DE3033121A1 - Waessrige emulgatorarme dispersionen von carboxylgruppen aufweisenden butadien-styrol-emulsionscopolymerisaten und ihre verwendung als bindemittel fuer korrosionsschutzfarben - Google Patents
Waessrige emulgatorarme dispersionen von carboxylgruppen aufweisenden butadien-styrol-emulsionscopolymerisaten und ihre verwendung als bindemittel fuer korrosionsschutzfarbenInfo
- Publication number
- DE3033121A1 DE3033121A1 DE19803033121 DE3033121A DE3033121A1 DE 3033121 A1 DE3033121 A1 DE 3033121A1 DE 19803033121 DE19803033121 DE 19803033121 DE 3033121 A DE3033121 A DE 3033121A DE 3033121 A1 DE3033121 A1 DE 3033121A1
- Authority
- DE
- Germany
- Prior art keywords
- carbon atoms
- butadiene
- weight
- parts
- dispersions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000006185 dispersion Substances 0.000 title claims abstract description 36
- 239000003973 paint Substances 0.000 title claims abstract description 33
- 229920001577 copolymer Polymers 0.000 title claims abstract description 30
- 239000011230 binding agent Substances 0.000 title claims abstract description 18
- 239000000839 emulsion Substances 0.000 title claims abstract description 18
- 238000005260 corrosion Methods 0.000 title abstract description 13
- 230000007797 corrosion Effects 0.000 title description 5
- 230000001681 protective effect Effects 0.000 title description 3
- -1 CARBOXYL GROUPS Chemical group 0.000 title description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 22
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 17
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 12
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 9
- 150000001991 dicarboxylic acids Chemical class 0.000 claims abstract description 8
- 150000002763 monocarboxylic acids Chemical class 0.000 claims abstract description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 5
- 150000005215 alkyl ethers Chemical class 0.000 claims abstract description 3
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 3
- 150000001408 amides Chemical class 0.000 claims abstract description 3
- XMYQHJDBLRZMLW-UHFFFAOYSA-N methanolamine Chemical class NCO XMYQHJDBLRZMLW-UHFFFAOYSA-N 0.000 claims abstract 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 8
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims 1
- 150000004996 alkyl benzenes Chemical class 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 7
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 20
- 239000000178 monomer Substances 0.000 description 17
- 150000003839 salts Chemical class 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 9
- 239000000049 pigment Substances 0.000 description 9
- 239000007921 spray Substances 0.000 description 9
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical class [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- DNTMQTKDNSEIFO-UHFFFAOYSA-N n-(hydroxymethyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCO DNTMQTKDNSEIFO-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 235000010323 ascorbic acid Nutrition 0.000 description 3
- 229960005070 ascorbic acid Drugs 0.000 description 3
- 239000011668 ascorbic acid Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 1
- FSQQTNAZHBEJLS-OWOJBTEDSA-M (e)-4-amino-4-oxobut-2-enoate Chemical compound NC(=O)\C=C\C([O-])=O FSQQTNAZHBEJLS-OWOJBTEDSA-M 0.000 description 1
- NQQRXZOPZBKCNF-NSCUHMNNSA-N (e)-but-2-enamide Chemical compound C\C=C\C(N)=O NQQRXZOPZBKCNF-NSCUHMNNSA-N 0.000 description 1
- BSSNZUFKXJJCBG-OWOJBTEDSA-N (e)-but-2-enediamide Chemical compound NC(=O)\C=C\C(N)=O BSSNZUFKXJJCBG-OWOJBTEDSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- 229920005789 ACRONAL® acrylic binder Polymers 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical class [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- 239000012935 ammoniumperoxodisulfate Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- UOUJSJZBMCDAEU-UHFFFAOYSA-N chromium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Cr+3].[Cr+3] UOUJSJZBMCDAEU-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- HRKQOINLCJTGBK-UHFFFAOYSA-L dioxidosulfate(2-) Chemical compound [O-]S[O-] HRKQOINLCJTGBK-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- ISXSFOPKZQZDAO-UHFFFAOYSA-N formaldehyde;sodium Chemical compound [Na].O=C ISXSFOPKZQZDAO-UHFFFAOYSA-N 0.000 description 1
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- ZQPKVJLLCXWPBV-UHFFFAOYSA-N iron(4+) oxygen(2-) Chemical class [O-2].[O-2].[Fe+4] ZQPKVJLLCXWPBV-UHFFFAOYSA-N 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- FSQQTNAZHBEJLS-UPHRSURJSA-N maleamic acid Chemical compound NC(=O)\C=C/C(O)=O FSQQTNAZHBEJLS-UPHRSURJSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- ULYOZOPEFCQZHH-UHFFFAOYSA-N n-(methoxymethyl)prop-2-enamide Chemical compound COCNC(=O)C=C ULYOZOPEFCQZHH-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000005385 peroxodisulfate group Chemical group 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- 235000019352 zinc silicate Nutrition 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L13/00—Compositions of rubbers containing carboxyl groups
- C08L13/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
- C08L9/08—Latex
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/10—Copolymers of styrene with conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19803033121 DE3033121A1 (de) | 1980-09-03 | 1980-09-03 | Waessrige emulgatorarme dispersionen von carboxylgruppen aufweisenden butadien-styrol-emulsionscopolymerisaten und ihre verwendung als bindemittel fuer korrosionsschutzfarben |
| DE8181105660T DE3160180D1 (en) | 1980-09-03 | 1981-07-18 | Aqueous low emulsifier-content dispersions of butadiene-styrene copolymers that contain carboxyl groups, and their use as binders in corrosion inhibiting paints |
| AT81105660T ATE3050T1 (de) | 1980-09-03 | 1981-07-18 | Waessrige emulgatorarme dispersionen von carboxylgruppen aufweisenden butadien-styrolemulsionscopolymerisaten und ihre verwendung als bindemittel fuer korrosionsschutzfarben. |
| EP81105660A EP0047380B1 (de) | 1980-09-03 | 1981-07-18 | Wässrige emulgatorarme Dispersionen von Carboxylgruppen aufweisenden Butadien-Styrol-Emulsionscopolymerisaten und ihre Verwendung als Bindemittel für Korrosionsschutzfarben |
| US06/292,223 US4358403A (en) | 1980-09-03 | 1981-08-12 | Aqueous low-emulsifier dispersions of butadiene-styrene emulsion copolymers containing carboxyl groups |
| JP56136215A JPS5776038A (en) | 1980-09-03 | 1981-09-01 | Low emulsifiability aqueous dispersion of carboxyl group-having butadiene-styrol emulsion copolymer and use as binder for anticorrosive coloring material |
| ES505136A ES8206572A1 (es) | 1980-09-03 | 1981-09-02 | Procedimiento para la obtencion de dispersiones acuosas de copolimerizados de emulsion de butadieno-estireno que pre- sentan grupos carboxilo |
| AU74881/81A AU544153B2 (en) | 1980-09-03 | 1981-09-02 | Carboxyl-containing butadiene-styrene copolymers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19803033121 DE3033121A1 (de) | 1980-09-03 | 1980-09-03 | Waessrige emulgatorarme dispersionen von carboxylgruppen aufweisenden butadien-styrol-emulsionscopolymerisaten und ihre verwendung als bindemittel fuer korrosionsschutzfarben |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3033121A1 true DE3033121A1 (de) | 1982-04-22 |
Family
ID=6111019
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19803033121 Withdrawn DE3033121A1 (de) | 1980-09-03 | 1980-09-03 | Waessrige emulgatorarme dispersionen von carboxylgruppen aufweisenden butadien-styrol-emulsionscopolymerisaten und ihre verwendung als bindemittel fuer korrosionsschutzfarben |
| DE8181105660T Expired DE3160180D1 (en) | 1980-09-03 | 1981-07-18 | Aqueous low emulsifier-content dispersions of butadiene-styrene copolymers that contain carboxyl groups, and their use as binders in corrosion inhibiting paints |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE8181105660T Expired DE3160180D1 (en) | 1980-09-03 | 1981-07-18 | Aqueous low emulsifier-content dispersions of butadiene-styrene copolymers that contain carboxyl groups, and their use as binders in corrosion inhibiting paints |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4358403A (enrdf_load_stackoverflow) |
| EP (1) | EP0047380B1 (enrdf_load_stackoverflow) |
| JP (1) | JPS5776038A (enrdf_load_stackoverflow) |
| AT (1) | ATE3050T1 (enrdf_load_stackoverflow) |
| AU (1) | AU544153B2 (enrdf_load_stackoverflow) |
| DE (2) | DE3033121A1 (enrdf_load_stackoverflow) |
| ES (1) | ES8206572A1 (enrdf_load_stackoverflow) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3216969A1 (de) * | 1982-05-06 | 1983-11-10 | Basf Farben + Fasern Ag, 2000 Hamburg | Verfahren zur herstellung eines korrosionsschuetzenden ueberzuges |
| US4540739A (en) * | 1984-04-10 | 1985-09-10 | Polysar Limited | Adhesive polymer latex |
| US4628071A (en) * | 1984-08-21 | 1986-12-09 | S. C. Johnson & Son, Inc. | Emulsion copolymerization process |
| JPS6163794A (ja) * | 1984-08-31 | 1986-04-01 | 日本ゼオン株式会社 | 紙塗被用組成物 |
| NL8501949A (nl) * | 1985-07-08 | 1987-02-02 | Dow Chemical Nederland | Styreenpolymeerhars met verbeterde vloeieigenschappen. |
| US4692502A (en) * | 1986-06-09 | 1987-09-08 | The Standard Oil Company | Polymerization process for carboxyl containing polymers utilizing oil soluble ionic surface active agents |
| DE3724858A1 (de) * | 1987-07-28 | 1989-02-09 | Texaco Ag | Waessrige kunststoffdispersion |
| DE3740972A1 (de) * | 1987-12-03 | 1989-06-15 | Bayerische Motoren Werke Ag | Beschichtung zur voruebergehenden markierung von gegenstaenden |
| US5006413A (en) * | 1989-09-05 | 1991-04-09 | E. I. Du Pont De Nemours And Company | Waterbased methylol (meth)acrylamide acrylic polymer and polyurethane containing coating composition |
| US5141986A (en) * | 1990-09-28 | 1992-08-25 | Shell Oil Company | Block copolymer dispersions and process to prepare block copolymer dispersions |
| US5120765A (en) * | 1990-09-28 | 1992-06-09 | Shell Oil Company | Block copolymer dispersions and process to prepare block copolymer dispersions |
| US5314945A (en) * | 1990-12-03 | 1994-05-24 | E. I. Du Pont De Nemours And Company | Waterbased coating compositions of methylol(meth)acrylamide acrylic polymer, polyurethane and melamine crosslinking agent |
| US5563204A (en) * | 1993-01-08 | 1996-10-08 | The Dow Chemical Company | High-strength films of block copolymer latices |
| US5905097A (en) * | 1993-01-08 | 1999-05-18 | The Dow Chemical Company | High-strength breathable films of block copolymer lattices |
| US5578674A (en) * | 1993-01-08 | 1996-11-26 | The Dow Chemical Company | High-strength films of block copolymer latices |
| US5693732A (en) * | 1996-01-08 | 1997-12-02 | Gencorp. Inc. | Latex binder for paper coating formulations having improved strength and blister resistance |
| US5962579A (en) * | 1997-09-26 | 1999-10-05 | The Goodyear Tire & Rubber Company | Coating for concrete structures |
| DE10000446A1 (de) | 2000-01-07 | 2001-07-12 | Polymer Latex Gmbh & Co Kg | Selbstvernetzende wäßrige Polystyrol-Butadien-Dispersionen zur Verfestigung von bituminierbaren Vliesstoffen sowie befestigte Vliesstoffe |
| DE10153932A1 (de) * | 2001-11-06 | 2003-05-22 | Basf Ag | Wässrige Kunstharzzubereitung |
| DE102004041142A1 (de) * | 2004-08-24 | 2006-03-02 | Basf Ag | Verfahren zum Passivieren von metallischen Oberflächen unter Verwendung von Itaconsäure Homo- oder Copolymeren |
| CA2594688A1 (en) * | 2005-01-25 | 2006-08-03 | Sigma Coatings B.V. | A binder composition |
| WO2006084879A1 (de) * | 2005-02-10 | 2006-08-17 | Basf Aktiengesellschaft | Verwendung von dithiophosphinsäuren und/oder deren salzen zur herstellung chromfreier korrosionsschutzschichten |
| WO2007125038A2 (de) | 2006-04-26 | 2007-11-08 | Basf Se | Verfahren zum aufbringen korrosionsschutzschichten auf metallische oberflächen |
| EP1860122A1 (en) * | 2006-05-24 | 2007-11-28 | Rhodia Recherches et Technologies | Process of making aqueous dispersions of polymers, emulsions polymers and use thereof |
| BRPI0813675A8 (pt) | 2007-06-20 | 2018-08-28 | Basf Se | método para aplicar um revestimento de proteção contra corrosão em uma superfície metálica, e, preparação para aplicar um revestimento de proteção contra corrosão em uma superfície metálica |
| EP2212360B1 (de) * | 2007-11-21 | 2013-07-03 | Basf Se | Verfahren zur herstellung von emulsionspolymerisation |
| JP6017912B2 (ja) * | 2012-10-04 | 2016-11-02 | 旭化成株式会社 | 水性防錆塗料組成物及びその塗装物 |
| US9221993B2 (en) * | 2014-03-31 | 2015-12-29 | Ppg Industries Ohio, Inc. | Waterborne acrylic coating compositions |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1279264B (de) * | 1963-11-14 | 1968-10-03 | Bayer Ag | Metallgrundierung |
| US3586519A (en) * | 1969-06-06 | 1971-06-22 | Sapolin Paints | Corrosion inhibiting butadiene styrene paint composition |
| DE2114974B2 (de) * | 1971-03-27 | 1976-01-08 | Chemische Werke Huels Ag, 4370 Marl | Verfahren zur Herstellung von wäßrigen Polymerlatices |
| US3740357A (en) * | 1971-04-09 | 1973-06-19 | Standard Brands Chem Ind Inc | Production of no-gel elastomeric foams |
| CA1009397A (en) | 1972-10-10 | 1977-04-26 | Roy W. Flynn | Corrosion-inhibiting latex paints |
| US3865772A (en) * | 1973-12-05 | 1975-02-11 | Dart Ind Inc | Polymerization process |
| GB1503552A (en) * | 1974-08-08 | 1978-03-15 | Huels Chemische Werke Ag | Coating agents containing synthetic polymeric binders |
| FR2298574A1 (fr) * | 1975-01-24 | 1976-08-20 | Rhone Poulenc Ind | Compositions aqueuses pour couchage du papier pour impression offset feuille |
| US4065423A (en) * | 1976-05-03 | 1977-12-27 | Uniroyal, Inc. | Paper coating latex compositions containing copolymers of monovinylidene aromatic monomer, aliphatic conjugated diene and an aryloyloxycarboxylic acid monomer |
| DE2939657A1 (de) * | 1979-09-29 | 1981-04-16 | Basf Ag, 6700 Ludwigshafen | Bindemittel fuer papierstreichmassen |
-
1980
- 1980-09-03 DE DE19803033121 patent/DE3033121A1/de not_active Withdrawn
-
1981
- 1981-07-18 DE DE8181105660T patent/DE3160180D1/de not_active Expired
- 1981-07-18 EP EP81105660A patent/EP0047380B1/de not_active Expired
- 1981-07-18 AT AT81105660T patent/ATE3050T1/de not_active IP Right Cessation
- 1981-08-12 US US06/292,223 patent/US4358403A/en not_active Expired - Fee Related
- 1981-09-01 JP JP56136215A patent/JPS5776038A/ja active Granted
- 1981-09-02 ES ES505136A patent/ES8206572A1/es not_active Expired
- 1981-09-02 AU AU74881/81A patent/AU544153B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| ATE3050T1 (de) | 1983-04-15 |
| AU7488181A (en) | 1982-03-11 |
| EP0047380B1 (de) | 1983-04-13 |
| ES505136A0 (es) | 1982-08-16 |
| US4358403A (en) | 1982-11-09 |
| AU544153B2 (en) | 1985-05-16 |
| ES8206572A1 (es) | 1982-08-16 |
| DE3160180D1 (en) | 1983-05-19 |
| JPS5776038A (en) | 1982-05-12 |
| JPH0131542B2 (enrdf_load_stackoverflow) | 1989-06-27 |
| EP0047380A1 (de) | 1982-03-17 |
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