DE4013392A1 - Transparente und waermedehnungsfreie glaskeramik - Google Patents
Transparente und waermedehnungsfreie glaskeramikInfo
- Publication number
- DE4013392A1 DE4013392A1 DE4013392A DE4013392A DE4013392A1 DE 4013392 A1 DE4013392 A1 DE 4013392A1 DE 4013392 A DE4013392 A DE 4013392A DE 4013392 A DE4013392 A DE 4013392A DE 4013392 A1 DE4013392 A1 DE 4013392A1
- Authority
- DE
- Germany
- Prior art keywords
- glass
- weight
- glass ceramic
- thermal expansion
- proportion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002241 glass-ceramic Substances 0.000 title claims description 57
- 239000011521 glass Substances 0.000 claims description 55
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 45
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 41
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 claims description 21
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 20
- 235000012239 silicon dioxide Nutrition 0.000 claims description 19
- 229910052681 coesite Inorganic materials 0.000 claims description 18
- 229910052906 cristobalite Inorganic materials 0.000 claims description 18
- 239000000377 silicon dioxide Substances 0.000 claims description 18
- 229910052682 stishovite Inorganic materials 0.000 claims description 18
- 229910052905 tridymite Inorganic materials 0.000 claims description 18
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 16
- 229910052593 corundum Inorganic materials 0.000 claims description 16
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 16
- GOLCXWYRSKYTSP-UHFFFAOYSA-N Arsenious Acid Chemical compound O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 claims description 14
- 239000013078 crystal Substances 0.000 claims description 12
- 229910000174 eucryptite Inorganic materials 0.000 claims description 12
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 8
- 229910000500 β-quartz Inorganic materials 0.000 claims description 7
- 239000011159 matrix material Substances 0.000 claims description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 28
- 238000002425 crystallisation Methods 0.000 description 14
- 230000008025 crystallization Effects 0.000 description 14
- 239000011787 zinc oxide Substances 0.000 description 14
- 238000010438 heat treatment Methods 0.000 description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 10
- 238000011282 treatment Methods 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 230000006911 nucleation Effects 0.000 description 8
- 238000010899 nucleation Methods 0.000 description 8
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000000156 glass melt Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000006121 base glass Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000002667 nucleating agent Substances 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- DHAHRLDIUIPTCJ-UHFFFAOYSA-K aluminium metaphosphate Chemical compound [Al+3].[O-]P(=O)=O.[O-]P(=O)=O.[O-]P(=O)=O DHAHRLDIUIPTCJ-UHFFFAOYSA-K 0.000 description 1
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 1
- 229910000413 arsenic oxide Inorganic materials 0.000 description 1
- 229960002594 arsenic trioxide Drugs 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000008395 clarifying agent Substances 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(II) oxide Inorganic materials [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- KTTMEOWBIWLMSE-UHFFFAOYSA-N diarsenic trioxide Chemical compound O1[As](O2)O[As]3O[As]1O[As]2O3 KTTMEOWBIWLMSE-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N nickel(II) oxide Inorganic materials [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 239000005392 opalescent glass Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0036—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents
- C03C10/0045—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents containing SiO2, Al2O3 and MgO as main constituents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1111442A JPH0686310B2 (ja) | 1989-04-28 | 1989-04-28 | 透明非膨張性結晶化ガラス |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE4013392A1 true DE4013392A1 (de) | 1990-10-31 |
| DE4013392C2 DE4013392C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1992-06-11 |
Family
ID=14561304
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE4013392A Granted DE4013392A1 (de) | 1989-04-28 | 1990-04-26 | Transparente und waermedehnungsfreie glaskeramik |
Country Status (4)
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2657079B1 (fr) * | 1990-01-12 | 1993-04-09 | Corning France | Verres precurseurs de vitroceramiques, procede de conversion de ces verres en vitroceramiques a dilation tres faible ou nulle et vitroceramiques obtenues. |
| US6506699B1 (en) | 1998-10-23 | 2003-01-14 | Kabushiki Kaisha Ohara | Negative thermal expansion glass ceramic and method for producing the same |
| DE69927511T3 (de) * | 1999-05-28 | 2009-06-25 | Nippon Electric Glass Co., Ltd., Otsu | Transparentes kristallisiertes LI2O-AI2O3-SiO2-Glas |
| KR20020038675A (ko) * | 1999-07-07 | 2002-05-23 | 모리 데쯔지 | 온도 보상용 부재 및 이를 이용한 광 통신 디바이스 |
| JP4704585B2 (ja) * | 2000-07-07 | 2011-06-15 | 株式会社オハラ | 低膨張透明結晶化ガラス、結晶化ガラス基板及び光導波路素子 |
| US6768654B2 (en) * | 2000-09-18 | 2004-07-27 | Wavezero, Inc. | Multi-layered structures and methods for manufacturing the multi-layered structures |
| CN100462318C (zh) * | 2001-03-27 | 2009-02-18 | Hoya株式会社 | 玻璃陶瓷及其基片、液晶嵌镶板用对置基片和防尘基片 |
| US7226881B2 (en) * | 2003-09-19 | 2007-06-05 | Kabushiki Kaisha Ohara | Ultra low thermal expansion transparent glass ceramics |
| KR101245196B1 (ko) * | 2011-01-25 | 2013-03-19 | 주식회사 아앤시티 | 자이로스코프 |
| US9196396B2 (en) * | 2011-10-08 | 2015-11-24 | Graduate School At Shenzhen, Tsinghua University | Insulator and power transmission line apparatus |
| US9359251B2 (en) | 2012-02-29 | 2016-06-07 | Corning Incorporated | Ion exchanged glasses via non-error function compressive stress profiles |
| CH707926A1 (de) * | 2013-04-17 | 2014-10-31 | Saint Gobain | Herstellung einer Scheibe aus keramischem Glas. |
| ES2444740B2 (es) | 2013-11-13 | 2014-09-02 | Esmalglass, Sau | Material vitrocerámico traslúcido estructura albita |
| TWI773291B (zh) | 2014-06-19 | 2022-08-01 | 美商康寧公司 | 無易碎應力分布曲線的玻璃 |
| EP3848336A1 (en) | 2014-10-08 | 2021-07-14 | Corning Incorporated | Glasses and glass ceramics including a metal oxide concentration gradient |
| EP3075714B1 (en) | 2015-03-31 | 2017-08-09 | Consejo Superior De Investigaciones Cientificas | Glass-ceramic material of albite and/or anorthite exhibing warmth |
| US10579106B2 (en) | 2015-07-21 | 2020-03-03 | Corning Incorporated | Glass articles exhibiting improved fracture performance |
| US11613103B2 (en) | 2015-07-21 | 2023-03-28 | Corning Incorporated | Glass articles exhibiting improved fracture performance |
| DE202016008995U1 (de) | 2015-12-11 | 2021-04-20 | Corning Incorporated | Durch Fusion bildbare glasbasierte Artikel mit einem Metalloxidkonzentrationsgradienten |
| US10271442B2 (en) | 2016-04-08 | 2019-04-23 | Corning Incorporated | Glass-based articles including a stress profile comprising two regions, and methods of making |
| DE202017007020U1 (de) | 2016-04-08 | 2019-03-22 | Corning Incorporated | Artikel auf Glasbasis mit einem Metalloxid-Konzentrationsgradienten |
| US10626046B2 (en) | 2016-10-12 | 2020-04-21 | Corning Incorporated | Glass ceramics |
| JP7332601B2 (ja) * | 2019-04-01 | 2023-08-23 | 日本電気硝子株式会社 | Ｌｉ２Ｏ－Ａｌ２Ｏ３－ＳｉＯ２系結晶化ガラス |
| CN110776259A (zh) * | 2019-11-01 | 2020-02-11 | 湖南嘉盛电陶新材料股份有限公司 | 低膨胀系数的中低温环保型玻璃粉及其制备方法和应用 |
| WO2022080226A1 (ja) * | 2020-10-15 | 2022-04-21 | 日本電気硝子株式会社 | 結晶化ガラス |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0290146A1 (en) * | 1987-05-08 | 1988-11-09 | Corning Glass Works | Ceramic matrix composites |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL106596C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1958-03-03 | |||
| GB1010513A (en) * | 1962-02-02 | 1965-11-17 | Fuji Photo Film Co Ltd | Improvements in or relating to crystalline glass and to methods of making the same |
| US3252811A (en) * | 1963-12-11 | 1966-05-24 | Corning Glass Works | Glass-ceramic bodies and method of making them |
| US3380818A (en) * | 1964-03-18 | 1968-04-30 | Owens Illinois Inc | Glass composition and method and product |
| US4018612A (en) * | 1976-03-25 | 1977-04-19 | Corning Glass Works | Transparent beta-quartz glass-ceramics |
| US4507392A (en) * | 1983-12-08 | 1985-03-26 | Corning Glass Works | Transparent glass-ceramics of high negative expansion for use as decorative glazes |
| JP2668075B2 (ja) * | 1987-01-19 | 1997-10-27 | 日本板硝子株式会社 | 透明結晶化ガラス |
-
1989
- 1989-04-28 JP JP1111442A patent/JPH0686310B2/ja not_active Expired - Lifetime
-
1990
- 1990-04-23 US US07/512,366 patent/US5017519A/en not_active Expired - Fee Related
- 1990-04-23 GB GB9009049A patent/GB2234504B/en not_active Expired - Fee Related
- 1990-04-26 DE DE4013392A patent/DE4013392A1/de active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0290146A1 (en) * | 1987-05-08 | 1988-11-09 | Corning Glass Works | Ceramic matrix composites |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2234504A (en) | 1991-02-06 |
| US5017519A (en) | 1991-05-21 |
| JPH0686310B2 (ja) | 1994-11-02 |
| JPH02293345A (ja) | 1990-12-04 |
| GB9009049D0 (en) | 1990-06-20 |
| GB2234504B (en) | 1992-08-05 |
| DE4013392C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1992-06-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OP8 | Request for examination as to paragraph 44 patent law | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |