DE3340492A1 - Verfahren zur herstellung von feinverteiltem, hochreaktivem magnesium und dessen verwendung - Google Patents
Verfahren zur herstellung von feinverteiltem, hochreaktivem magnesium und dessen verwendungInfo
- Publication number
- DE3340492A1 DE3340492A1 DE19833340492 DE3340492A DE3340492A1 DE 3340492 A1 DE3340492 A1 DE 3340492A1 DE 19833340492 DE19833340492 DE 19833340492 DE 3340492 A DE3340492 A DE 3340492A DE 3340492 A1 DE3340492 A1 DE 3340492A1
- Authority
- DE
- Germany
- Prior art keywords
- magnesium
- decomposition
- bar
- anthracene
- highly reactive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims abstract description 124
- 239000011777 magnesium Substances 0.000 title claims abstract description 99
- 229910052749 magnesium Inorganic materials 0.000 title claims abstract description 86
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 27
- 229910012375 magnesium hydride Inorganic materials 0.000 claims abstract description 22
- GRJWDJVTZAUGDZ-UHFFFAOYSA-N anthracene;magnesium Chemical compound [Mg].C1=CC=CC2=CC3=CC=CC=C3C=C21 GRJWDJVTZAUGDZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000006243 chemical reaction Methods 0.000 claims abstract description 18
- 238000000354 decomposition reaction Methods 0.000 claims abstract description 14
- 230000008569 process Effects 0.000 claims abstract description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 10
- 150000002901 organomagnesium compounds Chemical class 0.000 claims abstract description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 7
- 239000000376 reactant Substances 0.000 claims abstract description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical group N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims abstract description 6
- JUOXOUBQXJJXAO-UHFFFAOYSA-N [Mg].C=CC=C Chemical compound [Mg].C=CC=C JUOXOUBQXJJXAO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 230000002441 reversible effect Effects 0.000 claims abstract description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 3
- 125000005843 halogen group Chemical group 0.000 claims abstract description 3
- 125000005842 heteroatom Chemical group 0.000 claims abstract description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 3
- 239000001301 oxygen Chemical group 0.000 claims abstract description 3
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 3
- 239000011574 phosphorus Chemical group 0.000 claims abstract description 3
- 239000000843 powder Substances 0.000 claims abstract description 3
- 239000011593 sulfur Chemical group 0.000 claims abstract description 3
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 3
- 238000002360 preparation method Methods 0.000 claims abstract 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 claims description 26
- -1 magnesium compounds ethyl bromide Chemical class 0.000 claims description 10
- 150000001993 dienes Chemical class 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 7
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- 230000008021 deposition Effects 0.000 claims description 5
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 4
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 239000002815 homogeneous catalyst Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims description 2
- PAAZPARNPHGIKF-UHFFFAOYSA-N 1,2-dibromoethane Chemical compound BrCCBr PAAZPARNPHGIKF-UHFFFAOYSA-N 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims description 2
- 238000003780 insertion Methods 0.000 claims description 2
- 230000037431 insertion Effects 0.000 claims description 2
- 239000000010 aprotic solvent Substances 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- 150000003512 tertiary amines Chemical class 0.000 claims 1
- 238000001556 precipitation Methods 0.000 abstract 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 78
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 51
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 39
- 239000000725 suspension Substances 0.000 description 15
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 14
- 239000000203 mixture Substances 0.000 description 11
- 238000002474 experimental method Methods 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- QTBFPMKWQKYFLR-UHFFFAOYSA-N isobutyl chloride Chemical compound CC(C)CCl QTBFPMKWQKYFLR-UHFFFAOYSA-N 0.000 description 9
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 8
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 6
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 6
- 230000009257 reactivity Effects 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000001149 thermolysis Methods 0.000 description 6
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000004817 gas chromatography Methods 0.000 description 5
- 230000007062 hydrolysis Effects 0.000 description 5
- 238000006460 hydrolysis reaction Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 238000005984 hydrogenation reaction Methods 0.000 description 4
- CYSFUFRXDOAOMP-UHFFFAOYSA-M magnesium;prop-1-ene;chloride Chemical compound [Mg+2].[Cl-].[CH2-]C=C CYSFUFRXDOAOMP-UHFFFAOYSA-M 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 238000003747 Grignard reaction Methods 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000001282 iso-butane Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- YSMZEMQBSONIMJ-UHFFFAOYSA-M magnesium;2-methanidylpropane;chloride Chemical compound [Mg+2].[Cl-].CC(C)[CH2-] YSMZEMQBSONIMJ-UHFFFAOYSA-M 0.000 description 3
- 150000002896 organic halogen compounds Chemical class 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 238000005979 thermal decomposition reaction Methods 0.000 description 3
- 238000005160 1H NMR spectroscopy Methods 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 150000001500 aryl chlorides Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000003776 cleavage reaction Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 239000012039 electrophile Substances 0.000 description 2
- 238000000921 elemental analysis Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 150000003018 phosphorus compounds Chemical class 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000010626 work up procedure Methods 0.000 description 2
- NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 1
- WZGMIOQDQJETRK-UHFFFAOYSA-N (5-oxo-5-phenylpentyl) benzoate Chemical compound C=1C=CC=CC=1C(=O)CCCCOC(=O)C1=CC=CC=C1 WZGMIOQDQJETRK-UHFFFAOYSA-N 0.000 description 1
- JXGNHEUFHNJWDY-UHFFFAOYSA-N 2,5-dihydro-1h-phosphole Chemical class C1PCC=C1 JXGNHEUFHNJWDY-UHFFFAOYSA-N 0.000 description 1
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 1
- WOFPPJOZXUTRAU-UHFFFAOYSA-N 2-Ethyl-1-hexanol Natural products CCCCC(O)CCC WOFPPJOZXUTRAU-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical compound CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- RTAQCQOZRWKSTQ-UHFFFAOYSA-N CC(C)C[Mg]CC(C)C Chemical compound CC(C)C[Mg]CC(C)C RTAQCQOZRWKSTQ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 101150065749 Churc1 gene Proteins 0.000 description 1
- 108091006149 Electron carriers Proteins 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 238000005727 Friedel-Crafts reaction Methods 0.000 description 1
- WTDRDQBEARUVNC-LURJTMIESA-N L-DOPA Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C(O)=C1 WTDRDQBEARUVNC-LURJTMIESA-N 0.000 description 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- 102100038239 Protein Churchill Human genes 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 229910001508 alkali metal halide Inorganic materials 0.000 description 1
- 150000008045 alkali metal halides Chemical class 0.000 description 1
- 150000001454 anthracenes Chemical class 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 description 1
- 238000006480 benzoylation reaction Methods 0.000 description 1
- PVEOYINWKBTPIZ-UHFFFAOYSA-N but-3-enoic acid Chemical compound OC(=O)CC=C PVEOYINWKBTPIZ-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000005695 dehalogenation reaction Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000006471 dimerization reaction Methods 0.000 description 1
- 208000001848 dysentery Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012259 ether extract Substances 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 238000007172 homogeneous catalysis Methods 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 150000002680 magnesium Chemical class 0.000 description 1
- FRIJBUGBVQZNTB-UHFFFAOYSA-M magnesium;ethane;bromide Chemical compound [Mg+2].[Br-].[CH2-]C FRIJBUGBVQZNTB-UHFFFAOYSA-M 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000006884 silylation reaction Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- JFLKFZNIIQFQBS-FNCQTZNRSA-N trans,trans-1,4-Diphenyl-1,3-butadiene Chemical compound C=1C=CC=CC=1\C=C\C=C\C1=CC=CC=C1 JFLKFZNIIQFQBS-FNCQTZNRSA-N 0.000 description 1
- QKMNLIDNGUCJIK-UHFFFAOYSA-N trimethyl(4-trimethylsilylbutoxy)silane Chemical compound C[Si](C)(C)CCCCO[Si](C)(C)C QKMNLIDNGUCJIK-UHFFFAOYSA-N 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/023—Hydrogen absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/30—Making metallic powder or suspensions thereof using chemical processes with decomposition of metal compounds, e.g. by pyrolysis
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
- C01B6/04—Hydrides of alkali metals, alkaline earth metals, beryllium or magnesium; Addition complexes thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/02—Magnesium compounds
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
- C22B26/20—Obtaining alkaline earth metals or magnesium
- C22B26/22—Obtaining magnesium
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Metallurgy (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Glass Compositions (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Analysing Materials By The Use Of Radiation (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Catalysts (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Priority Applications (15)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19833340492 DE3340492A1 (de) | 1983-11-09 | 1983-11-09 | Verfahren zur herstellung von feinverteiltem, hochreaktivem magnesium und dessen verwendung |
| DK523284A DK164368C (da) | 1983-11-09 | 1984-11-02 | Fremgangsmaade til fremstilling af findelt, hoejreaktivt magnium og dets anvendelse |
| ES537364A ES537364A0 (es) | 1983-11-09 | 1984-11-05 | Procedimiento para preparar magnesio sumamente reactivo y finamente dividido a partir de hidruro de magnesio |
| DD84269170A DD229157A5 (de) | 1983-11-09 | 1984-11-06 | Verfahren zur herstellung von feinverteiltem, hochreaktivem magnesium |
| US06/669,209 US4659373A (en) | 1983-11-09 | 1984-11-07 | Process for preparing finely divided highly reactive magnesium and use thereof |
| DE8484113406T DE3476561D1 (en) | 1983-11-09 | 1984-11-07 | Process for producing finely divided, highly reactive magnesium and the use of the same |
| AT84113406T ATE40573T1 (de) | 1983-11-09 | 1984-11-07 | Verfahren zur herstellung von feinverteiltem, hochreaktivem magnesium und dessen verwendung. |
| CA000467265A CA1232764A (en) | 1983-11-09 | 1984-11-07 | Process for preparing finely divided highly reactive magnesium and use thereof |
| EP84113406A EP0147581B1 (de) | 1983-11-09 | 1984-11-07 | Verfahren zur Herstellung von feinverteiltem, hochreaktivem Magnesium und dessen Verwendung |
| IE2867/84A IE57704B1 (en) | 1983-11-09 | 1984-11-08 | Process for preparing finely divided highly reactive magnesium and use thereof |
| AU35230/84A AU575354B2 (en) | 1983-11-09 | 1984-11-08 | Preparing finely divided highly reactive magnesium |
| JP59236558A JPS60116732A (ja) | 1983-11-09 | 1984-11-08 | 高反応性微細マグネシウムの製造方法 |
| US06/895,658 US4731203A (en) | 1983-11-09 | 1986-08-12 | Process for using finely divided highly reactive magnesium |
| CA000543069A CA1240156A (en) | 1983-11-09 | 1987-07-27 | Process for preparing finely divided highly reactive magnesium and use thereof |
| US07/545,322 US5069894A (en) | 1978-02-02 | 1990-06-27 | Process for preparing finely divided highly reactive magnesium and use thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19833340492 DE3340492A1 (de) | 1983-11-09 | 1983-11-09 | Verfahren zur herstellung von feinverteiltem, hochreaktivem magnesium und dessen verwendung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3340492A1 true DE3340492A1 (de) | 1985-05-15 |
Family
ID=6213852
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19833340492 Withdrawn DE3340492A1 (de) | 1978-02-02 | 1983-11-09 | Verfahren zur herstellung von feinverteiltem, hochreaktivem magnesium und dessen verwendung |
| DE8484113406T Expired DE3476561D1 (en) | 1983-11-09 | 1984-11-07 | Process for producing finely divided, highly reactive magnesium and the use of the same |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE8484113406T Expired DE3476561D1 (en) | 1983-11-09 | 1984-11-07 | Process for producing finely divided, highly reactive magnesium and the use of the same |
Country Status (11)
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0685425A1 (de) * | 1994-06-03 | 1995-12-06 | Th. Goldschmidt AG | Verfahren zur Herstellung von Magnesium-hydrid |
| DE102008063895B3 (de) * | 2008-12-19 | 2010-06-10 | Gkss-Forschungszentrum Geesthacht Gmbh | Verfahren zur Aktivierung oder Regeneration eines Wasserstoffspeichermaterials |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3639545C1 (de) * | 1986-11-20 | 1988-06-01 | Studiengesellschaft Kohle Mbh | Verfahren zur Waermespeicherung und -transformation sowie Kaelteerzeugung |
| DE3722993A1 (de) * | 1987-07-11 | 1989-01-19 | Studiengesellschaft Kohle Mbh | Loesliche magnesiumdihydride, verfahren zu ihrer herstellung und ihre verwendung |
| JPH01136910A (ja) * | 1987-11-20 | 1989-05-30 | Nisshin Steel Co Ltd | 粒状微細金属粉末の製造方法 |
| US4933003A (en) * | 1989-07-18 | 1990-06-12 | The United States Of America As Represented By The Secretary Of The Army | Metal alloy formation by reduction of polyheterometallic complexes |
| US5061313A (en) * | 1990-09-07 | 1991-10-29 | Northeastern University | Direct alloy synthesis from heteropolymetallic precursors |
| AU2682492A (en) * | 1991-09-25 | 1993-04-27 | Research Corporation Technologies, Inc. | The sonochemical synthesis of amorphous metals |
| US6074447A (en) * | 1997-02-21 | 2000-06-13 | University Of Hawaii | Hydrogen storage |
| CN100427249C (zh) * | 2003-12-10 | 2008-10-22 | 辽宁师范大学 | 一种通过真空热解由卤代烃引发合成的蒽镧系金属有机化合物来制备纳米镧系金属粉末的方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1292322A (fr) * | 1961-03-03 | 1962-05-04 | Commissariat Energie Atomique | Procédé de préparation de masses à base de poudre de magnésium fluorée et comprimée |
| BE622459A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1961-09-14 | |||
| US3351646A (en) * | 1965-01-04 | 1967-11-07 | Exxon Research Engineering Co | Magnesium and tin derivatives of styrenes and the preparation thereof |
| US3388179A (en) * | 1965-01-04 | 1968-06-11 | Exxon Research Engineering Co | Organomagnesium addition compounds, process therefor, and derivatives thereof |
| US3354190A (en) * | 1965-01-04 | 1967-11-21 | Exxon Research Engineering Co | Magnesium and tin derivatives of fusedring hydrocarbons and the preparation thereof |
| US3969104A (en) * | 1974-02-19 | 1976-07-13 | Ivan Andreevich Barannik | Granules of magnesium and its alloys |
| DE2804445A1 (de) * | 1978-02-02 | 1979-08-09 | Studiengesellschaft Kohle Mbh | Verfahren zur herstellung von magnesiumhydriden |
| DE3247361A1 (de) * | 1982-12-22 | 1984-06-28 | Studiengesellschaft Kohle mbH, 4330 Mülheim | Verfahren zur abtrennung und reinigung von wasserstoff |
| DE3247362A1 (de) * | 1982-12-22 | 1984-06-28 | Studiengesellschaft Kohle mbH, 4330 Mülheim | Verfahren zur herstellung von silicium-wasserstoff-verbindungen, insbesondere des silans |
| US4543122A (en) * | 1983-10-19 | 1985-09-24 | Johannesburg Consolidated Investment Company Limited | Magnesium production |
| US4541867A (en) * | 1984-03-20 | 1985-09-17 | Amax Inc. | Varnish-bonded carbon-coated magnesium and aluminum granules |
-
1983
- 1983-11-09 DE DE19833340492 patent/DE3340492A1/de not_active Withdrawn
-
1984
- 1984-11-02 DK DK523284A patent/DK164368C/da not_active IP Right Cessation
- 1984-11-05 ES ES537364A patent/ES537364A0/es active Granted
- 1984-11-06 DD DD84269170A patent/DD229157A5/de not_active IP Right Cessation
- 1984-11-07 CA CA000467265A patent/CA1232764A/en not_active Expired
- 1984-11-07 US US06/669,209 patent/US4659373A/en not_active Expired - Fee Related
- 1984-11-07 EP EP84113406A patent/EP0147581B1/de not_active Expired
- 1984-11-07 AT AT84113406T patent/ATE40573T1/de active
- 1984-11-07 DE DE8484113406T patent/DE3476561D1/de not_active Expired
- 1984-11-08 JP JP59236558A patent/JPS60116732A/ja active Granted
- 1984-11-08 AU AU35230/84A patent/AU575354B2/en not_active Ceased
- 1984-11-08 IE IE2867/84A patent/IE57704B1/en not_active IP Right Cessation
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0685425A1 (de) * | 1994-06-03 | 1995-12-06 | Th. Goldschmidt AG | Verfahren zur Herstellung von Magnesium-hydrid |
| DE4419456A1 (de) * | 1994-06-03 | 1995-12-07 | Goldschmidt Ag Th | Verfahren zur Herstellung von Magnesiumhydrid |
| DE102008063895B3 (de) * | 2008-12-19 | 2010-06-10 | Gkss-Forschungszentrum Geesthacht Gmbh | Verfahren zur Aktivierung oder Regeneration eines Wasserstoffspeichermaterials |
| US8815207B2 (en) | 2008-12-19 | 2014-08-26 | Gkss-Forschungszentrum Geesthacht Gmbh | Method of activating or regenerating a hydrogen storage material |
Also Published As
| Publication number | Publication date |
|---|---|
| AU575354B2 (en) | 1988-07-28 |
| JPS60116732A (ja) | 1985-06-24 |
| JPH0331773B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1991-05-08 |
| DK164368C (da) | 1992-11-02 |
| ATE40573T1 (de) | 1989-02-15 |
| DK523284A (da) | 1985-05-10 |
| IE842867L (en) | 1985-05-09 |
| DE3476561D1 (en) | 1989-03-09 |
| US4659373A (en) | 1987-04-21 |
| IE57704B1 (en) | 1993-03-10 |
| EP0147581B1 (de) | 1989-02-01 |
| ES8600418A1 (es) | 1985-09-16 |
| AU3523084A (en) | 1985-05-30 |
| DK523284D0 (da) | 1984-11-02 |
| ES537364A0 (es) | 1985-09-16 |
| EP0147581A1 (de) | 1985-07-10 |
| DK164368B (da) | 1992-06-15 |
| CA1232764A (en) | 1988-02-16 |
| DD229157A5 (de) | 1985-10-30 |
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| 8141 | Disposal/no request for examination |