DE2502006C3 - Abtrennung von Selen aus kupferhaltigen Lösungen - Google Patents
Abtrennung von Selen aus kupferhaltigen LösungenInfo
- Publication number
- DE2502006C3 DE2502006C3 DE2502006A DE2502006A DE2502006C3 DE 2502006 C3 DE2502006 C3 DE 2502006C3 DE 2502006 A DE2502006 A DE 2502006A DE 2502006 A DE2502006 A DE 2502006A DE 2502006 C3 DE2502006 C3 DE 2502006C3
- Authority
- DE
- Germany
- Prior art keywords
- copper
- solution
- selenium
- iron
- precipitated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010949 copper Substances 0.000 title claims description 76
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims description 52
- 229910052802 copper Inorganic materials 0.000 title claims description 51
- 239000011669 selenium Substances 0.000 title claims description 51
- 229910052711 selenium Inorganic materials 0.000 title claims description 38
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 title claims description 36
- 238000000926 separation method Methods 0.000 title description 4
- 239000000243 solution Substances 0.000 claims description 78
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 52
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 34
- 239000012535 impurity Substances 0.000 claims description 26
- 229910052742 iron Inorganic materials 0.000 claims description 24
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 20
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 17
- 239000002244 precipitate Substances 0.000 claims description 12
- 238000001556 precipitation Methods 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 8
- 239000002002 slurry Substances 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 239000003929 acidic solution Substances 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims description 3
- 238000005273 aeration Methods 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 2
- 238000004090 dissolution Methods 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 16
- 229910052785 arsenic Inorganic materials 0.000 description 12
- 229910052797 bismuth Inorganic materials 0.000 description 12
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 10
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 10
- 229910052759 nickel Inorganic materials 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910000570 Cupronickel Inorganic materials 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005363 electrowinning Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- YFLLTMUVNFGTIW-UHFFFAOYSA-N nickel;sulfanylidenecopper Chemical compound [Ni].[Cu]=S YFLLTMUVNFGTIW-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- YALHCTUQSQRCSX-UHFFFAOYSA-N sulfane sulfuric acid Chemical compound S.OS(O)(=O)=O YALHCTUQSQRCSX-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- -1 sulphate ions Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G3/00—Compounds of copper
- C01G3/10—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0065—Leaching or slurrying
- C22B15/0067—Leaching or slurrying with acids or salts thereof
- C22B15/0071—Leaching or slurrying with acids or salts thereof containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0084—Treating solutions
- C22B15/0089—Treating solutions by chemical methods
- C22B15/0093—Treating solutions by chemical methods by gases, e.g. hydrogen or hydrogen sulfide
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/12—Electrolytic production, recovery or refining of metals by electrolysis of solutions of copper
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US45904174 US3914375A (en) | 1974-04-08 | 1974-04-08 | Method of removing selenium from copper solution |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2502006A1 DE2502006A1 (de) | 1975-10-09 |
| DE2502006B2 DE2502006B2 (de) | 1977-08-18 |
| DE2502006C3 true DE2502006C3 (de) | 1978-04-20 |
Family
ID=23823158
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2502006A Expired DE2502006C3 (de) | 1974-04-08 | 1975-01-20 | Abtrennung von Selen aus kupferhaltigen Lösungen |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3914375A (cg-RX-API-DMAC7.html) |
| JP (2) | JPS5522536B2 (cg-RX-API-DMAC7.html) |
| CA (1) | CA1024351A (cg-RX-API-DMAC7.html) |
| CU (1) | CU34174A (cg-RX-API-DMAC7.html) |
| DE (1) | DE2502006C3 (cg-RX-API-DMAC7.html) |
| FR (1) | FR2266755B1 (cg-RX-API-DMAC7.html) |
| ZA (1) | ZA748147B (cg-RX-API-DMAC7.html) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4026797A (en) * | 1976-04-19 | 1977-05-31 | Amax Inc. | Precipitation of selenium from copper electrowinning solutions |
| US4076605A (en) * | 1976-08-26 | 1978-02-28 | Inspiration Consolidated Copper Company | Dichromate leach of copper anode slimes |
| CA1089188A (en) * | 1977-08-19 | 1980-11-11 | Donald R. Weir | Purification of copper sulfate solution |
| US4214900A (en) * | 1979-08-08 | 1980-07-29 | Amax Inc. | Production of nonferrous metals with low selenium contents |
| CA1139258A (en) * | 1980-08-19 | 1983-01-11 | Donald R. Weir | Removal of selenium from acidic copper sulphate solutions |
| CA1154599A (en) * | 1980-09-30 | 1983-10-04 | John A. Thomas | Hydrometallurgical processing of precious metal-containing materials |
| JPS5786933U (cg-RX-API-DMAC7.html) * | 1980-11-07 | 1982-05-28 | ||
| CA1146723A (en) * | 1981-10-30 | 1983-05-24 | Donald R. Weir | Removal of selenium from acidic copper/nickel solutions |
| US4377556A (en) * | 1982-04-09 | 1983-03-22 | Sherritt Gordon Mines Limited | Process for removing dissolved selenium values from an acidic aqueous copper sulphate solution |
| US4792405A (en) * | 1987-05-08 | 1988-12-20 | Shell Oil Company | Removal of hydrogen selenide liquids |
| US4790945A (en) * | 1987-05-08 | 1988-12-13 | Shell Oil Company | Removal of hydrogen selenide |
| US4935146A (en) * | 1988-11-15 | 1990-06-19 | Aluminum Company Of America | Method for removing arsenic or selenium from an aqueous solution containing a substantial background of another contaminant |
| US7144362B2 (en) * | 2004-10-29 | 2006-12-05 | Heritage Environmental Servicers, Llc | Method for chemically stabilizing waste materials containing multivalent oxyanions |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1598296A (en) * | 1924-05-29 | 1926-08-31 | Mackay Henry Squarebrigs | Electrochemical treatment of copper ores |
| US3026175A (en) * | 1958-09-22 | 1962-03-20 | Monsanto Chemicals | Method for the preparation of tellurides and selenides |
-
1974
- 1974-04-08 US US45904174 patent/US3914375A/en not_active Expired - Lifetime
- 1974-11-05 CA CA212,971A patent/CA1024351A/en not_active Expired
- 1974-12-16 CU CU34174A patent/CU34174A/es unknown
- 1974-12-20 ZA ZA00748147A patent/ZA748147B/xx unknown
-
1975
- 1975-01-20 DE DE2502006A patent/DE2502006C3/de not_active Expired
- 1975-03-06 FR FR7506976A patent/FR2266755B1/fr not_active Expired
- 1975-04-08 JP JP4194275A patent/JPS5522536B2/ja not_active Expired
-
1979
- 1979-05-17 JP JP5979079A patent/JPS54151506A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE2502006B2 (de) | 1977-08-18 |
| ZA748147B (en) | 1976-01-28 |
| JPS5522536B2 (cg-RX-API-DMAC7.html) | 1980-06-17 |
| CU34174A (es) | 1980-10-30 |
| JPS50136224A (cg-RX-API-DMAC7.html) | 1975-10-29 |
| FR2266755B1 (cg-RX-API-DMAC7.html) | 1977-04-15 |
| JPS54151506A (en) | 1979-11-28 |
| CA1024351A (en) | 1978-01-17 |
| DE2502006A1 (de) | 1975-10-09 |
| FR2266755A1 (cg-RX-API-DMAC7.html) | 1975-10-31 |
| AU7693874A (en) | 1976-07-01 |
| US3914375A (en) | 1975-10-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |