DE3029187C2 - Verfahren zur Entfernung von Schwefelwasserstoff aus sauerstofffreien oder sauerstoffhaltigen Gasgemischen - Google Patents

Verfahren zur Entfernung von Schwefelwasserstoff aus sauerstofffreien oder sauerstoffhaltigen Gasgemischen

Info

Publication number
DE3029187C2
DE3029187C2 DE3029187A DE3029187A DE3029187C2 DE 3029187 C2 DE3029187 C2 DE 3029187C2 DE 3029187 A DE3029187 A DE 3029187A DE 3029187 A DE3029187 A DE 3029187A DE 3029187 C2 DE3029187 C2 DE 3029187C2
Authority
DE
Germany
Prior art keywords
oxygen
adsorption
hydrogen sulfide
carbon
molecular sieve
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE3029187A
Other languages
German (de)
English (en)
Other versions
DE3029187A1 (de
Inventor
Burkhard Dipl.-Chem. Dr. 4320 Hattingen Harder
Klaus-Dirk Ing.(Grad.) Henning
Jürgen Dipl.-Phys. Dr. 4300 Essen Klein
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bergwerksverband GmbH
Original Assignee
Bergwerksverband GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bergwerksverband GmbH filed Critical Bergwerksverband GmbH
Priority to DE3029187A priority Critical patent/DE3029187C2/de
Priority to EP81105648A priority patent/EP0045422B1/de
Priority to NO812617A priority patent/NO152114C/no
Priority to JP56119434A priority patent/JPS5756025A/ja
Priority to ZA815309A priority patent/ZA815309B/xx
Priority to US06/289,515 priority patent/US4440551A/en
Publication of DE3029187A1 publication Critical patent/DE3029187A1/de
Application granted granted Critical
Publication of DE3029187C2 publication Critical patent/DE3029187C2/de
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00Nitrogen; Compounds thereof
    • C01B21/04Purification or separation of nitrogen
    • C01B21/0405Purification or separation processes
    • C01B21/0433Physical processing only
    • C01B21/045Physical processing only by adsorption in solids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/30Active carbon
    • C01B32/306Active carbon with molecular sieve properties
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042Purification by adsorption on solids
    • C01B2203/043Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0485Composition of the impurity the impurity being a sulfur compound
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2210/00Purification or separation of specific gases
    • C01B2210/0043Impurity removed
    • C01B2210/0064Hydrogen sulfide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)
  • Hydrogen, Water And Hydrids (AREA)
DE3029187A 1980-08-01 1980-08-01 Verfahren zur Entfernung von Schwefelwasserstoff aus sauerstofffreien oder sauerstoffhaltigen Gasgemischen Expired DE3029187C2 (de)

Priority Applications (6)

Application Number Priority Date Filing Date Title
DE3029187A DE3029187C2 (de) 1980-08-01 1980-08-01 Verfahren zur Entfernung von Schwefelwasserstoff aus sauerstofffreien oder sauerstoffhaltigen Gasgemischen
EP81105648A EP0045422B1 (de) 1980-08-01 1981-07-18 Verfahren zur adsorptiven Entfernung von Schwefelwasserstoff aus Gasgemischen
NO812617A NO152114C (no) 1980-08-01 1981-07-31 Fremgangsmaate til adsorbtiv fjerning av svovelhydrogen fra gassblandinger
JP56119434A JPS5756025A (en) 1980-08-01 1981-07-31 Method of adsorbing and removing hydrogen sulfide from gas mixture
ZA815309A ZA815309B (en) 1980-08-01 1981-08-03 Process for the removal of hydrogen sulphide from gas mixtures containing hydrocarbons
US06/289,515 US4440551A (en) 1980-08-01 1981-08-03 Method for the adsorptive removal of hydrogen sulfide from gas mixtures

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE3029187A DE3029187C2 (de) 1980-08-01 1980-08-01 Verfahren zur Entfernung von Schwefelwasserstoff aus sauerstofffreien oder sauerstoffhaltigen Gasgemischen

Publications (2)

Publication Number Publication Date
DE3029187A1 DE3029187A1 (de) 1982-04-01
DE3029187C2 true DE3029187C2 (de) 1986-04-17

Family

ID=6108646

Family Applications (1)

Application Number Title Priority Date Filing Date
DE3029187A Expired DE3029187C2 (de) 1980-08-01 1980-08-01 Verfahren zur Entfernung von Schwefelwasserstoff aus sauerstofffreien oder sauerstoffhaltigen Gasgemischen

Country Status (6)

Country Link
US (1) US4440551A (enExample)
EP (1) EP0045422B1 (enExample)
JP (1) JPS5756025A (enExample)
DE (1) DE3029187C2 (enExample)
NO (1) NO152114C (enExample)
ZA (1) ZA815309B (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3214771A1 (de) * 1982-04-21 1983-10-27 Bergwerksverband Gmbh, 4300 Essen Verfahren zur gewinnung von edelgasen mit kleinen atomdurchmessern, insbesondere helium, aus sauerstoff und/oder stickstoff enthaltenden gasgemischen
US4627857A (en) * 1983-12-13 1986-12-09 Calgon Carbon Corporation Carbon molecular sieves and a process for their preparation and use
JPH0593519A (ja) * 1991-04-02 1993-04-16 Mitsubishi Heavy Ind Ltd ガス化複合発電プラント
US5916438A (en) * 1994-07-01 1999-06-29 International Fuel Cells, Llc Removal of hydrogen sulfide from anaerobic digester gas
JP3513346B2 (ja) * 1996-12-13 2004-03-31 味の素ゼネラルフーヅ株式会社 アロマ含有ガスの改質方法
US7780846B2 (en) * 2004-09-01 2010-08-24 Sud-Chemie Inc. Sulfur adsorbent, desulfurization system and method for desulfurizing
US8323603B2 (en) * 2004-09-01 2012-12-04 Sud-Chemie Inc. Desulfurization system and method for desulfurizing a fuel stream
US20060283780A1 (en) * 2004-09-01 2006-12-21 Sud-Chemie Inc., Desulfurization system and method for desulfurizing a fuel stream
US20060043001A1 (en) * 2004-09-01 2006-03-02 Sud-Chemie Inc. Desulfurization system and method for desulfurizing afuel stream
US7803215B2 (en) * 2007-12-12 2010-09-28 Uop Llc Adsorber for pretreatment of natural gas containing bulk hydrogen sulfide
CN109569193B (zh) * 2017-09-28 2021-10-29 中国石油化工股份有限公司 一种吸收与再生同步的脱硫方法

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1181210A (fr) * 1956-08-21 1959-06-12 Basf Ag Procédé pour séparer, des gaz et des liquides, les composés de soufre
US3222412A (en) * 1960-06-27 1965-12-07 Exxon Research Engineering Co Carbonaceous adsorbents
DE1544108B1 (de) * 1964-07-15 1970-06-18 Zieren Chemiebau Gmbh Dr A Verfahren zur Herstellung eines aktivierbaren Adsorptionsmittels
DE1594673A1 (de) * 1965-11-13 1971-02-04 Bergwerksverband Gmbh Verfahren zur Entfernung von Schwefeldioxyd aus schwefeldioxydhaltigen Gasen
DE1544084B2 (de) * 1966-10-27 1972-12-14 Metallgesellschaft AG, 6000 Frank fürt Verfahren zur entschwefelung von gasen
US3672125A (en) * 1971-01-28 1972-06-27 Nalco Chemical Co Nta solid support for hydrogen sulfide removal
GB1364674A (en) * 1971-04-23 1974-08-29 Bergwerksverband Gmbh Carbon-containing molecular sieves
US3960768A (en) * 1972-01-28 1976-06-01 Sirmac Ltd. Production of carbon by eliminating hydrogen halide from polymerized halohydrocarbons
DE2305435C3 (de) * 1973-02-03 1979-08-09 Bergwerksverband Gmbh, 4300 Essen Kohlenstoffhaltige Molekularsiebe
JPS5111037B2 (enExample) * 1973-04-26 1976-04-08
JPS5039636B2 (enExample) * 1973-05-29 1975-12-18
CA1070249A (en) * 1974-07-08 1980-01-22 John D. Sherman Suppression of cos formation in molecular sieve purification of hydrocarbon streams
US3988129A (en) * 1974-12-16 1976-10-26 Union Carbide Corporation Process for removing sulfur dioxide from gas streams
SE424631B (sv) * 1975-02-18 1982-08-02 Rohm & Haas Partiklar av makroporos syntetisk polymer samt for forfarande for dess framstellning
US4082694A (en) * 1975-12-24 1978-04-04 Standard Oil Company (Indiana) Active carbon process and composition
US4072479A (en) * 1976-03-01 1978-02-07 Calgon Corporation Impregnated activated carbon for improved removal of malodorous compounds
JPS53131989A (en) * 1977-04-22 1978-11-17 Takeda Chem Ind Ltd Molecular sieving organic gas removing agent
JPS6037047B2 (ja) * 1979-03-09 1985-08-23 住友重機械工業株式会社 脱硫用活性炭の再生法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
NICHTS-ERMITTELT

Also Published As

Publication number Publication date
JPH0144368B2 (enExample) 1989-09-27
ZA815309B (en) 1982-08-25
EP0045422B1 (de) 1984-10-03
NO812617L (no) 1982-02-02
NO152114B (no) 1985-04-29
NO152114C (no) 1985-08-14
JPS5756025A (en) 1982-04-03
EP0045422A1 (de) 1982-02-10
US4440551A (en) 1984-04-03
DE3029187A1 (de) 1982-04-01

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Legal Events

Date Code Title Description
8110 Request for examination paragraph 44
D2 Grant after examination
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee