DE2927088A1 - Weichgemachtes vinylchloridharz und verfahren zu dessen herstellung - Google Patents
Weichgemachtes vinylchloridharz und verfahren zu dessen herstellungInfo
- Publication number
- DE2927088A1 DE2927088A1 DE19792927088 DE2927088A DE2927088A1 DE 2927088 A1 DE2927088 A1 DE 2927088A1 DE 19792927088 DE19792927088 DE 19792927088 DE 2927088 A DE2927088 A DE 2927088A DE 2927088 A1 DE2927088 A1 DE 2927088A1
- Authority
- DE
- Germany
- Prior art keywords
- vinyl acetate
- chloride resin
- vinyl
- vinyl chloride
- liquid ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 35
- 238000000034 method Methods 0.000 title claims description 14
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 229920005989 resin Polymers 0.000 claims description 60
- 239000011347 resin Substances 0.000 claims description 60
- 239000004014 plasticizer Substances 0.000 claims description 52
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 29
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 26
- 239000007788 liquid Substances 0.000 claims description 24
- 239000004800 polyvinyl chloride Substances 0.000 claims description 23
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 22
- 150000002148 esters Chemical class 0.000 claims description 21
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 15
- 229920001577 copolymer Polymers 0.000 claims description 14
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical group CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 11
- -1 characterized by Substances 0.000 claims description 11
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 9
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 229920002554 vinyl polymer Polymers 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims 1
- 238000013329 compounding Methods 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 16
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 6
- 239000002585 base Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 229920012485 Plasticized Polyvinyl chloride Polymers 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 229920005992 thermoplastic resin Polymers 0.000 description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 125000001557 phthalyl group Chemical group C(=O)(O)C1=C(C(=O)*)C=CC=C1 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- ZANNOFHADGWOLI-UHFFFAOYSA-N ethyl 2-hydroxyacetate Chemical compound CCOC(=O)CO ZANNOFHADGWOLI-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229920000578 graft copolymer Polymers 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RLPSARLYTKXVSE-UHFFFAOYSA-N 1-(1,3-thiazol-5-yl)ethanamine Chemical compound CC(N)C1=CN=CS1 RLPSARLYTKXVSE-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 1
- JQXYBDVZAUEPDL-UHFFFAOYSA-N 2-methylidene-5-phenylpent-4-enoic acid Chemical compound OC(=O)C(=C)CC=CC1=CC=CC=C1 JQXYBDVZAUEPDL-UHFFFAOYSA-N 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- 239000004801 Chlorinated PVC Substances 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 description 1
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920001756 Polyvinyl chloride acetate Polymers 0.000 description 1
- 239000004614 Process Aid Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 239000011354 acetal resin Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- VFGRALUHHHDIQI-UHFFFAOYSA-N butyl 2-hydroxyacetate Chemical compound CCCCOC(=O)CO VFGRALUHHHDIQI-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- IEPRKVQEAMIZSS-AATRIKPKSA-N diethyl fumarate Chemical compound CCOC(=O)\C=C\C(=O)OCC IEPRKVQEAMIZSS-AATRIKPKSA-N 0.000 description 1
- GQIDSVPVVYHXAP-UHFFFAOYSA-N dihexyl decanedioate Chemical compound CCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCC GQIDSVPVVYHXAP-UHFFFAOYSA-N 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- AFSIMBWBBOJPJG-UHFFFAOYSA-N ethenyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC=C AFSIMBWBBOJPJG-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 229920005648 ethylene methacrylic acid copolymer Polymers 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229920002681 hypalon Polymers 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 150000002485 inorganic esters Chemical class 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 150000002895 organic esters Chemical class 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical class OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 229920000638 styrene acrylonitrile Polymers 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C08L31/04—Homopolymers or copolymers of vinyl acetate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/924,465 US4209437A (en) | 1978-07-14 | 1978-07-14 | Extraction resistant liquid ethylene-vinyl acetate copolymer plasticized polyvinyl chloride resin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2927088A1 true DE2927088A1 (de) | 1980-01-24 |
| DE2927088C2 DE2927088C2 (en:Method) | 1990-06-28 |
Family
ID=25450235
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19792927088 Granted DE2927088A1 (de) | 1978-07-14 | 1979-07-04 | Weichgemachtes vinylchloridharz und verfahren zu dessen herstellung |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4209437A (en:Method) |
| JP (1) | JPS5513784A (en:Method) |
| AU (1) | AU531672B2 (en:Method) |
| BE (1) | BE877697A (en:Method) |
| BR (1) | BR7904400A (en:Method) |
| CA (1) | CA1141056A (en:Method) |
| DE (1) | DE2927088A1 (en:Method) |
| FR (1) | FR2430961A1 (en:Method) |
| GB (1) | GB2025431B (en:Method) |
| IT (1) | IT1122177B (en:Method) |
| MX (1) | MX6593E (en:Method) |
| NL (1) | NL7905495A (en:Method) |
| NO (1) | NO156943C (en:Method) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4362834A (en) * | 1979-12-26 | 1982-12-07 | The Dow Chemical Company | Extrusion-grade vinylidene chloride copolymer compositions and films prepared therefrom |
| DE3112667C2 (de) * | 1981-03-31 | 1987-04-30 | Feinwerktechnik Schleicher & Co, 7778 Markdorf | Aktenvernichtungsgerät |
| US4436863A (en) | 1981-05-01 | 1984-03-13 | Allied Corporation | Use of ethylene-vinyl acetate copolymers and oxidized high density polyethylene homopolymers as processing aids for talc filled polypropylene compounds |
| JPS58141230A (ja) * | 1982-02-17 | 1983-08-22 | Dainippon Ink & Chem Inc | 振動吸収材 |
| JPS604543A (ja) * | 1983-06-22 | 1985-01-11 | Nippon Carbide Ind Co Ltd | 半硬質塩化ビニル樹脂成形用組成物 |
| US5104741A (en) * | 1989-10-06 | 1992-04-14 | The B. F. Goodrich Company | Plasticized articles having vinyl resin-based products in contact with polymeric or polymer coated substrates |
| NL9002557A (nl) * | 1990-11-23 | 1992-06-16 | Avery International Corp | Drukgevoelig kleefmiddel en zelfklevende constructie die een laag van het kleefmiddel bevat. |
| CA2103274A1 (en) * | 1991-05-23 | 1992-11-24 | Robert J. Statz | Free-flowing powdered polyvinyl chloride compositions |
| US5470894A (en) * | 1992-02-18 | 1995-11-28 | Patel; Naresh D. | Low VOC (volatile organic compounds), solvent-based CPVC pipe adhesives which maintain joint adhesive performance |
| US5821289A (en) * | 1996-07-19 | 1998-10-13 | The B.F. Goodrich Company | Low volatile organic solvent based adhesive |
| US5817708A (en) * | 1996-07-19 | 1998-10-06 | The B. F. Goodrich Company | Low volatile organic solvent based adhesive |
| US6063846A (en) * | 1997-05-30 | 2000-05-16 | Teknor Apex Company | Polyvinyl chloride compositions |
| DE102008019804B4 (de) | 2008-04-15 | 2019-11-14 | Byk-Chemie Gmbh | Funktionalisierte Ethylenpolymere mit hohem Haftvermögen und Verfahren zu ihrer Herstellung |
| WO2011129926A1 (en) * | 2010-04-13 | 2011-10-20 | Exxonmobil Chemical Patents Inc. | Adhesive compositions and methods |
| CN111138997B (zh) * | 2019-12-31 | 2022-04-15 | 苏州中世惠华合成材料有限公司 | 一种软质pvc胶带/保护膜 |
| CN113861477B (zh) * | 2021-09-30 | 2022-06-10 | 无锡市金华屹圆科技有限公司 | 一种冰箱用pvc管及其表面处理工艺 |
| CN118580411B (zh) * | 2024-06-14 | 2025-04-29 | 云南正邦科技有限公司 | 一种低迁移的增塑剂及其在制备高分子聚合材料中的应用 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2657188A (en) * | 1948-10-02 | 1953-10-27 | Union Carbide & Carbon Corp | Olefin-vinyl acetate copolymers and vinyl resins plasticized therewith |
| JPS4918733A (en:Method) * | 1972-05-29 | 1974-02-19 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3010931A (en) * | 1958-12-08 | 1961-11-28 | Monsanto Chemicals | Resinous composition comprising a vinyl halide polymer and a nitroethylbenzene |
| NL293796A (en:Method) * | 1962-06-13 | |||
| FR1377801A (fr) * | 1962-12-22 | 1964-11-06 | Bayer Ag | Procédé de traitement de polymères de chlorure de vinyle |
| US3760036A (en) * | 1972-04-12 | 1973-09-18 | Reynolds Metals Co | Pva lubricant for polyvinyl chloride |
| US4041002A (en) * | 1974-03-19 | 1977-08-09 | Asahi Kasei Kogyo Kabushiki Kaisha | Thermoplastic resin composition |
| US3929700A (en) * | 1974-04-29 | 1975-12-30 | Hooker Chemicals Plastics Corp | Polyvinyl chloride composition |
| GB1550819A (en) * | 1975-06-04 | 1979-08-22 | Nat Res Dev | Polymeric support for biogically active materials |
| JPS523643A (en) * | 1975-06-26 | 1977-01-12 | Sumitomo Chem Co Ltd | Polyvinyl chloride compositions |
-
1978
- 1978-07-14 US US05/924,465 patent/US4209437A/en not_active Expired - Lifetime
-
1979
- 1979-06-20 CA CA000330200A patent/CA1141056A/en not_active Expired
- 1979-06-27 AU AU48421/79A patent/AU531672B2/en not_active Ceased
- 1979-07-04 DE DE19792927088 patent/DE2927088A1/de active Granted
- 1979-07-09 JP JP8601979A patent/JPS5513784A/ja active Granted
- 1979-07-11 BR BR7904400A patent/BR7904400A/pt unknown
- 1979-07-13 IT IT24352/79A patent/IT1122177B/it active
- 1979-07-13 FR FR7918210A patent/FR2430961A1/fr active Granted
- 1979-07-13 NO NO792342A patent/NO156943C/no unknown
- 1979-07-13 NL NL7905495A patent/NL7905495A/nl active Search and Examination
- 1979-07-13 BE BE0/196297A patent/BE877697A/fr not_active IP Right Cessation
- 1979-07-13 MX MX798190U patent/MX6593E/es unknown
- 1979-07-16 GB GB7924741A patent/GB2025431B/en not_active Expired
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2657188A (en) * | 1948-10-02 | 1953-10-27 | Union Carbide & Carbon Corp | Olefin-vinyl acetate copolymers and vinyl resins plasticized therewith |
| JPS4918733A (en:Method) * | 1972-05-29 | 1974-02-19 |
Non-Patent Citations (1)
| Title |
|---|
| Ref. in Hochmolekularbericht 1975 * |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5513784A (en) | 1980-01-30 |
| BR7904400A (pt) | 1980-03-25 |
| DE2927088C2 (en:Method) | 1990-06-28 |
| IT1122177B (it) | 1986-04-23 |
| JPS6258386B2 (en:Method) | 1987-12-05 |
| GB2025431B (en) | 1982-09-29 |
| NO792342L (no) | 1980-01-15 |
| NO156943B (no) | 1987-09-14 |
| BE877697A (fr) | 1980-01-14 |
| IT7924352A0 (it) | 1979-07-13 |
| NL7905495A (nl) | 1980-01-16 |
| AU531672B2 (en) | 1983-09-01 |
| CA1141056A (en) | 1983-02-08 |
| MX6593E (es) | 1985-08-14 |
| GB2025431A (en) | 1980-01-23 |
| FR2430961B1 (en:Method) | 1983-02-25 |
| AU4842179A (en) | 1980-01-17 |
| NO156943C (no) | 1987-12-23 |
| FR2430961A1 (fr) | 1980-02-08 |
| US4209437A (en) | 1980-06-24 |
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|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |