DE2313068A1 - Verfahren zur herstellung von acrylnitril - Google Patents
Verfahren zur herstellung von acrylnitrilInfo
- Publication number
- DE2313068A1 DE2313068A1 DE2313068A DE2313068A DE2313068A1 DE 2313068 A1 DE2313068 A1 DE 2313068A1 DE 2313068 A DE2313068 A DE 2313068A DE 2313068 A DE2313068 A DE 2313068A DE 2313068 A1 DE2313068 A1 DE 2313068A1
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- dar
- bia
- antimony
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000000034 method Methods 0.000 title claims description 8
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 150000002825 nitriles Chemical class 0.000 title 1
- 239000003054 catalyst Substances 0.000 claims description 19
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 11
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 239000010949 copper Substances 0.000 claims description 8
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 7
- 229910052787 antimony Inorganic materials 0.000 claims description 6
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 6
- 229910021529 ammonia Inorganic materials 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- 229910001882 dioxygen Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 229910052790 beryllium Inorganic materials 0.000 claims description 2
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- QRDZSRWEULKVNW-UHFFFAOYSA-N 6-hydroxy-2-oxo-1h-quinoline-4-carboxylic acid Chemical compound C1=C(O)C=C2C(C(=O)O)=CC(=O)NC2=C1 QRDZSRWEULKVNW-UHFFFAOYSA-N 0.000 claims 1
- 229910052788 barium Inorganic materials 0.000 claims 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 201000002266 mite infestation Diseases 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 229910052760 oxygen Inorganic materials 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- -1 copper Chemical class 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 238000004508 fractional distillation Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 101100072702 Drosophila melanogaster defl gene Proteins 0.000 description 1
- 241001026509 Kata Species 0.000 description 1
- 101100332755 Mus musculus Edar gene Proteins 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 101100332756 Oryzias latipes edar gene Proteins 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- ZINJLDJMHCUBIP-UHFFFAOYSA-N ethametsulfuron-methyl Chemical compound CCOC1=NC(NC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(=O)OC)=N1 ZINJLDJMHCUBIP-UHFFFAOYSA-N 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000012258 stirred mixture Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- ZZIZZTHXZRDOFM-XFULWGLBSA-N tamsulosin hydrochloride Chemical compound [H+].[Cl-].CCOC1=CC=CC=C1OCCN[C@H](C)CC1=CC=C(OC)C(S(N)(=O)=O)=C1 ZZIZZTHXZRDOFM-XFULWGLBSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
- 229940007718 zinc hydroxide Drugs 0.000 description 1
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/18—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/843—Arsenic, antimony or bismuth
- B01J23/8435—Antimony
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1260772A GB1364587A (en) | 1972-03-17 | 1972-03-17 | Catalyst composition |
| GB4596072 | 1972-10-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2313068A1 true DE2313068A1 (de) | 1973-09-27 |
Family
ID=26249134
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2313068A Ceased DE2313068A1 (de) | 1972-03-17 | 1973-03-16 | Verfahren zur herstellung von acrylnitril |
| DE2313065A Withdrawn DE2313065A1 (de) | 1972-03-17 | 1973-03-16 | Verfahren zur herstellung von acrylnitril |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2313065A Withdrawn DE2313065A1 (de) | 1972-03-17 | 1973-03-16 | Verfahren zur herstellung von acrylnitril |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US3914278A (enExample) |
| JP (1) | JPS5747181B2 (enExample) |
| BE (2) | BE796922A (enExample) |
| CA (2) | CA973203A (enExample) |
| DE (2) | DE2313068A1 (enExample) |
| FR (2) | FR2176770B1 (enExample) |
| GB (1) | GB1364587A (enExample) |
| IT (1) | IT981475B (enExample) |
| NL (2) | NL7303627A (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2265732B1 (enExample) * | 1974-03-28 | 1978-07-28 | Ugine Kuhlmann | |
| FR2265730B1 (enExample) * | 1974-03-28 | 1978-12-01 | Ugine Kuhlmann | |
| US4115434A (en) * | 1976-06-04 | 1978-09-19 | Produits Chimiques Ugine Kuhlmann | Catalysts and processes for preparing unsaturated nitriles |
| US4309361A (en) * | 1977-12-20 | 1982-01-05 | Standard Oil Company | Ammoxidation of olefins with novel antimonate catalysts |
| US4565658A (en) * | 1979-12-17 | 1986-01-21 | Monsanto Company | Oxidation and ammoxidation process |
| US4316855A (en) * | 1979-12-28 | 1982-02-23 | The Standard Oil Co. | Multiply promoted Sn-Sb oxide catalysts |
| US4339394A (en) * | 1980-10-01 | 1982-07-13 | The Standard Oil Co. | Process of ammoxidation of olefins in the presence of multiply promoted Sn-Sb oxide catalysts |
| US4532083A (en) * | 1982-10-29 | 1985-07-30 | The Standard Oil Company | Multiply promoted Sn/Sb oxide catalysts |
| JPH0696034B2 (ja) * | 1991-09-25 | 1994-11-30 | 川澄化学工業株式会社 | 医療容器の高圧蒸気滅菌方法 |
| US5854172A (en) * | 1997-01-17 | 1998-12-29 | The Standard Oil Company | Preparation of vanadium antimonate based catalysts using SnO2 ·xH2 O |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL275292A (enExample) * | 1960-04-26 | |||
| US3338952A (en) * | 1965-11-15 | 1967-08-29 | Standard Oil Co | Process for the catalytic ammoxidation of olefins to nitriles |
| US3431292A (en) * | 1966-12-23 | 1969-03-04 | Standard Oil Co | Olefinic nitriles by ammoxidation of olefins with promoted antimony oxideuranium oxide catalyst |
| IT829026A (enExample) * | 1967-04-18 | |||
| US3625867A (en) * | 1967-06-02 | 1971-12-07 | Takachika Yoshino | Process for production of metal oxide-antimony oxide catalysts |
| US3636066A (en) * | 1969-03-05 | 1972-01-18 | Ube Industries | Process for the manufacture of acrylonitrile by ammoxidation |
-
1972
- 1972-03-17 GB GB1260772A patent/GB1364587A/en not_active Expired
-
1973
- 1973-03-09 CA CA165,742A patent/CA973203A/en not_active Expired
- 1973-03-12 US US339998A patent/US3914278A/en not_active Expired - Lifetime
- 1973-03-12 US US00339999A patent/US3847965A/en not_active Expired - Lifetime
- 1973-03-15 NL NL7303627A patent/NL7303627A/xx not_active Application Discontinuation
- 1973-03-15 NL NL7303628A patent/NL7303628A/xx not_active Application Discontinuation
- 1973-03-16 DE DE2313068A patent/DE2313068A1/de not_active Ceased
- 1973-03-16 DE DE2313065A patent/DE2313065A1/de not_active Withdrawn
- 1973-03-16 BE BE128923A patent/BE796922A/xx not_active IP Right Cessation
- 1973-03-16 JP JP48030799A patent/JPS5747181B2/ja not_active Expired
- 1973-03-16 CA CA166,231A patent/CA1008882A/en not_active Expired
- 1973-03-16 IT IT21798/73A patent/IT981475B/it active
- 1973-03-16 FR FR7309442A patent/FR2176770B1/fr not_active Expired
- 1973-03-16 FR FR7309443A patent/FR2176771B1/fr not_active Expired
- 1973-03-16 BE BE128922A patent/BE796921A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CA1008882A (en) | 1977-04-19 |
| JPS4911830A (enExample) | 1974-02-01 |
| DE2313065A1 (de) | 1973-09-27 |
| BE796922A (fr) | 1973-09-17 |
| NL7303627A (enExample) | 1973-09-19 |
| IT981475B (it) | 1974-10-10 |
| FR2176771B1 (enExample) | 1977-02-04 |
| US3847965A (en) | 1974-11-12 |
| US3914278A (en) | 1975-10-21 |
| CA973203A (en) | 1975-08-19 |
| JPS5747181B2 (enExample) | 1982-10-07 |
| GB1364587A (en) | 1974-08-21 |
| BE796921A (fr) | 1973-09-17 |
| FR2176770B1 (enExample) | 1977-02-04 |
| NL7303628A (enExample) | 1973-09-19 |
| FR2176770A1 (enExample) | 1973-11-02 |
| FR2176771A1 (enExample) | 1973-11-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OGA | New person/name/address of the applicant | ||
| OD | Request for examination | ||
| 8131 | Rejection |