DE3712133C2 - - Google Patents
Info
- Publication number
- DE3712133C2 DE3712133C2 DE3712133A DE3712133A DE3712133C2 DE 3712133 C2 DE3712133 C2 DE 3712133C2 DE 3712133 A DE3712133 A DE 3712133A DE 3712133 A DE3712133 A DE 3712133A DE 3712133 C2 DE3712133 C2 DE 3712133C2
- Authority
- DE
- Germany
- Prior art keywords
- lubricant
- mpa
- oil
- viscosity
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000314 lubricant Substances 0.000 claims abstract description 104
- 239000012141 concentrate Substances 0.000 claims abstract description 44
- 239000003921 oil Substances 0.000 claims abstract description 34
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 21
- 239000000654 additive Substances 0.000 claims abstract description 18
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 13
- 239000011707 mineral Substances 0.000 claims abstract description 13
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims description 31
- 239000002184 metal Substances 0.000 claims description 31
- 235000019198 oils Nutrition 0.000 claims description 31
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 30
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 19
- 125000000217 alkyl group Chemical group 0.000 claims description 19
- -1 antonone Chemical compound 0.000 claims description 19
- 150000002148 esters Chemical class 0.000 claims description 19
- 229910052750 molybdenum Inorganic materials 0.000 claims description 19
- 239000011733 molybdenum Substances 0.000 claims description 19
- 229910052725 zinc Inorganic materials 0.000 claims description 17
- 239000011701 zinc Substances 0.000 claims description 17
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 15
- 229910052759 nickel Inorganic materials 0.000 claims description 15
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 15
- 229910052721 tungsten Inorganic materials 0.000 claims description 15
- 239000010937 tungsten Substances 0.000 claims description 15
- 229910052796 boron Inorganic materials 0.000 claims description 13
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 11
- 229910052719 titanium Inorganic materials 0.000 claims description 11
- 239000010936 titanium Substances 0.000 claims description 11
- 229910052720 vanadium Inorganic materials 0.000 claims description 11
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 11
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 10
- 229910052804 chromium Inorganic materials 0.000 claims description 10
- 239000011651 chromium Substances 0.000 claims description 10
- 229920002367 Polyisobutene Polymers 0.000 claims description 9
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 9
- 125000003118 aryl group Chemical group 0.000 claims description 9
- 229910052718 tin Inorganic materials 0.000 claims description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 8
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 7
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 7
- 229910052793 cadmium Inorganic materials 0.000 claims description 7
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 7
- 229910017052 cobalt Inorganic materials 0.000 claims description 7
- 239000010941 cobalt Substances 0.000 claims description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 7
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 7
- 239000002480 mineral oil Substances 0.000 claims description 7
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 7
- 229910052709 silver Inorganic materials 0.000 claims description 7
- 239000004332 silver Substances 0.000 claims description 7
- 229910052726 zirconium Inorganic materials 0.000 claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 claims description 6
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- 239000012990 dithiocarbamate Substances 0.000 claims description 6
- 229910052787 antimony Inorganic materials 0.000 claims description 5
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 5
- 235000010446 mineral oil Nutrition 0.000 claims description 5
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 5
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 5
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000003599 detergent Substances 0.000 claims description 4
- 229910052715 tantalum Inorganic materials 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 239000007983 Tris buffer Substances 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 239000002199 base oil Substances 0.000 claims description 3
- 239000002270 dispersing agent Substances 0.000 claims description 3
- 239000006078 metal deactivator Substances 0.000 claims description 3
- 229920000151 polyglycol Polymers 0.000 claims description 3
- 239000010695 polyglycol Substances 0.000 claims description 3
- 229920000193 polymethacrylate Polymers 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 2
- 230000001476 alcoholic effect Effects 0.000 claims description 2
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 2
- 125000004122 cyclic group Chemical group 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 229920013639 polyalphaolefin Polymers 0.000 claims description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims 2
- GBURUDXSBYGPBL-UHFFFAOYSA-N 2,2,3-trimethylhexanedioic acid Chemical compound OC(=O)C(C)(C)C(C)CCC(O)=O GBURUDXSBYGPBL-UHFFFAOYSA-N 0.000 claims 1
- AJPJKRUYKSUHIT-UHFFFAOYSA-K N,N-dipentylcarbamodithioate nickel(3+) Chemical compound [Ni+3].CCCCCN(CCCCC)C([S-])=S.CCCCCN(CCCCC)C([S-])=S.CCCCCN(CCCCC)C([S-])=S AJPJKRUYKSUHIT-UHFFFAOYSA-K 0.000 claims 1
- 229940000425 combination drug Drugs 0.000 claims 1
- 150000001991 dicarboxylic acids Chemical class 0.000 claims 1
- XXECZMBIIXJGFS-UHFFFAOYSA-N dihydroxy-octan-3-ylsulfanyl-sulfanylidene-$l^{5}-phosphane Chemical compound CCCCCC(CC)SP(O)(O)=S XXECZMBIIXJGFS-UHFFFAOYSA-N 0.000 claims 1
- CBQPQMSTIARRSA-UHFFFAOYSA-M n,n-bis(2-methylpropyl)carbamodithioate Chemical compound CC(C)CN(C([S-])=S)CC(C)C CBQPQMSTIARRSA-UHFFFAOYSA-M 0.000 claims 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims 1
- 230000001050 lubricating effect Effects 0.000 abstract description 14
- 238000005260 corrosion Methods 0.000 abstract description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 3
- 150000002902 organometallic compounds Chemical class 0.000 abstract description 3
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 3
- 239000011574 phosphorus Substances 0.000 abstract description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 2
- 239000005864 Sulphur Substances 0.000 abstract 1
- 235000008504 concentrate Nutrition 0.000 description 32
- 239000010687 lubricating oil Substances 0.000 description 19
- 239000000047 product Substances 0.000 description 19
- 239000000203 mixture Substances 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 11
- 238000005461 lubrication Methods 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- 238000010586 diagram Methods 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 9
- 235000010755 mineral Nutrition 0.000 description 9
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 238000005299 abrasion Methods 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 150000001721 carbon Chemical group 0.000 description 5
- 239000004519 grease Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 230000007774 longterm Effects 0.000 description 4
- 239000003879 lubricant additive Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- NMAKPIATXQEXBT-UHFFFAOYSA-N didecyl phenyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OC1=CC=CC=C1 NMAKPIATXQEXBT-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 3
- 239000004711 α-olefin Substances 0.000 description 3
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical class OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- VKCLPVFDVVKEKU-UHFFFAOYSA-N S=[P] Chemical class S=[P] VKCLPVFDVVKEKU-UHFFFAOYSA-N 0.000 description 2
- GNVMUORYQLCPJZ-UHFFFAOYSA-M Thiocarbamate Chemical compound NC([S-])=O GNVMUORYQLCPJZ-UHFFFAOYSA-M 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- IBKKMFMBXQARGV-UHFFFAOYSA-N [3-nonanoyloxy-2,2-bis(nonanoyloxymethyl)propyl] nonanoate Chemical compound CCCCCCCCC(=O)OCC(COC(=O)CCCCCCCC)(COC(=O)CCCCCCCC)COC(=O)CCCCCCCC IBKKMFMBXQARGV-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 150000004659 dithiocarbamates Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 239000011133 lead Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 2
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 2
- 150000002903 organophosphorus compounds Chemical class 0.000 description 2
- 150000008301 phosphite esters Chemical class 0.000 description 2
- CYQAYERJWZKYML-UHFFFAOYSA-N phosphorus pentasulfide Chemical compound S1P(S2)(=S)SP3(=S)SP1(=S)SP2(=S)S3 CYQAYERJWZKYML-UHFFFAOYSA-N 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- FFMKLGYETFERPE-UHFFFAOYSA-N (3,4-didecyl-2-methylphenyl) dihydrogen phosphite Chemical compound CCCCCCCCCCC1=C(C(=C(C=C1)OP(O)O)C)CCCCCCCCCC FFMKLGYETFERPE-UHFFFAOYSA-N 0.000 description 1
- YGMLOGWOEDZXIJ-UHFFFAOYSA-N 2-ethylhexylsulfanyl-dihydroxy-sulfanylidene-$l^{5}-phosphane Chemical compound CCCCC(CC)CSP(O)(O)=S YGMLOGWOEDZXIJ-UHFFFAOYSA-N 0.000 description 1
- GBRSPKXOFRTAHS-UHFFFAOYSA-N 5-(4-nitrophenyl)-1,2-oxazole-3-carboxylic acid Chemical compound O1N=C(C(=O)O)C=C1C1=CC=C([N+]([O-])=O)C=C1 GBRSPKXOFRTAHS-UHFFFAOYSA-N 0.000 description 1
- FQDUFEQLLLIHJC-UHFFFAOYSA-N 5-ethyl-4-hexylthiadiazole Chemical compound C(C)C1=C(N=NS1)CCCCCC FQDUFEQLLLIHJC-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N Butanol Natural products CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- DMAYKHBXUCBEEU-UHFFFAOYSA-L C(C)C(CNC([S-])=S)CCCC.C(C)C(CNC([S-])=S)CCCC.[Mo+2] Chemical compound C(C)C(CNC([S-])=S)CCCC.C(C)C(CNC([S-])=S)CCCC.[Mo+2] DMAYKHBXUCBEEU-UHFFFAOYSA-L 0.000 description 1
- IRKCRFNXAMIAHN-UHFFFAOYSA-N CCCCC(CC)C[S+]=P([O-])([O-])[S-].CCCCC(CC)C[S+]=P([O-])([O-])[S-].[Mo+6] Chemical compound CCCCC(CC)C[S+]=P([O-])([O-])[S-].CCCCC(CC)C[S+]=P([O-])([O-])[S-].[Mo+6] IRKCRFNXAMIAHN-UHFFFAOYSA-N 0.000 description 1
- LWWXXIYHMFVRSF-UHFFFAOYSA-N CCCCCCCCCCC1=C(C=CC(=C1CCCCCCCCCC)OP(O)O)C Chemical compound CCCCCCCCCCC1=C(C=CC(=C1CCCCCCCCCC)OP(O)O)C LWWXXIYHMFVRSF-UHFFFAOYSA-N 0.000 description 1
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 241000978750 Havardia Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241000282376 Panthera tigris Species 0.000 description 1
- 102220470005 Parvalbumin-like EF-hand-containing protein_N36A_mutation Human genes 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical class CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- XCYKXNWUFTZFJC-UHFFFAOYSA-A [V+5].[V+5].[V+5].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S Chemical compound [V+5].[V+5].[V+5].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S XCYKXNWUFTZFJC-UHFFFAOYSA-A 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- QZVZCEVBUGOXCL-UHFFFAOYSA-K antimony(3+);tricarbamothioate Chemical compound [Sb+3].NC([O-])=S.NC([O-])=S.NC([O-])=S QZVZCEVBUGOXCL-UHFFFAOYSA-K 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- SXXILWLQSQDLDL-UHFFFAOYSA-N bis(8-methylnonyl) phenyl phosphite Chemical compound CC(C)CCCCCCCOP(OCCCCCCCC(C)C)OC1=CC=CC=C1 SXXILWLQSQDLDL-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical class O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000010730 cutting oil Substances 0.000 description 1
- 125000006165 cyclic alkyl group Chemical group 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 1
- RGMHCYNAXLBTPP-UHFFFAOYSA-N didecyl 2,2,3-trimethylhexanedioate Chemical compound CCCCCCCCCCOC(=O)CCC(C)C(C)(C)C(=O)OCCCCCCCCCC RGMHCYNAXLBTPP-UHFFFAOYSA-N 0.000 description 1
- UHKDZFIPIJSOTR-UHFFFAOYSA-N didodecyl phenyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OC1=CC=CC=C1 UHKDZFIPIJSOTR-UHFFFAOYSA-N 0.000 description 1
- HAHARTSOYLFEBH-UHFFFAOYSA-N dihexyl phenyl phosphite Chemical compound CCCCCCOP(OCCCCCC)OC1=CC=CC=C1 HAHARTSOYLFEBH-UHFFFAOYSA-N 0.000 description 1
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 description 1
- MKZVQIIAAIPNGH-UHFFFAOYSA-N dioctyl phenyl phosphite Chemical compound CCCCCCCCOP(OCCCCCCCC)OC1=CC=CC=C1 MKZVQIIAAIPNGH-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- VJJPUSNTGOMMGY-MRVIYFEKSA-N etoposide Chemical compound COC1=C(O)C(OC)=CC([C@@H]2C3=CC=4OCOC=4C=C3[C@@H](O[C@H]3[C@@H]([C@@H](O)[C@@H]4O[C@H](C)OC[C@H]4O3)O)[C@@H]3[C@@H]2C(OC3)=O)=C1 VJJPUSNTGOMMGY-MRVIYFEKSA-N 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
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- 239000002904 solvent Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 102000055501 telomere Human genes 0.000 description 1
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- 235000007586 terpenes Nutrition 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- WMYJOZQKDZZHAC-UHFFFAOYSA-H trizinc;dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S WMYJOZQKDZZHAC-UHFFFAOYSA-H 0.000 description 1
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- 239000011592 zinc chloride Substances 0.000 description 1
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Classifications
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- C10M101/02—Petroleum fractions
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- C10M101/04—Fatty oil fractions
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- C10M135/18—Thio-acids; Thiocyanates; Derivatives thereof having a carbon-to-sulfur double bond thiocarbamic type, e.g. containing the groups
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19873712133 DE3712133A1 (de) | 1987-04-10 | 1987-04-10 | Schmiermittel bzw. schmiermittelkonzentrat |
| CA000563732A CA1340272C (en) | 1987-04-10 | 1988-04-08 | Lubricant or lubricant concentrate |
| EP88105725A EP0286139B1 (de) | 1987-04-10 | 1988-04-11 | Schmiermittel bzw. Schmiermittelkonzentrat |
| JP63503324A JP2843584B2 (ja) | 1987-04-10 | 1988-04-11 | 潤滑剤又は潤滑剤濃縮物 |
| ES88105725T ES2064326T3 (es) | 1987-04-10 | 1988-04-11 | Agente lubricante o concentrado de agente lubricante. |
| DE3851355T DE3851355D1 (de) | 1987-04-10 | 1988-04-11 | Schmiermittel bzw. Schmiermittelkonzentrat. |
| AT88105725T ATE111149T1 (de) | 1987-04-10 | 1988-04-11 | Schmiermittel bzw. schmiermittelkonzentrat. |
| KR1019880701563A KR960014936B1 (ko) | 1987-04-10 | 1988-04-11 | 윤활제 및 윤활제 농축물 |
| PCT/EP1988/000300 WO1988008021A1 (fr) | 1987-04-10 | 1988-04-11 | Lubrifiant ou concentre de lubrifiant |
| US08/147,014 US5665683A (en) | 1987-04-10 | 1993-11-03 | Lubricant and lubricant concentrate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19873712133 DE3712133A1 (de) | 1987-04-10 | 1987-04-10 | Schmiermittel bzw. schmiermittelkonzentrat |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3712133A1 DE3712133A1 (de) | 1988-10-20 |
| DE3712133C2 true DE3712133C2 (OSRAM) | 1993-07-15 |
Family
ID=6325305
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19873712133 Granted DE3712133A1 (de) | 1987-04-10 | 1987-04-10 | Schmiermittel bzw. schmiermittelkonzentrat |
| DE3851355T Expired - Lifetime DE3851355D1 (de) | 1987-04-10 | 1988-04-11 | Schmiermittel bzw. Schmiermittelkonzentrat. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3851355T Expired - Lifetime DE3851355D1 (de) | 1987-04-10 | 1988-04-11 | Schmiermittel bzw. Schmiermittelkonzentrat. |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0286139B1 (OSRAM) |
| JP (1) | JP2843584B2 (OSRAM) |
| KR (1) | KR960014936B1 (OSRAM) |
| AT (1) | ATE111149T1 (OSRAM) |
| CA (1) | CA1340272C (OSRAM) |
| DE (2) | DE3712133A1 (OSRAM) |
| ES (1) | ES2064326T3 (OSRAM) |
| WO (1) | WO1988008021A1 (OSRAM) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3714260A1 (de) * | 1987-04-29 | 1988-11-10 | Spiess C F & Sohn | Bor-tris-(dialkyl-dithiocarbamate) und verfahren zu ihrer herstellung |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4832867A (en) * | 1987-10-22 | 1989-05-23 | Idemitsu Kosan Co., Ltd. | Lubricating oil composition |
| GB2241707A (en) * | 1990-03-07 | 1991-09-11 | Exxon Research Engineering Co | Lubricating grease composition |
| DE4128646A1 (de) * | 1991-08-29 | 1993-03-04 | Henkel Kgaa | Estermischungen von stark verzweigten carbonsaeuren |
| DE4128647A1 (de) * | 1991-08-29 | 1993-03-11 | Henkel Kgaa | Verwendung von isopalmitinsaeureestern als schmiermittel fuer zweitaktmotoren |
| FR2684108B1 (fr) * | 1991-11-27 | 1994-10-28 | Mobil Oil France | Nouvelle graisse destinee notamment a etre utilisee dans des joints homocinetiques. |
| RU2131452C1 (ru) * | 1997-11-25 | 1999-06-10 | Открытое акционерное общество "Северсталь" | Концентрат для приготовления смазочно-охлаждающей жидкости для холодной обработки металлов давлением |
| JP4098513B2 (ja) * | 2001-02-02 | 2008-06-11 | 新日本石油株式会社 | 潤滑油組成物 |
| JP4801574B2 (ja) * | 2006-12-11 | 2011-10-26 | 株式会社リコー | 像担持体用保護剤、及び保護層形成装置、並びに画像形成方法、画像形成装置、及びプロセスカートリッジ |
| JP2008297501A (ja) * | 2007-06-01 | 2008-12-11 | New Japan Chem Co Ltd | 軸受用潤滑油 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1543830A (fr) * | 1966-11-10 | 1968-10-25 | Mobil Oil Corp | Compositions lubrifiantes contenant des additifs anti-corrosion perfectionnés |
| GB1301003A (en) * | 1969-07-10 | 1972-12-29 | Ethyl Corp | Lubricant materials |
| JPS5328862B2 (OSRAM) * | 1972-04-18 | 1978-08-17 | ||
| US3843542A (en) * | 1972-07-31 | 1974-10-22 | Chevron Res | Hydraulic oil |
| IT1010487B (it) * | 1974-05-08 | 1977-01-10 | Snam Progetti | Esteri come componenti di lubrifi canti |
| US3896050A (en) * | 1974-07-05 | 1975-07-22 | Texaco Inc | Lubricating oil additives |
| US4097388A (en) * | 1976-10-12 | 1978-06-27 | The United States Of America As Represented By The Secretary Of The Air Force | Linear fluorinated polyether lubricant compositions containing perfluoroalkylether substituted phosphines |
| JPS59133297A (ja) * | 1983-01-20 | 1984-07-31 | Idemitsu Kosan Co Ltd | 高温用潤滑油組成物 |
| GB8422562D0 (en) * | 1984-09-06 | 1984-10-10 | Exxon Research Engineering Co | Hot forming lubricant compositions |
| IT1188166B (it) * | 1985-04-24 | 1988-01-07 | Montefluos Spa | Stabilizzanti a struttura arilfosfinica per olii e grassi perfluoropolieterei |
| DE3682715D1 (de) * | 1985-07-08 | 1992-01-16 | Nippon Oil Co Ltd | Schmiermittelzusammensetzungen. |
| JPS6210193A (ja) * | 1985-07-08 | 1987-01-19 | Nippon Oil Co Ltd | トラクシヨンドライブ用流体組成物 |
-
1987
- 1987-04-10 DE DE19873712133 patent/DE3712133A1/de active Granted
-
1988
- 1988-04-08 CA CA000563732A patent/CA1340272C/en not_active Expired - Fee Related
- 1988-04-11 DE DE3851355T patent/DE3851355D1/de not_active Expired - Lifetime
- 1988-04-11 WO PCT/EP1988/000300 patent/WO1988008021A1/de not_active Ceased
- 1988-04-11 ES ES88105725T patent/ES2064326T3/es not_active Expired - Lifetime
- 1988-04-11 KR KR1019880701563A patent/KR960014936B1/ko not_active Expired - Fee Related
- 1988-04-11 EP EP88105725A patent/EP0286139B1/de not_active Expired - Lifetime
- 1988-04-11 JP JP63503324A patent/JP2843584B2/ja not_active Expired - Fee Related
- 1988-04-11 AT AT88105725T patent/ATE111149T1/de not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3714260A1 (de) * | 1987-04-29 | 1988-11-10 | Spiess C F & Sohn | Bor-tris-(dialkyl-dithiocarbamate) und verfahren zu ihrer herstellung |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE111149T1 (de) | 1994-09-15 |
| WO1988008021A1 (fr) | 1988-10-20 |
| ES2064326T3 (es) | 1995-02-01 |
| JP2843584B2 (ja) | 1999-01-06 |
| JPH01503543A (ja) | 1989-11-30 |
| EP0286139A1 (de) | 1988-10-12 |
| EP0286139B1 (de) | 1994-09-07 |
| CA1340272C (en) | 1998-12-15 |
| DE3851355D1 (de) | 1994-10-13 |
| KR890701717A (ko) | 1989-12-21 |
| DE3712133A1 (de) | 1988-10-20 |
| KR960014936B1 (ko) | 1996-10-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OP8 | Request for examination as to paragraph 44 patent law | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8327 | Change in the person/name/address of the patent owner |
Owner name: BREMER & LEGUIL GMBH, 47051 DUISBURG, DE |