DE3612491A1 - Verfahren zur gewinnung von blei aus oxidischen bzw. oxidisch-sulfatischen sekundaervorstoffen - Google Patents
Verfahren zur gewinnung von blei aus oxidischen bzw. oxidisch-sulfatischen sekundaervorstoffenInfo
- Publication number
- DE3612491A1 DE3612491A1 DE19863612491 DE3612491A DE3612491A1 DE 3612491 A1 DE3612491 A1 DE 3612491A1 DE 19863612491 DE19863612491 DE 19863612491 DE 3612491 A DE3612491 A DE 3612491A DE 3612491 A1 DE3612491 A1 DE 3612491A1
- Authority
- DE
- Germany
- Prior art keywords
- lead
- solution
- stage
- carbonate
- oxidic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 27
- 239000000463 material Substances 0.000 title abstract description 6
- 239000002243 precursor Substances 0.000 title abstract 3
- 239000000243 solution Substances 0.000 claims abstract description 28
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 27
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000012670 alkaline solution Substances 0.000 claims abstract description 6
- 238000002386 leaching Methods 0.000 claims description 12
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 7
- 238000006477 desulfuration reaction Methods 0.000 claims description 6
- 230000023556 desulfurization Effects 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- YALHCTUQSQRCSX-UHFFFAOYSA-N sulfane sulfuric acid Chemical compound S.OS(O)(=O)=O YALHCTUQSQRCSX-UHFFFAOYSA-N 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 238000004064 recycling Methods 0.000 abstract 1
- 239000011734 sodium Substances 0.000 description 13
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 7
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 7
- 239000011593 sulfur Substances 0.000 description 7
- 229910052717 sulfur Inorganic materials 0.000 description 7
- 235000011121 sodium hydroxide Nutrition 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 description 5
- 235000011152 sodium sulphate Nutrition 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229910000464 lead oxide Inorganic materials 0.000 description 4
- 229910001415 sodium ion Inorganic materials 0.000 description 4
- MFEVGQHCNVXMER-UHFFFAOYSA-L 1,3,2$l^{2}-dioxaplumbetan-4-one Chemical compound [Pb+2].[O-]C([O-])=O MFEVGQHCNVXMER-UHFFFAOYSA-L 0.000 description 3
- 229910000003 Lead carbonate Inorganic materials 0.000 description 3
- 229910000004 White lead Inorganic materials 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 3
- RYZCLUQMCYZBJQ-UHFFFAOYSA-H lead(2+);dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Pb+2].[Pb+2].[Pb+2].[O-]C([O-])=O.[O-]C([O-])=O RYZCLUQMCYZBJQ-UHFFFAOYSA-H 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 229920001875 Ebonite Polymers 0.000 description 1
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- NMGSERJNPJZFFC-UHFFFAOYSA-N carbonic acid;sulfuric acid Chemical compound OC(O)=O.OS(O)(=O)=O NMGSERJNPJZFFC-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000009853 pyrometallurgy Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B13/00—Obtaining lead
- C22B13/04—Obtaining lead by wet processes
- C22B13/045—Recovery from waste materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Processing Of Solid Wastes (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19863612491 DE3612491A1 (de) | 1986-04-14 | 1986-04-14 | Verfahren zur gewinnung von blei aus oxidischen bzw. oxidisch-sulfatischen sekundaervorstoffen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19863612491 DE3612491A1 (de) | 1986-04-14 | 1986-04-14 | Verfahren zur gewinnung von blei aus oxidischen bzw. oxidisch-sulfatischen sekundaervorstoffen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3612491A1 true DE3612491A1 (de) | 1987-10-15 |
| DE3612491C2 DE3612491C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1991-07-18 |
Family
ID=6298634
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19863612491 Granted DE3612491A1 (de) | 1986-04-14 | 1986-04-14 | Verfahren zur gewinnung von blei aus oxidischen bzw. oxidisch-sulfatischen sekundaervorstoffen |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE3612491A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998058878A1 (en) * | 1996-01-14 | 1998-12-30 | Margulead Ltd. | Process for the manufacture of lead oxide |
| WO2003025235A1 (en) * | 2001-09-17 | 2003-03-27 | Paques B.V. | Process for the recovery of lead from scrap batteries |
| EP1619261A1 (en) * | 2004-07-20 | 2006-01-25 | ENGITEC S.r.l. | Desulfurization process of pastel and grids of lead accumulators |
| CN106282540A (zh) * | 2016-08-25 | 2017-01-04 | 安徽华铂再生资源科技有限公司 | 铅膏中铅金属低能耗高效回收工艺 |
| CN106337112A (zh) * | 2016-08-25 | 2017-01-18 | 安徽华铂再生资源科技有限公司 | 一种湿法、低液固比废铅酸蓄电池铅膏脱硫工艺 |
| CN106435194A (zh) * | 2016-09-30 | 2017-02-22 | 刘振 | 废旧铅酸电池铅膏高效脱硫工艺 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2016104C1 (ru) * | 1992-05-27 | 1994-07-15 | Ходов Николай Владимирович | Способ переработки свинецсодержащего аккумуляторного лака |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3689253A (en) * | 1970-08-27 | 1972-09-05 | Minerals Technology Corp | Reclaiming lead from storage batteries |
| DE3215592A1 (de) * | 1981-04-29 | 1982-11-18 | Tonolli Costruzioni S.p.A., Milano | Verfahren zur behandlung sulfatierter bleiverbindungen zur rueckgewinnung metallischen bleis und eines sulfats hoher reinheit, sowie anlage zur durchfuehrung des verfahrens |
-
1986
- 1986-04-14 DE DE19863612491 patent/DE3612491A1/de active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3689253A (en) * | 1970-08-27 | 1972-09-05 | Minerals Technology Corp | Reclaiming lead from storage batteries |
| DE3215592A1 (de) * | 1981-04-29 | 1982-11-18 | Tonolli Costruzioni S.p.A., Milano | Verfahren zur behandlung sulfatierter bleiverbindungen zur rueckgewinnung metallischen bleis und eines sulfats hoher reinheit, sowie anlage zur durchfuehrung des verfahrens |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998058878A1 (en) * | 1996-01-14 | 1998-12-30 | Margulead Ltd. | Process for the manufacture of lead oxide |
| WO2003025235A1 (en) * | 2001-09-17 | 2003-03-27 | Paques B.V. | Process for the recovery of lead from scrap batteries |
| EP1619261A1 (en) * | 2004-07-20 | 2006-01-25 | ENGITEC S.r.l. | Desulfurization process of pastel and grids of lead accumulators |
| US7498012B2 (en) | 2004-07-20 | 2009-03-03 | Engitec S.R.L. | Desulfurization process of pastel and grids of lead accumulators |
| RU2379364C2 (ru) * | 2004-07-20 | 2010-01-20 | ЭНДЖИТЕК С.р.л. | Способ десульфирования активной массы и решеток свинцовых аккумуляторов |
| CN106282540A (zh) * | 2016-08-25 | 2017-01-04 | 安徽华铂再生资源科技有限公司 | 铅膏中铅金属低能耗高效回收工艺 |
| CN106337112A (zh) * | 2016-08-25 | 2017-01-18 | 安徽华铂再生资源科技有限公司 | 一种湿法、低液固比废铅酸蓄电池铅膏脱硫工艺 |
| CN106435194A (zh) * | 2016-09-30 | 2017-02-22 | 刘振 | 废旧铅酸电池铅膏高效脱硫工艺 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3612491C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1991-07-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |