DE3123833C2 - Verfahren zur Steuerung der Zusammensetzung von elektrolytisch abgeschiedenen Nickel-Kobalt-Legierungen - Google Patents
Verfahren zur Steuerung der Zusammensetzung von elektrolytisch abgeschiedenen Nickel-Kobalt-LegierungenInfo
- Publication number
- DE3123833C2 DE3123833C2 DE3123833A DE3123833A DE3123833C2 DE 3123833 C2 DE3123833 C2 DE 3123833C2 DE 3123833 A DE3123833 A DE 3123833A DE 3123833 A DE3123833 A DE 3123833A DE 3123833 C2 DE3123833 C2 DE 3123833C2
- Authority
- DE
- Germany
- Prior art keywords
- cobalt
- electrolyte
- nickel
- composition
- anode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims description 23
- 238000000034 method Methods 0.000 title claims description 18
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 title claims description 12
- 229910000531 Co alloy Inorganic materials 0.000 title claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 53
- 239000003792 electrolyte Substances 0.000 claims description 50
- 229910017052 cobalt Inorganic materials 0.000 claims description 29
- 239000010941 cobalt Substances 0.000 claims description 29
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 29
- 229910045601 alloy Inorganic materials 0.000 claims description 19
- 239000000956 alloy Substances 0.000 claims description 19
- 229910052759 nickel Inorganic materials 0.000 claims description 16
- 239000000758 substrate Substances 0.000 claims description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- 239000010936 titanium Substances 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 229910017709 Ni Co Inorganic materials 0.000 claims description 4
- 229910003267 Ni-Co Inorganic materials 0.000 claims description 4
- 229910003262 Ni‐Co Inorganic materials 0.000 claims description 4
- 229910001429 cobalt ion Inorganic materials 0.000 claims description 4
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 claims description 4
- 229910001453 nickel ion Inorganic materials 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 2
- 238000000151 deposition Methods 0.000 description 14
- 230000008021 deposition Effects 0.000 description 14
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- RZBAOHIEEDMCNK-UHFFFAOYSA-J S(N)([O-])(=O)=O.[Co+2].[Ni+2].S(N)([O-])(=O)=O.S(N)([O-])(=O)=O.S(N)([O-])(=O)=O Chemical compound S(N)([O-])(=O)=O.[Co+2].[Ni+2].S(N)([O-])(=O)=O.S(N)([O-])(=O)=O.S(N)([O-])(=O)=O RZBAOHIEEDMCNK-UHFFFAOYSA-J 0.000 description 2
- 239000010405 anode material Substances 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- WLQXLCXXAPYDIU-UHFFFAOYSA-L cobalt(2+);disulfamate Chemical compound [Co+2].NS([O-])(=O)=O.NS([O-])(=O)=O WLQXLCXXAPYDIU-UHFFFAOYSA-L 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000004070 electrodeposition Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 241000380131 Ammophila arenaria Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
- 241000321453 Paranthias colonus Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- POVGIDNLKNVCTJ-UHFFFAOYSA-J cobalt(2+);nickel(2+);disulfate Chemical compound [Co+2].[Ni+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O POVGIDNLKNVCTJ-UHFFFAOYSA-J 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002659 electrodeposit Substances 0.000 description 1
- 238000005323 electroforming Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- KERTUBUCQCSNJU-UHFFFAOYSA-L nickel(2+);disulfamate Chemical compound [Ni+2].NS([O-])(=O)=O.NS([O-])(=O)=O KERTUBUCQCSNJU-UHFFFAOYSA-L 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007785 strong electrolyte Substances 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-M sulfamate Chemical compound NS([O-])(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-M 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/562—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of iron or nickel or cobalt
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/10—Agitating of electrolytes; Moving of racks
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/160,336 US4439284A (en) | 1980-06-17 | 1980-06-17 | Composition control of electrodeposited nickel-cobalt alloys |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3123833A1 DE3123833A1 (de) | 1982-03-04 |
| DE3123833C2 true DE3123833C2 (de) | 1994-02-03 |
Family
ID=22576476
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3123833A Expired - Fee Related DE3123833C2 (de) | 1980-06-17 | 1981-06-16 | Verfahren zur Steuerung der Zusammensetzung von elektrolytisch abgeschiedenen Nickel-Kobalt-Legierungen |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4439284A (forum.php) |
| JP (1) | JPS5729599A (forum.php) |
| DE (1) | DE3123833C2 (forum.php) |
| FR (1) | FR2484465A1 (forum.php) |
| GB (1) | GB2078258B (forum.php) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996019840A1 (de) * | 1994-12-20 | 1996-06-27 | Varta Batterie Aktiengesellschaft | Verfahren zur rückgewinnung von metallen aus gebrauchten nickel-metallhydrid-akkumulatoren |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4613388A (en) * | 1982-09-17 | 1986-09-23 | Rockwell International Corporation | Superplastic alloys formed by electrodeposition |
| DE3416993A1 (de) * | 1984-05-09 | 1985-11-21 | Gerhard Collardin GmbH, 5000 Köln | Waessrige, saure, nickel- und cobalt-ionen enthaltende elektrolyte zur galvanischen abscheidung von harten, anlaufbestaendigen, weiss glaenzenden legierungsueberzuegen |
| IT1182782B (it) * | 1985-07-18 | 1987-10-05 | Centro Speriment Metallurg | Perfezionamento nei procedimenti di zincatura elettrolitica |
| US5695621A (en) * | 1996-07-31 | 1997-12-09 | Framatome Technologies, Inc. | Resonating electroplating anode and process |
| JP2005163152A (ja) * | 2003-12-05 | 2005-06-23 | Renesas Technology Corp | 電気メッキ方法及び半導体装置の製造方法 |
| JP4797739B2 (ja) * | 2006-03-27 | 2011-10-19 | Ｔｄｋ株式会社 | 合金メッキ装置及び合金メッキ方法 |
| US8425751B1 (en) * | 2011-02-03 | 2013-04-23 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Systems and methods for the electrodeposition of a nickel-cobalt alloy |
| US9926641B2 (en) * | 2012-10-15 | 2018-03-27 | Toyo Kohan Co., Ltd | Method of manufacturing metal sheet having alloy plated layer |
| JP6524939B2 (ja) * | 2016-02-26 | 2019-06-05 | 豊田合成株式会社 | ニッケルめっき皮膜及びその製造方法 |
| JP6484586B2 (ja) * | 2016-04-28 | 2019-03-13 | 三島光産株式会社 | 電鋳材の製造方法及び構造物の製造方法 |
| WO2020049655A1 (ja) * | 2018-09-05 | 2020-03-12 | 日本製鉄株式会社 | 電気めっき浴、電気めっき製品の製造方法、及び電気めっき装置 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2778787A (en) * | 1954-03-15 | 1957-01-22 | British Iron Steel Research | Electrodeposition of iron zinc alloys |
| GB910858A (en) * | 1959-12-11 | 1962-11-21 | Ibm | Electrodeposition of a nickel-cobalt alloy |
| GB1060753A (en) * | 1963-07-01 | 1967-03-08 | M & T Chemicals Inc | Improvements in or relating to high speed bright nickel electroplating |
| DE1302891B (forum.php) * | 1964-12-21 | 1971-01-07 | ||
| US3300396A (en) * | 1965-11-24 | 1967-01-24 | Charles T Walker | Electroplating techniques and anode assemblies therefor |
| US3556959A (en) * | 1968-03-29 | 1971-01-19 | Frank Passal | Nickel plating |
| US3719568A (en) * | 1970-12-11 | 1973-03-06 | Oxy Metal Finishing Corp | Nickel electroplating composition and process |
| ZA746191B (en) * | 1973-11-05 | 1975-11-26 | M & T Chemicals Inc | Electrodeposition of alloys of nickel or nickel and cobalt with iron |
| US4062755A (en) * | 1976-05-03 | 1977-12-13 | Bell Telephone Laboratories, Incorporated | Electroplating anode plenum |
| JPS53119227A (en) * | 1977-03-28 | 1978-10-18 | Sankuesuto Kk | Plating method |
| JPS5424971A (en) * | 1977-07-27 | 1979-02-24 | Ube Ind Ltd | Inflation film with network taht can be rapidly and its production |
-
1980
- 1980-06-17 US US06/160,336 patent/US4439284A/en not_active Expired - Lifetime
-
1981
- 1981-04-28 FR FR8108458A patent/FR2484465A1/fr active Granted
- 1981-05-27 GB GB8116181A patent/GB2078258B/en not_active Expired
- 1981-06-16 JP JP9162581A patent/JPS5729599A/ja active Granted
- 1981-06-16 DE DE3123833A patent/DE3123833C2/de not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996019840A1 (de) * | 1994-12-20 | 1996-06-27 | Varta Batterie Aktiengesellschaft | Verfahren zur rückgewinnung von metallen aus gebrauchten nickel-metallhydrid-akkumulatoren |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2078258A (en) | 1982-01-06 |
| DE3123833A1 (de) | 1982-03-04 |
| GB2078258B (en) | 1984-03-28 |
| JPS5729599A (en) | 1982-02-17 |
| JPH0424439B2 (forum.php) | 1992-04-27 |
| US4439284A (en) | 1984-03-27 |
| FR2484465A1 (fr) | 1981-12-18 |
| FR2484465B1 (forum.php) | 1984-12-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8125 | Change of the main classification |
Ipc: C25D 21/12 |
|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |