DE2821308C2 - - Google Patents
Info
- Publication number
- DE2821308C2 DE2821308C2 DE2821308A DE2821308A DE2821308C2 DE 2821308 C2 DE2821308 C2 DE 2821308C2 DE 2821308 A DE2821308 A DE 2821308A DE 2821308 A DE2821308 A DE 2821308A DE 2821308 C2 DE2821308 C2 DE 2821308C2
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- tin
- weight
- percent
- cracking
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 claims description 34
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 13
- 238000005336 cracking Methods 0.000 claims description 11
- 229910001385 heavy metal Inorganic materials 0.000 claims description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- 229930195733 hydrocarbon Natural products 0.000 claims description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims description 8
- 239000003921 oil Substances 0.000 claims description 8
- 238000004523 catalytic cracking Methods 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052787 antimony Inorganic materials 0.000 claims description 4
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 4
- 239000010457 zeolite Substances 0.000 claims description 4
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- 238000002474 experimental method Methods 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000008929 regeneration Effects 0.000 description 5
- 238000011069 regeneration method Methods 0.000 description 5
- 150000003606 tin compounds Chemical class 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 3
- 239000000571 coke Substances 0.000 description 3
- 235000011150 stannous chloride Nutrition 0.000 description 3
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- FRKBDVGTLHBNSN-UHFFFAOYSA-N 1,3,2,4lambda2-dioxazastannetidin-2-ium 2-oxide nitrate Chemical compound [Sn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O FRKBDVGTLHBNSN-UHFFFAOYSA-N 0.000 description 1
- OQXQWBAPFLMGSZ-UHFFFAOYSA-H 2-hydroxypropane-1,2,3-tricarboxylate;tin(2+) Chemical compound [Sn+2].[Sn+2].[Sn+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O OQXQWBAPFLMGSZ-UHFFFAOYSA-H 0.000 description 1
- YXTDAZMTQFUZHK-UHFFFAOYSA-L 5,6-dihydroxy-1,3,2$l^{2}-dioxastannepane-4,7-dione Chemical compound [Sn+2].[O-]C(=O)C(O)C(O)C([O-])=O YXTDAZMTQFUZHK-UHFFFAOYSA-L 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- -1 Tin (II) naphthenate Chemical compound 0.000 description 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- VDEKURXOWJYWCG-UHFFFAOYSA-N dodecyltin Chemical compound CCCCCCCCCCCC[Sn] VDEKURXOWJYWCG-UHFFFAOYSA-N 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 239000012013 faujasite Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 125000005609 naphthenate group Chemical group 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- AFCAKJKUYFLYFK-UHFFFAOYSA-N tetrabutyltin Chemical compound CCCC[Sn](CCCC)(CCCC)CCCC AFCAKJKUYFLYFK-UHFFFAOYSA-N 0.000 description 1
- RWWNQEOPUOCKGR-UHFFFAOYSA-N tetraethyltin Chemical compound CC[Sn](CC)(CC)CC RWWNQEOPUOCKGR-UHFFFAOYSA-N 0.000 description 1
- JTGNPNLBCGBCMP-UHFFFAOYSA-N tetraoctylstannane Chemical compound CCCCCCCC[Sn](CCCCCCCC)(CCCCCCCC)CCCCCCCC JTGNPNLBCGBCMP-UHFFFAOYSA-N 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- SBXWFLISHPUINY-UHFFFAOYSA-N triphenyltin Chemical compound C1=CC=CC=C1[Sn](C=1C=CC=CC=1)C1=CC=CC=C1 SBXWFLISHPUINY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7715318A FR2391264A1 (fr) | 1977-05-18 | 1977-05-18 | Procede de craquage catalytique d'hydrocarbures, et catalyseur pour la mise en oeuvre du procede |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2821308A1 DE2821308A1 (de) | 1978-11-30 |
| DE2821308C2 true DE2821308C2 (enrdf_load_stackoverflow) | 1987-11-26 |
Family
ID=9191022
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19782821308 Granted DE2821308A1 (de) | 1977-05-18 | 1978-05-16 | Verfahren fuer das katalytische kracken von kohlenwasserstoffoelen |
Country Status (15)
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4255287A (en) | 1978-09-12 | 1981-03-10 | Phillips Petroleum Company | Cracking catalyst |
| US4321129A (en) | 1978-09-12 | 1982-03-23 | Phillips Petroleum Company | Cracking process employing catalyst having combination of antimony and tin |
| JPS5734188A (en) * | 1980-08-08 | 1982-02-24 | Nippon Oil Co Ltd | Fluid catalytic cracking of heavy petroleum including distillation residue |
| EP0033791B1 (en) * | 1980-02-07 | 1985-05-15 | United Industries Corporation | Preparations containing cocodiethanolamide |
| US5358630A (en) * | 1980-11-17 | 1994-10-25 | Phillips Petroleum Company | Regenerating zeolitic cracking catalyst |
| US4397767A (en) * | 1982-02-12 | 1983-08-09 | Phillips Petroleum Company | Catalyst poisons passivated with tin compounds plus both sulfur and phosphorus |
| GB2159168B (en) * | 1984-05-25 | 1989-05-10 | Gulf Research Development Co | Process for cracking high metals content feedstocks using a cracking catalyst mixture containing antimony and/or tin |
| JPS60258288A (ja) * | 1984-06-01 | 1985-12-20 | ガルフ・リサ−チ・エンド・デベロツプメント・コンパニ− | 接触分解方法 |
| US4601815A (en) * | 1984-12-27 | 1986-07-22 | Betz Laboratories, Inc. | Passivation of FCC catalysts |
| AU572733B2 (en) * | 1985-07-08 | 1988-05-12 | David Ambrose Brett | A method of fixing jambs |
| US4889617A (en) * | 1986-03-24 | 1989-12-26 | Chevron Research Company | Method of suppressing sodium poisoning of cracking catalysts during fluid catalytic cracking |
| JP6660458B1 (ja) * | 2018-12-27 | 2020-03-11 | 株式会社アマダホールディングス | 金型管理装置及び金型管理方法 |
| JP6920273B2 (ja) * | 2018-12-27 | 2021-08-18 | 株式会社アマダ | 金型管理装置及び金型管理方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3711422A (en) * | 1970-09-08 | 1973-01-16 | Phillips Petroleum Co | Cracking catalyst restoration with antimony compounds |
| US3977963A (en) * | 1975-04-17 | 1976-08-31 | Gulf Research & Development Company | Method of negating the effects of metals poisoning on cracking catalysts |
| US4101417A (en) * | 1976-10-04 | 1978-07-18 | Gulf Research & Development Company | Method of negating the effects of metals poisoning on zeolitic cracking catalysts |
-
1977
- 1977-05-18 FR FR7715318A patent/FR2391264A1/fr active Granted
-
1978
- 1978-04-07 CA CA000300701A patent/CA1223835A/en not_active Expired
- 1978-04-10 IN IN260/DEL/78A patent/IN148037B/en unknown
- 1978-05-10 BE BE1008872A patent/BE866885A/xx not_active IP Right Cessation
- 1978-05-12 MX MX173489A patent/MX148049A/es unknown
- 1978-05-16 BR BR7803074A patent/BR7803074A/pt unknown
- 1978-05-16 DE DE19782821308 patent/DE2821308A1/de active Granted
- 1978-05-16 ES ES469871A patent/ES469871A1/es not_active Expired
- 1978-05-16 AU AU36152/78A patent/AU519866B2/en not_active Expired
- 1978-05-16 JP JP5724878A patent/JPS53142406A/ja active Granted
- 1978-05-16 IT IT23450/78A patent/IT1096215B/it active
- 1978-05-16 NL NLAANVRAGE7805233,A patent/NL189919C/xx not_active IP Right Cessation
- 1978-05-16 GB GB19801/78A patent/GB1598289A/en not_active Expired
- 1978-05-16 AR AR272195A patent/AR223462A1/es active
- 1978-05-16 ZA ZA00782792A patent/ZA782792B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JPS53142406A (en) | 1978-12-12 |
| FR2391264A1 (fr) | 1978-12-15 |
| AU3615278A (en) | 1979-11-22 |
| AU519866B2 (en) | 1981-12-24 |
| IT7823450A0 (it) | 1978-05-16 |
| ZA782792B (en) | 1979-05-30 |
| FR2391264B1 (enrdf_load_stackoverflow) | 1981-01-09 |
| BR7803074A (pt) | 1979-01-02 |
| ES469871A1 (es) | 1978-12-16 |
| DE2821308A1 (de) | 1978-11-30 |
| BE866885A (nl) | 1978-11-10 |
| CA1223835A (en) | 1987-07-07 |
| NL189919C (nl) | 1993-09-01 |
| NL7805233A (nl) | 1978-11-21 |
| IN148037B (enrdf_load_stackoverflow) | 1980-10-04 |
| MX148049A (es) | 1983-03-09 |
| GB1598289A (en) | 1981-09-16 |
| JPS6328957B2 (enrdf_load_stackoverflow) | 1988-06-10 |
| AR223462A1 (es) | 1981-08-31 |
| IT1096215B (it) | 1985-08-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8128 | New person/name/address of the agent |
Representative=s name: JUNG, E., DIPL.-CHEM. DR.PHIL. SCHIRDEWAHN, J., DI |
|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |