DE2923483A1 - Polarographischer messfuehler fuer die bestimmung des sauerstoffgehaltes in gasen, insbesondere in abgasen von verbrennungsmotoren - Google Patents
Polarographischer messfuehler fuer die bestimmung des sauerstoffgehaltes in gasen, insbesondere in abgasen von verbrennungsmotorenInfo
- Publication number
- DE2923483A1 DE2923483A1 DE19792923483 DE2923483A DE2923483A1 DE 2923483 A1 DE2923483 A1 DE 2923483A1 DE 19792923483 DE19792923483 DE 19792923483 DE 2923483 A DE2923483 A DE 2923483A DE 2923483 A1 DE2923483 A1 DE 2923483A1
- Authority
- DE
- Germany
- Prior art keywords
- cathode
- sensor according
- anode
- gas
- platinum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000001301 oxygen Substances 0.000 title claims description 28
- 229910052760 oxygen Inorganic materials 0.000 title claims description 28
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims description 23
- 239000007789 gas Substances 0.000 title claims description 23
- 238000002485 combustion reaction Methods 0.000 title claims description 5
- 239000003792 electrolyte Substances 0.000 claims description 21
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 20
- 229910052697 platinum Inorganic materials 0.000 claims description 10
- 238000009792 diffusion process Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 3
- 230000004888 barrier function Effects 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 241001600407 Aphis <genus> Species 0.000 claims 1
- FVODKISHRVZUFG-UHFFFAOYSA-N oxygen(2-) platinum(2+) zirconium(4+) Chemical compound [Pt+2].[O-2].[O-2].[Zr+4] FVODKISHRVZUFG-UHFFFAOYSA-N 0.000 claims 1
- 239000000523 sample Substances 0.000 claims 1
- 239000007784 solid electrolyte Substances 0.000 claims 1
- 239000011241 protective layer Substances 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 5
- -1 oxygen ions Chemical class 0.000 description 5
- 230000002146 bilateral effect Effects 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 3
- 238000005192 partition Methods 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4075—Composition or fabrication of the electrodes and coatings thereon, e.g. catalysts
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4071—Cells and probes with solid electrolytes for investigating or analysing gases using sensor elements of laminated structure
- G01N27/4072—Cells and probes with solid electrolytes for investigating or analysing gases using sensor elements of laminated structure characterized by the diffusion barrier
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/416—Systems
- G01N27/48—Systems using polarography, i.e. measuring changes in current under a slowly-varying voltage
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0004—Gaseous mixtures, e.g. polluted air
- G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
- G01N33/0011—Sample conditioning
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Analytical Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Pathology (AREA)
- Immunology (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Medicinal Chemistry (AREA)
- Food Science & Technology (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19792923483 DE2923483A1 (de) | 1979-06-09 | 1979-06-09 | Polarographischer messfuehler fuer die bestimmung des sauerstoffgehaltes in gasen, insbesondere in abgasen von verbrennungsmotoren |
EP80102284A EP0020938B1 (de) | 1979-06-09 | 1980-04-26 | Polarographischer Messfühler für die Bestimmung des Sauerstoffgehaltes in Gasen, insbesondere in Abgasen von Verbrennungsmotoren |
DE8080102284T DE3065133D1 (en) | 1979-06-09 | 1980-04-26 | Polarographic sensor for determining the oxygen content in gases, especially in exhaust gases of internal-combustion engines |
JP7566580A JPS55166038A (en) | 1979-06-09 | 1980-06-06 | Polarograph measuring sensor for oxitygen content of gas |
US06/157,303 US4292158A (en) | 1979-06-09 | 1980-06-09 | Oxygen sensor of the polarographic type, particularly for use with internal combustion engines |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19792923483 DE2923483A1 (de) | 1979-06-09 | 1979-06-09 | Polarographischer messfuehler fuer die bestimmung des sauerstoffgehaltes in gasen, insbesondere in abgasen von verbrennungsmotoren |
Publications (1)
Publication Number | Publication Date |
---|---|
DE2923483A1 true DE2923483A1 (de) | 1980-12-11 |
Family
ID=6072898
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19792923483 Withdrawn DE2923483A1 (de) | 1979-06-09 | 1979-06-09 | Polarographischer messfuehler fuer die bestimmung des sauerstoffgehaltes in gasen, insbesondere in abgasen von verbrennungsmotoren |
DE8080102284T Expired DE3065133D1 (en) | 1979-06-09 | 1980-04-26 | Polarographic sensor for determining the oxygen content in gases, especially in exhaust gases of internal-combustion engines |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE8080102284T Expired DE3065133D1 (en) | 1979-06-09 | 1980-04-26 | Polarographic sensor for determining the oxygen content in gases, especially in exhaust gases of internal-combustion engines |
Country Status (4)
Country | Link |
---|---|
US (1) | US4292158A (enrdf_load_stackoverflow) |
EP (1) | EP0020938B1 (enrdf_load_stackoverflow) |
JP (1) | JPS55166038A (enrdf_load_stackoverflow) |
DE (2) | DE2923483A1 (enrdf_load_stackoverflow) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3626162A1 (de) * | 1985-08-02 | 1987-02-12 | Hitachi Ltd | Luft-kraftstoff-verhaeltnisermittlungssystem fuer ein motorauspuffgas |
DE3529335A1 (de) * | 1985-08-16 | 1987-02-26 | Draegerwerk Ag | Festkoerperkette zur aktivitaetsmessung mit festem ionenleiter |
DE3728289C1 (de) * | 1987-08-25 | 1988-08-04 | Bosch Gmbh Robert | Nach dem polarographischen Messprinzip arbeitende Grenzstromsonde |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2494445A1 (fr) * | 1980-11-17 | 1982-05-21 | Socapex | Capteur electrochimique des concentrations d'especes dans un melange fluide et systeme de regulation de la richesse d'un melange air-carburant mettant en oeuvre un tel capteur |
JPS5958356A (ja) * | 1982-09-28 | 1984-04-04 | Fuji Electric Corp Res & Dev Ltd | ガス分析機器の製造方法 |
JPS59147250A (ja) * | 1983-02-14 | 1984-08-23 | Fuji Electric Corp Res & Dev Ltd | ガス分析機器 |
JPS59166854A (ja) * | 1983-03-14 | 1984-09-20 | Toyota Central Res & Dev Lab Inc | 限界電流式酸素センサ |
JPS59184854A (ja) * | 1983-04-06 | 1984-10-20 | Hitachi Ltd | 酸素センサ |
JPS6086457A (ja) * | 1983-10-19 | 1985-05-16 | Hitachi Ltd | エンジン制御用空燃比センサ |
JPH0612354B2 (ja) * | 1983-11-28 | 1994-02-16 | 株式会社日立製作所 | 酸素濃度測定装置の製造方法 |
US4579643A (en) * | 1983-11-18 | 1986-04-01 | Ngk Insulators, Ltd. | Electrochemical device |
JPH081426B2 (ja) * | 1983-11-18 | 1996-01-10 | 日本碍子株式会社 | 電気化学的装置 |
JPS60135756A (ja) * | 1983-12-24 | 1985-07-19 | Ngk Insulators Ltd | 電気化学的セルの製造方法 |
DE3405162A1 (de) * | 1984-02-14 | 1985-08-22 | Bosch Gmbh Robert | Polarographischer sauerstoffmessfuehler |
JPS60173461A (ja) * | 1984-02-20 | 1985-09-06 | Nissan Motor Co Ltd | 酸素センサ |
US4571285A (en) * | 1984-05-29 | 1986-02-18 | Fujikura Ltd. | Oxygen sensor for and method of determining concentration of oxygen |
JPS6147553A (ja) * | 1984-08-13 | 1986-03-08 | Hitachi Ltd | 空燃比センサ |
EP0218707B1 (de) * | 1985-04-17 | 1992-06-24 | Bayer Diagnostic GmbH | Elektrochemischer messfühler |
DE3635157A1 (de) * | 1986-10-16 | 1988-04-21 | Bosch Gmbh Robert | Gassensor mit cermet-elektroden |
JPH0752171B2 (ja) * | 1987-05-30 | 1995-06-05 | 日本碍子株式会社 | 電気化学的素子 |
DE3834987A1 (de) * | 1988-10-14 | 1990-04-19 | Bosch Gmbh Robert | Sensorelement fuer grenzstromsensoren zur bestimmung des (lambda)-wertes von gasgemischen |
DE3841611A1 (de) * | 1988-12-10 | 1990-06-13 | Bosch Gmbh Robert | Sensorelement fuer grenzstromsensoren zur bestimmung des (lambda)-wertes von gasgemischen |
US5435901A (en) * | 1989-08-18 | 1995-07-25 | Robert Bosch Gmbh | Electrochemical measuring sensor |
US5486279A (en) * | 1989-10-17 | 1996-01-23 | Robert Bosch Gmbh | Electrochemical measuring probe |
GB9116385D0 (en) * | 1991-07-30 | 1991-09-11 | British Gas Plc | Oxygen sensor |
DE4226540A1 (de) * | 1992-08-11 | 1994-04-21 | Bosch Gmbh Robert | Polarographischer Sensor |
DE4319573A1 (de) * | 1993-06-14 | 1994-12-15 | Mannesmann Ag | Elektrochemischer Gasdetektor |
WO1995014226A1 (en) * | 1993-11-19 | 1995-05-26 | Ceramatec, Inc. | Multi-functional sensor for combustion systems |
US6051123A (en) * | 1995-06-15 | 2000-04-18 | Gas Research Institute | Multi-functional and NOx sensor for combustion systems |
JP4309491B2 (ja) * | 1997-05-28 | 2009-08-05 | ローベルト ボツシユ ゲゼルシヤフト ミツト ベシユレンクテル ハフツング | 混合ガスのラムダ値を規定するための限界電流ゾンデ用のセンサ部材、ならびに該センサ部材を寸法決めするための方法 |
US7771576B2 (en) * | 2006-07-18 | 2010-08-10 | Ngk Spark Plug Co., Ltd. | Gas sensor and method for manufacturing gas sensor |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2300417A1 (de) * | 1973-01-05 | 1974-07-11 | Bbc Brown Boveri & Cie | Messaufnehmer fuer geloeste gase |
FR2252041A5 (enrdf_load_stackoverflow) * | 1973-11-16 | 1975-06-13 | Thomson Csf | |
JPS5267697A (en) * | 1975-12-03 | 1977-06-04 | Nissan Motor | Method and instrument for airrfuel ratio detection |
CA1071709A (en) * | 1975-12-05 | 1980-02-12 | Arnold O. Isenberg | Gas analysis apparatus |
-
1979
- 1979-06-09 DE DE19792923483 patent/DE2923483A1/de not_active Withdrawn
-
1980
- 1980-04-26 EP EP80102284A patent/EP0020938B1/de not_active Expired
- 1980-04-26 DE DE8080102284T patent/DE3065133D1/de not_active Expired
- 1980-06-06 JP JP7566580A patent/JPS55166038A/ja active Granted
- 1980-06-09 US US06/157,303 patent/US4292158A/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3626162A1 (de) * | 1985-08-02 | 1987-02-12 | Hitachi Ltd | Luft-kraftstoff-verhaeltnisermittlungssystem fuer ein motorauspuffgas |
DE3529335A1 (de) * | 1985-08-16 | 1987-02-26 | Draegerwerk Ag | Festkoerperkette zur aktivitaetsmessung mit festem ionenleiter |
DE3728289C1 (de) * | 1987-08-25 | 1988-08-04 | Bosch Gmbh Robert | Nach dem polarographischen Messprinzip arbeitende Grenzstromsonde |
Also Published As
Publication number | Publication date |
---|---|
EP0020938B1 (de) | 1983-10-05 |
US4292158A (en) | 1981-09-29 |
JPS634137B2 (enrdf_load_stackoverflow) | 1988-01-27 |
DE3065133D1 (en) | 1983-11-10 |
EP0020938A1 (de) | 1981-01-07 |
JPS55166038A (en) | 1980-12-24 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8139 | Disposal/non-payment of the annual fee |