CA1105406A - Catalytic cracking of metal-contaminated oils - Google Patents
Catalytic cracking of metal-contaminated oilsInfo
- Publication number
- CA1105406A CA1105406A CA275,889A CA275889A CA1105406A CA 1105406 A CA1105406 A CA 1105406A CA 275889 A CA275889 A CA 275889A CA 1105406 A CA1105406 A CA 1105406A
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- metal
- process according
- ppm
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004523 catalytic cracking Methods 0.000 title claims abstract description 6
- 239000003921 oil Substances 0.000 title abstract description 58
- 239000003054 catalyst Substances 0.000 claims abstract description 70
- 238000000034 method Methods 0.000 claims abstract description 38
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 22
- 229910052751 metal Inorganic materials 0.000 claims description 66
- 239000002184 metal Substances 0.000 claims description 66
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 59
- 229910052759 nickel Inorganic materials 0.000 claims description 29
- 238000005336 cracking Methods 0.000 claims description 24
- 239000007789 gas Substances 0.000 claims description 17
- 238000002485 combustion reaction Methods 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 230000000737 periodic effect Effects 0.000 claims description 3
- 229910021536 Zeolite Inorganic materials 0.000 claims description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
- 238000009434 installation Methods 0.000 claims description 2
- 229910052702 rhenium Inorganic materials 0.000 claims description 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 2
- 239000010457 zeolite Substances 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 7
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 7
- 239000001257 hydrogen Substances 0.000 abstract description 7
- 238000004231 fluid catalytic cracking Methods 0.000 abstract description 5
- 150000002739 metals Chemical class 0.000 description 33
- 239000004215 Carbon black (E152) Substances 0.000 description 9
- 229930195733 hydrocarbon Natural products 0.000 description 9
- 150000002430 hydrocarbons Chemical class 0.000 description 9
- 239000003208 petroleum Substances 0.000 description 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 7
- 239000000571 coke Substances 0.000 description 7
- 239000000356 contaminant Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 230000008929 regeneration Effects 0.000 description 6
- 238000011069 regeneration method Methods 0.000 description 6
- 229910052720 vanadium Inorganic materials 0.000 description 6
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 description 4
- 239000003502 gasoline Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000007324 demetalation reaction Methods 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 239000003546 flue gas Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000000295 fuel oil Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 238000003556 assay Methods 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- BHMLFPOTZYRDKA-IRXDYDNUSA-N (2s)-2-[(s)-(2-iodophenoxy)-phenylmethyl]morpholine Chemical compound IC1=CC=CC=C1O[C@@H](C=1C=CC=CC=1)[C@H]1OCCNC1 BHMLFPOTZYRDKA-IRXDYDNUSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 101100385237 Mus musculus Creg1 gene Proteins 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- -1 distillate stocks Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 150000004032 porphyrins Chemical class 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
- C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
- C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
- C10G69/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of catalytic cracking in the absence of hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US68137976A | 1976-04-29 | 1976-04-29 | |
| US681,379 | 1976-04-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1105406A true CA1105406A (en) | 1981-07-21 |
Family
ID=24735032
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA275,889A Expired CA1105406A (en) | 1976-04-29 | 1977-04-07 | Catalytic cracking of metal-contaminated oils |
Country Status (16)
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4347122A (en) * | 1979-11-14 | 1982-08-31 | Ashland Oil, Inc. | Carbo-metallic oil conversion with liquid water |
| US4407714A (en) * | 1981-05-13 | 1983-10-04 | Ashland Oil, Inc. | Process for cracking high-boiling hydrocarbons using high pore volume, low density catalyst |
| US4406773A (en) * | 1981-05-13 | 1983-09-27 | Ashland Oil, Inc. | Magnetic separation of high activity catalyst from low activity catalyst |
| DE3390537C2 (de) * | 1983-10-20 | 1995-08-10 | Stone & Webster Eng Corp | Verfahren zum katalytischen Spalten von Rückstandsölen |
| CN112725020B (zh) * | 2019-10-28 | 2023-03-07 | 中国石油化工股份有限公司 | 一种生产低碳烯烃的方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3193494A (en) * | 1962-07-24 | 1965-07-06 | Sinclair Research Inc | Progressive flow cracking of contaminated hydrocarbon feedstocks |
| US3379639A (en) * | 1964-10-09 | 1968-04-23 | Sinclair Research Inc | Residual deasphalting and cracking with catalyst demetallization |
| US3711422A (en) * | 1970-09-08 | 1973-01-16 | Phillips Petroleum Co | Cracking catalyst restoration with antimony compounds |
| US3696025A (en) * | 1970-11-09 | 1972-10-03 | Chevron Res | Catalytic cracking by addition of titanium to catalyst |
| BE792165A (fr) * | 1971-11-30 | 1973-05-30 | Standard Oil Co | Procede perfectionne de cracking catalytique avec combustion sensiblement complete du monoxyde de carbone pendant la regeneration du catalyseur |
| US3862898A (en) * | 1973-07-30 | 1975-01-28 | Pullman Inc | Process for the production of olefinically unsaturated hydrocarbons |
| US3944482A (en) * | 1973-08-08 | 1976-03-16 | Gulf Research & Development Company | Process for the cracking of high metals content feedstocks |
| CA1051411A (en) * | 1973-09-20 | 1979-03-27 | Mobil Oil Corporation | Cracking catalyst and cracking process using same |
| NL7501695A (nl) * | 1974-03-04 | 1975-09-08 | Standard Oil Co | Werkwijze voor het regenereren van kraakkata- lysatoren. |
| US3990992A (en) * | 1974-04-12 | 1976-11-09 | Standard Oil Company | Regeneration of cracking catalyst in a vessel with a partition forming an upper and lower zone |
| CA1069871A (en) * | 1975-07-08 | 1980-01-15 | Exxon Research And Engineering Company | Process for regenerating metal-contaminated hydrocarbon conversion catalysts |
-
1977
- 1977-04-07 CA CA275,889A patent/CA1105406A/en not_active Expired
- 1977-04-19 BE BE176841A patent/BE853743A/xx not_active IP Right Cessation
- 1977-04-19 FR FR7711676A patent/FR2349639A1/fr active Granted
- 1977-04-22 GB GB16834/77A patent/GB1556901A/en not_active Expired
- 1977-04-25 ZA ZA00772478A patent/ZA772478B/xx unknown
- 1977-04-26 TR TR19565A patent/TR19565A/xx unknown
- 1977-04-26 MX MX775663U patent/MX4516E/es unknown
- 1977-04-26 NL NLAANVRAGE7704564,A patent/NL188857C/xx not_active IP Right Cessation
- 1977-04-27 JP JP4799877A patent/JPS52133304A/ja active Granted
- 1977-04-27 DE DE19772718788 patent/DE2718788A1/de active Granted
- 1977-04-27 AU AU24603/77A patent/AU505813B2/en not_active Expired
- 1977-04-28 IT IT22934/77A patent/IT1075515B/it active
- 1977-04-28 BR BR7702726A patent/BR7702726A/pt unknown
- 1977-04-28 ES ES458265A patent/ES458265A1/es not_active Expired
- 1977-04-29 AT AT306277A patent/AT360628B/de not_active IP Right Cessation
- 1977-04-29 AR AR77267419A patent/AR241923A1/es active
Also Published As
| Publication number | Publication date |
|---|---|
| MX4516E (es) | 1982-06-02 |
| FR2349639A1 (fr) | 1977-11-25 |
| AR241923A1 (es) | 1993-01-29 |
| FR2349639B1 (enrdf_load_stackoverflow) | 1983-09-16 |
| GB1556901A (en) | 1979-11-28 |
| DE2718788A1 (de) | 1977-11-17 |
| ES458265A1 (es) | 1978-02-16 |
| AT360628B (de) | 1981-01-26 |
| IT1075515B (it) | 1985-04-22 |
| TR19565A (tr) | 1979-08-02 |
| NL188857B (nl) | 1992-05-18 |
| BE853743A (fr) | 1977-10-19 |
| JPS614871B2 (enrdf_load_stackoverflow) | 1986-02-13 |
| JPS52133304A (en) | 1977-11-08 |
| AU505813B2 (en) | 1979-12-06 |
| DE2718788C2 (enrdf_load_stackoverflow) | 1988-02-25 |
| NL7704564A (nl) | 1977-11-01 |
| ZA772478B (en) | 1978-11-29 |
| AU2460377A (en) | 1978-11-02 |
| NL188857C (nl) | 1992-10-16 |
| ATA306277A (de) | 1980-06-15 |
| BR7702726A (pt) | 1978-03-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |