DE3445203A1 - Simultane so(pfeil abwaerts)2(pfeil abwaerts)- und no(pfeil abwaerts)x(pfeil abwaerts)-abscheidung in einem einstufigen waescher - Google Patents
Simultane so(pfeil abwaerts)2(pfeil abwaerts)- und no(pfeil abwaerts)x(pfeil abwaerts)-abscheidung in einem einstufigen waescherInfo
- Publication number
- DE3445203A1 DE3445203A1 DE19843445203 DE3445203A DE3445203A1 DE 3445203 A1 DE3445203 A1 DE 3445203A1 DE 19843445203 DE19843445203 DE 19843445203 DE 3445203 A DE3445203 A DE 3445203A DE 3445203 A1 DE3445203 A1 DE 3445203A1
- Authority
- DE
- Germany
- Prior art keywords
- nozzle
- added
- nox
- redox potential
- arrangement
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007788 liquid Substances 0.000 claims abstract description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 7
- 239000003546 flue gas Substances 0.000 claims abstract description 7
- 238000005201 scrubbing Methods 0.000 claims abstract description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 6
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims abstract description 6
- 239000000920 calcium hydroxide Substances 0.000 claims abstract description 6
- 235000011116 calcium hydroxide Nutrition 0.000 claims abstract description 6
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims abstract description 6
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000654 additive Substances 0.000 claims abstract description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000019738 Limestone Nutrition 0.000 claims abstract description 4
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 4
- 229910052742 iron Inorganic materials 0.000 claims abstract description 4
- 239000006028 limestone Substances 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims abstract description 4
- 230000000996 additive effect Effects 0.000 claims abstract description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract description 3
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 claims abstract 2
- 238000001816 cooling Methods 0.000 claims abstract 2
- 238000005406 washing Methods 0.000 claims description 10
- 238000000926 separation method Methods 0.000 claims description 3
- 230000001590 oxidative effect Effects 0.000 claims 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 abstract description 5
- 229910052925 anhydrite Inorganic materials 0.000 abstract description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 2
- 239000001301 oxygen Substances 0.000 abstract description 2
- 229910052760 oxygen Inorganic materials 0.000 abstract description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 235000010216 calcium carbonate Nutrition 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000010261 calcium sulphite Nutrition 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/60—Simultaneously removing sulfur oxides and nitrogen oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19843445203 DE3445203A1 (de) | 1984-12-12 | 1984-12-12 | Simultane so(pfeil abwaerts)2(pfeil abwaerts)- und no(pfeil abwaerts)x(pfeil abwaerts)-abscheidung in einem einstufigen waescher |
| AU38857/85A AU569775B2 (en) | 1984-01-25 | 1985-01-23 | Stripping nox and sox from flue gases discharged from combustion plants |
| EP85900664A EP0168453A1 (de) | 1984-01-25 | 1985-01-23 | Verfahren zur abscheidung von stickstoffoxiden und schwefeloxiden sowie gegebenenfalls anderen schadstoffen aus den rauchgasen von verbrennungsanlagen |
| US06/781,235 US4670234A (en) | 1984-01-25 | 1985-01-23 | Process for stripping nitrogen oxides and sulphur oxides as well as optionally other noxious elements of flue gas from combustion plants |
| PCT/EP1985/000018 WO1985003238A2 (en) | 1984-01-25 | 1985-01-23 | Process for stripping nitrogen oxides and sulphur oxides as well as optionally other noxious elements of flue gas from combustion plants |
| IT19231/85A IT1199650B (it) | 1984-01-25 | 1985-01-25 | Procedimento per la separazione di ossidi di azoto e ossidi di zolfo nonche'eventualmente di altre sostanze dannose dai gas di combustione di impianti di combustione |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19843445203 DE3445203A1 (de) | 1984-12-12 | 1984-12-12 | Simultane so(pfeil abwaerts)2(pfeil abwaerts)- und no(pfeil abwaerts)x(pfeil abwaerts)-abscheidung in einem einstufigen waescher |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3445203A1 true DE3445203A1 (de) | 1986-06-12 |
| DE3445203C2 DE3445203C2 (enrdf_load_stackoverflow) | 1989-05-18 |
Family
ID=6252504
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19843445203 Granted DE3445203A1 (de) | 1984-01-25 | 1984-12-12 | Simultane so(pfeil abwaerts)2(pfeil abwaerts)- und no(pfeil abwaerts)x(pfeil abwaerts)-abscheidung in einem einstufigen waescher |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE3445203A1 (enrdf_load_stackoverflow) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3701339A1 (de) * | 1987-01-19 | 1988-07-28 | Hoelter Heinz | Verfahren zur abscheidung von no(pfeil abwaerts)x(pfeil abwaerts)-spitzenbelastungen bei der rauchgasreinigung hinter fossilen verbrennungskesseln |
| DE3725715A1 (de) * | 1987-08-04 | 1989-02-16 | Karl Clemens Dipl Che Kaeuffer | Verfahren und vorrichtung zur verminderung der stickoxide in abgasen, vorzugsweise in rauchgasen |
| AT400005B (de) * | 1994-03-25 | 1995-09-25 | Staudinger Gernot | Verfahren zum kühlen von mit staub beladenen rauchgasen |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2460231A1 (de) * | 1973-12-27 | 1975-07-03 | Chisso Eng Co Ltd | Verfahren zum entfernen von stickstoffoxiden aus industriellen abgasen und dafuer geeignete waessrige behandlungsloesungen |
-
1984
- 1984-12-12 DE DE19843445203 patent/DE3445203A1/de active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2460231A1 (de) * | 1973-12-27 | 1975-07-03 | Chisso Eng Co Ltd | Verfahren zum entfernen von stickstoffoxiden aus industriellen abgasen und dafuer geeignete waessrige behandlungsloesungen |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3701339A1 (de) * | 1987-01-19 | 1988-07-28 | Hoelter Heinz | Verfahren zur abscheidung von no(pfeil abwaerts)x(pfeil abwaerts)-spitzenbelastungen bei der rauchgasreinigung hinter fossilen verbrennungskesseln |
| DE3725715A1 (de) * | 1987-08-04 | 1989-02-16 | Karl Clemens Dipl Che Kaeuffer | Verfahren und vorrichtung zur verminderung der stickoxide in abgasen, vorzugsweise in rauchgasen |
| AT400005B (de) * | 1994-03-25 | 1995-09-25 | Staudinger Gernot | Verfahren zum kühlen von mit staub beladenen rauchgasen |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3445203C2 (enrdf_load_stackoverflow) | 1989-05-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OM8 | Search report available as to paragraph 43 lit. 1 sentence 1 patent law | ||
| OP8 | Request for examination as to paragraph 44 patent law | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |