DE2912430A1 - Alkalisiliconatsilylalkylphosphonate - Google Patents
AlkalisiliconatsilylalkylphosphonateInfo
- Publication number
- DE2912430A1 DE2912430A1 DE19792912430 DE2912430A DE2912430A1 DE 2912430 A1 DE2912430 A1 DE 2912430A1 DE 19792912430 DE19792912430 DE 19792912430 DE 2912430 A DE2912430 A DE 2912430A DE 2912430 A1 DE2912430 A1 DE 2912430A1
- Authority
- DE
- Germany
- Prior art keywords
- hydrocarbon radical
- carbon atoms
- stands
- sodium
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 32
- 238000005260 corrosion Methods 0.000 claims description 24
- 230000007797 corrosion Effects 0.000 claims description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 17
- 150000004760 silicates Chemical class 0.000 claims description 17
- 239000011734 sodium Substances 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 125000005625 siliconate group Chemical group 0.000 claims description 13
- 239000003112 inhibitor Substances 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 11
- 239000003513 alkali Substances 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- 239000004215 Carbon black (E152) Substances 0.000 claims description 10
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 10
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 10
- 229930195733 hydrocarbon Natural products 0.000 claims description 10
- 229910052744 lithium Inorganic materials 0.000 claims description 10
- 150000002739 metals Chemical class 0.000 claims description 10
- 229910052700 potassium Inorganic materials 0.000 claims description 10
- 239000011591 potassium Substances 0.000 claims description 10
- 229910052701 rubidium Inorganic materials 0.000 claims description 10
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 10
- 239000012736 aqueous medium Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 230000002401 inhibitory effect Effects 0.000 claims description 6
- 230000000087 stabilizing effect Effects 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 3
- 229910004283 SiO 4 Inorganic materials 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 37
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 13
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 13
- 239000000499 gel Substances 0.000 description 12
- 239000000463 material Substances 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 9
- 239000004115 Sodium Silicate Substances 0.000 description 8
- 229910052911 sodium silicate Inorganic materials 0.000 description 8
- 150000001298 alcohols Chemical class 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 238000001556 precipitation Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 5
- 235000019795 sodium metasilicate Nutrition 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 229940075614 colloidal silicon dioxide Drugs 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 235000019353 potassium silicate Nutrition 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 4
- 230000006641 stabilisation Effects 0.000 description 4
- 238000011105 stabilization Methods 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- CBKFKFQKLIHLSB-UHFFFAOYSA-N [Si](O)(O)(O)O.P(O)(O)=O Chemical compound [Si](O)(O)(O)O.P(O)(O)=O CBKFKFQKLIHLSB-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 230000001476 alcoholic effect Effects 0.000 description 3
- 230000002528 anti-freeze Effects 0.000 description 3
- 239000002826 coolant Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 229910052913 potassium silicate Inorganic materials 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- -1 silyl cationic carboxylates Chemical class 0.000 description 3
- 125000005353 silylalkyl group Chemical group 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229910003870 O—Li Inorganic materials 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000004111 Potassium silicate Substances 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000007798 antifreeze agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- UFFNHUYHCDHKHK-UHFFFAOYSA-N hexapotassium trioxido(trioxidosilyloxy)silane Chemical compound [K+].[K+].[K+].[K+].[K+].[K+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] UFFNHUYHCDHKHK-UHFFFAOYSA-N 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 150000003018 phosphorus compounds Chemical class 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 2
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 2
- 108010053481 Antifreeze Proteins Proteins 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- GWBUCYZQRDZQGQ-UHFFFAOYSA-N [dichloro(phenyl)methyl] dimethyl phosphate Chemical compound COP(=O)(OC)OC(Cl)(Cl)C1=CC=CC=C1 GWBUCYZQRDZQGQ-UHFFFAOYSA-N 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- YOUGRGFIHBUKRS-UHFFFAOYSA-N benzyl(trimethyl)azanium Chemical compound C[N+](C)(C)CC1=CC=CC=C1 YOUGRGFIHBUKRS-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 125000004966 cyanoalkyl group Chemical group 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- WVMPCBWWBLZKPD-UHFFFAOYSA-N dilithium oxido-[oxido(oxo)silyl]oxy-oxosilane Chemical compound [Li+].[Li+].[O-][Si](=O)O[Si]([O-])=O WVMPCBWWBLZKPD-UHFFFAOYSA-N 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011067 equilibration Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000006277 halobenzyl group Chemical group 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- PMYUVOOOQDGQNW-UHFFFAOYSA-N hexasodium;trioxido(trioxidosilyloxy)silane Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] PMYUVOOOQDGQNW-UHFFFAOYSA-N 0.000 description 1
- 230000001976 improved effect Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 description 1
- 229910052912 lithium silicate Inorganic materials 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229910052605 nesosilicate Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229920001558 organosilicon polymer Polymers 0.000 description 1
- 150000004762 orthosilicates Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000007793 ph indicator Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- HTVWJMRHLQGPCE-UHFFFAOYSA-N rubidium(1+) tetrasilicate Chemical compound [Si]([O-])([O-])([O-])[O-].[Si]([O-])([O-])([O-])[O-].[Si]([O-])([O-])([O-])[O-].[Si]([O-])([O-])([O-])[O-].[Rb+].[Rb+].[Rb+].[Rb+].[Rb+].[Rb+].[Rb+].[Rb+].[Rb+].[Rb+].[Rb+].[Rb+].[Rb+].[Rb+].[Rb+].[Rb+] HTVWJMRHLQGPCE-UHFFFAOYSA-N 0.000 description 1
- WXLGTIBEROWTTK-UHFFFAOYSA-N rubidium(1+) trioxido(trioxidosilyloxy)silane Chemical compound [Si]([O-])([O-])([O-])O[Si]([O-])([O-])[O-].[Rb+].[Rb+].[Rb+].[Rb+].[Rb+].[Rb+] WXLGTIBEROWTTK-UHFFFAOYSA-N 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- MRKAVJXPGLUQKP-UHFFFAOYSA-N tetrakis(2-hydroxyethyl)azanium Chemical compound OCC[N+](CCO)(CCO)CCO MRKAVJXPGLUQKP-UHFFFAOYSA-N 0.000 description 1
- YTZVWGRNMGHDJE-UHFFFAOYSA-N tetralithium;silicate Chemical compound [Li+].[Li+].[Li+].[Li+].[O-][Si]([O-])([O-])[O-] YTZVWGRNMGHDJE-UHFFFAOYSA-N 0.000 description 1
- RLQWHDODQVOVKU-UHFFFAOYSA-N tetrapotassium;silicate Chemical compound [K+].[K+].[K+].[K+].[O-][Si]([O-])([O-])[O-] RLQWHDODQVOVKU-UHFFFAOYSA-N 0.000 description 1
- POWFTOSLLWLEBN-UHFFFAOYSA-N tetrasodium;silicate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])[O-] POWFTOSLLWLEBN-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- ZNEOHLHCKGUAEB-UHFFFAOYSA-N trimethylphenylammonium Chemical compound C[N+](C)(C)C1=CC=CC=C1 ZNEOHLHCKGUAEB-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/32—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing two or more of boron, silicon, phosphorus, selenium, tellurium or a metal
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/167—Phosphorus-containing compounds
- C23F11/1673—Esters of phosphoric or thiophosphoric acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Engineering & Computer Science (AREA)
- Molecular Biology (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US89158478A | 1978-03-30 | 1978-03-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2912430A1 true DE2912430A1 (de) | 1979-10-04 |
| DE2912430C2 DE2912430C2 (en18) | 1988-04-14 |
Family
ID=25398465
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2954388A Expired DE2954388C2 (en18) | 1978-03-30 | 1979-03-29 | |
| DE19792912430 Granted DE2912430A1 (de) | 1978-03-30 | 1979-03-29 | Alkalisiliconatsilylalkylphosphonate |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2954388A Expired DE2954388C2 (en18) | 1978-03-30 | 1979-03-29 |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS5942752B2 (en18) |
| AU (1) | AU523148B2 (en18) |
| BR (1) | BR7901923A (en18) |
| CA (1) | CA1143925A (en18) |
| CH (1) | CH648325A5 (en18) |
| DE (2) | DE2954388C2 (en18) |
| FR (1) | FR2421205A1 (en18) |
| GB (1) | GB2018266B (en18) |
| IT (1) | IT1114218B (en18) |
| NL (1) | NL178972C (en18) |
| SE (1) | SE448240B (en18) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0061694A1 (en) * | 1981-04-01 | 1982-10-06 | Basf Wyandotte Corporation | Antifreeze concentrate and coolant for cooling systems of internal combustion engines, containing copolymers of an organo silicone sulfonate and a silicate |
| EP0189527A2 (de) * | 1984-11-03 | 1986-08-06 | BASF Aktiengesellschaft | Organosilansilikatcopolymere und ihre Verwendung in Kühlerfrostschutzmitteln und zur Stabilisierung von Silikaten |
| US11525186B2 (en) | 2019-06-11 | 2022-12-13 | Ecolab Usa Inc. | Corrosion inhibitor formulation for geothermal reinjection well |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4333843A (en) | 1980-05-27 | 1982-06-08 | The Dow Chemical Company | Glycol compositions containing a hydrolyzate of an organo phosphorus-silicon compound |
| US4344860A (en) * | 1981-03-30 | 1982-08-17 | Dow Corning Corporation | Stabilization of silicates using salts of substituted nitrogen or sulfur containing siliconates |
| US4367154A (en) | 1981-07-29 | 1983-01-04 | The Dow Chemical Company | Glycol compositions containing a phosphorous-modified silane |
| DE3272207D1 (en) * | 1982-12-03 | 1986-08-28 | Dow Chemical Co | Glycol compositions containing phosphorous-modified silane |
| TW530029B (en) * | 1999-11-17 | 2003-05-01 | Akzo Nobel Nv | A method for manufacturing of silica sols |
| KR100477676B1 (ko) | 1999-11-17 | 2005-03-18 | 악조 노벨 엔.브이. | 실리카졸 제조방법 |
| US8591762B2 (en) * | 2011-10-21 | 2013-11-26 | Chevron U.S.A. Inc. | Coolant formulations |
| JP7291512B2 (ja) * | 2019-03-26 | 2023-06-15 | 株式会社デンソー | 熱輸送システム |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2835651A (en) * | 1954-02-19 | 1958-05-20 | Gen Electric | Organosilicon compositions containing phosphorus and their preparation |
| US2889349A (en) * | 1955-11-07 | 1959-06-02 | Ici Ltd | Organosiloxy aryl phosphonates |
| GB1014051A (en) * | 1961-08-11 | 1965-12-22 | Midland Silicones Ltd | Novel silanes and siloxanes |
| US3607757A (en) | 1968-07-24 | 1971-09-21 | Stauffer Chemical Co | Corrosion resistant antifreeze compositions |
| DE1795565A1 (de) * | 1964-05-05 | 1972-01-27 | Tondeo Werk Noss A | Verfahren zur Herstellung von lincarpolymeren Polydiorganosiloxanen,welche Organophosphorseitengruppen tragen |
| US3816184A (en) | 1970-10-12 | 1974-06-11 | Petrolite Corp | Corrosion inhibiting process using silicon-containing aminomethyl phosphonates |
| US3960576A (en) | 1973-06-25 | 1976-06-01 | Betz Laboratories, Inc. | Silicate-based corrosion inhibitor |
| US4093641A (en) * | 1977-09-26 | 1978-06-06 | Dow Corning Corporation | Preparation of silylalkyl esters of phosphorus |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2963503A (en) * | 1958-12-23 | 1960-12-06 | Union Carbide Corp | Process for producing phosphorus-containing organosilicon compounds |
| FR1252655A (fr) * | 1959-12-02 | 1961-02-03 | Union Carbide Corp | Nouvelles compositions antigel pour moteurs à combustion interne |
| GB1003450A (en) * | 1961-04-26 | 1965-09-02 | Union Carbide Corp | Novel organosiloxane-silicate copolymers |
| BE790735A (fr) * | 1971-11-03 | 1973-02-15 | Dynamit Nobel Ag | Application de phosphoro-organosilanes comme promoteurs d'adhesion |
-
1979
- 1979-02-12 CA CA000321287A patent/CA1143925A/en not_active Expired
- 1979-03-26 IT IT21277/79A patent/IT1114218B/it active
- 1979-03-29 DE DE2954388A patent/DE2954388C2/de not_active Expired
- 1979-03-29 DE DE19792912430 patent/DE2912430A1/de active Granted
- 1979-03-29 FR FR7907914A patent/FR2421205A1/fr active Granted
- 1979-03-29 JP JP54037670A patent/JPS5942752B2/ja not_active Expired
- 1979-03-29 BR BR7901923A patent/BR7901923A/pt unknown
- 1979-03-29 AU AU45576/79A patent/AU523148B2/en not_active Expired
- 1979-03-29 CH CH2934/79A patent/CH648325A5/de not_active IP Right Cessation
- 1979-03-29 SE SE7902801A patent/SE448240B/sv not_active IP Right Cessation
- 1979-03-30 GB GB7911243A patent/GB2018266B/en not_active Expired
- 1979-03-30 NL NLAANVRAGE7902495,A patent/NL178972C/xx not_active IP Right Cessation
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2835651A (en) * | 1954-02-19 | 1958-05-20 | Gen Electric | Organosilicon compositions containing phosphorus and their preparation |
| US2889349A (en) * | 1955-11-07 | 1959-06-02 | Ici Ltd | Organosiloxy aryl phosphonates |
| GB1014051A (en) * | 1961-08-11 | 1965-12-22 | Midland Silicones Ltd | Novel silanes and siloxanes |
| DE1795565A1 (de) * | 1964-05-05 | 1972-01-27 | Tondeo Werk Noss A | Verfahren zur Herstellung von lincarpolymeren Polydiorganosiloxanen,welche Organophosphorseitengruppen tragen |
| US3607757A (en) | 1968-07-24 | 1971-09-21 | Stauffer Chemical Co | Corrosion resistant antifreeze compositions |
| US3816184A (en) | 1970-10-12 | 1974-06-11 | Petrolite Corp | Corrosion inhibiting process using silicon-containing aminomethyl phosphonates |
| US3960576A (en) | 1973-06-25 | 1976-06-01 | Betz Laboratories, Inc. | Silicate-based corrosion inhibitor |
| US4093641A (en) * | 1977-09-26 | 1978-06-06 | Dow Corning Corporation | Preparation of silylalkyl esters of phosphorus |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0061694A1 (en) * | 1981-04-01 | 1982-10-06 | Basf Wyandotte Corporation | Antifreeze concentrate and coolant for cooling systems of internal combustion engines, containing copolymers of an organo silicone sulfonate and a silicate |
| EP0189527A2 (de) * | 1984-11-03 | 1986-08-06 | BASF Aktiengesellschaft | Organosilansilikatcopolymere und ihre Verwendung in Kühlerfrostschutzmitteln und zur Stabilisierung von Silikaten |
| EP0189527A3 (en) * | 1984-11-03 | 1987-03-18 | Basf Aktiengesellschaft | Organosilane-silicate copolymers, their use in anti-freeze and coolant liquids and in stabilising silicates |
| US11525186B2 (en) | 2019-06-11 | 2022-12-13 | Ecolab Usa Inc. | Corrosion inhibitor formulation for geothermal reinjection well |
Also Published As
| Publication number | Publication date |
|---|---|
| IT1114218B (it) | 1986-01-27 |
| DE2954388C2 (en18) | 1988-08-11 |
| JPS5942752B2 (ja) | 1984-10-17 |
| GB2018266B (en) | 1983-02-02 |
| DE2912430C2 (en18) | 1988-04-14 |
| NL178972C (nl) | 1986-06-16 |
| SE448240B (sv) | 1987-02-02 |
| CH648325A5 (de) | 1985-03-15 |
| NL7902495A (nl) | 1979-10-02 |
| CA1143925A (en) | 1983-04-05 |
| FR2421205A1 (fr) | 1979-10-26 |
| IT7921277A0 (it) | 1979-03-26 |
| JPS54133441A (en) | 1979-10-17 |
| NL178972B (nl) | 1986-01-16 |
| GB2018266A (en) | 1979-10-17 |
| AU523148B2 (en) | 1982-07-15 |
| FR2421205B1 (en18) | 1981-04-30 |
| BR7901923A (pt) | 1979-10-23 |
| DE2954388A1 (en18) | 1985-03-21 |
| SE7902801L (en18) | 1979-12-03 |
| AU4557679A (en) | 1979-10-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2141441C3 (de) | Wasserunempfindliche hydraulische Flüssigkeit | |
| DE2912430A1 (de) | Alkalisiliconatsilylalkylphosphonate | |
| DE1546050A1 (de) | Mischpolymerisate aus organischen Siliciumverbindungen,insbesondere aus organischen Siloxanen und Silikaten | |
| DE1745923A1 (de) | Organosiliciummischpolymerisate und ihre Verwendung als Korrosionsinhibitor | |
| DE3035327A1 (de) | Kuehlfluessigkeit mit korrosions- und kavitationshemmenden zusaetzen | |
| EP0189527B1 (de) | Organosilansilikatcopolymere und ihre Verwendung in Kühlerfrostschutzmitteln und zur Stabilisierung von Silikaten | |
| DE3208284A1 (de) | Stabilisierung von silikaten mit salzen von substituierten stickstoffhaltigen oder schwefelhaltigen silikonaten | |
| DE69300678T2 (de) | Gefrierschutzmittel. | |
| DE1521737B2 (de) | Verfahren zur Verhinderung der Kor rosion von Metallen, die in Berührung mit Wasser stehen durch Zusatz von Polypho phatglas | |
| DE1811060B2 (de) | Verwendung von Diäthenolaminborsäureestern zum Rostschutz | |
| US2629696A (en) | Essentially non-aqueous acid emulsion cleaning composition | |
| EP0035649A2 (de) | Flüssige, kältestabile Titan-Katalysatorzubereitung und Verfahren zu deren Herstellung | |
| DE3806007C2 (en18) | ||
| EP0863960B1 (de) | Gefrierschutzmittel | |
| DE1295963B (de) | Korrosionsinhibitor | |
| DE2036628C2 (de) | Gefrierschutzmittel | |
| DE2355395C2 (de) | Verwendung eines Siliciumdioxid enthaltenden Bindemittels in Anstrichmitteln | |
| DE2407123C3 (de) | Nicht schäumendes Gefrierschutzmittel | |
| DE3420369C1 (de) | Verwendung von Schwefelsäureestern siliciumorganischer Verbindungen in Gefrierschutzmitteln | |
| DE2557557A1 (de) | Verfahren zur herstellung von polyvinylalkohol enthaltenden filmen und beschichtungen mit verminderter wasserloeslichkeit | |
| DE539038C (de) | Fluessigkeit fuer hydraulische Druckvorrichtungen und Verfahren zu ihrer Herstellung | |
| AT211458B (de) | Hydraulische Flüssigkeiten, Wärmeaustauschflüssigkeiten, z. B. Kühlflüssigkeiten für Verbrennungskraftmaschinen, Schmieröle, Schneidflüssigkeiten und Verfahren zu ihrer Herstellung | |
| EP0345613B1 (de) | Korrosionsinhibierte und physiologisch vorteilhafte funktionelle Flüssigkeiten auf der Basis von Glykolen | |
| DE1908980C3 (de) | Alky 1-diäthylentriammonium verbindungen, ihre Herstellung und Verwendung | |
| DE4129337C1 (en) | Silane derivs. with bunte salt gps. - used as stabilisers for antifreeze compsns. and prevent pptes. forming on diluting concentrates with hard water |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OAP | Request for examination filed | ||
| OD | Request for examination | ||
| 8128 | New person/name/address of the agent |
Representative=s name: SPOTT, G., DIPL.-CHEM. DR.RER.NAT., PAT.-ANW., 800 |
|
| 8172 | Supplementary division/partition in: |
Ref country code: DE Ref document number: 2954388 Format of ref document f/p: P |
|
| Q171 | Divided out to: |
Ref country code: DE Ref document number: 2954388 |
|
| AH | Division in |
Ref country code: DE Ref document number: 2954388 Format of ref document f/p: P |
|
| D2 | Grant after examination | ||
| AH | Division in |
Ref country code: DE Ref document number: 2954388 Format of ref document f/p: P |
|
| 8364 | No opposition during term of opposition |