DE2817841C2 - Verfahren zur Herstellung eines wärmestabilisierenden Zusatzes für Methylpolysiloxane - Google Patents
Verfahren zur Herstellung eines wärmestabilisierenden Zusatzes für MethylpolysiloxaneInfo
- Publication number
- DE2817841C2 DE2817841C2 DE2817841A DE2817841A DE2817841C2 DE 2817841 C2 DE2817841 C2 DE 2817841C2 DE 2817841 A DE2817841 A DE 2817841A DE 2817841 A DE2817841 A DE 2817841A DE 2817841 C2 DE2817841 C2 DE 2817841C2
- Authority
- DE
- Germany
- Prior art keywords
- liquid
- metal
- mixture
- methylpolysiloxane
- methylpolysiloxanes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000654 additive Substances 0.000 title claims description 28
- 238000000034 method Methods 0.000 title claims description 22
- 230000000996 additive effect Effects 0.000 title claims description 20
- 230000008569 process Effects 0.000 title claims description 14
- 230000000087 stabilizing effect Effects 0.000 title claims description 11
- 238000002360 preparation method Methods 0.000 title claims description 4
- 239000007788 liquid Substances 0.000 claims description 50
- -1 Metal compound zirconium octanoate Chemical class 0.000 claims description 49
- 239000000203 mixture Substances 0.000 claims description 38
- 150000002736 metal compounds Chemical class 0.000 claims description 23
- 150000001875 compounds Chemical class 0.000 claims description 18
- 229910052751 metal Inorganic materials 0.000 claims description 16
- 239000002184 metal Substances 0.000 claims description 16
- 239000012298 atmosphere Substances 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 125000000962 organic group Chemical group 0.000 claims description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 17
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 17
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- 230000008707 rearrangement Effects 0.000 description 16
- 229920001296 polysiloxane Polymers 0.000 description 15
- 230000009969 flowable effect Effects 0.000 description 13
- 229910052726 zirconium Inorganic materials 0.000 description 13
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 10
- 238000000354 decomposition reaction Methods 0.000 description 10
- 239000004205 dimethyl polysiloxane Substances 0.000 description 9
- 229910052735 hafnium Inorganic materials 0.000 description 9
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 239000010936 titanium Substances 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- BPYXFMVJXTUYRV-UHFFFAOYSA-J octanoate;zirconium(4+) Chemical compound [Zr+4].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O BPYXFMVJXTUYRV-UHFFFAOYSA-J 0.000 description 7
- 230000004580 weight loss Effects 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 238000012546 transfer Methods 0.000 description 6
- 229910052845 zircon Inorganic materials 0.000 description 6
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000002411 thermogravimetry Methods 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229910004283 SiO 4 Inorganic materials 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 150000002902 organometallic compounds Chemical group 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000005979 thermal decomposition reaction Methods 0.000 description 3
- YOBOXHGSEJBUPB-MTOQALJVSA-N (z)-4-hydroxypent-3-en-2-one;zirconium Chemical compound [Zr].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O YOBOXHGSEJBUPB-MTOQALJVSA-N 0.000 description 2
- KTXWGMUMDPYXNN-UHFFFAOYSA-N 2-ethylhexan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCCC(CC)C[O-].CCCCC(CC)C[O-].CCCCC(CC)C[O-].CCCCC(CC)C[O-] KTXWGMUMDPYXNN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 125000005595 acetylacetonate group Chemical group 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- DDJSWKLBKSLAAZ-UHFFFAOYSA-N cyclotetrasiloxane Chemical compound O1[SiH2]O[SiH2]O[SiH2]O[SiH2]1 DDJSWKLBKSLAAZ-UHFFFAOYSA-N 0.000 description 2
- JJRDHFIVAPVZJN-UHFFFAOYSA-N cyclotrisiloxane Chemical compound O1[SiH2]O[SiH2]O[SiH2]1 JJRDHFIVAPVZJN-UHFFFAOYSA-N 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000001030 gas--liquid chromatography Methods 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 150000004678 hydrides Chemical class 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 2
- 239000004848 polyfunctional curative Substances 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 150000003608 titanium Chemical class 0.000 description 2
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical compound [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 description 2
- 150000003754 zirconium Chemical class 0.000 description 2
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 1
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 1
- 150000000703 Cerium Chemical class 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 239000005046 Chlorosilane Substances 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical group F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- 229910020175 SiOH Inorganic materials 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007866 anti-wear additive Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- BSDOQSMQCZQLDV-UHFFFAOYSA-N butan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] BSDOQSMQCZQLDV-UHFFFAOYSA-N 0.000 description 1
- PXGPQCBSBQOPLZ-UHFFFAOYSA-N butanoic acid;propanoic acid Chemical compound CCC(O)=O.CCCC(O)=O PXGPQCBSBQOPLZ-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001734 carboxylic acid salts Chemical class 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical class Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 238000004455 differential thermal analysis Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- HHFAWKCIHAUFRX-UHFFFAOYSA-N ethoxide Chemical compound CC[O-] HHFAWKCIHAUFRX-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- BMQOJZRWRYIBEA-UHFFFAOYSA-J hafnium(4+);octanoate Chemical compound [Hf+4].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O BMQOJZRWRYIBEA-UHFFFAOYSA-J 0.000 description 1
- 239000013529 heat transfer fluid Substances 0.000 description 1
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- FYKBHPZYQWSXTG-UHFFFAOYSA-L iron(2+);octanoate Chemical compound [Fe+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O FYKBHPZYQWSXTG-UHFFFAOYSA-L 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000012806 monitoring device Methods 0.000 description 1
- 125000005609 naphthenate group Chemical group 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- IKNCGYCHMGNBCP-UHFFFAOYSA-N propan-1-olate Chemical compound CCC[O-] IKNCGYCHMGNBCP-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000006462 rearrangement reaction Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- 150000004819 silanols Chemical class 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Chemical compound [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
- C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
- C08G77/398—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing boron or metal atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/12—Polysiloxanes containing silicon bound to hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/821,251 US4122109A (en) | 1977-08-02 | 1977-08-02 | Method for preparing a thermal-stability additive and a thermally stabilized methylpolysiloxane and compositions therefrom |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2817841A1 DE2817841A1 (de) | 1979-02-08 |
| DE2817841C2 true DE2817841C2 (de) | 1985-02-14 |
Family
ID=25232918
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2817841A Expired DE2817841C2 (de) | 1977-08-02 | 1978-04-24 | Verfahren zur Herstellung eines wärmestabilisierenden Zusatzes für Methylpolysiloxane |
| DE2857669A Expired DE2857669C2 (de) | 1977-08-02 | 1978-04-24 | Verwendung eines Gemisches aus einem flüssigen Methylpolysiloxan und einer Siloxymetallverbindung als wärmestabilisierender Zusatz für Methylpolysiloxane |
| DE2857670A Expired DE2857670C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1977-08-02 | 1978-04-24 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2857669A Expired DE2857669C2 (de) | 1977-08-02 | 1978-04-24 | Verwendung eines Gemisches aus einem flüssigen Methylpolysiloxan und einer Siloxymetallverbindung als wärmestabilisierender Zusatz für Methylpolysiloxane |
| DE2857670A Expired DE2857670C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1977-08-02 | 1978-04-24 |
Country Status (11)
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61185597A (ja) * | 1985-02-12 | 1986-08-19 | Toray Silicone Co Ltd | 粘性流体継手用オルガノポリシロキサン組成物 |
| US4722957A (en) * | 1986-12-19 | 1988-02-02 | Dow Corning Corporation | Hydraulic silicone crumb with improved heat stability |
| ZW9990A1 (en) * | 1989-06-14 | 1990-10-31 | Dantex Explosives | Explosive composition |
| US4898956A (en) * | 1989-06-27 | 1990-02-06 | Dow Corning Corporation | Method to prepare thermo-oxidatively stable phenylmethylsiloxane fluids |
| US5254656A (en) * | 1992-08-31 | 1993-10-19 | Dow Corning Corporation | Curable organosiloxane compositions containing organotitanate/microencapsulated platinum co-catalysts |
| US6399208B1 (en) | 1999-10-07 | 2002-06-04 | Advanced Technology Materials Inc. | Source reagent composition and method for chemical vapor deposition formation or ZR/HF silicate gate dielectric thin films |
| RU2357979C1 (ru) * | 2007-11-07 | 2009-06-10 | Открытое акционерное общество "Всероссийский научно-исследовательский институт по переработке нефти" | Способ получения присадки к олиго-(поли-)органосилоксанам |
| TWI565732B (zh) * | 2012-06-13 | 2017-01-11 | 財團法人工業技術研究院 | 有機－無機金屬氧化物混成樹脂、其形成方法、及其形成的樹脂組成物 |
| DE102012211258A1 (de) | 2012-06-29 | 2014-01-02 | Wacker Chemie Ag | Siloxan-Mischungen |
| DE102014209670A1 (de) * | 2014-05-21 | 2015-11-26 | Wacker Chemie Ag | Verfahren zum Betrieb einer Anlage mit Siloxan-Hochtemperaturflüssigkeit |
| DE102015202158A1 (de) | 2015-02-06 | 2016-08-11 | Technische Universität München | Verzweigte Organosiloxane als Wärmeträgerflüssigkeit |
| RU2569895C1 (ru) * | 2015-02-20 | 2015-12-10 | Общество с ограниченной ответственностью "Инженерная смазочная компания "МИСКОМ" | Композиция синтетического масла для теплонапряженных газотурбинных двигателей |
| CN107760033A (zh) * | 2017-10-19 | 2018-03-06 | 中国石油化工股份有限公司 | 一种甲基硅油组合物及其制备方法 |
| CN111471178A (zh) * | 2020-05-14 | 2020-07-31 | 哈尔滨工业大学 | 一种骨架掺铪的耐高温杂化有机硅树脂及其制备方法 |
| CN113388117B (zh) * | 2021-03-02 | 2022-04-19 | 杭州师范大学 | 一种含铈多元金属有机化合物改性的二甲基硅油及其制备方法与应用 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2445567A (en) * | 1948-07-20 | Stabilizing organo-substituted | ||
| US2465296A (en) * | 1944-09-20 | 1949-03-22 | Westinghouse Electric Corp | Metal chelate stabilized organic silicon compositions and products thereof |
| GB706703A (en) * | 1950-03-24 | 1954-04-07 | Westinghouse Electric Int Co | Improvements in or relating to organosilicon compositions |
| US2687388A (en) | 1950-11-13 | 1954-08-24 | Nat Distillers Prod Corp | Phenyl methyl siloxane solution containing a zirconium salt |
| US2728736A (en) * | 1954-06-21 | 1955-12-27 | Dow Corning | Organosilicon compositions containing zirconium compound and leather treated with same |
| US2970162A (en) * | 1956-08-16 | 1961-01-31 | Gen Electric | High temperature lubricant and process of making the same |
| US3002927A (en) * | 1959-01-02 | 1961-10-03 | Dow Corning | Stabilized organic silicon fluids |
| US3151099A (en) | 1960-05-30 | 1964-09-29 | Rhone Poulenc Sa | Water curable organopolysiloxanes containing silicic esters and zirconic or titanic esters |
| BE634818A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1962-07-13 | |||
| NL130971C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1963-12-23 | 1900-01-01 | ||
| GB1029040A (en) * | 1964-01-02 | 1966-05-11 | Distillers Co Yeast Ltd | Chelated metalloxane-siloxane polymers |
| US3649660A (en) * | 1970-07-20 | 1972-03-14 | Edgar D Brown Jr | Silyl organometallocenes useful as antioxidants |
| DE2138824B2 (de) * | 1971-08-03 | 1978-03-16 | Moskovskij Institut Tonkoj Chimitscheskoj Technologii Imeni M.V. Lomonosova Moskau | Gegebenenfalls Titan enthaltende Organopolysiloxane Spirocyclischer Struktur |
| US3745129A (en) | 1971-08-27 | 1973-07-10 | E Brown | Silyl organometallocenes useful as antioxidants |
| JPS509039B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1971-10-26 | 1975-04-09 | ||
| GB1424101A (en) * | 1972-05-23 | 1976-02-11 | Wacker Chemie Gmbh | Rendering surfaces hydrophobic |
| GB1522814A (en) * | 1974-11-27 | 1978-08-31 | Gen Electric | Vulcanizable silicone compositions |
-
1977
- 1977-08-02 US US05/821,251 patent/US4122109A/en not_active Expired - Lifetime
-
1978
- 1978-03-03 CA CA298,145A patent/CA1096602A/en not_active Expired
- 1978-04-05 NL NL7803611.A patent/NL166965C/xx not_active IP Right Cessation
- 1978-04-19 BR BR7802421A patent/BR7802421A/pt unknown
- 1978-04-24 DE DE2817841A patent/DE2817841C2/de not_active Expired
- 1978-04-24 DE DE2857669A patent/DE2857669C2/de not_active Expired
- 1978-04-24 IT IT22638/78A patent/IT1094926B/it active
- 1978-04-24 DE DE2857670A patent/DE2857670C2/de not_active Expired
- 1978-04-25 AT AT0295678A patent/AT378965B/de not_active IP Right Cessation
- 1978-05-08 JP JP5434178A patent/JPS5426899A/ja active Granted
- 1978-05-31 GB GB25581/78A patent/GB1604989A/en not_active Expired
- 1978-06-28 AU AU37555/78A patent/AU520054B2/en not_active Expired
- 1978-08-01 FR FR7822675A patent/FR2412583B1/fr not_active Expired
-
1979
- 1979-01-26 FR FR7902065A patent/FR2412584B1/fr not_active Expired
-
1980
- 1980-04-14 JP JP4908980A patent/JPS55147551A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| ATA295678A (de) | 1985-03-15 |
| CA1096602A (en) | 1981-03-03 |
| NL7803611A (nl) | 1979-02-06 |
| FR2412584B1 (fr) | 1985-06-21 |
| DE2857669C2 (de) | 1983-10-20 |
| FR2412583A1 (fr) | 1979-07-20 |
| DE2857670C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1988-01-21 |
| IT1094926B (it) | 1985-08-10 |
| FR2412583B1 (fr) | 1985-06-21 |
| IT7822638A0 (it) | 1978-04-24 |
| FR2412584A1 (fr) | 1979-07-20 |
| GB1604989A (en) | 1981-12-16 |
| JPS5550970B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1980-12-22 |
| NL166965B (nl) | 1981-05-15 |
| JPS5426899A (en) | 1979-02-28 |
| JPS5757501B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1982-12-04 |
| NL166965C (nl) | 1981-10-15 |
| US4122109A (en) | 1978-10-24 |
| AT378965B (de) | 1985-10-25 |
| AU3755578A (en) | 1980-01-03 |
| BR7802421A (pt) | 1979-03-06 |
| AU520054B2 (en) | 1982-01-14 |
| DE2817841A1 (de) | 1979-02-08 |
| JPS55147551A (en) | 1980-11-17 |
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