DE2614070A1 - Feinteilige verseifte aethylen/vinylacetat-copolymere - Google Patents
Feinteilige verseifte aethylen/vinylacetat-copolymereInfo
- Publication number
- DE2614070A1 DE2614070A1 DE19762614070 DE2614070A DE2614070A1 DE 2614070 A1 DE2614070 A1 DE 2614070A1 DE 19762614070 DE19762614070 DE 19762614070 DE 2614070 A DE2614070 A DE 2614070A DE 2614070 A1 DE2614070 A1 DE 2614070A1
- Authority
- DE
- Germany
- Prior art keywords
- product
- saponification
- polymer
- temperature
- vinyl acetate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920001577 copolymer Polymers 0.000 title claims description 32
- 239000010419 fine particle Substances 0.000 title 1
- 238000007127 saponification reaction Methods 0.000 claims description 54
- 238000000034 method Methods 0.000 claims description 47
- 239000006185 dispersion Substances 0.000 claims description 42
- 229920000642 polymer Polymers 0.000 claims description 31
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 27
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 26
- 239000005977 Ethylene Substances 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 239000002270 dispersing agent Substances 0.000 claims description 23
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 19
- 239000002245 particle Substances 0.000 claims description 16
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 15
- 229920001400 block copolymer Polymers 0.000 claims description 15
- 150000003839 salts Chemical class 0.000 claims description 15
- 150000007529 inorganic bases Chemical class 0.000 claims description 13
- 125000006353 oxyethylene group Chemical group 0.000 claims description 8
- 150000001768 cations Chemical class 0.000 claims description 7
- 238000000354 decomposition reaction Methods 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims 1
- 239000000047 product Substances 0.000 description 42
- 238000003756 stirring Methods 0.000 description 16
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 15
- 239000012798 spherical particle Substances 0.000 description 11
- 239000000843 powder Substances 0.000 description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 8
- 230000007062 hydrolysis Effects 0.000 description 8
- 238000006460 hydrolysis reaction Methods 0.000 description 8
- 239000002585 base Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- 239000002609 medium Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- -1 polyethylene Polymers 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 4
- 238000006136 alcoholysis reaction Methods 0.000 description 4
- 239000012736 aqueous medium Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000002955 isolation Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011362 coarse particle Substances 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- ZEFVHSWKYCYFFL-UHFFFAOYSA-N diethyl 2-methylidenebutanedioate Chemical compound CCOC(=O)CC(=C)C(=O)OCC ZEFVHSWKYCYFFL-UHFFFAOYSA-N 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920001983 poloxamer Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 101100189378 Caenorhabditis elegans pat-3 gene Proteins 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-methyltaurine Natural products CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
- 229920002065 Pluronic® P 105 Polymers 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- JBSLOWBPDRZSMB-BQYQJAHWSA-N dibutyl (e)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C\C(=O)OCCCC JBSLOWBPDRZSMB-BQYQJAHWSA-N 0.000 description 1
- IEPRKVQEAMIZSS-AATRIKPKSA-N diethyl fumarate Chemical compound CCOC(=O)\C=C\C(=O)OCC IEPRKVQEAMIZSS-AATRIKPKSA-N 0.000 description 1
- URLYMBMJTPDVEP-UHFFFAOYSA-N dimethyl 2-methylidenepentanedioate Chemical compound COC(=O)CCC(=C)C(=O)OC URLYMBMJTPDVEP-UHFFFAOYSA-N 0.000 description 1
- LDCRTTXIJACKKU-ARJAWSKDSA-N dimethyl maleate Chemical compound COC(=O)\C=C/C(=O)OC LDCRTTXIJACKKU-ARJAWSKDSA-N 0.000 description 1
- XGZRAKBCYZIBKP-UHFFFAOYSA-L disodium;dihydroxide Chemical compound [OH-].[OH-].[Na+].[Na+] XGZRAKBCYZIBKP-UHFFFAOYSA-L 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002168 ethanoic acid esters Chemical class 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000004482 other powder Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/12—Hydrolysis
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/50—Chemical modification of a polymer wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/564,200 US4027079A (en) | 1975-04-01 | 1975-04-01 | Finely divided saponified ethylene-vinyl acetate interpolymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2614070A1 true DE2614070A1 (de) | 1976-10-14 |
Family
ID=24253544
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19762614070 Withdrawn DE2614070A1 (de) | 1975-04-01 | 1976-04-01 | Feinteilige verseifte aethylen/vinylacetat-copolymere |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US4027079A (cg-RX-API-DMAC7.html) |
| JP (1) | JPS51122190A (cg-RX-API-DMAC7.html) |
| AU (1) | AU1249276A (cg-RX-API-DMAC7.html) |
| BE (1) | BE840290A (cg-RX-API-DMAC7.html) |
| BR (1) | BR7601957A (cg-RX-API-DMAC7.html) |
| DE (1) | DE2614070A1 (cg-RX-API-DMAC7.html) |
| DK (1) | DK144276A (cg-RX-API-DMAC7.html) |
| ES (1) | ES446594A1 (cg-RX-API-DMAC7.html) |
| FI (1) | FI760883A7 (cg-RX-API-DMAC7.html) |
| FR (1) | FR2306220A1 (cg-RX-API-DMAC7.html) |
| GB (1) | GB1548653A (cg-RX-API-DMAC7.html) |
| IT (1) | IT1058897B (cg-RX-API-DMAC7.html) |
| LU (1) | LU74673A1 (cg-RX-API-DMAC7.html) |
| NL (1) | NL7603407A (cg-RX-API-DMAC7.html) |
| NO (1) | NO761110L (cg-RX-API-DMAC7.html) |
| SE (1) | SE7603854L (cg-RX-API-DMAC7.html) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10321942A1 (de) * | 2003-05-15 | 2004-12-09 | Wacker Polymer Systems Gmbh & Co. Kg | Verfahren zur Herstellung von pulverförmigen Ethylen-Vinylalkohol-Mischpolymerisaten |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51126291A (en) * | 1975-04-25 | 1976-11-04 | Toyo Soda Mfg Co Ltd | Process for preparing a saponfied ethyhlenevinyl acetate copolymer hav ing high whiteness |
| US4104453A (en) * | 1977-07-05 | 1978-08-01 | National Distillers And Chemical Corporation | Melt dispersion saponification of ethylene-vinyl acetate polymer |
| US4151134A (en) * | 1977-08-15 | 1979-04-24 | National Distillers And Chemical Corporation | Process for simultaneously dispersing and saponifying ethylene-vinyl acetate copolymer |
| DE2830328C2 (de) * | 1978-07-10 | 1982-09-16 | Ruhrchemie Ag, 4200 Oberhausen | Mischpolymerisate des Äthylens und ihre Verwendung zur Herstellung von Schaumstoffen |
| US4309525A (en) * | 1979-05-21 | 1982-01-05 | Takeda Chemical Industries, Ltd. | Production of sphere-formed powdery copolymers |
| US4389506A (en) * | 1981-06-29 | 1983-06-21 | E. I. Du Pont De Nemours And Company | Polyvinyl alcohol dust suppression by admixing polyglycol |
| US5753753A (en) * | 1997-02-19 | 1998-05-19 | Air Products And Chemicals, Inc. | Hydrolysis of polyvinyl aklaenoates |
| WO2009091893A1 (en) * | 2008-01-16 | 2009-07-23 | Penn Color, Inc. | Production of toner for use in printing applications |
| US8652745B2 (en) | 2008-01-16 | 2014-02-18 | Penn Color, Inc. | Ink toner particles with controlled surface morphology |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE88404C (cg-RX-API-DMAC7.html) * | ||||
| US2467774A (en) * | 1945-02-16 | 1949-04-19 | Du Pont | Process of hydrolyzing vinyl ester polymers |
| US3422049A (en) * | 1961-12-20 | 1969-01-14 | Nat Distillers Chem Corp | Process of preparing finely divided thermoplastic resins |
| US3547858A (en) * | 1967-05-19 | 1970-12-15 | Monsanto Chemicals | Hydrolysis of esters in the molten state |
-
1975
- 1975-04-01 US US05/564,200 patent/US4027079A/en not_active Expired - Lifetime
-
1976
- 1976-03-30 AU AU12492/76A patent/AU1249276A/en not_active Expired
- 1976-03-30 FR FR7609218A patent/FR2306220A1/fr active Granted
- 1976-03-30 DK DK144276A patent/DK144276A/da not_active IP Right Cessation
- 1976-03-31 LU LU74673A patent/LU74673A1/xx unknown
- 1976-03-31 BR BR7601957A patent/BR7601957A/pt unknown
- 1976-03-31 GB GB13000/76A patent/GB1548653A/en not_active Expired
- 1976-03-31 IT IT21774/76A patent/IT1058897B/it active
- 1976-03-31 SE SE7603854A patent/SE7603854L/xx unknown
- 1976-03-31 NO NO761110A patent/NO761110L/no unknown
- 1976-04-01 JP JP51035211A patent/JPS51122190A/ja active Pending
- 1976-04-01 DE DE19762614070 patent/DE2614070A1/de not_active Withdrawn
- 1976-04-01 FI FI760883A patent/FI760883A7/fi not_active Application Discontinuation
- 1976-04-01 NL NL7603407A patent/NL7603407A/xx not_active Application Discontinuation
- 1976-04-01 BE BE165772A patent/BE840290A/xx unknown
- 1976-04-01 ES ES446594A patent/ES446594A1/es not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10321942A1 (de) * | 2003-05-15 | 2004-12-09 | Wacker Polymer Systems Gmbh & Co. Kg | Verfahren zur Herstellung von pulverförmigen Ethylen-Vinylalkohol-Mischpolymerisaten |
Also Published As
| Publication number | Publication date |
|---|---|
| NO761110L (cg-RX-API-DMAC7.html) | 1976-10-04 |
| US4027079A (en) | 1977-05-31 |
| FR2306220B1 (cg-RX-API-DMAC7.html) | 1980-08-14 |
| NL7603407A (nl) | 1976-10-05 |
| GB1548653A (en) | 1979-07-18 |
| FI760883A7 (cg-RX-API-DMAC7.html) | 1976-10-02 |
| BR7601957A (pt) | 1976-10-05 |
| BE840290A (fr) | 1976-10-01 |
| FR2306220A1 (fr) | 1976-10-29 |
| SE7603854L (sv) | 1976-10-02 |
| LU74673A1 (cg-RX-API-DMAC7.html) | 1976-09-01 |
| ES446594A1 (es) | 1977-06-16 |
| JPS51122190A (en) | 1976-10-26 |
| AU1249276A (en) | 1977-10-20 |
| IT1058897B (it) | 1982-05-10 |
| DK144276A (da) | 1976-10-02 |
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