DE60023353T2 - Lichtstabile gegenstände - Google Patents
Lichtstabile gegenstände Download PDFInfo
- Publication number
- DE60023353T2 DE60023353T2 DE60023353T DE60023353T DE60023353T2 DE 60023353 T2 DE60023353 T2 DE 60023353T2 DE 60023353 T DE60023353 T DE 60023353T DE 60023353 T DE60023353 T DE 60023353T DE 60023353 T2 DE60023353 T2 DE 60023353T2
- Authority
- DE
- Germany
- Prior art keywords
- light
- article
- composition
- hals
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 claims abstract description 33
- 229920006267 polyester film Polymers 0.000 claims abstract description 25
- 150000001875 compounds Chemical class 0.000 claims abstract description 22
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims abstract description 10
- 150000001412 amines Chemical class 0.000 claims abstract description 6
- 239000004611 light stabiliser Substances 0.000 claims abstract description 5
- 229920000642 polymer Polymers 0.000 claims description 17
- 230000000475 sunscreen effect Effects 0.000 claims description 11
- 239000000516 sunscreening agent Substances 0.000 claims description 11
- 239000003381 stabilizer Substances 0.000 claims description 9
- 239000011888 foil Substances 0.000 claims description 6
- ZSSVCEUEVMALRD-UHFFFAOYSA-N 2-[4,6-bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-(octyloxy)phenol Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C1=NC(C=2C(=CC(C)=CC=2)C)=NC(C=2C(=CC(C)=CC=2)C)=N1 ZSSVCEUEVMALRD-UHFFFAOYSA-N 0.000 claims description 5
- LKPFBGKZCCBZDK-UHFFFAOYSA-N n-hydroxypiperidine Chemical class ON1CCCCC1 LKPFBGKZCCBZDK-UHFFFAOYSA-N 0.000 claims description 3
- 238000006068 polycondensation reaction Methods 0.000 claims description 3
- 230000001681 protective effect Effects 0.000 claims description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 claims description 3
- YAXWOADCWUUUNX-UHFFFAOYSA-N 1,2,2,3-tetramethylpiperidine Chemical compound CC1CCCN(C)C1(C)C YAXWOADCWUUUNX-UHFFFAOYSA-N 0.000 claims description 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 2
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 claims description 2
- LEVFXWNQQSSNAC-UHFFFAOYSA-N 2-(4,6-diphenyl-1,3,5-triazin-2-yl)-5-hexoxyphenol Chemical compound OC1=CC(OCCCCCC)=CC=C1C1=NC(C=2C=CC=CC=2)=NC(C=2C=CC=CC=2)=N1 LEVFXWNQQSSNAC-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims 1
- 238000010276 construction Methods 0.000 abstract description 15
- 239000002131 composite material Substances 0.000 abstract description 7
- 239000002356 single layer Substances 0.000 abstract description 2
- 230000000087 stabilizing effect Effects 0.000 abstract description 2
- 239000010408 film Substances 0.000 description 46
- 229920000728 polyester Polymers 0.000 description 22
- 239000010410 layer Substances 0.000 description 16
- -1 polyethylene Polymers 0.000 description 14
- 230000003287 optical effect Effects 0.000 description 13
- 238000000034 method Methods 0.000 description 11
- 239000000463 material Substances 0.000 description 9
- 238000005266 casting Methods 0.000 description 8
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 239000004698 Polyethylene Substances 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 230000005855 radiation Effects 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 238000009998 heat setting Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229920001225 polyester resin Polymers 0.000 description 5
- 239000004645 polyester resin Substances 0.000 description 5
- GGUBFICZYGKNTD-UHFFFAOYSA-N triethyl phosphonoacetate Chemical compound CCOC(=O)CP(=O)(OCC)OCC GGUBFICZYGKNTD-UHFFFAOYSA-N 0.000 description 5
- 230000008033 biological extinction Effects 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 239000012788 optical film Substances 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- JLZIIHMTTRXXIN-UHFFFAOYSA-N 2-(2-hydroxy-4-methoxybenzoyl)benzoic acid Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1C(O)=O JLZIIHMTTRXXIN-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- BBITXNWQALLODC-UHFFFAOYSA-N 2-[4-(4-oxo-3,1-benzoxazin-2-yl)phenyl]-3,1-benzoxazin-4-one Chemical compound C1=CC=C2C(=O)OC(C3=CC=C(C=C3)C=3OC(C4=CC=CC=C4N=3)=O)=NC2=C1 BBITXNWQALLODC-UHFFFAOYSA-N 0.000 description 2
- STEYNUVPFMIUOY-UHFFFAOYSA-N 4-Hydroxy-1-(2-hydroxyethyl)-2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CC(O)CC(C)(C)N1CCO STEYNUVPFMIUOY-UHFFFAOYSA-N 0.000 description 2
- SWZOQAGVRGQLDV-UHFFFAOYSA-N 4-[2-(4-hydroxy-2,2,6,6-tetramethylpiperidin-1-yl)ethoxy]-4-oxobutanoic acid Chemical compound CC1(C)CC(O)CC(C)(C)N1CCOC(=O)CCC(O)=O SWZOQAGVRGQLDV-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- JVLRYPRBKSMEBF-UHFFFAOYSA-K diacetyloxystibanyl acetate Chemical compound [Sb+3].CC([O-])=O.CC([O-])=O.CC([O-])=O JVLRYPRBKSMEBF-UHFFFAOYSA-K 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 2
- 239000004005 microsphere Substances 0.000 description 2
- 125000005487 naphthalate group Chemical group 0.000 description 2
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 2
- 230000003711 photoprotective effect Effects 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920006254 polymer film Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000004224 protection Effects 0.000 description 2
- 239000011253 protective coating Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000002310 reflectometry Methods 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- OLFNXLXEGXRUOI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-phenylpropan-2-yl)phenol Chemical compound C=1C(N2N=C3C=CC=CC3=N2)=C(O)C(C(C)(C)C=2C=CC=CC=2)=CC=1C(C)(C)C1=CC=CC=C1 OLFNXLXEGXRUOI-UHFFFAOYSA-N 0.000 description 1
- OWXXKGVQBCBSFJ-UHFFFAOYSA-N 6-n-[3-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]-[2-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]-[3-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]ami Chemical compound N=1C(NCCCN(CCN(CCCNC=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)C=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)C=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)=NC(N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)=NC=1N(CCCC)C1CC(C)(C)N(C)C(C)(C)C1 OWXXKGVQBCBSFJ-UHFFFAOYSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 229910000968 Chilled casting Inorganic materials 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- MUXOBHXGJLMRAB-UHFFFAOYSA-N Dimethyl succinate Chemical compound COC(=O)CCC(=O)OC MUXOBHXGJLMRAB-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- MCVFQMKVVDTIKL-UHFFFAOYSA-N [4-[2-[2-(4-benzoyl-3-hydroxyphenoxy)ethoxy]ethoxy]-2-hydroxyphenyl]-phenylmethanone Chemical compound C=1C=C(C(=O)C=2C=CC=CC=2)C(O)=CC=1OCCOCCOC(C=C1O)=CC=C1C(=O)C1=CC=CC=C1 MCVFQMKVVDTIKL-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 229940011182 cobalt acetate Drugs 0.000 description 1
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000013213 extrapolation Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- QQVIHTHCMHWDBS-UHFFFAOYSA-L isophthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC(C([O-])=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-L 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229940071125 manganese acetate Drugs 0.000 description 1
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229960005137 succinic acid Drugs 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
- C08K5/5333—Esters of phosphonic acids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Confectionery (AREA)
- Materials For Medical Uses (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US54815500A | 2000-04-13 | 2000-04-13 | |
| US548155 | 2000-04-13 | ||
| PCT/US2000/021314 WO2001079340A1 (en) | 2000-04-13 | 2000-08-04 | Light stable articles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60023353D1 DE60023353D1 (de) | 2006-03-02 |
| DE60023353T2 true DE60023353T2 (de) | 2006-07-06 |
Family
ID=24187638
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60023353T Expired - Lifetime DE60023353T2 (de) | 2000-04-13 | 2000-08-04 | Lichtstabile gegenstände |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6613819B2 (https=) |
| EP (1) | EP1274784B1 (https=) |
| JP (1) | JP2003532752A (https=) |
| KR (1) | KR100650482B1 (https=) |
| AT (1) | ATE307165T1 (https=) |
| AU (1) | AU2000266214A1 (https=) |
| DE (1) | DE60023353T2 (https=) |
| WO (1) | WO2001079340A1 (https=) |
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CO5231248A1 (es) | 2000-07-26 | 2002-12-27 | Ciba Sc Holding Ag | Articulos transparentes de polimero de baja consistencia |
| KR20020030007A (ko) * | 2000-09-29 | 2002-04-22 | 힐커트 | 결정성 열가소성 수지로부터 제조된 내가수분해성 투명이축배향 필름 및 그 제조방법 |
| US6562083B2 (en) * | 2001-04-02 | 2003-05-13 | Ciba Specialty Chemicals Corporation | Candle wax stabilized with s-triazines/hals |
| EP1302309B2 (en) * | 2001-10-12 | 2016-09-07 | SABIC Innovative Plastics IP B.V. | Multi-layer, weatherable compositions and method of manufacture thereof |
| US7297409B2 (en) | 2001-10-12 | 2007-11-20 | Sabic Innovative Plastics Ip Bv | Multilayer, weatherable compositions and method of manufacture thereof |
| KR100583387B1 (ko) * | 2001-11-20 | 2006-05-25 | 다케모토 유시 가부시키 가이샤 | 열가소성 고분자용 자외선 흡수제 및 그의 제조방법 |
| DE10227442A1 (de) * | 2002-06-20 | 2004-01-08 | Mitsubishi Polyester Film Gmbh | Mehrschichtige, transparente, Folie aus Polyethylenterephthalat (PET) und Polyethylennaphthalat PEN) zur Herstellung von Verbundverpackungen mit UV-Schutz |
| US6811841B1 (en) * | 2003-04-15 | 2004-11-02 | 3M Innovative Properties Company | Light-stable structures |
| JP2004352803A (ja) * | 2003-05-28 | 2004-12-16 | Daicel Chem Ind Ltd | ヒンダードアミン化合物 |
| JPWO2005109052A1 (ja) * | 2004-05-12 | 2008-03-21 | 株式会社Adeka | 光学フィルム |
| JP2006077148A (ja) * | 2004-09-10 | 2006-03-23 | Mitsubishi Polyester Film Copp | 光学フィルム用ポリエテルフィルム |
| DE102004046771A1 (de) * | 2004-09-24 | 2006-04-06 | Zimmer Ag | Mischung, Polyesterzusammensetzung, Folie sowie Verfahren zu deren Herstellung |
| US7329465B2 (en) | 2004-10-29 | 2008-02-12 | 3M Innovative Properties Company | Optical films incorporating cyclic olefin copolymers |
| US7582690B2 (en) | 2004-11-19 | 2009-09-01 | Eastman Chemical Company | Stabilized aliphatic polyester compositions |
| DE602005016714D1 (de) | 2004-12-06 | 2009-10-29 | Eastman Chem Co | Cobaltkonzentrate auf polyesterbasis für sauerstoffspülende zusammensetzungen |
| WO2006063032A2 (en) * | 2004-12-06 | 2006-06-15 | Constar International Inc. | Blends of oxygen scavenging polyamides with polyesters which contain zinc and cobalt |
| US7375154B2 (en) * | 2004-12-06 | 2008-05-20 | Eastman Chemical Company | Polyester/polyamide blend having improved flavor retaining property and clarity |
| US20060227421A1 (en) | 2005-04-06 | 2006-10-12 | Stover Carl A | Optical bodies including strippable boundary layers |
| US9709700B2 (en) | 2005-04-06 | 2017-07-18 | 3M Innovative Properties Company | Optical bodies including rough strippable boundary layers |
| WO2006107969A1 (en) | 2005-04-06 | 2006-10-12 | 3M Innovative Properties Company | Optical bodies including rough strippable boundary layers and asymmetric surface structures |
| US7586566B2 (en) * | 2005-06-03 | 2009-09-08 | 3M Innovative Properties Company | Brightness enhancing film and display device having the same |
| US7557989B2 (en) * | 2005-06-03 | 2009-07-07 | 3M Innovative Properties Company | Reflective polarizer and display device having the same |
| US20070203267A1 (en) | 2006-02-28 | 2007-08-30 | 3M Innovative Properties Company | Optical display with fluted optical plate |
| US7766531B2 (en) * | 2006-03-29 | 2010-08-03 | 3M Innovative Properties Company | Edge-lit optical display with fluted optical plate |
| US20080063900A1 (en) * | 2006-09-11 | 2008-03-13 | Hewlett-Packard Development Company Lp | Optical storage medium |
| JP2008266470A (ja) * | 2007-04-20 | 2008-11-06 | Unitika Ltd | ポリ乳酸系樹脂組成物、およびそれを成形してなる成形体 |
| US20080292820A1 (en) | 2007-05-23 | 2008-11-27 | 3M Innovative Properties Company | Light diffusing solar control film |
| KR101530407B1 (ko) * | 2008-01-08 | 2015-06-19 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 나노입자 분산물, 그를 포함하는 조성물, 및 그로부터 제조된 용품 |
| US20090283133A1 (en) * | 2008-05-14 | 2009-11-19 | 3M Innovative Properties Company | Solar concentrating mirror |
| US20090283144A1 (en) * | 2008-05-14 | 2009-11-19 | 3M Innovative Properties Company | Solar concentrating mirror |
| KR101011009B1 (ko) * | 2008-06-20 | 2011-01-26 | 김태형 | 정수 꼭지필터 카트리지 및 이를 적용한 정수기 |
| US8865293B2 (en) | 2008-12-15 | 2014-10-21 | 3M Innovative Properties Company | Optically active materials and articles and systems in which they may be used |
| US9523516B2 (en) | 2008-12-30 | 2016-12-20 | 3M Innovative Properties Company | Broadband reflectors, concentrated solar power systems, and methods of using the same |
| ES2463674T3 (es) | 2009-01-19 | 2014-05-28 | Basf Se | Pigmentos negros orgánicos y su preparación |
| DE102009032820A1 (de) * | 2009-07-13 | 2011-01-20 | Mitsubishi Polyester Film Gmbh | Ein- oder mehrschichtige, stabilisierte Polyesterfolie |
| WO2011062836A1 (en) | 2009-11-18 | 2011-05-26 | 3M Innovative Properties Company | Multi-layer optical films |
| KR100971930B1 (ko) * | 2010-01-26 | 2010-07-22 | 조원재 | 정수 탱크 및 그에 따른 자연여과식 정수기 |
| GB201001947D0 (en) * | 2010-02-05 | 2010-03-24 | Dupont Teijin Films Us Ltd | Polyester films |
| JP5650565B2 (ja) * | 2011-03-02 | 2015-01-07 | 帝人株式会社 | 難燃透明性共重合ポリエチレンナフタレート組成物 |
| US10137625B2 (en) | 2011-07-08 | 2018-11-27 | Toray Plastics (America), Inc. | Biaxially oriented bio-based polyester films and laminates |
| US20130344345A1 (en) * | 2011-07-08 | 2013-12-26 | Toray Plastics (America), Inc. | Biaxially oriented bio-based polyester window films and laminates |
| JP2013067811A (ja) * | 2012-12-06 | 2013-04-18 | Adeka Corp | 遮光フィルム |
| TW201435830A (zh) * | 2012-12-11 | 2014-09-16 | 3M Innovative Properties Co | 不顯眼之光學標籤及其方法 |
| KR101582369B1 (ko) * | 2012-12-27 | 2016-01-04 | 제일모직주식회사 | 열전사 필름 및 이를 사용하여 제조된 유기전계발광소자 |
| US20150352810A1 (en) * | 2013-03-05 | 2015-12-10 | Jeffrey Green | Graffiti covering skin |
| JP6809222B2 (ja) | 2015-03-17 | 2021-01-06 | 東レ株式会社 | 積層フィルム、それを用いた液晶ディスプレイ、タッチパネルおよび有機elディスプレイ |
| DE102016200875A1 (de) * | 2016-01-22 | 2017-07-27 | Mitsubishi Polyester Film Gmbh | Biaxial orientierte, UV-stabilisierte, ein- oder mehrschichtige Polyesterfolie mit einer Kombination aus Siliziumdioxidpartikeln als Lichtstreupartikel und einem UV-Stabilisator sowie Verfahren zu ihrer Herstellung und ihre Verwendung in Gewächshausschattenmatten |
| US10975221B2 (en) | 2016-10-27 | 2021-04-13 | 3M Innovative Properties Company | Crosslinkable composition including a (meth)acrylic polymer and methods of making a crosslinked composition |
| WO2019228959A1 (de) | 2018-05-29 | 2019-12-05 | Covestro Deutschland Ag | Opaker mehrschichtkörper aus polycarbonat mit hoher bewitterungsstabilität |
| CN114634652A (zh) * | 2022-01-07 | 2022-06-17 | 中国人民解放军国防科技大学 | 一种高效彩色隔热降温涂层及其制备方法和应用 |
Family Cites Families (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3124639A (en) | 1964-03-10 | figure | ||
| US540768A (en) | 1895-06-11 | Richard walsingham western | ||
| US3610729A (en) | 1969-06-18 | 1971-10-05 | Polaroid Corp | Multilayered light polarizer |
| US3860036A (en) | 1970-11-02 | 1975-01-14 | Dow Chemical Co | Variable geometry feed block for multilayer extrusion |
| US3711176A (en) | 1971-01-14 | 1973-01-16 | Dow Chemical Co | Highly reflective thermoplastic bodies for infrared, visible or ultraviolet light |
| US4024206A (en) * | 1975-11-19 | 1977-05-17 | Vistron Corporation | Stabilized brominated polyesters |
| JPS5379935A (en) * | 1976-12-24 | 1978-07-14 | Adeka Argus Chem Co Ltd | Stabilized synthetic resin composition |
| US4521588A (en) | 1981-03-02 | 1985-06-04 | Polaroid Corporation | Optical device including birefringent polyhydrazide polymer |
| US4446305A (en) | 1981-03-02 | 1984-05-01 | Polaroid Corporation | Optical device including birefringent polymer |
| US4525413A (en) | 1981-03-02 | 1985-06-25 | Polaroid Corporation | Optical device including birefringent polymer |
| US4520189A (en) | 1981-03-02 | 1985-05-28 | Polaroid Corporation | Optical device including birefringent aromatic amino carboxylic acid polymer |
| US4720426A (en) | 1986-06-30 | 1988-01-19 | General Electric Company | Reflective coating for solid-state scintillator bar |
| US5211878A (en) | 1988-03-10 | 1993-05-18 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Difluorobenzonitrile derivatives |
| US5486949A (en) | 1989-06-20 | 1996-01-23 | The Dow Chemical Company | Birefringent interference polarizer |
| US5235443A (en) | 1989-07-10 | 1993-08-10 | Hoffmann-La Roche Inc. | Polarizer device |
| US5319478A (en) | 1989-11-01 | 1994-06-07 | Hoffmann-La Roche Inc. | Light control systems with a circular polarizer and a twisted nematic liquid crystal having a minimum path difference of λ/2 |
| NL9000808A (nl) | 1990-04-06 | 1991-11-01 | Koninkl Philips Electronics Nv | Vloeibaar kristallijn materiaal en beeldweergeefcel die dit materiaal bevat. |
| DE69125095T2 (de) | 1990-10-29 | 1997-08-21 | Cytec Tech Corp | Hydroxyaryltriazine und Tetraalkylpiperidine enthaltende synergistische UV-Absorbermischung |
| US5217794A (en) | 1991-01-22 | 1993-06-08 | The Dow Chemical Company | Lamellar polymeric body |
| US5294657A (en) | 1992-05-15 | 1994-03-15 | Melendy Peter S | Adhesive composition with decorative glitter |
| DE4326521B4 (de) | 1992-08-10 | 2005-12-22 | Bridgestone Corp. | Lichtstreuendes Material und Verfahren zu seiner Herstellung |
| US5269995A (en) | 1992-10-02 | 1993-12-14 | The Dow Chemical Company | Coextrusion of multilayer articles using protective boundary layers and apparatus therefor |
| DE69325283T2 (de) | 1992-10-29 | 1999-11-04 | Minnesota Mining & Mfg | Formbarer reflektierender multischichtenkörper |
| TW289095B (https=) | 1993-01-11 | 1996-10-21 | ||
| DE69409977T2 (de) | 1993-01-11 | 1998-10-22 | Koninkl Philips Electronics Nv | Beleuchtungssystem und ein solches System umfassendes Anzeigegerät |
| FR2705679B1 (fr) | 1993-05-24 | 1998-07-10 | Sandoz Sa | Nouvelles compositions stabilisantes des matières polymères, à base de phosphonites ou phosphites et d'un stabilisant contre l'hydrolyse. |
| US5389324A (en) | 1993-06-07 | 1995-02-14 | The Dow Chemical Company | Layer thickness gradient control in multilayer polymeric bodies |
| US5486935A (en) | 1993-06-29 | 1996-01-23 | Kaiser Aerospace And Electronics Corporation | High efficiency chiral nematic liquid crystal rear polarizer for liquid crystal displays having a notch polarization bandwidth of 100 nm to 250 nm |
| US5882774A (en) | 1993-12-21 | 1999-03-16 | Minnesota Mining And Manufacturing Company | Optical film |
| EP0736187B1 (en) | 1993-12-21 | 2002-04-03 | Minnesota Mining And Manufacturing Company | Optical polarizer |
| AU1866395A (en) | 1993-12-21 | 1995-07-10 | Minnesota Mining And Manufacturing Company | Multilayered optical film |
| JP4091978B2 (ja) | 1993-12-21 | 2008-05-28 | スリーエム カンパニー | 明るさを強化した反射偏光子 |
| KR100407210B1 (ko) | 1993-12-21 | 2004-05-31 | 미네소타 마이닝 앤드 매뉴팩춰링 캄파니 | 반사편광기디스플레이 |
| US5629055A (en) | 1994-02-14 | 1997-05-13 | Pulp And Paper Research Institute Of Canada | Solidified liquid crystals of cellulose with optically variable properties |
| WO1995027919A2 (en) | 1994-04-06 | 1995-10-19 | Minnesota Mining And Manufacturing Company | Polarized light sources |
| JP4034365B2 (ja) | 1995-03-09 | 2008-01-16 | 大日本印刷株式会社 | 超微粒子含有反射防止フィルム、偏光板及び液晶表示装置 |
| US5751388A (en) | 1995-04-07 | 1998-05-12 | Honeywell Inc. | High efficiency polarized display |
| AU708412B2 (en) | 1995-06-26 | 1999-08-05 | Minnesota Mining And Manufacturing Company | Diffusely reflecting multilayer polarizers and mirrors |
| US6080467A (en) | 1995-06-26 | 2000-06-27 | 3M Innovative Properties Company | High efficiency optical devices |
| US5686979A (en) | 1995-06-26 | 1997-11-11 | Minnesota Mining And Manufacturing Company | Optical panel capable of switching between reflective and transmissive states |
| US5699188A (en) | 1995-06-26 | 1997-12-16 | Minnesota Mining And Manufacturing Co. | Metal-coated multilayer mirror |
| AU6390396A (en) | 1995-06-26 | 1997-01-30 | Minnesota Mining And Manufacturing Company | Multilayer polymer film with additional coatings or layers |
| US5767935A (en) | 1995-08-31 | 1998-06-16 | Sumitomo Chemical Company, Limited | Light control sheet and liquid crystal display device comprising the same |
| US5783120A (en) | 1996-02-29 | 1998-07-21 | Minnesota Mining And Manufacturing Company | Method for making an optical film |
| US5825543A (en) | 1996-02-29 | 1998-10-20 | Minnesota Mining And Manufacturing Company | Diffusely reflecting polarizing element including a first birefringent phase and a second phase |
| GB2311528A (en) * | 1996-03-29 | 1997-10-01 | Ciba Geigy Ag | Stabiliser mixtures for polyamides, polyesters and polyketones |
| US5808794A (en) | 1996-07-31 | 1998-09-15 | Weber; Michael F. | Reflective polarizers having extended red band edge for controlled off axis color |
| DE19630599A1 (de) * | 1996-07-31 | 1998-02-05 | Hoechst Ag | Polyethylenterephthalat-Platte mit verbesserter Hydrolysestabilität, Verfahren zur Herstellung und Verwendung |
| JPH10182805A (ja) * | 1996-12-27 | 1998-07-07 | Mitsui Chem Inc | ポリエチレンテレフタレ−トの製造方法 |
| GB2322374B (en) * | 1997-02-21 | 2001-04-04 | Ciba Sc Holding Ag | Stabilizer mixture for organic materials |
| US5824465A (en) * | 1997-04-07 | 1998-10-20 | Agfa-Gevaert, N.V. | Polyalkylene naphthalate film comprising specific UV-absorber |
| US5940149A (en) | 1997-12-11 | 1999-08-17 | Minnesota Mining And Manufacturing Company | Planar polarizer for LCD projectors |
| CA2316974A1 (en) | 1998-01-13 | 1999-07-22 | Minnesota Mining And Manufacturing Company | Process for making multilayer optical films |
| JP4274696B2 (ja) * | 1998-01-13 | 2009-06-10 | スリーエム カンパニー | 変性コポリエステルおよび改善された多層反射フィルム |
| US6136441A (en) * | 1998-03-24 | 2000-10-24 | General Electric Company | Multilayer plastic articles |
| MY119540A (en) * | 1998-04-24 | 2005-06-30 | Ciba Spacialty Chemicals Holding Inc | Increasing the molecular weight of polyesters |
| BR9911401A (pt) * | 1998-06-22 | 2001-03-20 | Cytec Tech Corp | Composto, processos de estabilização de um material que está sujeito a degradação por radiação actìnica, e de proteção de um substrato contra a degradação por radiação actìnica, composição de revestimento adequada para a formação de uma pelìcula estabilizada contra a degradação por radiação actìnica, composição de estabilização da radiação actìnica, material fotográfico, e, composição cosmética |
| EP0982356A3 (en) * | 1998-08-28 | 2001-11-07 | Clariant Finance (BVI) Limited | Improved stabilized coatings |
| US6274221B2 (en) * | 1999-01-29 | 2001-08-14 | 3M Innovative Properties Company | Angular brightness microprismatic retroreflective film or sheeting incorporating a syndiotactic vinyl aromatic polymer |
| US6265072B1 (en) * | 1999-04-27 | 2001-07-24 | Eastman Chemical Company | UV-stabilized polymeric structures |
| US6449093B2 (en) * | 1999-10-12 | 2002-09-10 | 3M Innovative Properties Company | Optical bodies made with a birefringent polymer |
-
2000
- 2000-08-04 JP JP2001576930A patent/JP2003532752A/ja active Pending
- 2000-08-04 WO PCT/US2000/021314 patent/WO2001079340A1/en not_active Ceased
- 2000-08-04 DE DE60023353T patent/DE60023353T2/de not_active Expired - Lifetime
- 2000-08-04 EP EP00953835A patent/EP1274784B1/en not_active Expired - Lifetime
- 2000-08-04 AU AU2000266214A patent/AU2000266214A1/en not_active Abandoned
- 2000-08-04 AT AT00953835T patent/ATE307165T1/de not_active IP Right Cessation
- 2000-08-04 KR KR1020027013719A patent/KR100650482B1/ko not_active Expired - Fee Related
-
2001
- 2001-06-27 US US09/893,200 patent/US6613819B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE60023353D1 (de) | 2006-03-02 |
| KR20020091201A (ko) | 2002-12-05 |
| KR100650482B1 (ko) | 2006-11-28 |
| US20020028862A1 (en) | 2002-03-07 |
| AU2000266214A1 (en) | 2001-10-30 |
| WO2001079340A1 (en) | 2001-10-25 |
| US6613819B2 (en) | 2003-09-02 |
| EP1274784B1 (en) | 2005-10-19 |
| ATE307165T1 (de) | 2005-11-15 |
| EP1274784A1 (en) | 2003-01-15 |
| JP2003532752A (ja) | 2003-11-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE60023353T2 (de) | Lichtstabile gegenstände | |
| DE69921806T3 (de) | Methoden und zusammensetzungen zum schutz von polymeren vor uv-licht | |
| EP1132424B1 (de) | Weisse, biaxial orientierte, schwer entflammbare und UV-stabilisierte Polyesterfolie mit Cycloolefincopolymer, Verfahren zu ihrer Herstellung und ihre Verwendung | |
| EP1127912A1 (de) | Weisse, biaxial orientierte und UV-stabilisierte Polyesterfolie mit Cycloolefincopolymer (COC), Verfahren zu ihrer Herstellung und ihre Verwendung | |
| EP1118635B1 (de) | Transparente, schwerentflammbare, UV-stabile Folie aus einem kristallisierbaren Thermoplasten | |
| DE10126149A1 (de) | Gedeckt eingefärbte, hydrolysebeständige, biaxial orientierte Folie aus einem kristallisierbaren Thermoplasten und Verfahren zu ihrer Herstellung | |
| DE10009295A1 (de) | Weisse, biaxial orientierte, schwer entflammbare Polyesterfolie mit Cycloolefincopolymer, Verfahren zu ihrer Herstellung und ihre Verwendung | |
| EP1125968B1 (de) | Weiss-opake, UV-stabilisierte Folie mit niedriger Transparanz aus einem kristallisierbaren Thermoplasten | |
| DE10002172A1 (de) | Transparente, UV-stabilisierte thermoformbare Folie aus kristallisierbaren Thermoplasten, Verfahren zu ihrer Herstellung und ihre Verwendung | |
| EP2275255B1 (de) | Ein- oder mehrschichtige, stabilisierte Polyesterfolie | |
| EP1125966A1 (de) | Weiss-opake, schwer entflammbare, UV-stabilisierte Folie mit niedriger Transparenz aus einem kristallisierbaren Thermoplasten | |
| DE102004032595A1 (de) | Matte, thermoformbare, IR-reflektierende Polyesterfolie | |
| EP1193050B1 (de) | Hydrolysebeständig ausgerüstete, transparente, biaxial orientierte Folie aus einem kristallisierbaren Thermoplasten und Verfahren zu ihrer Herstellung | |
| DE19630599A1 (de) | Polyethylenterephthalat-Platte mit verbesserter Hydrolysestabilität, Verfahren zur Herstellung und Verwendung | |
| EP1038905A2 (de) | Transparente, UV-stabilisierte Folie aus einem kristallisierbaren Thermoplast | |
| DE69514624T2 (de) | Methode zur Verhinderung der Fluoreszenzemission aus Polyalkylennaphthalin-2,6-dicarboxylat | |
| DE10002173A1 (de) | Transparente, schwerentflammbare, thermoformbare, UV-stabile Folie aus kristallisierbaren Thermoplasten, Verfahren zu ihrer Herstellung und ihre Verwendung | |
| WO2002068511A1 (de) | Amorphe, funktionalisierte folie aus einem bibenzolmodifizierten thermoplasten, verfahren zu ihrer herstellung und ihre verwendung | |
| DE10022946A1 (de) | Weisse, zumindest einseitig matte, biaxial orientierte, UV-stabilisierte und schwer entflammbare Polyesterfolie mit Cycloolefincopolymer (COC), Verfahren zu ihrer Herstellung und ihre Verwendung | |
| DE10105108A1 (de) | Funktionalisierte, transparente, antimikrobielle, biaxial orientierte, teilkristalline Folie aus einem kristallisierbaren Thermoplasten | |
| DE10026163A1 (de) | Weiße, hochglänzende, UV-stabilisierte, schwerentflammbare Polyesterfolie enthaltend Cycloolefincopolymer (COC), Verfahren zu ihrer Herstellung und ihre Verwendung | |
| DE10042329A1 (de) | Verbundfolie aus einer weißen, UV-stabilisierten, schwerentflammbaren Polyesterfolie enthaltend Cycloolefincopolymer (COC), Verfahren zu ihrer Herstellung und ihre Verwendung | |
| DE10026167A1 (de) | Weiße, hochglänzende, UV-stabilisierte Polyesterfolie enthaltend Cycloolefincopolymer (COC), Verfahren zu ihrer Herstellung und ihre Verwendung | |
| DE10012140A1 (de) | Eingefärbte, schwer entflammbare, UV-stabile, thermoformbare Folie aus einem kristallisierbaren Thermoplasten, Verfahren zu ihrer Herstellung und ihre Verwendung | |
| DE102006059888A1 (de) | Ein- oder mehrschichtige, stabilisierte Polyesterfolie |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition |