DE3309465C2 - - Google Patents
Info
- Publication number
- DE3309465C2 DE3309465C2 DE3309465A DE3309465A DE3309465C2 DE 3309465 C2 DE3309465 C2 DE 3309465C2 DE 3309465 A DE3309465 A DE 3309465A DE 3309465 A DE3309465 A DE 3309465A DE 3309465 C2 DE3309465 C2 DE 3309465C2
- Authority
- DE
- Germany
- Prior art keywords
- cmc
- irradiated
- carboxymethyl cellulose
- molecular weight
- viscosity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 52
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 52
- 238000000034 method Methods 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 11
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 10
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 9
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 230000000087 stabilizing effect Effects 0.000 claims description 5
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 4
- 230000001678 irradiating effect Effects 0.000 claims 1
- 239000000243 solution Substances 0.000 description 18
- 239000000523 sample Substances 0.000 description 9
- 230000005855 radiation Effects 0.000 description 6
- 238000006467 substitution reaction Methods 0.000 description 6
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000004435 EPR spectroscopy Methods 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 230000003113 alkalizing effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000000887 hydrating effect Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B11/00—Preparation of cellulose ethers
- C08B11/20—Post-etherification treatments of chemical or physical type, e.g. mixed etherification in two steps, including purification
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Materials For Medical Uses (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Medicinal Preparation (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/359,553 US4420611A (en) | 1982-03-18 | 1982-03-18 | Stabilization of irradiated carboxymethyl cellulose |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3309465A1 DE3309465A1 (de) | 1983-09-29 |
| DE3309465C2 true DE3309465C2 (en, 2012) | 1990-12-13 |
Family
ID=23414317
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3309465A Granted DE3309465A1 (de) | 1982-03-18 | 1983-03-16 | Verfahren zum behandeln bestrahlter carboxymethylcellulose |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4420611A (en, 2012) |
| JP (1) | JPS58208301A (en, 2012) |
| BR (1) | BR8301337A (en, 2012) |
| CA (1) | CA1216815A (en, 2012) |
| DE (1) | DE3309465A1 (en, 2012) |
| FR (1) | FR2523585B1 (en, 2012) |
| NL (1) | NL8300939A (en, 2012) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0714419A4 (en) * | 1993-08-10 | 1996-11-13 | Planet Polymer Tech Inc | BIODEGRADABLE AND COMPOSTABLE PLASTIC AND PROCESS FOR OBTAINING SAME |
| DE4434280C2 (de) * | 1994-09-26 | 1998-09-10 | Clariant Gmbh | Verfahren zur Herstellung von niedermolekularen Celluloseethern und ihre Verwendung als Überzugsmaterial für feste Dosiereinheiten |
| US6383344B1 (en) * | 2000-07-19 | 2002-05-07 | Genzyme Corporation | Molecular weight reduction of polymer using irradiation treatment |
| DE10117208A1 (de) * | 2001-04-06 | 2002-10-10 | Wolff Walsrode Ag | Verfahren zur Herstellung von niederviskosen, wässrigen Celluloseetherlösungen |
| KR20170134541A (ko) | 2015-04-07 | 2017-12-06 | 질레코 인코포레이티드 | 바이어매스를 가공처리하기 위한 모니터링 방법 및 시스템 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1834040A (en) * | 1929-11-08 | 1931-12-01 | Wacker Chemie Gmbh | Process for reducing the viscosity characteristics of cellulose ethers |
| US2383361A (en) * | 1943-05-05 | 1945-08-21 | Dow Chemical Co | Stabilizing cellulose ethers |
| US3108890A (en) * | 1960-05-23 | 1963-10-29 | Dow Chemical Co | Aqueous cellulosic compositions and method of making same |
| GB1086323A (en) * | 1963-07-18 | 1967-10-11 | Courtaulds Ltd | Derivative of carboxy methyl cellulose |
| CH407034A (de) * | 1964-03-13 | 1965-09-15 | Heberlein & Co Ag | Verfahren zur Entfernung von Energie aus mit ionisierenden Strahlen behandeltem cellulosehaltigem Textilgut |
| US3379721A (en) * | 1964-10-12 | 1968-04-23 | Hercules Inc | Process of treating water-soluble alkali metal salts of cmc and product |
| DE1928046A1 (de) * | 1968-06-13 | 1969-12-18 | Dow Chemical Co | Verfahren zur Herstellung von Zellulosederivaten mit niedrigem Viskositaetsgrad |
| US3728331A (en) * | 1969-04-04 | 1973-04-17 | Dow Chemical Co | Process for reducing the viscosity of a cellulose ether with hydrogen peroxide |
| US4051306A (en) * | 1972-03-27 | 1977-09-27 | Owens-Illinois, Inc. | Controlled environmental deterioration of plastics |
| JPS5317629B2 (en, 2012) * | 1972-09-14 | 1978-06-09 | ||
| FR2204734B1 (en, 2012) * | 1972-10-27 | 1978-03-03 | Anvar | |
| DE2917104A1 (de) * | 1979-04-27 | 1980-11-06 | Hoechst Ag | Verfahren zur viskositaetserniedrigung von celluloseethern durch ozon und seine verwendung |
-
1982
- 1982-03-18 US US06/359,553 patent/US4420611A/en not_active Expired - Lifetime
-
1983
- 1983-02-25 CA CA000422370A patent/CA1216815A/en not_active Expired
- 1983-03-15 NL NL8300939A patent/NL8300939A/nl not_active Application Discontinuation
- 1983-03-15 FR FR8304610A patent/FR2523585B1/fr not_active Expired
- 1983-03-16 DE DE3309465A patent/DE3309465A1/de active Granted
- 1983-03-17 BR BR8301337A patent/BR8301337A/pt unknown
- 1983-03-18 JP JP58045836A patent/JPS58208301A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| DE3309465A1 (de) | 1983-09-29 |
| CA1216815A (en) | 1987-01-20 |
| FR2523585A1 (fr) | 1983-09-23 |
| US4420611A (en) | 1983-12-13 |
| BR8301337A (pt) | 1983-11-29 |
| NL8300939A (nl) | 1983-10-17 |
| FR2523585B1 (fr) | 1988-01-15 |
| JPH0481B2 (en, 2012) | 1992-01-06 |
| JPS58208301A (ja) | 1983-12-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8128 | New person/name/address of the agent |
Representative=s name: LEDERER, F., DIPL.-CHEM. DR., PAT.-ANW., 8000 MUEN |
|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |