DE3208598A1 - Verfahren zur herstellung von mit organosilanen oberflaechenmodifizierten zeolithen - Google Patents
Verfahren zur herstellung von mit organosilanen oberflaechenmodifizierten zeolithenInfo
- Publication number
- DE3208598A1 DE3208598A1 DE19823208598 DE3208598A DE3208598A1 DE 3208598 A1 DE3208598 A1 DE 3208598A1 DE 19823208598 DE19823208598 DE 19823208598 DE 3208598 A DE3208598 A DE 3208598A DE 3208598 A1 DE3208598 A1 DE 3208598A1
- Authority
- DE
- Germany
- Prior art keywords
- zeolite
- zeolites
- silane
- organosilanes
- organosilane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000010457 zeolite Substances 0.000 title claims description 41
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims description 24
- 150000001282 organosilanes Chemical group 0.000 title claims description 18
- 238000000034 method Methods 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 229910021536 Zeolite Inorganic materials 0.000 claims description 22
- 239000000725 suspension Substances 0.000 claims description 4
- -1 methoxy, ethoxy, phenyl Chemical group 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 239000012459 cleaning agent Substances 0.000 claims 1
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 20
- 229910000077 silane Inorganic materials 0.000 description 20
- 150000004756 silanes Chemical class 0.000 description 8
- 239000002904 solvent Substances 0.000 description 7
- 108010045403 Calcium-Binding Proteins Proteins 0.000 description 5
- 102000005701 Calcium-Binding Proteins Human genes 0.000 description 5
- 239000003599 detergent Substances 0.000 description 5
- 238000005054 agglomeration Methods 0.000 description 4
- 230000002776 aggregation Effects 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 4
- 239000002245 particle Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 101150096316 5 gene Proteins 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- GHOSHMRGNJZOML-UHFFFAOYSA-N [SiH4].C(CC)[Si](OCC)(OCC)OCC Chemical compound [SiH4].C(CC)[Si](OCC)(OCC)OCC GHOSHMRGNJZOML-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/026—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/162—Organic compounds containing Si
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/12—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
- Y10T428/2995—Silane, siloxane or silicone coating
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Detergent Compositions (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19823208598 DE3208598A1 (de) | 1982-03-10 | 1982-03-10 | Verfahren zur herstellung von mit organosilanen oberflaechenmodifizierten zeolithen |
| DE8282110922T DE3262571D1 (en) | 1982-03-10 | 1982-11-26 | Method of producing zeolites surface-modified with organo-silanes |
| EP82110922A EP0088158B1 (de) | 1982-03-10 | 1982-11-26 | Verfahren zur Herstellung von mit Organosilanen oberflächenmodifizierten Zeolithen |
| US06/473,634 US4454056A (en) | 1982-03-10 | 1983-03-09 | Process for the production of zeolites modified on the surface with organosilanes |
| JP58038410A JPS58167423A (ja) | 1982-03-10 | 1983-03-10 | オルガノシランで表面改質されたゼオライトの製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19823208598 DE3208598A1 (de) | 1982-03-10 | 1982-03-10 | Verfahren zur herstellung von mit organosilanen oberflaechenmodifizierten zeolithen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3208598A1 true DE3208598A1 (de) | 1983-09-22 |
Family
ID=6157813
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19823208598 Ceased DE3208598A1 (de) | 1982-03-10 | 1982-03-10 | Verfahren zur herstellung von mit organosilanen oberflaechenmodifizierten zeolithen |
| DE8282110922T Expired DE3262571D1 (en) | 1982-03-10 | 1982-11-26 | Method of producing zeolites surface-modified with organo-silanes |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE8282110922T Expired DE3262571D1 (en) | 1982-03-10 | 1982-11-26 | Method of producing zeolites surface-modified with organo-silanes |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4454056A (OSRAM) |
| EP (1) | EP0088158B1 (OSRAM) |
| JP (1) | JPS58167423A (OSRAM) |
| DE (2) | DE3208598A1 (OSRAM) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6284696B1 (en) | 1996-06-07 | 2001-09-04 | Asahi Kasei Kogyo Kabushiki Kaisha | Mesopore molecular sieve and process for the production thereof |
| CN115724438A (zh) * | 2022-10-20 | 2023-03-03 | 陕西科技大学 | 一种高疏水性有机修饰天然沸石及其制备方法 |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8329880D0 (en) * | 1983-11-09 | 1983-12-14 | Unilever Plc | Particulate adjuncts |
| US4534880A (en) * | 1984-03-27 | 1985-08-13 | Dow Corning Corporation | Detergent composition with siliconate-zeolite and silicate builder |
| US4600646A (en) * | 1984-08-15 | 1986-07-15 | E. I. Du Pont De Nemours And Company | Metal oxide stabilized chromatography packings |
| US4927749A (en) * | 1986-04-09 | 1990-05-22 | Jeanette Simpson | Reagent for cell separation |
| US5064668A (en) * | 1989-06-30 | 1991-11-12 | Nabisco Brands, Inc. | Process for separation of sterol compounds from fluid mixtures |
| US5063070A (en) * | 1989-06-30 | 1991-11-05 | Nabisco Brands, Inc. | Processes for separation of sterol compounds from fluid mixtures using substantially insoluble compounds |
| FR2652818B1 (fr) * | 1989-10-09 | 1994-04-01 | Rhone Poulenc Chimie | Suspension de zeolite comprenant une resine silicone. |
| FR2652819B1 (fr) * | 1989-10-09 | 1994-01-07 | Rhone Poulenc Chimie | Suspension de zeolite comprenant un siliconate. |
| US5243117A (en) * | 1990-06-05 | 1993-09-07 | Mobil Oil Corp. | Catalyst and process for the selective production of para-dialkyl substituted benzenes |
| US5091117A (en) * | 1990-04-16 | 1992-02-25 | Nabisco Brands, Inc. | Process for the removal of sterol compounds and saturated fatty acids |
| US5183710A (en) * | 1990-08-30 | 1993-02-02 | U-Sus Distributors, Inc. | Hydrophobic inorganic materials and process for making same |
| GB9209366D0 (en) * | 1992-04-30 | 1992-06-17 | Unilever Plc | Builder and bleach system |
| US5714453A (en) * | 1996-04-01 | 1998-02-03 | S. C. Johnson & Son, Inc. | Alkaline cleaning formulation containing a hydrolyzed silane and method of applying the same |
| US5948383A (en) * | 1997-03-26 | 1999-09-07 | Engelhard Corporation | Hybrid zeolite-silica compositions |
| DE19853971B4 (de) | 1998-11-23 | 2011-06-16 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Anorganisch/organische Polysiloxanhybridpolymere und ihre Verwendung |
| DE19901302A1 (de) * | 1999-01-15 | 2000-07-20 | Degussa | Alkylhalogensilan enthaltene Zeolithpulver |
| US20040120915A1 (en) * | 2002-12-19 | 2004-06-24 | Kaiyuan Yang | Multifunctional compositions for surface applications |
| US9107455B2 (en) * | 2003-11-21 | 2015-08-18 | Philip Morris Usa Inc. | Cigarette filter |
| US7827996B2 (en) | 2003-12-22 | 2010-11-09 | Philip Morris Usa Inc. | Amphiphile-modified sorbents in smoking articles and filters |
| WO2006069061A1 (en) * | 2004-12-21 | 2006-06-29 | Degussa Gmbh | Perfume delivery system |
| US20060165740A1 (en) * | 2005-01-24 | 2006-07-27 | Goldschmidt Chemical Corporation | Perfume delivery system |
| US9714371B2 (en) | 2005-05-02 | 2017-07-25 | Trican Well Service Ltd. | Method for making particulate slurries and particulate slurry compositions |
| US7723274B2 (en) * | 2005-05-02 | 2010-05-25 | Trican Well Service Ltd. | Method for making particulate slurries and particulate slurry compositions |
| CN103382387A (zh) * | 2005-09-23 | 2013-11-06 | 川汉油田服务有限公司 | 浆液组合物及其制备方法 |
| DE102006029849A1 (de) * | 2006-06-27 | 2008-01-03 | Nanoscape Ag | Beschichtetes Molekularsieb |
| AR066304A1 (es) | 2007-04-26 | 2009-08-12 | Trican Well Service Ltd | Composicion de solucion acuosa espesa y metodo para controlar la arena en una formacion productora de hideocarburos para usar con dicha composicion |
| CA2889374A1 (en) | 2014-04-25 | 2015-10-25 | Trican Well Service Ltd. | Compositions and methods for making aqueous slurry |
| CA2856942A1 (en) | 2014-07-16 | 2016-01-16 | Trican Well Service Ltd. | Aqueous slurry for particulates transportation |
| CA2880646A1 (en) | 2015-01-30 | 2016-07-30 | Trican Well Service Ltd. | Composition and method of using polymerizable natural oils to treat proppants |
| US20210402381A1 (en) * | 2017-08-04 | 2021-12-30 | Fernando Thome Kreutz | Rubber compositions and methods |
| WO2021029979A1 (en) | 2019-08-14 | 2021-02-18 | Exxonmobil Research And Engineering Company | Increasing hydrothermal stability of an adsorbent comprising a small pore zeolite in a swing adsorption process |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4138363A (en) * | 1977-09-14 | 1979-02-06 | Pq Corporation | Silane-zeolite compositions |
| DE2843709A1 (de) * | 1977-10-14 | 1979-04-26 | Pq Corp | Waschmittelgemische, die silan-zeolith-geruestsubstanzen enthalten |
| US4183814A (en) * | 1978-01-03 | 1980-01-15 | Union Carbide Corporation | Asbestos composition having organo-silane coating |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5034537B2 (OSRAM) * | 1972-08-24 | 1975-11-10 | ||
| FR2267992A1 (OSRAM) * | 1974-04-19 | 1975-11-14 | Rhone Poulenc Ind | |
| DE2447021C3 (de) * | 1974-10-02 | 1984-03-22 | Degussa Ag, 6000 Frankfurt | Kristallines Zeolithpulver des Typs A und das Verfahren zu seiner Herstellung |
| DE2517218B2 (de) * | 1975-04-18 | 1977-05-05 | Henkel & Cie GmbH, 4000 Düsseldorf; Deutsche Gold- und Silber-Scheideanstalt vormals Roessler, 6000 Frankfurt | Kristallines zeolithpulver des typs a |
| US4013574A (en) * | 1975-04-22 | 1977-03-22 | The Procter & Gamble Company | Organosilane-containing prill |
| FR2351156A1 (fr) * | 1976-05-11 | 1977-12-09 | Rhone Poulenc Ind | Compositions organosiliciques presentant une activite antimousse stable |
| DE2651419A1 (de) * | 1976-11-11 | 1978-05-18 | Degussa | Kristallines zeolithpulver des typs a iv |
| DE2651420A1 (de) * | 1976-11-11 | 1978-05-18 | Degussa | Kristallines zeolithpulver des typs a v |
| DE2651437A1 (de) * | 1976-11-11 | 1978-05-18 | Degussa | Kristallines zeolithpulver des typs a vi |
| DE2651485A1 (de) * | 1976-11-11 | 1978-05-24 | Degussa | Kristallines zeolithpulver des typs a i |
| DE2651436A1 (de) * | 1976-11-11 | 1978-05-18 | Degussa | Kristallines zeolithpulver des typs a iii |
| US4216125A (en) * | 1978-12-07 | 1980-08-05 | Pq Corporation | Detergent compositions with silane-zeolite silicate builder |
| US4243545A (en) * | 1979-12-10 | 1981-01-06 | Pq Corporation | Detergent compositions with silane-zeolite silicate builder |
-
1982
- 1982-03-10 DE DE19823208598 patent/DE3208598A1/de not_active Ceased
- 1982-11-26 EP EP82110922A patent/EP0088158B1/de not_active Expired
- 1982-11-26 DE DE8282110922T patent/DE3262571D1/de not_active Expired
-
1983
- 1983-03-09 US US06/473,634 patent/US4454056A/en not_active Expired - Lifetime
- 1983-03-10 JP JP58038410A patent/JPS58167423A/ja active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4138363A (en) * | 1977-09-14 | 1979-02-06 | Pq Corporation | Silane-zeolite compositions |
| DE2843709A1 (de) * | 1977-10-14 | 1979-04-26 | Pq Corp | Waschmittelgemische, die silan-zeolith-geruestsubstanzen enthalten |
| US4183814A (en) * | 1978-01-03 | 1980-01-15 | Union Carbide Corporation | Asbestos composition having organo-silane coating |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6284696B1 (en) | 1996-06-07 | 2001-09-04 | Asahi Kasei Kogyo Kabushiki Kaisha | Mesopore molecular sieve and process for the production thereof |
| DE19781813B4 (de) * | 1996-06-07 | 2006-06-29 | Asahi Kasei Kabushiki Kaisha | Mesoporen-Molekularsieb und Verfahren zu dessen Herstellung |
| DE19781813B8 (de) * | 1996-06-07 | 2006-12-07 | Asahi Kasei Kabushiki Kaisha | Mesoporen-Molekularsieb und Verfahren zu dessen Herstellung |
| CN115724438A (zh) * | 2022-10-20 | 2023-03-03 | 陕西科技大学 | 一种高疏水性有机修饰天然沸石及其制备方法 |
| CN115724438B (zh) * | 2022-10-20 | 2024-03-22 | 陕西科技大学 | 一种高疏水性有机修饰天然沸石及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0239447B2 (OSRAM) | 1990-09-05 |
| EP0088158A1 (de) | 1983-09-14 |
| JPS58167423A (ja) | 1983-10-03 |
| DE3262571D1 (en) | 1985-04-18 |
| US4454056A (en) | 1984-06-12 |
| EP0088158B1 (de) | 1985-03-13 |
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