous ATRP in the presence of an activator regenerator
US10005042B2 (en) 2015-02-16 2018-06-26 International Business Machines Corporation Thin film composite forward osmosis membranes with performance enhancing layers
US9931598B2 (en) 2015-02-16 2018-04-03 International Business Machines Corporation Anti-fouling coatings with star polymers for filtration membranes
JP2018525463A (ja) * 2015-06-26 2018-09-06 フィッシャーヴェルケ ゲゼルシャフト ミット ベシュレンクテル ハフツング ウント コンパニー コマンディートゲゼルシャフトｆｉｓｃｈｅｒｗｅｒｋｅ ＧｍｂＨ ＆ Ｃｏ． ＫＧ 硬化剤系における開始剤としてのアルジミンおよびケチミンならびに、とりわけ固着技術用の相応の樹脂組成物
WO2017118544A1 (en) 2016-01-05 2017-07-13 Sabic Global Technologies B.V. Method for preparing ethylene copolymer
WO2017132137A1 (en) 2016-01-25 2017-08-03 Carnegie Mellon University Composite composition and modification of inorganic particles for use in composite compositions
KR102332048B1 (ko) * 2016-10-17 2021-11-29 오소본드 코포레이션 올리고머성 또는 폴리머성 항미생물제를 갖는 표면
US10982266B2 (en) 2016-11-03 2021-04-20 Carnegie Mellon University Nucleic acid-polymer conjugates for bright fluorescent tags
JP6965703B2 (ja) 2016-11-28 2021-11-10 東洋インキＳｃホールディングス株式会社 （メタ）アクリル系重合体、（メタ）アクリル系ブロック共重合体、顔料分散体、感光性着色組成物、カラーフィルタ、インキ組成物、複合ブロック共重合体、顔料分散剤。
WO2018132582A1 (en) 2017-01-12 2018-07-19 Carnegie Mellon University Surfactant assisted formation of a catalyst complex for emulsion atom transfer radical polymerization processes
WO2018132696A2 (en) 2017-01-12 2018-07-19 Russell Alan J Stomach acid-stable and mucin-binding protein-polymer conjugates
CN110382568B (zh) 2017-03-07 2022-03-04 心脏起搏器股份公司 烯丙基封端的聚异丁烯的硼氢化/氧化
KR101893690B1 (ko) * 2017-05-12 2018-08-31 부산대학교 산학협력단 에폭시 접착제용 첨가제 및 이를 포함하는 구조용 에폭시 접착제 조성물
CN107056976B (zh) * 2017-05-31 2019-05-21 华中科技大学 一种碱活化卤代烃作用的反向原子转移自由基聚合方法
JP7311510B2 (ja) * 2017-12-06 2023-07-19 ディディピー スペシャルティ エレクトロニック マテリアルズ ユーエス，エルエルシー 酸化スズ（ｉｉ）を含む陰イオン交換体によるクロム（ｉｖ）を含有する水の処理
US11472911B2 (en) 2018-01-17 2022-10-18 Cardiac Pacemakers, Inc. End-capped polyisobutylene polyurethane
WO2019204799A1 (en) 2018-04-20 2019-10-24 University Of Pittsburgh -Of The Commonwealth System Of Higher Education Cationic amphiphilic polymers for codelivery of hydrophobic agents and nucleic acids
US20210237002A1 (en) * 2018-06-05 2021-08-05 Rensselaer Polytechnic Institute Rapid and facile membrane adsorber fabrication with ultra high binding capacity
US11472894B2 (en) 2018-07-23 2022-10-18 Carnegie Mellon University Enzyme-assisted ATRP procedures
WO2020028715A1 (en) 2018-08-01 2020-02-06 Russell Alan J Amino-reactive positively charged atrp initiators that maintain their positive charge during synthesis of biomacro-initiators
CA3112451A1 (en) 2018-10-12 2020-04-16 University Of Pittsburgh-Of The Commonwealth System Of Higher Education Small polymeric carriers for delivery of agents
WO2021222655A1 (en) * 2020-04-30 2021-11-04 Dow Global Technologies Llc Process for preparing olefin-acrylate block copolymers by atrp
JP2025097474A (ja) 2023-12-19 2025-07-01 Dic株式会社 重合体の製造方法、重合体、組成物、レジスト組成物およびレジストパターン
CN119751751B (zh) * 2024-12-30 2025-10-31 齐鲁工业大学(山东省科学院) 一种耐高温高盐聚合物及其制备与应用
CN119978251B (zh) * 2025-04-14 2025-07-11 山东三润助剂科技股份有限公司 一种透明型pvc加工改性剂及其制备方法

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3183217A (en) 1961-03-01 1965-05-11 Exxon Research Engineering Co Copolymerization of polar with nonpolar monomers in the presence of a friedel-craftsand a free radical initator
US4007165A (en) 1971-06-01 1977-02-08 Pennwalt Corporation Unsymmetrical tertiary-aliphatic azoalkanes
US3959225A (en) 1974-03-20 1976-05-25 Exxon Research And Engineering Company Thermally-staged polymer process
US4374751A (en) 1980-08-08 1983-02-22 General Electric Company Polymerization initiator compositions
US4728706A (en) 1986-08-29 1988-03-01 E. I. Du Pont De Nemours And Company Titanium, zirconium- and hafnium containing initiators in the polymerization of acrylic monomers to "living" polymers
US5089135A (en) 1988-01-20 1992-02-18 Mitsubishi Rayon Co., Ltd. Carbon based porous hollow fiber membrane and method for producing same
US4940648A (en) 1988-02-12 1990-07-10 Hoechst Celanese Corporation Increased sensitivity photoinitiation compositions
US5169914A (en) 1988-05-03 1992-12-08 Edison Polymer Innovation Corporation Uniform molecular weight polymers
CA1326322C (en) 1988-05-03 1994-01-18 Gabor Kaszas Uniform molecular weight polymers
US4954416A (en) 1988-12-21 1990-09-04 Minnesota Mining And Manufacturing Company Tethered sulfonium salt photoinitiators for free radical polymerization
ES2113431T3 (es) 1991-07-15 1998-05-01 Exxon Chemical Patents Inc Procedimiento de polimerizacion carbocationica viva.
US5405913A (en) 1993-03-22 1995-04-11 The University Of Akron Free radical copper(II)-enolate polymerization initiators
US5510307A (en) 1993-04-08 1996-04-23 Isp Investments Inc. Free radical initiator delivery system
US5312871A (en) 1993-07-27 1994-05-17 Carnegie Mellon University Free radical polymerization process
US6541580B1 (en) 1995-03-31 2003-04-01 Carnegie Mellon University Atom or group transfer radical polymerization
US5763548A (en) 1995-03-31 1998-06-09 Carnegie-Mellon University (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization
US5807937A (en) 1995-11-15 1998-09-15 Carnegie Mellon University Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties
US5789487A (en) 1996-07-10 1998-08-04 Carnegie-Mellon University Preparation of novel homo- and copolymers using atom transfer radical polymerization
US5910549A (en) 1996-08-22 1999-06-08 Carnegie-Mellon University Method for preparation of alkoxyamines from nitroxyl radicals
TW593347B (en) * 1997-03-11 2004-06-21 Univ Carnegie Mellon Improvements in atom or group transfer radical polymerization
JP3946309B2 (ja) 1997-04-10 2007-07-18 富士フイルム株式会社 着色感光性組成物
US5986015A (en) 1997-05-16 1999-11-16 The Procter & Gamble Company Method of making graft polymers
US5891971A (en) * 1997-08-15 1999-04-06 Xerox Corporation Polymerization processes
JP3620248B2 (ja) * 1997-12-01 2005-02-16 財団法人化学技術戦略推進機構 リビングラジカル重合開始剤系及びそれを用いる重合体の製造方法
US6121371A (en) 1998-07-31 2000-09-19 Carnegie Mellon University Application of atom transfer radical polymerization to water-borne polymerization systems
JP3832133B2 (ja) * 1999-03-16 2006-10-11 財団法人化学技術戦略推進機構 リビングラジカル重合開始剤系及びそれを用いる重合体の製造方法
JP5264030B2 (ja) 1999-03-23 2013-08-14 カーネギー−メロン ユニバーシティ フリーラジカル的に（共）重合可能なモノマーの制御された重合のための触媒法、およびそれによって製造される官能性高分子系
AU2002216619A1 (en) 2000-10-06 2002-04-15 Carnegie-Mellon University Polymerization process for ionic monomers
AU2002211467A1 (en) 2000-10-06 2002-04-15 Carnegie-Mellon University Preparation of nanocomposite structures by controlled polymerization

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007051694A1 (de) 2007-10-26 2009-04-30 Justus-Liebig-Universität Giessen Kupfer-Sauerstoff-Adduktkomplexe
US8338600B2 (en) 2007-10-26 2012-12-25 Justus-Liebig-Universitat Giessen Copper-oxygen adduct complexes, and methods of making and use
DE102008002016A1 (de) * 2008-05-28 2009-12-03 Evonik Röhm Gmbh Verfahren zur Herstellung von silyl-funktionalisierten ABA-Triblockcopolymeren auf (Meth)acrylatbasis

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