DE3148545C2 - Verfahren zum Färben von Flachglas durch Diffusion und Reduktion von Silberionen - Google Patents
Verfahren zum Färben von Flachglas durch Diffusion und Reduktion von SilberionenInfo
- Publication number
- DE3148545C2 DE3148545C2 DE3148545A DE3148545A DE3148545C2 DE 3148545 C2 DE3148545 C2 DE 3148545C2 DE 3148545 A DE3148545 A DE 3148545A DE 3148545 A DE3148545 A DE 3148545A DE 3148545 C2 DE3148545 C2 DE 3148545C2
- Authority
- DE
- Germany
- Prior art keywords
- flat glass
- silver
- glass
- ions
- coloring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000005357 flat glass Substances 0.000 title claims abstract description 49
- 238000000034 method Methods 0.000 title claims abstract description 34
- 229910052709 silver Inorganic materials 0.000 title claims abstract description 32
- 239000004332 silver Substances 0.000 title claims abstract description 32
- 238000004040 coloring Methods 0.000 title claims abstract description 15
- 230000008569 process Effects 0.000 title claims description 11
- -1 silver ions Chemical class 0.000 title abstract description 9
- 230000009467 reduction Effects 0.000 title abstract description 3
- 238000009792 diffusion process Methods 0.000 title 1
- 239000003086 colorant Substances 0.000 claims abstract description 26
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910000314 transition metal oxide Inorganic materials 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 16
- 150000002500 ions Chemical class 0.000 claims abstract description 15
- 239000002344 surface layer Substances 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims abstract description 9
- 229910052751 metal Inorganic materials 0.000 claims abstract description 5
- 239000002184 metal Substances 0.000 claims abstract description 5
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 229910052703 rhodium Inorganic materials 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims 1
- 239000011521 glass Substances 0.000 abstract description 30
- 238000006124 Pilkington process Methods 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 4
- 229910001432 tin ion Inorganic materials 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 230000002542 deteriorative effect Effects 0.000 abstract 1
- 229940100890 silver compound Drugs 0.000 description 12
- 150000003379 silver compounds Chemical class 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000010410 layer Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 238000004043 dyeing Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 4
- 229910052718 tin Inorganic materials 0.000 description 4
- 229910052723 transition metal Inorganic materials 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 2
- 150000001983 dialkylethers Chemical class 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- VUQJFUDRDSVDCY-UHFFFAOYSA-N oxotungsten;silver Chemical compound [Ag].[W]=O VUQJFUDRDSVDCY-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 229910001961 silver nitrate Inorganic materials 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- 229940116411 terpineol Drugs 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229910052946 acanthite Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Inorganic materials O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 229910000367 silver sulfate Inorganic materials 0.000 description 1
- YPNVIBVEFVRZPJ-UHFFFAOYSA-L silver sulfate Chemical compound [Ag+].[Ag+].[O-]S([O-])(=O)=O YPNVIBVEFVRZPJ-UHFFFAOYSA-L 0.000 description 1
- XUARKZBEFFVFRG-UHFFFAOYSA-N silver sulfide Chemical compound [S-2].[Ag+].[Ag+] XUARKZBEFFVFRG-UHFFFAOYSA-N 0.000 description 1
- 229940056910 silver sulfide Drugs 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/008—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in solid phase, e.g. using pastes, powders
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP55172636A JPS5914413B2 (ja) | 1980-12-09 | 1980-12-09 | 板ガラスの着色方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3148545A1 DE3148545A1 (de) | 1982-07-08 |
| DE3148545C2 true DE3148545C2 (de) | 1986-02-06 |
Family
ID=15945545
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3148545A Expired DE3148545C2 (de) | 1980-12-09 | 1981-12-08 | Verfahren zum Färben von Flachglas durch Diffusion und Reduktion von Silberionen |
Country Status (5)
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4844589A (en) * | 1984-07-17 | 1989-07-04 | Hoya Corporation | Lenses having plural contiguous refractive index distribution substrates and method of manufacture |
| DE3840071A1 (de) * | 1988-11-28 | 1990-05-31 | Schott Glaswerke | Verfahren zum ionenaustausch an glas oder glaskeramik |
| US5091003A (en) * | 1990-06-15 | 1992-02-25 | Ford Motor Company | Ink compositions and method for placing indicia on glass |
| US5275979A (en) * | 1992-10-30 | 1994-01-04 | Corning Incorporated | Colored glasses and method |
| WO2003048063A1 (en) * | 2001-12-06 | 2003-06-12 | Eurokera | Method for decorating articles made of glass material |
| KR20040000332A (ko) * | 2002-06-24 | 2004-01-03 | 아사히 가라스 가부시키가이샤 | 음극선관용 유리깔때기 및 그 제조방법 |
| JP2023082564A (ja) * | 2021-12-02 | 2023-06-14 | 登 野村 | 造形物の製作方法および造形物 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2468402A (en) * | 1945-06-14 | 1949-04-26 | Bausch & Lomb | Method of marking glass |
| US3420698A (en) * | 1964-10-05 | 1969-01-07 | Owens Illinois Inc | Method of staining glass and glass staining compositions |
| GB1400823A (en) | 1971-10-01 | 1975-07-23 | Glaverbel | Process of forming coloured glass bodies |
| NL7216461A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1972-12-05 | 1974-06-07 | ||
| US4155735A (en) * | 1977-11-30 | 1979-05-22 | Ppg Industries, Inc. | Electromigration method for making stained glass photomasks |
| DE2813681A1 (de) * | 1978-03-30 | 1979-10-04 | Westfaelische Metall Industrie | Verfahren zum gelbfaerben von scheinwerfer-streuscheiben aus glas |
-
1980
- 1980-12-09 JP JP55172636A patent/JPS5914413B2/ja not_active Expired
-
1981
- 1981-11-12 GB GB8134115A patent/GB2088848B/en not_active Expired
- 1981-12-08 US US06/328,630 patent/US4397667A/en not_active Expired - Fee Related
- 1981-12-08 DE DE3148545A patent/DE3148545C2/de not_active Expired
- 1981-12-08 FR FR8122931A patent/FR2495603A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| FR2495603A1 (fr) | 1982-06-11 |
| FR2495603B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1985-03-22 |
| JPS5914413B2 (ja) | 1984-04-04 |
| US4397667A (en) | 1983-08-09 |
| GB2088848B (en) | 1984-02-08 |
| GB2088848A (en) | 1982-06-16 |
| DE3148545A1 (de) | 1982-07-08 |
| JPS5795854A (en) | 1982-06-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |