DE2424091C3 - Verfahren zur anodischen Oxidation organischer Belastungsstoffe im Wasser in einer Wirbelschicht aus leitfähigem Adsorbens - Google Patents
Verfahren zur anodischen Oxidation organischer Belastungsstoffe im Wasser in einer Wirbelschicht aus leitfähigem AdsorbensInfo
- Publication number
- DE2424091C3 DE2424091C3 DE2424091A DE2424091A DE2424091C3 DE 2424091 C3 DE2424091 C3 DE 2424091C3 DE 2424091 A DE2424091 A DE 2424091A DE 2424091 A DE2424091 A DE 2424091A DE 2424091 C3 DE2424091 C3 DE 2424091C3
- Authority
- DE
- Germany
- Prior art keywords
- anodic oxidation
- water
- adsorbent
- anode
- organic pollutants
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000003647 oxidation Effects 0.000 title claims description 21
- 238000007254 oxidation reaction Methods 0.000 title claims description 21
- 238000000034 method Methods 0.000 title claims description 15
- 239000003463 adsorbent Substances 0.000 title claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 11
- 239000002957 persistent organic pollutant Substances 0.000 title claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
- 239000013590 bulk material Substances 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 239000008187 granular material Substances 0.000 claims description 7
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 claims description 3
- 239000003830 anthracite Substances 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims 1
- 239000003245 coal Substances 0.000 claims 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 15
- 238000012360 testing method Methods 0.000 description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
- 239000000126 substance Substances 0.000 description 6
- 235000006408 oxalic acid Nutrition 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000003673 groundwater Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 230000003389 potentiating effect Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229920005372 Plexiglas® Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000011231 conductive filler Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- JLYXXMFPNIAWKQ-GNIYUCBRSA-N gamma-hexachlorocyclohexane Chemical compound Cl[C@H]1[C@H](Cl)[C@@H](Cl)[C@@H](Cl)[C@H](Cl)[C@H]1Cl JLYXXMFPNIAWKQ-GNIYUCBRSA-N 0.000 description 1
- JLYXXMFPNIAWKQ-UHFFFAOYSA-N gamma-hexachlorocyclohexane Natural products ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 description 1
- 229960002809 lindane Drugs 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- LCCNCVORNKJIRZ-UHFFFAOYSA-N parathion Chemical compound CCOP(=S)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 LCCNCVORNKJIRZ-UHFFFAOYSA-N 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 238000005029 sieve analysis Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F1/46114—Electrodes in particulate form or with conductive and/or non conductive particles between them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
- C02F1/4672—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Water Treatment By Sorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2424091A DE2424091C3 (de) | 1974-05-17 | 1974-05-17 | Verfahren zur anodischen Oxidation organischer Belastungsstoffe im Wasser in einer Wirbelschicht aus leitfähigem Adsorbens |
| US05/577,044 US4013554A (en) | 1974-05-17 | 1975-05-13 | Method and apparatus for purifying water contaminated with anodically oxidizable organic matter |
| IT68279/75A IT1032918B (it) | 1974-05-17 | 1975-05-16 | Procedimento e dispositivo per ossidazione anodica di cariche organiche in acqua particolarmente per la depurazione elle acque |
| FR7516249A FR2271177A1 (enExample) | 1974-05-17 | 1975-05-16 | |
| GB2088175A GB1476587A (en) | 1974-05-17 | 1975-05-16 | Method and apparatus for anodic oxidation of organic contaminants in water |
| JP50059176A JPS50158572A (enExample) | 1974-05-17 | 1975-05-17 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2424091A DE2424091C3 (de) | 1974-05-17 | 1974-05-17 | Verfahren zur anodischen Oxidation organischer Belastungsstoffe im Wasser in einer Wirbelschicht aus leitfähigem Adsorbens |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2424091A1 DE2424091A1 (de) | 1975-12-04 |
| DE2424091B2 DE2424091B2 (de) | 1980-04-10 |
| DE2424091C3 true DE2424091C3 (de) | 1980-11-27 |
Family
ID=5915858
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2424091A Expired DE2424091C3 (de) | 1974-05-17 | 1974-05-17 | Verfahren zur anodischen Oxidation organischer Belastungsstoffe im Wasser in einer Wirbelschicht aus leitfähigem Adsorbens |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4013554A (enExample) |
| JP (1) | JPS50158572A (enExample) |
| DE (1) | DE2424091C3 (enExample) |
| FR (1) | FR2271177A1 (enExample) |
| GB (1) | GB1476587A (enExample) |
| IT (1) | IT1032918B (enExample) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL180742C (nl) * | 1976-03-04 | 1987-04-16 | Westinghouse Electric Corp | Werkwijze en inrichting voor het zuiveren van afvalwater. |
| DE2741317C3 (de) * | 1977-09-14 | 1980-04-24 | Institut Fuer Biomedizinische Technik, 8000 Muenchen | Verfahren zur Entkeimung von elektrisch nicht leitenden Flüssigkeiten in Verbindung mit der anodischen Oxidation |
| US4130483A (en) * | 1977-10-14 | 1978-12-19 | Nuclear Supreme | Sewage treating and conversion process |
| US4260463A (en) * | 1979-09-20 | 1981-04-07 | Ppg Industries, Inc. | Removal of organic contaminants from waste water |
| DE3023703A1 (de) * | 1980-06-25 | 1982-01-21 | Kernforschungsanlage Jülich GmbH, 5170 Jülich | Verfahren zur oxidation oder reduktion von stoffen in waessriger loesung an einem katalysator, der elektrochemisch wirksam und auf poroesem traegermaterial aufgebracht ist, sowie traegerkoerper fuer den katalysator und verfahren zur herstellung eines den katalysator enthaltenden beschichtungsmaterials fuer den traegerkoerper |
| EP0063236B1 (de) * | 1981-04-14 | 1985-06-19 | DORNIER SYSTEM GmbH | Vorrichtung zur Spülwasserbehandlung mittels Ionenaustauscher |
| DE3221306C2 (de) * | 1982-06-05 | 1986-01-09 | Kernforschungsanlage Jülich GmbH, 5170 Jülich | Verfahren zur Reduktion oder Oxidation von reduzierbaren oder oxidierbaren Stoffen in wässriger Lösung |
| US4601808A (en) * | 1984-05-16 | 1986-07-22 | Hanns-Heinz Eumann | Apparatus for desalting water by electrodialysis |
| US4569739A (en) * | 1984-12-31 | 1986-02-11 | Dorr-Oliver Incorporated | Electrofilter using an improved electrode assembly |
| JPS61270752A (ja) * | 1985-05-25 | 1986-12-01 | Konishiroku Photo Ind Co Ltd | 写真処理液の脱銀方法及び写真処理機 |
| JPS61270754A (ja) * | 1985-05-25 | 1986-12-01 | Konishiroku Photo Ind Co Ltd | 写真処理液の脱銀方法及び写真処理機 |
| JPS6223407A (ja) * | 1985-06-17 | 1987-01-31 | Fujimasa Kiko Kk | 流体中の微小不純物除去方法 |
| US5364527A (en) * | 1990-06-20 | 1994-11-15 | Heinz Zimmermann | Apparatus and process for treating water |
| EP0462523B1 (de) * | 1990-06-20 | 1994-08-31 | Heinz Zimmermann | Vorrichtung und Verfahren zum Aufbereiten von Wasser |
| DE4119606A1 (de) * | 1991-06-14 | 1992-12-17 | Sigri Great Lakes Carbon Gmbh | Verfahren und vorrichtung zur aufarbeitung von salzsaeurehaltigem, mit begleitstoffen verunreinigtem wasser |
| NL9200989A (nl) * | 1992-06-04 | 1994-01-03 | Eco Purification Syst | Werkwijze en inrichting voor het zuiveren van stromen. |
| JPH07106283B2 (ja) * | 1993-10-07 | 1995-11-15 | 有限会社ゼオテック | 荷電コアレッサー型油水分離装置 |
| US6024850A (en) | 1993-10-27 | 2000-02-15 | Halox Technologies Corporation | Modified ion exchange materials |
| US5419816A (en) * | 1993-10-27 | 1995-05-30 | Halox Technologies Corporation | Electrolytic process and apparatus for the controlled oxidation of inorganic and organic species in aqueous solutions |
| US6402916B1 (en) | 1993-10-27 | 2002-06-11 | Richard L. Sampson | Electrolytic process and apparatus controlled regeneration of modified ion exchangers to purify aqueous solutions and adjust ph |
| US5705050A (en) * | 1996-04-29 | 1998-01-06 | Sampson; Richard L. | Electrolytic process and apparatus for the controlled oxidation and reduction of inorganic and organic species in aqueous solutions |
| JPH10314724A (ja) * | 1997-05-15 | 1998-12-02 | Sanden Corp | 飲料供給装置 |
| US5990684A (en) * | 1997-12-02 | 1999-11-23 | Merrill; John H. | Method and apparatus for continuously monitoring an aqueous flow to detect and quantify ions |
| WO2003027029A1 (en) * | 2001-09-19 | 2003-04-03 | Fluid Dynamics International Ltd. | Method and apparatus for the destruction of dyes and other organic molecules |
| US7050146B2 (en) | 2004-02-09 | 2006-05-23 | Asml Netherlands B.V. | Lithographic apparatus and device manufacturing method |
| DE102006007773B4 (de) * | 2006-02-20 | 2010-02-11 | Walter Dr. Kothe | Anordnung zum Spalten von Wasser |
| GB2470042B (en) * | 2009-05-06 | 2011-10-19 | Arvia Technology Ltd | Treatment of contaminated liquids |
| EP2446908B1 (en) * | 2010-11-02 | 2015-07-15 | ICinnovation BV | Electrosorption and decomposition device for the purification of blood and other fluids |
| GB2495701A (en) * | 2011-10-11 | 2013-04-24 | Arvia Technology Ltd | Treating liquid with adsorbent |
| GB2588211B (en) * | 2019-10-16 | 2024-11-27 | Arvia Tech Limited | Water treatment unit |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US673452A (en) * | 1892-01-21 | 1901-05-07 | Roberts Chemical Company | Electrolytic apparatus. |
| US3716459A (en) * | 1969-10-16 | 1973-02-13 | Brown John Constr | Electrochemical processes |
| US3730885A (en) * | 1971-01-21 | 1973-05-01 | Tvco Lab Inc | Electrochemical control of adsorption and desorption with activated carbon |
| JPS5338712B2 (enExample) * | 1971-12-23 | 1978-10-17 |
-
1974
- 1974-05-17 DE DE2424091A patent/DE2424091C3/de not_active Expired
-
1975
- 1975-05-13 US US05/577,044 patent/US4013554A/en not_active Expired - Lifetime
- 1975-05-16 IT IT68279/75A patent/IT1032918B/it active
- 1975-05-16 GB GB2088175A patent/GB1476587A/en not_active Expired
- 1975-05-16 FR FR7516249A patent/FR2271177A1/fr not_active Withdrawn
- 1975-05-17 JP JP50059176A patent/JPS50158572A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| IT1032918B (it) | 1979-06-20 |
| DE2424091A1 (de) | 1975-12-04 |
| DE2424091B2 (de) | 1980-04-10 |
| JPS50158572A (enExample) | 1975-12-22 |
| FR2271177A1 (enExample) | 1975-12-12 |
| US4013554A (en) | 1977-03-22 |
| GB1476587A (en) | 1977-06-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |