DE2647208A1 - Verfahren zur anreicherung von schwefelwasserstoff in sauren gasen - Google Patents
Verfahren zur anreicherung von schwefelwasserstoff in sauren gasenInfo
- Publication number
- DE2647208A1 DE2647208A1 DE19762647208 DE2647208A DE2647208A1 DE 2647208 A1 DE2647208 A1 DE 2647208A1 DE 19762647208 DE19762647208 DE 19762647208 DE 2647208 A DE2647208 A DE 2647208A DE 2647208 A1 DE2647208 A1 DE 2647208A1
- Authority
- DE
- Germany
- Prior art keywords
- mdea
- solution
- flow rate
- mass flow
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007789 gas Substances 0.000 title claims description 89
- 238000000034 method Methods 0.000 title claims description 33
- 239000002253 acid Substances 0.000 title claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 7
- 229910052717 sulfur Inorganic materials 0.000 title description 16
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title description 14
- 239000011593 sulfur Substances 0.000 title description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title 1
- 239000001257 hydrogen Substances 0.000 title 1
- 230000002378 acidificating effect Effects 0.000 claims description 40
- 239000000243 solution Substances 0.000 claims description 38
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 claims description 30
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 16
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 14
- 230000008929 regeneration Effects 0.000 claims description 14
- 238000011069 regeneration method Methods 0.000 claims description 14
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 2
- PVXVWWANJIWJOO-UHFFFAOYSA-N 1-(1,3-benzodioxol-5-yl)-N-ethylpropan-2-amine Chemical compound CCNC(C)CC1=CC=C2OCOC2=C1 PVXVWWANJIWJOO-UHFFFAOYSA-N 0.000 claims 10
- QMMZSJPSPRTHGB-UHFFFAOYSA-N MDEA Natural products CC(C)CCCCC=CCC=CC(O)=O QMMZSJPSPRTHGB-UHFFFAOYSA-N 0.000 claims 10
- 238000004519 manufacturing process Methods 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 description 14
- 150000001412 amines Chemical class 0.000 description 14
- 241000196324 Embryophyta Species 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 7
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000006477 desulfuration reaction Methods 0.000 description 5
- 230000023556 desulfurization Effects 0.000 description 5
- 238000000605 extraction Methods 0.000 description 5
- 230000032683 aging Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 150000003512 tertiary amines Chemical class 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 2
- 230000002427 irreversible effect Effects 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1462—Removing mixtures of hydrogen sulfide and carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1406—Multiple stage absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/16—Hydrogen sulfides
- C01B17/167—Separation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Gas Separation By Absorption (AREA)
- Treating Waste Gases (AREA)
- Industrial Gases (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7532154A FR2328657A1 (fr) | 1975-10-21 | 1975-10-21 | Procede d'enrichissement en h2s des gaz acides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2647208A1 true DE2647208A1 (de) | 1977-04-28 |
| DE2647208C2 DE2647208C2 (enrdf_load_stackoverflow) | 1987-07-02 |
Family
ID=9161442
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19762647208 Granted DE2647208A1 (de) | 1975-10-21 | 1976-10-19 | Verfahren zur anreicherung von schwefelwasserstoff in sauren gasen |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS5250978A (enrdf_load_stackoverflow) |
| AU (1) | AU499571B2 (enrdf_load_stackoverflow) |
| CA (1) | CA1097485A (enrdf_load_stackoverflow) |
| DE (1) | DE2647208A1 (enrdf_load_stackoverflow) |
| ES (1) | ES452507A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2328657A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1554594A (enrdf_load_stackoverflow) |
| IT (1) | IT1069035B (enrdf_load_stackoverflow) |
| NL (1) | NL188328C (enrdf_load_stackoverflow) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1128293A (en) * | 1978-04-07 | 1982-07-27 | Roelof Cornelisse | Removal of acid gases from a gas mixture |
| FR2439613A1 (fr) * | 1978-10-27 | 1980-05-23 | Elf Aquitaine | Procede d'extraction selective de h2s de melanges gazeux contenant du co2 |
| FR2537888B1 (fr) * | 1982-12-21 | 1985-06-28 | Elf Aquitaine | Perfectionnement a l'enrichissement en hydrogene sulfure de gaz qui en contiennent |
| US4869884A (en) * | 1988-05-06 | 1989-09-26 | Kerr-Mcgee Chemical Corporation | Process for recovering acidic gases |
| FR2990880B1 (fr) | 2012-05-25 | 2017-04-28 | Total Sa | Procede d'elimination selective du sulfure d'hydrogene de melanges gazeux et utilisation d'un thioalcanol pour l'elimination selective du sulfure d'hydrogene. |
| FR2990878B1 (fr) | 2012-05-25 | 2014-05-16 | Total Sa | Procede de purification de melanges gazeux contenant des gaz acides. |
| WO2021038716A1 (ja) * | 2019-08-27 | 2021-03-04 | 三菱電機株式会社 | 受信装置 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2134942A1 (de) * | 1970-07-15 | 1972-01-20 | Shell Int Research | Verfahren zum selektiven Entfernen von Schwefelwasserstoff aus Schwefelwasserstoff und Kohlendioxid enthaltenden Gasen |
-
1975
- 1975-10-21 FR FR7532154A patent/FR2328657A1/fr active Granted
-
1976
- 1976-10-18 GB GB43183/76A patent/GB1554594A/en not_active Expired
- 1976-10-19 AU AU18812/76A patent/AU499571B2/en not_active Expired
- 1976-10-19 DE DE19762647208 patent/DE2647208A1/de active Granted
- 1976-10-19 ES ES452507A patent/ES452507A1/es not_active Expired
- 1976-10-19 JP JP51125988A patent/JPS5250978A/ja active Pending
- 1976-10-20 CA CA263,810A patent/CA1097485A/fr not_active Expired
- 1976-10-21 IT IT28531/76A patent/IT1069035B/it active
- 1976-10-21 NL NLAANVRAGE7611690,A patent/NL188328C/xx not_active IP Right Cessation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2134942A1 (de) * | 1970-07-15 | 1972-01-20 | Shell Int Research | Verfahren zum selektiven Entfernen von Schwefelwasserstoff aus Schwefelwasserstoff und Kohlendioxid enthaltenden Gasen |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5250978A (en) | 1977-04-23 |
| IT1069035B (it) | 1985-03-21 |
| NL188328C (nl) | 1992-06-01 |
| FR2328657A1 (fr) | 1977-05-20 |
| DE2647208C2 (enrdf_load_stackoverflow) | 1987-07-02 |
| NL7611690A (nl) | 1977-04-25 |
| CA1097485A (fr) | 1981-03-17 |
| FR2328657B1 (enrdf_load_stackoverflow) | 1979-05-04 |
| AU1881276A (en) | 1978-04-27 |
| GB1554594A (en) | 1979-10-24 |
| NL188328B (nl) | 1992-01-02 |
| ES452507A1 (es) | 1977-11-01 |
| AU499571B2 (en) | 1979-04-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE3222282C2 (de) | Verfahren zum Entfernen von Schwefelwasserstoff und Kohlendioxid aus einem Gasgemisch | |
| DE2407405C2 (de) | Verfahren zur Regeneration von zur Entfernung von gasförmigen Verunreinigungen aus Gasgemischen verwendeten Absorptionslösungen durch Abstreifen mit Wasserdampf | |
| DE2548700C2 (de) | Verfahren und Vorrichtung zur Wasserstoffreinigung unter gleichzeitiger Kohlendioxidgewinnung | |
| DE2148244A1 (de) | Verfahren zur Reinigung von Ver brennungsprodukten vor ihrem Ausstoß in die Atmosphäre | |
| DE2459913A1 (de) | Verfahren zur gleichzeitigen entfernung von so tief x und no tief x aus abgasen | |
| DD241015A5 (de) | Verfahren zur selektiven trennung von schwefelwasserstoff aus gasgemischen die auch kohlendioxid enthalten | |
| DE2034453A1 (de) | Verfahren zum Abtrennen von Schwefel dioxyd aus Gasen | |
| DE2817084C2 (de) | Verfahren zum Entfernen saurer Gase aus einem diese enthaltenden Gasgemisch | |
| DE2423828C3 (de) | Verfahren zum Reinigen von Industriegasen | |
| DE1544106C3 (de) | Verfahren zum Entfernen saurer Gase aus Gasgemischen | |
| DE69408874T2 (de) | Reinigung von erdgas | |
| DE2131507B2 (de) | Verfahren und Vorrichtung zur Anreicherung von Edelgasspuren, insbesondere Krypton, aus einer Kohlendioxid als Bestandteil enthaltenden Gasmischung | |
| DE2647208C2 (enrdf_load_stackoverflow) | ||
| DE2800491C2 (de) | Verfahren zur selektiven Entschwefelung eines Gasgemisches | |
| EP0520316B1 (de) | Verfahren zur selektiven H2S-Auswaschung | |
| DE351633C (de) | Verfahren zur Reinigung von Kohlengasen mittels Ammoniak | |
| DE1519955C3 (de) | Verfahren zur Abtrennung von CO 2 aus Gasgemischen | |
| DE2804451C2 (de) | Verfahren zur Erhöhung des H↓2↓S/CO↓2↓-Verhältnisses in einem Gasgemisch | |
| DE2605287C2 (de) | Verfahren zur Entfernung von sauren Bestandteilen aus Gasen | |
| DE3006238A1 (de) | Verfahren zur behandlung der abgase aus schwefelextraktionsanlagen und anlage zum einsatz dieses verfahrens | |
| DD239728A5 (de) | Verfahren zur selektiven trennung von schwefelwasserstoff aus gasgemischen, die auch kohlendioxid enthalten | |
| DE2943434A1 (de) | Verfahren zur selektiven extraktion von h tief 2 s aus c0 tief 2 enthaltenden gasgemischen | |
| EP0628519B1 (de) | Verfahren zur Reinigung von alkalischem Prozesskondensat-Abwasser | |
| DE2649719A1 (de) | Kontinuierliches verfahren zur selektiven schwefelwasserstoffabsorption | |
| DE1544141B2 (de) | Verfahren zum Entfernen von Gasoder Flüssigkeitsresten aus angereicherten Lösungsmitteln |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition |