DE2356914A1 - Sekundaerbatterie - Google Patents
SekundaerbatterieInfo
- Publication number
- DE2356914A1 DE2356914A1 DE2356914A DE2356914A DE2356914A1 DE 2356914 A1 DE2356914 A1 DE 2356914A1 DE 2356914 A DE2356914 A DE 2356914A DE 2356914 A DE2356914 A DE 2356914A DE 2356914 A1 DE2356914 A1 DE 2356914A1
- Authority
- DE
- Germany
- Prior art keywords
- zinc
- bromide
- battery
- cathode
- electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003792 electrolyte Substances 0.000 claims description 41
- VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 claims description 41
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 29
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 28
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 25
- 229910052794 bromium Inorganic materials 0.000 claims description 25
- 229940102001 zinc bromide Drugs 0.000 claims description 20
- 229940006460 bromide ion Drugs 0.000 claims description 19
- 150000003751 zinc Chemical class 0.000 claims description 18
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 14
- 239000011701 zinc Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 8
- 229910052725 zinc Inorganic materials 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 230000008021 deposition Effects 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- 150000001450 anions Chemical class 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 6
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 5
- 229960001763 zinc sulfate Drugs 0.000 claims description 5
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 5
- 230000007423 decrease Effects 0.000 claims description 4
- 239000008151 electrolyte solution Substances 0.000 claims description 4
- 239000011592 zinc chloride Substances 0.000 claims description 3
- 235000005074 zinc chloride Nutrition 0.000 claims description 3
- 230000001590 oxidative effect Effects 0.000 claims 1
- 239000010410 layer Substances 0.000 description 33
- 239000002245 particle Substances 0.000 description 9
- 238000002474 experimental method Methods 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 238000010276 construction Methods 0.000 description 7
- 239000003463 adsorbent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 239000002516 radical scavenger Substances 0.000 description 4
- 239000002344 surface layer Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- DTQVDTLACAAQTR-UHFFFAOYSA-M Trifluoroacetate Chemical compound [O-]C(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-M 0.000 description 3
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000004246 zinc acetate Substances 0.000 description 3
- -1 zinc tetrafluoroborate Chemical compound 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 229910001509 metal bromide Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- 241001111321 Borismene Species 0.000 description 1
- 229920006370 Kynar Polymers 0.000 description 1
- 206010035148 Plague Diseases 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- QRXWMOHMRWLFEY-UHFFFAOYSA-N isoniazide Chemical compound NNC(=O)C1=CC=NC=C1 QRXWMOHMRWLFEY-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- RGCLLPNLLBQHPF-HJWRWDBZSA-N phosphamidon Chemical compound CCN(CC)C(=O)C(\Cl)=C(/C)OP(=O)(OC)OC RGCLLPNLLBQHPF-HJWRWDBZSA-N 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- WGIWBXUNRXCYRA-UHFFFAOYSA-H trizinc;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WGIWBXUNRXCYRA-UHFFFAOYSA-H 0.000 description 1
- 239000011746 zinc citrate Substances 0.000 description 1
- 235000006076 zinc citrate Nutrition 0.000 description 1
- 229940068475 zinc citrate Drugs 0.000 description 1
- VCQWRGCXUWPSGY-UHFFFAOYSA-L zinc;2,2,2-trifluoroacetate Chemical compound [Zn+2].[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F VCQWRGCXUWPSGY-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/365—Zinc-halogen accumulators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Hybrid Cells (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US00306211A US3806368A (en) | 1972-11-14 | 1972-11-14 | Zinc bromide battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2356914A1 true DE2356914A1 (de) | 1974-05-16 |
Family
ID=23184314
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2356914A Pending DE2356914A1 (de) | 1972-11-14 | 1973-11-14 | Sekundaerbatterie |
Country Status (7)
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4113924A (en) * | 1977-05-26 | 1978-09-12 | Exxon Research & Engineering Co. | Zinc-halogen compound electrochemical cell having an auxiliary electrode and method |
| US4251568A (en) * | 1979-08-27 | 1981-02-17 | Energy Development Associates, Inc. | Method of storing electrical energy |
| US4312931A (en) * | 1980-09-02 | 1982-01-26 | General Motors Corporation | Zinc electrode containing porous calcium silicate |
| US4482614A (en) * | 1982-11-15 | 1984-11-13 | Gel, Inc. | Zinc-bromine battery with long term stability |
| US4491625A (en) * | 1984-03-26 | 1985-01-01 | Exxon Research & Engineering Co. | Zinc-bromine batteries with improved electrolyte |
| US4748095A (en) * | 1987-03-06 | 1988-05-31 | Nagakazu Furuya | Halogen cell |
| JPS6412473A (en) * | 1987-07-03 | 1989-01-17 | Toyota Motor Corp | Zinc-bromine battery |
| US4948681A (en) * | 1988-05-02 | 1990-08-14 | Globe-Union Inc. | Terminal electrode |
| IL108252A0 (en) * | 1993-12-28 | 1994-04-12 | Yeda Res & Dev | Rechargeable zinc halide electrochemical cell |
| US5591538A (en) * | 1995-07-07 | 1997-01-07 | Zbb Technologies, Inc. | Zinc-bromine battery with non-flowing electrolyte |
| RU2400871C1 (ru) * | 2009-10-12 | 2010-09-27 | Государственное образовательное учреждение высшего профессионального образования Самарский государственный аэрокосмический университет имени академика С.П. Королева (СГАУ) | Бромно-цинковый аккумулятор с непроточным электролитом |
| AU2011201241B2 (en) * | 2010-03-22 | 2014-09-18 | Bromine Compounds Ltd. | A method of operating metal-bromine cells |
| WO2016040810A2 (en) * | 2014-09-11 | 2016-03-17 | Case Western Reserve University | Bromide removal from aqueous solutions |
| CA2963078C (en) | 2014-10-06 | 2022-03-22 | Eos Energy Storage, Llc | Electolyte composition for a zinc-halide battery and bipolar electrode comprising a titanium carbide coated cathode box |
| WO2017132348A1 (en) | 2016-01-27 | 2017-08-03 | Ensync, Inc. | Improved electrolyte system for rechargeable flow battery |
| ES2997364T3 (en) | 2016-03-29 | 2025-02-17 | Eos Energy Tech Holdings Llc | Electrolyte for rechargeable electrochemical cell |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB320916A (en) * | 1928-04-27 | 1929-10-28 | Leonard Angelo Levy | Improvements in and relating to secondary electric cells |
| BE364349A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1928-11-05 |
-
1972
- 1972-11-14 US US00306211A patent/US3806368A/en not_active Expired - Lifetime
-
1973
- 1973-10-26 AU AU61892/73A patent/AU6189273A/en not_active Expired
- 1973-10-29 JP JP48120837A patent/JPS4974342A/ja active Pending
- 1973-11-07 GB GB5170673A patent/GB1425358A/en not_active Expired
- 1973-11-13 CA CA185,637A patent/CA995301A/en not_active Expired
- 1973-11-14 DE DE2356914A patent/DE2356914A1/de active Pending
- 1973-11-14 FR FR7340457A patent/FR2206595B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2206595A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1974-06-07 |
| US3806368A (en) | 1974-04-23 |
| JPS4974342A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1974-07-18 |
| AU6189273A (en) | 1975-05-01 |
| GB1425358A (en) | 1976-02-18 |
| FR2206595B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1978-12-01 |
| CA995301A (en) | 1976-08-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OHJ | Non-payment of the annual fee |