DE2505845A1 - Verfahren zur gewinnung von cyanurverbindungen und chlor aus mutterlaugen - Google Patents
Verfahren zur gewinnung von cyanurverbindungen und chlor aus mutterlaugenInfo
- Publication number
- DE2505845A1 DE2505845A1 DE19752505845 DE2505845A DE2505845A1 DE 2505845 A1 DE2505845 A1 DE 2505845A1 DE 19752505845 DE19752505845 DE 19752505845 DE 2505845 A DE2505845 A DE 2505845A DE 2505845 A1 DE2505845 A1 DE 2505845A1
- Authority
- DE
- Germany
- Prior art keywords
- acid
- mother liquor
- cyanuric
- cyanuric acid
- chlorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000460 chlorine Substances 0.000 title claims description 29
- 229910052801 chlorine Inorganic materials 0.000 title claims description 25
- 238000000034 method Methods 0.000 title claims description 22
- 150000001875 compounds Chemical class 0.000 title description 9
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 title description 2
- 238000000605 extraction Methods 0.000 title description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 64
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 27
- 239000012452 mother liquor Substances 0.000 claims description 25
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 23
- 239000002253 acid Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 17
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 15
- 239000011707 mineral Substances 0.000 claims description 15
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 14
- 150000007973 cyanuric acids Chemical class 0.000 claims description 14
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 9
- 238000005660 chlorination reaction Methods 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- 239000012736 aqueous medium Substances 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 3
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims 1
- CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical class ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 description 21
- 235000010755 mineral Nutrition 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 238000011084 recovery Methods 0.000 description 11
- 239000000706 filtrate Substances 0.000 description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- -1 alkaline earth metal salts Chemical class 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 7
- 229950009390 symclosene Drugs 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000004677 hydrates Chemical class 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- IFIDXBCRSWOUSB-UHFFFAOYSA-M potassium;1,5-dichloro-4,6-dioxo-1,3,5-triazin-2-olate Chemical compound [K+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O IFIDXBCRSWOUSB-UHFFFAOYSA-M 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 239000012431 aqueous reaction media Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- XLJMAIOERFSOGZ-UHFFFAOYSA-N cyanic acid Chemical compound OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 description 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- ISAOUZVKYLHALD-UHFFFAOYSA-N 1-chloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)NC(=O)NC1=O ISAOUZVKYLHALD-UHFFFAOYSA-N 0.000 description 1
- KKADPXVIOXHVKN-UHFFFAOYSA-N 4-hydroxyphenylpyruvic acid Chemical compound OC(=O)C(=O)CC1=CC=C(O)C=C1 KKADPXVIOXHVKN-UHFFFAOYSA-N 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 159000000006 cesium salts Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001804 chlorine Chemical class 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000010413 mother solution Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000011027 product recovery Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/443,113 US3944548A (en) | 1974-02-15 | 1974-02-15 | Process for recovery of cyanuric acid from chlorinator mother liquor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2505845A1 true DE2505845A1 (de) | 1975-08-28 |
| DE2505845C2 DE2505845C2 (OSRAM) | 1987-06-04 |
Family
ID=23759451
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19752505845 Granted DE2505845A1 (de) | 1974-02-15 | 1975-02-12 | Verfahren zur gewinnung von cyanurverbindungen und chlor aus mutterlaugen |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3944548A (OSRAM) |
| JP (1) | JPS603074B2 (OSRAM) |
| BE (1) | BE825501A (OSRAM) |
| BR (1) | BR7500881A (OSRAM) |
| CA (1) | CA1023737A (OSRAM) |
| DE (1) | DE2505845A1 (OSRAM) |
| ES (1) | ES434721A1 (OSRAM) |
| FR (1) | FR2261277B1 (OSRAM) |
| GB (1) | GB1467195A (OSRAM) |
| IT (1) | IT1031723B (OSRAM) |
| NL (1) | NL180586C (OSRAM) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4138559A (en) * | 1978-01-30 | 1979-02-06 | Olin Corporation | Recovery of chlorine and cyanuric acid values from polychloroisocyanuric acids and salts thereof |
| BRPI0607180A2 (pt) * | 2005-02-14 | 2009-08-11 | Total Separation Solutions Llc | método de conservação de componentes de um fluido de poço de petróleo usado contendo componentes de fluido de poço de petróleo, método de conservação dos componentes de um fluido de poço de petróleo contendo componentes de fluido de poço de petróleo usado, método de processamento de um fluido de poço de petróleo usado e método de reconstituição de uma solução que contém césio |
| US7546874B2 (en) * | 2005-02-14 | 2009-06-16 | Total Separation Solutions, Llc | Conserving components of fluids |
| US7568523B2 (en) * | 2005-02-14 | 2009-08-04 | Total Separation Solutions, Llc | Treatment of cesium-containing fluids |
| CN102602892B (zh) * | 2012-04-11 | 2015-04-01 | 万华化学集团股份有限公司 | 通过氯化氢的催化氧化制备氯气的方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3107244A (en) * | 1963-10-15 | Production of cyanuric acid | ||
| US3296262A (en) * | 1965-03-08 | 1967-01-03 | Allied Chem | Purification of cyanuric acid |
| US3846424A (en) * | 1973-05-22 | 1974-11-05 | Olin Corp | Recovery of chlorine and cyanuric acid values from polychloroisocyanuric acid and salts thereof |
| US3835136A (en) * | 1973-05-22 | 1974-09-10 | Olin Corp | Recovery of chlorine and cyanuric acid values from polychloroisocyanuric acid and salts thereof |
-
1974
- 1974-02-15 US US05/443,113 patent/US3944548A/en not_active Expired - Lifetime
-
1975
- 1975-01-29 CA CA218,983A patent/CA1023737A/en not_active Expired
- 1975-02-06 JP JP50014943A patent/JPS603074B2/ja not_active Expired
- 1975-02-10 GB GB553175A patent/GB1467195A/en not_active Expired
- 1975-02-12 DE DE19752505845 patent/DE2505845A1/de active Granted
- 1975-02-13 NL NLAANVRAGE7501689,A patent/NL180586C/xx not_active IP Right Cessation
- 1975-02-13 BE BE153335A patent/BE825501A/xx not_active IP Right Cessation
- 1975-02-13 BR BR881/75A patent/BR7500881A/pt unknown
- 1975-02-13 IT IT20250/75A patent/IT1031723B/it active
- 1975-02-14 FR FR7504741A patent/FR2261277B1/fr not_active Expired
- 1975-02-14 ES ES434721A patent/ES434721A1/es not_active Expired
Non-Patent Citations (1)
| Title |
|---|
| Beilstein: Bd. 26, S. 256 * |
Also Published As
| Publication number | Publication date |
|---|---|
| BR7500881A (pt) | 1975-12-02 |
| IT1031723B (it) | 1979-05-10 |
| DE2505845C2 (OSRAM) | 1987-06-04 |
| FR2261277B1 (OSRAM) | 1979-03-16 |
| NL180586C (nl) | 1987-03-16 |
| CA1023737A (en) | 1978-01-03 |
| FR2261277A1 (OSRAM) | 1975-09-12 |
| AU7773975A (en) | 1976-08-05 |
| GB1467195A (en) | 1977-03-16 |
| JPS50112383A (OSRAM) | 1975-09-03 |
| BE825501A (fr) | 1975-08-13 |
| US3944548A (en) | 1976-03-16 |
| NL7501689A (nl) | 1975-08-19 |
| JPS603074B2 (ja) | 1985-01-25 |
| NL180586B (nl) | 1986-10-16 |
| ES434721A1 (es) | 1977-02-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8127 | New person/name/address of the applicant |
Owner name: OLIN CORP., STAMFORD, CONN., US |
|
| 8128 | New person/name/address of the agent |
Representative=s name: DANNENBERG, G., DIPL.-ING., 6000 FRANKFURT WEINHOL |
|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition |