DE2718788A1 - Verfahren zum katalytischen kracken von mit metall verunreinigten oelen - Google Patents
Verfahren zum katalytischen kracken von mit metall verunreinigten oelenInfo
- Publication number
- DE2718788A1 DE2718788A1 DE19772718788 DE2718788A DE2718788A1 DE 2718788 A1 DE2718788 A1 DE 2718788A1 DE 19772718788 DE19772718788 DE 19772718788 DE 2718788 A DE2718788 A DE 2718788A DE 2718788 A1 DE2718788 A1 DE 2718788A1
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- metal
- feed material
- percent
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052751 metal Inorganic materials 0.000 title claims description 84
- 239000002184 metal Substances 0.000 title claims description 84
- 239000003921 oil Substances 0.000 title claims description 64
- 238000000034 method Methods 0.000 title claims description 47
- 238000004523 catalytic cracking Methods 0.000 title claims description 4
- 239000003054 catalyst Substances 0.000 claims description 77
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 61
- 239000000463 material Substances 0.000 claims description 49
- 238000005336 cracking Methods 0.000 claims description 32
- 229910052759 nickel Inorganic materials 0.000 claims description 30
- 239000007789 gas Substances 0.000 claims description 25
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 21
- 229910052799 carbon Inorganic materials 0.000 claims description 21
- 238000002485 combustion reaction Methods 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 239000010457 zeolite Substances 0.000 claims description 4
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 3
- 239000000446 fuel Substances 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 229910052702 rhenium Inorganic materials 0.000 claims description 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 2
- 235000015250 liver sausages Nutrition 0.000 claims 1
- 230000000717 retained effect Effects 0.000 claims 1
- XYSQXZCMOLNHOI-UHFFFAOYSA-N s-[2-[[4-(acetylsulfamoyl)phenyl]carbamoyl]phenyl] 5-pyridin-1-ium-1-ylpentanethioate;bromide Chemical compound [Br-].C1=CC(S(=O)(=O)NC(=O)C)=CC=C1NC(=O)C1=CC=CC=C1SC(=O)CCCC[N+]1=CC=CC=C1 XYSQXZCMOLNHOI-UHFFFAOYSA-N 0.000 claims 1
- 150000002739 metals Chemical class 0.000 description 13
- 239000000571 coke Substances 0.000 description 10
- 239000004215 Carbon black (E152) Substances 0.000 description 9
- 229930195733 hydrocarbon Natural products 0.000 description 9
- 150000002430 hydrocarbons Chemical class 0.000 description 9
- 239000010779 crude oil Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 230000008929 regeneration Effects 0.000 description 7
- 238000011069 regeneration method Methods 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000012535 impurity Substances 0.000 description 6
- 229910052720 vanadium Inorganic materials 0.000 description 6
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 4
- 239000003502 gasoline Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- 239000010949 copper Substances 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- -1 derived from shale Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000002354 daily effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007324 demetalation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 150000004032 porphyrins Chemical class 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
- C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
- C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
- C10G69/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of catalytic cracking in the absence of hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US68137976A | 1976-04-29 | 1976-04-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2718788A1 true DE2718788A1 (de) | 1977-11-17 |
| DE2718788C2 DE2718788C2 (enrdf_load_stackoverflow) | 1988-02-25 |
Family
ID=24735032
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19772718788 Granted DE2718788A1 (de) | 1976-04-29 | 1977-04-27 | Verfahren zum katalytischen kracken von mit metall verunreinigten oelen |
Country Status (16)
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4347122A (en) * | 1979-11-14 | 1982-08-31 | Ashland Oil, Inc. | Carbo-metallic oil conversion with liquid water |
| US4407714A (en) * | 1981-05-13 | 1983-10-04 | Ashland Oil, Inc. | Process for cracking high-boiling hydrocarbons using high pore volume, low density catalyst |
| US4406773A (en) * | 1981-05-13 | 1983-09-27 | Ashland Oil, Inc. | Magnetic separation of high activity catalyst from low activity catalyst |
| DE3390537C2 (de) * | 1983-10-20 | 1995-08-10 | Stone & Webster Eng Corp | Verfahren zum katalytischen Spalten von Rückstandsölen |
| CN112725020B (zh) * | 2019-10-28 | 2023-03-07 | 中国石油化工股份有限公司 | 一种生产低碳烯烃的方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3696025A (en) * | 1970-11-09 | 1972-10-03 | Chevron Res | Catalytic cracking by addition of titanium to catalyst |
| DE2444911A1 (de) * | 1973-09-20 | 1975-04-03 | Mobil Oil Corp | Krackkatalysator und dessen verwendung |
| DE2507343A1 (de) * | 1974-03-04 | 1975-09-11 | Standard Oil Co | Verfahren zur regenerierung eines crackkatalysators |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3193494A (en) * | 1962-07-24 | 1965-07-06 | Sinclair Research Inc | Progressive flow cracking of contaminated hydrocarbon feedstocks |
| US3379639A (en) * | 1964-10-09 | 1968-04-23 | Sinclair Research Inc | Residual deasphalting and cracking with catalyst demetallization |
| US3711422A (en) * | 1970-09-08 | 1973-01-16 | Phillips Petroleum Co | Cracking catalyst restoration with antimony compounds |
| BE792165A (fr) * | 1971-11-30 | 1973-05-30 | Standard Oil Co | Procede perfectionne de cracking catalytique avec combustion sensiblement complete du monoxyde de carbone pendant la regeneration du catalyseur |
| US3862898A (en) * | 1973-07-30 | 1975-01-28 | Pullman Inc | Process for the production of olefinically unsaturated hydrocarbons |
| US3944482A (en) * | 1973-08-08 | 1976-03-16 | Gulf Research & Development Company | Process for the cracking of high metals content feedstocks |
| US3990992A (en) * | 1974-04-12 | 1976-11-09 | Standard Oil Company | Regeneration of cracking catalyst in a vessel with a partition forming an upper and lower zone |
| CA1069871A (en) * | 1975-07-08 | 1980-01-15 | Exxon Research And Engineering Company | Process for regenerating metal-contaminated hydrocarbon conversion catalysts |
-
1977
- 1977-04-07 CA CA275,889A patent/CA1105406A/en not_active Expired
- 1977-04-19 BE BE176841A patent/BE853743A/xx not_active IP Right Cessation
- 1977-04-19 FR FR7711676A patent/FR2349639A1/fr active Granted
- 1977-04-22 GB GB16834/77A patent/GB1556901A/en not_active Expired
- 1977-04-25 ZA ZA00772478A patent/ZA772478B/xx unknown
- 1977-04-26 TR TR19565A patent/TR19565A/xx unknown
- 1977-04-26 MX MX775663U patent/MX4516E/es unknown
- 1977-04-26 NL NLAANVRAGE7704564,A patent/NL188857C/xx not_active IP Right Cessation
- 1977-04-27 JP JP4799877A patent/JPS52133304A/ja active Granted
- 1977-04-27 DE DE19772718788 patent/DE2718788A1/de active Granted
- 1977-04-27 AU AU24603/77A patent/AU505813B2/en not_active Expired
- 1977-04-28 IT IT22934/77A patent/IT1075515B/it active
- 1977-04-28 BR BR7702726A patent/BR7702726A/pt unknown
- 1977-04-28 ES ES458265A patent/ES458265A1/es not_active Expired
- 1977-04-29 AT AT306277A patent/AT360628B/de not_active IP Right Cessation
- 1977-04-29 AR AR77267419A patent/AR241923A1/es active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3696025A (en) * | 1970-11-09 | 1972-10-03 | Chevron Res | Catalytic cracking by addition of titanium to catalyst |
| DE2444911A1 (de) * | 1973-09-20 | 1975-04-03 | Mobil Oil Corp | Krackkatalysator und dessen verwendung |
| DE2507343A1 (de) * | 1974-03-04 | 1975-09-11 | Standard Oil Co | Verfahren zur regenerierung eines crackkatalysators |
Also Published As
| Publication number | Publication date |
|---|---|
| MX4516E (es) | 1982-06-02 |
| FR2349639A1 (fr) | 1977-11-25 |
| AR241923A1 (es) | 1993-01-29 |
| FR2349639B1 (enrdf_load_stackoverflow) | 1983-09-16 |
| GB1556901A (en) | 1979-11-28 |
| ES458265A1 (es) | 1978-02-16 |
| AT360628B (de) | 1981-01-26 |
| IT1075515B (it) | 1985-04-22 |
| TR19565A (tr) | 1979-08-02 |
| NL188857B (nl) | 1992-05-18 |
| BE853743A (fr) | 1977-10-19 |
| JPS614871B2 (enrdf_load_stackoverflow) | 1986-02-13 |
| JPS52133304A (en) | 1977-11-08 |
| AU505813B2 (en) | 1979-12-06 |
| DE2718788C2 (enrdf_load_stackoverflow) | 1988-02-25 |
| NL7704564A (nl) | 1977-11-01 |
| ZA772478B (en) | 1978-11-29 |
| AU2460377A (en) | 1978-11-02 |
| NL188857C (nl) | 1992-10-16 |
| CA1105406A (en) | 1981-07-21 |
| ATA306277A (de) | 1980-06-15 |
| BR7702726A (pt) | 1978-03-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8128 | New person/name/address of the agent |
Representative=s name: KADOR, U., DIPL.-CHEM. DR.RER.NAT., PAT.-ANW., 800 |
|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |